Ionic Liquid Bulk And Interface Properties

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Ionic Liquid Bulk and Interface Properties

Author : Till Cremer
Publisher : Springer Science & Business Media
ISBN 13 : 3319003801
Total Pages : 179 pages
Book Rating : 4.3/5 (19 download)

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Book Synopsis Ionic Liquid Bulk and Interface Properties by : Till Cremer

Download or read book Ionic Liquid Bulk and Interface Properties written by Till Cremer and published by Springer Science & Business Media. This book was released on 2013-06-17 with total page 179 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this thesis, Till Cremer investigates the bulk properties of ionic liquids (IL), the IL/vacuum interface and the IL/solid interface. For these studies the author primarily uses angle-resolved X-ray photoelectron spectroscopy under ultrahigh vacuum conditions. ILs represent a class of materials with unique physico-chemical properties. Many applications take advantage of the extremely low vapor pressure of aprotic ILs to fabricate permanent, non-volatile liquid coatings on solid materials. The author focuses on issues related to thin IL coatings, in particular concerning new catalytic concepts such as the supported ionic liquid phase (SILP) and solid catalyst with ionic liquid layer (SCILL) systems. Till Cremer presents a number of fundamental contributions to the new field of "Ionic Liquid Surface and Interface Science". Highlights are his results concerning anion/cation-interactions and the growth of ultrathin layers of ionic liquids on various substrates in the context of supported ionic liquid catalysis. His results have significantly contributed to the present level of understanding in the field and accordingly he is author and coauthor of ten publications on the topic in high-ranked journals.

Ionic Liquids UnCOILed

Author : Kenneth R. Seddon
Publisher : John Wiley & Sons
ISBN 13 : 1118435001
Total Pages : 348 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Ionic Liquids UnCOILed by : Kenneth R. Seddon

Download or read book Ionic Liquids UnCOILed written by Kenneth R. Seddon and published by John Wiley & Sons. This book was released on 2012-10-26 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic Liquids UnCOILed presents decisively important reviews on new processes and recent developments in ionic liquid technology with an emphasis on commercial applications in which ionic liquids are replacing, or may replace, processes currently using conventional solvents. Ranging from applied to theoretical, synthetic to analytical, and biotechnological to electrochemical, the book features eleven chapters written by an international group of key academic and industrial chemists, exercising the judicious evaluation which they are uniquely qualified to do. This book is a must for R&D chemists in industrial, governmental and academic laboratories, and for commercial developers of environmentally-friendly, sustainable processes.

Ionic Liquids: Properties and Applications

Author : Francesca D’Anna
Publisher : Frontiers Media SA
ISBN 13 : 2889630056
Total Pages : 360 pages
Book Rating : 4.8/5 (896 download)

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Book Synopsis Ionic Liquids: Properties and Applications by : Francesca D’Anna

Download or read book Ionic Liquids: Properties and Applications written by Francesca D’Anna and published by Frontiers Media SA. This book was released on 2019-10-17 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sustainability, defined as the way to meet the needs of the present generation without compromising the ability of future ones to meet their own, is one of the main challenges of modern society. Within this context, chemistry plays a significant role, and solvent nature as well as its environmental impact are pivotal issues frequently addressed. Ionic liquids, i.e. organic salts that have melting temperatures lower than 100 °C, have been frequently hailed as alternatives to conventional organic solvents. Their greenness has been mainly ascribed to their low vapor pressure and flammability. However, in addition to this, their high solubilizing ability and low miscibility with conventional organic solvents frequently allow for reducing the amount used, as well as for their recycling. Ionic liquids, especially the ones featured by aromatic cations, are frequently described as “polymeric supramolecular fluids” constructed through the establishment of feeble but cooperative supramolecular interactions like Coulomb and π-π interactions, as well as hydrogen bonds. In general, ionic liquids are also indicated as “designer solvents” as it is possible to tailor their features to specific applications by simply modifying their cation or anion structure. In this way, small changes in the ion’s structure can give rise to solvents showing very different properties. The above premises widely justify the growing interest in the properties and applications of ionic liquids, seen in recent literature (according to Scopus, more than 27,000 papers published in the last five years have “ionic liquids” as a keyword). Thanks to their properties, they have been variously used as solvent media, solvents for the obtainment of gel phases, components in the building of dye-sensitized solar cells, media for the preparation of thermochromic materials, etc. This Research Topic aims to present how structural features can determine not only the properties of ionic liquids, but also their possible employment. In this latter case, the interest arises from their ability to affect the outcome of a given reaction in terms of rate, yield, and nature of the products obtained for general use in the field of materials chemistry. This article collection is dedicated to Prof. Kenneth R. Seddon for his outstanding contribution to the formation and development of the ionic liquids community.

Electrochemistry in Ionic Liquids

Author : Angel A. J. Torriero
Publisher : Springer
ISBN 13 : 331913485X
Total Pages : 358 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Electrochemistry in Ionic Liquids by : Angel A. J. Torriero

Download or read book Electrochemistry in Ionic Liquids written by Angel A. J. Torriero and published by Springer. This book was released on 2015-07-17 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: This set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books: The first volume critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed The second volumes major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.

Ionic Liquids

Author : Alexander Kokorin
Publisher : BoD – Books on Demand
ISBN 13 : 9533073497
Total Pages : 752 pages
Book Rating : 4.5/5 (33 download)

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Book Synopsis Ionic Liquids by : Alexander Kokorin

Download or read book Ionic Liquids written by Alexander Kokorin and published by BoD – Books on Demand. This book was released on 2011-02-28 with total page 752 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic Liquids (ILs) are one of the most interesting and rapidly developing areas of modern physical chemistry, technologies and engineering. This book, consisting of 29 chapters gathered in 4 sections, reviews in detail and compiles information about some important physical-chemical properties of ILs and new practical approaches. This is the first book of a series of forthcoming publications on this field by this publisher. The first volume covers some aspects of synthesis, isolation, production, modification, the analysis methods and modeling to reveal the structures and properties of some room temperature ILs, as well as their new possible applications. The book will be of help to chemists, physicists, biologists, technologists and other experts in a variety of disciplines, both academic and industrial, as well as to students and PhD students. It may help to promote the progress in ILs development also.

Ionic Liquids (ILs) in Organometallic Catalysis

Author : Jairton Dupont
Publisher : Springer
ISBN 13 : 3662478579
Total Pages : 354 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Ionic Liquids (ILs) in Organometallic Catalysis by : Jairton Dupont

Download or read book Ionic Liquids (ILs) in Organometallic Catalysis written by Jairton Dupont and published by Springer. This book was released on 2015-07-13 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal

Ionic Liquids further UnCOILed

Author : Natalia V. Plechkova
Publisher : John Wiley & Sons
ISBN 13 : 1118839617
Total Pages : 274 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Ionic Liquids further UnCOILed by : Natalia V. Plechkova

Download or read book Ionic Liquids further UnCOILed written by Natalia V. Plechkova and published by John Wiley & Sons. This book was released on 2014-03-05 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical overviews from the front line of ionic liquids research Ionic Liquids Further UnCOILed: Critical Expert Overviews continues the discussion of new processes and developments in ionic liquid technology introduced in the first volume. Written by an international group of key academic and industrial chemists, this next book in the series includes eleven overviews of specific areas of ionic liquid chemistry including: Physicochemical properties of ionic liquids A patent survey Ionic liquid membrane technology Engineering simulations Molecular simulations The goal of this volume is to provide expert overviews that range from applied to theoretical, synthetic to analytical, and biotechnological to electrochemical, while also offering consistent abbreviations of ionic liquids throughout the text. The value of Ionic Liquids Further UnCOILed: Critical Expert Overviews lies in the authors’ expertise and their willingness to share it with the reader. Included in the book is insight into typical problems related to experimental techniques, selection of liquids, and variability of data—all of which were overseen by Professor Ken Seddon, one of the book’s editors and a world leader in ionic liquids. This book is a must read for R&D chemists in industrial, governmental, and academic laboratories, and for commercial developers of environmentally sustainable processes. It offers insight and appreciation for the direction in which the field is going, while also highlighting the best published works available, making it equally valuable to new and experienced chemists alike.

Theoretical and Computational Approaches to Predicting Ionic Liquid Properties

Author : Aswathy Joseph
Publisher : Elsevier
ISBN 13 : 0128202815
Total Pages : 292 pages
Book Rating : 4.1/5 (282 download)

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Book Synopsis Theoretical and Computational Approaches to Predicting Ionic Liquid Properties by : Aswathy Joseph

Download or read book Theoretical and Computational Approaches to Predicting Ionic Liquid Properties written by Aswathy Joseph and published by Elsevier. This book was released on 2020-11-18 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Theoretical and Computational Approaches to Predicting Ionic Liquid Properties highlights new approaches to predicting and understanding ionic liquid behavior and selecting ionic liquids based on theoretical knowledge corroborated by experimental studies. Supported throughout with case studies, the book provides a comparison of the accuracy and efficiency of different theoretical approaches. Sections cover the need for integrating theoretical research with experimental data, conformations, electronic structure and non-covalent interactions, microstructures and template effects, thermodynamics and transport properties, and spectro-chemical characteristics. Catalytic and electrochemical properties are then explored, followed by interfacial properties and solvation dynamics. Structured for ease of use, and combining the research knowledge of a global team of experts in the field, this book is an indispensable tool for those involved with the research, development and application of ionic liquids across a vast range of fields. Highlights new approaches for selecting ionic liquids by combining theoretical knowledge with experimental and simulation-based observations Discusses how theoretical simulation can help in selecting specific anion-cation combinations to show enhanced properties of interest Compares the accuracy and efficiency of different theoretical approaches for predicting ionic and liquid characteristics

Ionic Liquids

Author : Rasmus Fehrmann
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110582120
Total Pages : 175 pages
Book Rating : 4.1/5 (15 download)

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Book Synopsis Ionic Liquids by : Rasmus Fehrmann

Download or read book Ionic Liquids written by Rasmus Fehrmann and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-05-20 with total page 175 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current book brings together the latest developments in the area of ionic liquids, including synthesis, purity control, toxicity, and scaling-up technologies. In addition, the authors explore the applications of ionic liquids in organic synthesis and catalysis, separation techniques and nanomaterials engineering. Written by key experts in the field, this book is an invaluable material for organic and green chemists in academia and industry.

Coulombic Fluids

Author : Werner Freyland
Publisher : Springer
ISBN 13 : 9783642177804
Total Pages : 180 pages
Book Rating : 4.1/5 (778 download)

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Book Synopsis Coulombic Fluids by : Werner Freyland

Download or read book Coulombic Fluids written by Werner Freyland and published by Springer. This book was released on 2011-07-23 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic liquids have attracted considerable interest in recent years. In this book the bulk and interfacial physico-chemical characteristics of various fluid systems dominated by Coulomb interactions are treated which includes molten salts, ionic liquids as well as metal-molten salt mixtures and expanded fluid metals. Of particular interest is the comparison of the different systems. Topics in the bulk phase concern the microscopic structure, the phase behaviour and critical phenomena, and the metal-nonmetal transition. Interfacial phenomena include wetting transitions, electrowetting, surface freezing, and the electrified ionic liquid/ electrode interface. With regard to the latter 2D and 3D electrochemical phase formation of metals and semi-conductors on the nanometer scale is described for a number of selected examples. The basic concepts and various experimental methods are introduced making the book suitable for both graduate students and researchers interested in Coulombic fluids.

Ionic Liquids: Eco-friendly Substitutes for Surface and Interface Applications

Author : Chandrabhan Verma
Publisher : Bentham Science Publishers
ISBN 13 : 9815136240
Total Pages : 427 pages
Book Rating : 4.8/5 (151 download)

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Book Synopsis Ionic Liquids: Eco-friendly Substitutes for Surface and Interface Applications by : Chandrabhan Verma

Download or read book Ionic Liquids: Eco-friendly Substitutes for Surface and Interface Applications written by Chandrabhan Verma and published by Bentham Science Publishers. This book was released on 2023-07-05 with total page 427 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic Liquids: Eco-friendly Substitutes for Surface and Interface Applications explores the growing interest in utilizing ionic liquids as sustainable alternatives for various industrial and biological applications. With their unique properties and environmentally friendly nature, ionic liquids have emerged as promising substitutes for toxic and volatile solvents, offering significant advantages in surface and interface chemistry. This book is divided into two parts: Part 1 covers the basics of ionic liquids, their surface/interface properties, and interactions with metallic surfaces. Part 2 focuses on the wide range of surface and interface applications of ionic liquids, including wastewater treatment, corrosion protection, catalysis, separation processes, medical devices, and sensing applications. Key Features: A complete book fully dedicated to the surface and interface chemistry of ionic liquids with seventeen chapters Covers fundamentals, recent progress, and applications in surface/interface chemistry Presents up-to-date research and interdisciplinary insights Includes relevant references and resources for further exploration This is a valuable reference for scientists and engineers who want to learn about ionic liquids' chemistry and applications

Ionic Liquid-Based Surfactant Science

Author : Bidyut K. Paul
Publisher : John Wiley & Sons
ISBN 13 : 1118834194
Total Pages : 578 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Ionic Liquid-Based Surfactant Science by : Bidyut K. Paul

Download or read book Ionic Liquid-Based Surfactant Science written by Bidyut K. Paul and published by John Wiley & Sons. This book was released on 2015-09-21 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume will be summarized on the basis of the topics of Ionic Liquids in the form of chapters and sections. It would be emphasized on the synthesis of ILs of different types, and stabilization of amphiphilic self-assemblies in conventional and newly developed ILs to reveal formulation, physicochemical properties, microstructures, internal dynamics, thermodynamics as well as new possible applications. It covers: Topics of ionic liquid assisted micelles and microemulsions in relation to their fundamental characteristics and theories Development bio-ionic liquids or greener, environment-friendly solvents, and manifold interesting and promising applications of ionic liquid based micelles and micremulsions

Electrolytes at Interfaces

Author : S. Durand-Vidal
Publisher : Springer Science & Business Media
ISBN 13 : 0306469405
Total Pages : 347 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Electrolytes at Interfaces by : S. Durand-Vidal

Download or read book Electrolytes at Interfaces written by S. Durand-Vidal and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 347 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim of this book is to provide the reader with a modern presentation of ionic solutions at interfaces, for physical chemists, chemists and theoretically oriented experimentalists in this field. The discussion is mainly on the structural and thermodynamic properties, in relation to presently available statistical mechanical models. Some dynamic properties are also presented, at a more phenomenological level. The initial chapters are devoted to the presentation of some basic concepts for bulk properties: hydrodynamic interactions, electrostatics, van der Waals forces and thermodynamics of ionic solutions in the framework of a particular model: the mean spherical approximation (MSA). Specific features of interfaces are then discussed: experimental techniques such as in-situ X-ray diffraction, STM and AFM microscopy are described. Ions at liquid/air, liquid/metal and liquid/liquid interfaces are considered from the experimental and theoretical viewpoint. Lastly some dynamic (transport) properties are included, namely the self-diffusion and conductance of small colloids (polyelectrolytes and micelles) and the kinetics of solute transfer at free liquid/liquid interfaces.

Supported Ionic Liquids

Author : Rasmus Fehrmann
Publisher : John Wiley & Sons
ISBN 13 : 3527324291
Total Pages : 498 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Supported Ionic Liquids by : Rasmus Fehrmann

Download or read book Supported Ionic Liquids written by Rasmus Fehrmann and published by John Wiley & Sons. This book was released on 2014-03-24 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: This unique book gives a timely overview about the fundamentals and applications of supported ionic liquids in modern organic synthesis. It introduces the concept and synthesis of SILP materials and presents important applications in the field of catalysis (e.g. hydroformylation, hydrogenation, coupling reactions, fine chemical synthesis) as well as energy technology and gas separation. Written by pioneers in the field, this book is an invaluable reference book for organic chemists in academia or industry.

Surface Second Harmonic Generation

Author : Pierre-François Brevet
Publisher : EPFL Press
ISBN 13 : 9782880743451
Total Pages : 162 pages
Book Rating : 4.7/5 (434 download)

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Book Synopsis Surface Second Harmonic Generation by : Pierre-François Brevet

Download or read book Surface Second Harmonic Generation written by Pierre-François Brevet and published by EPFL Press. This book was released on 1997-01-01 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Theoretical Insights into the Electrochemical Properties of Ionic Liquid Electrolytes in Lithium-Ion Batteries

Author : Leila Maftoon-Azad
Publisher : CRC Press
ISBN 13 : 1040157610
Total Pages : 75 pages
Book Rating : 4.0/5 (41 download)

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Book Synopsis Theoretical Insights into the Electrochemical Properties of Ionic Liquid Electrolytes in Lithium-Ion Batteries by : Leila Maftoon-Azad

Download or read book Theoretical Insights into the Electrochemical Properties of Ionic Liquid Electrolytes in Lithium-Ion Batteries written by Leila Maftoon-Azad and published by CRC Press. This book was released on 2024-09-17 with total page 75 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a concise overview of the use of ionic liquids as electrolytes in lithium-ion batteries (LIBs) from a theoretical and computational perspective. It focuses on computational studies to understand the behavior of lithium ions in different ionic liquids and to optimize the performance of ionic liquid-based electrolytes. The main features of the book are as follows: • Provides a thorough understanding of the theoretical and computational aspects of using ionic liquids as electrolytes in LIBs, including the evaluation and reproducibility of the theoretical paths. • Covers various computational methods such as density functional theory, molecular dynamics, and quantum mechanics that have been used to study the behavior of lithium ions in different solvents and to optimize the performance of ionic liquid-based electrolytes. • Discusses recent advances such as new computational methods for predicting the properties of ionic liquid-based electrolytes, new strategies for improving the stability and conductivity of these electrolytes, and new approaches for understanding the kinetics and thermodynamics of redox reactions with ionic liquids. • Suggests how theoretical insights can be translated into practical applications for improving performance and safety. This monograph will be of interest to engineers working on LIB optimization.

Properties and Manipulation of Ionic Liquid-solid Interfaces in Complex Oxide Materials

Author : Anthony Thomas Wong
Publisher :
ISBN 13 :
Total Pages : 147 pages
Book Rating : 4.:/5 (11 download)

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Book Synopsis Properties and Manipulation of Ionic Liquid-solid Interfaces in Complex Oxide Materials by : Anthony Thomas Wong

Download or read book Properties and Manipulation of Ionic Liquid-solid Interfaces in Complex Oxide Materials written by Anthony Thomas Wong and published by . This book was released on 2017 with total page 147 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionic liquids are liquid salts that are bringing rapid changes to the field of solid electronic materials. The implementation of ionic liquids in conjunction with these solid materials produces interfacial effects, especially when a bias is applied across the ionic liquid, forming an electric double layer. Electric double layers in ionic liquids are unique in their formation and the interfacial charges that are orders of magnitude higher than conventional techniques they can impart, providing new techniques for device design and implementation. In chapter 1, the fundamentals of the solid state electronic and magnetic materials are introduced, along with ionic liquids, and their essential properties that make them appropriate for use with solid films. Chapter 2 discusses the geometric impacts that should be taken into consideration when designing electric double layer devices, determining that the gate area to device area ratio plays the greatest role. Chapter 3 explores the application of electric double layer interfacial effects on ferroelectric lead zirconate- titanate films. The demonstrated large area switching, coupled with the minimal changes to film quality, and use on low quality films make this ionic liquid-solid interface an exciting proposition for future study and applications. Chapter 4 uses the same electric double layer to interrogate the ability to produce stoichiometry induced crystallographic transformations in strontium cobaltite family of films. Chapter 5 evaluates an antiferromagnetic lanthanum-strontium manganite that shows an unprecedented anisotropic magnetoresistance. These materials are excellent candidates for future spin based devices. The work discussed in this dissertation demonstrates a wide range of possible applications that can be affected by the use of ionic liquid solid interfaces, while also showing diversity in the types of studies and measurements that can be conducted by ionic liquids. Combining the electrostatic and electrochemical capabilities of ionic liquids with complex oxide films, the manipulation oxide properties can lead to advances in future electronic and magnetic properties and applications.