Fused Salt Processing of Impure Plutonium Dioxide to High-purity Plutonium Metal

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Fused Salt Processing of Impure Plutonium Dioxide to High-purity Plutonium Metal by :

Download or read book Fused Salt Processing of Impure Plutonium Dioxide to High-purity Plutonium Metal written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A process for converting impure plutonium dioxide (approx. 96% pure) to high-purity plutonium metal (>99.9%) was developed. The process consists of reducing the oxide to an impure plutonium metal intermediate with calcium metal in molten calcium chloride. The impure intermediate metal is cast into an anode and electrorefined to produce high-purity plutonium metal. The oxide reduction step is being done now on a 0.6-kg scale with the resulting yield being>99.5%. The electrorefining is being done on a 4.0-kg scale with the resulting yield being 80 to 85%. The purity of the product, which averages 99.98%, is essentially insensitive to the purity of the feed metal. The yield, however, is directly dependent on the chemical composition of the feed. To date, approximately 250 kg of impure oxide has been converted to pure metal by this processing sequence. The availability of impure plutonium dioxide, together with the need for pure plutonium metal, makes this sequence a valuable plutonium processing tool.

Plutonium Processing in the Nuclear Weapons Complex

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Publisher : DIANE Publishing
ISBN 13 : 9781568065687
Total Pages : 40 pages
Book Rating : 4.0/5 (656 download)

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Book Synopsis Plutonium Processing in the Nuclear Weapons Complex by :

Download or read book Plutonium Processing in the Nuclear Weapons Complex written by and published by DIANE Publishing. This book was released on 1993-07 with total page 40 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describes the methods and facilities for DOE's processing of plutonium for use in nuclear weapons. DOE no longer produces plutonium but processes and recycles the plutonium from retired nuclear weapons and the plutonium that remains as scrap or residue from plutonium processing. It has used two basic processes: aqueous and pyrochemical, at four processing sites, although only one site is currently operating. Photos, drawings and charts.

Large Scale Preparation of High Purity Plutonium Metal by Electrorefining (preliminary Report)

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ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Large Scale Preparation of High Purity Plutonium Metal by Electrorefining (preliminary Report) by : Lorin John Mullins

Download or read book Large Scale Preparation of High Purity Plutonium Metal by Electrorefining (preliminary Report) written by Lorin John Mullins and published by . This book was released on 1960 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Preparation of High-purity Plutonium Dioxide and Plutonium (III) Chloride Solution

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ISBN 13 :
Total Pages : 32 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Preparation of High-purity Plutonium Dioxide and Plutonium (III) Chloride Solution by : James E. Rein

Download or read book The Preparation of High-purity Plutonium Dioxide and Plutonium (III) Chloride Solution written by James E. Rein and published by . This book was released on 1959 with total page 32 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fused Salt Electrorefining of Molten Plutonium and Its Alloys

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ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Fused Salt Electrorefining of Molten Plutonium and Its Alloys by : Lorin John Mullins

Download or read book Fused Salt Electrorefining of Molten Plutonium and Its Alloys written by Lorin John Mullins and published by . This book was released on 1964 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Pyrochemical Processing of Plutonium. Technology Review Report

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Pyrochemical Processing of Plutonium. Technology Review Report by :

Download or read book Pyrochemical Processing of Plutonium. Technology Review Report written by and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Non-aqueous processes are now in routine use for direct conversion of plutonium oxide to metal, molten salt extraction of americium, and purification of impure metals by electrorefining. These processes are carried out at elevated temperatures in either refractory metal crucibles or magnesium-oxide ceramics in batch-mode operation. Direct oxide reduction is performed in units up to 700 gram PuO2 batch size with molten calcium metal as the reductant and calcium chloride as the reaction flux. Americium metal is removed from plutonium metal by salt extraction with molten magnesium chloride. Electrorefining is used to isolate impurities from molten plutonium by molten salt ion transport in a controlled potential oxidation-reduction cell. Such cells can purify five or more kilograms of impure metal per 5-day electrorefining cycle. The product metal obtained is typically> 99.9% pure, starting from impure feeds. Metal scrap and crucible skulls are recovered by hydriding of the metallic residues and recovered either as impure metal or oxide feeds.

Reactor Fuel Processing

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ISBN 13 :
Total Pages : 282 pages
Book Rating : 4.3/5 (243 download)

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Book Synopsis Reactor Fuel Processing by :

Download or read book Reactor Fuel Processing written by and published by . This book was released on 1965 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:

A Pyrochemical Process for the Reduction of Plutonium Dioxide to Metal

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ISBN 13 :
Total Pages : 28 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis A Pyrochemical Process for the Reduction of Plutonium Dioxide to Metal by : Rowland E. Felt

Download or read book A Pyrochemical Process for the Reduction of Plutonium Dioxide to Metal written by Rowland E. Felt and published by . This book was released on 1969 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Plutonium-241 Processing

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (16 download)

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Book Synopsis Plutonium-241 Processing by :

Download or read book Plutonium-241 Processing written by and published by . This book was released on 1975 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6)

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Publisher : Springer Science & Business Media
ISBN 13 : 9400702116
Total Pages : 4511 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) by : L.R. Morss

Download or read book The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2010-10-21 with total page 4511 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.

Reduction of Plutonium Dioxide to Plutonium Metal

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ISBN 13 :
Total Pages : 16 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Reduction of Plutonium Dioxide to Plutonium Metal by : Major C. Thompson

Download or read book Reduction of Plutonium Dioxide to Plutonium Metal written by Major C. Thompson and published by . This book was released on 1965 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Publications of Los Alamos Research

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ISBN 13 :
Total Pages : 348 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Publications of Los Alamos Research by : Los Alamos National Laboratory

Download or read book Publications of Los Alamos Research written by Los Alamos National Laboratory and published by . This book was released on 1983 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos

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ISBN 13 :
Total Pages : 16 pages
Book Rating : 4.:/5 (826 download)

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Book Synopsis The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos by : Keith W. Fife

Download or read book The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos written by Keith W. Fife and published by . This book was released on 1986 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (826 download)

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Book Synopsis The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos by :

Download or read book The Preparation of Fused Chloride Salts for Use in Pyrochemical Plutonium Recovery Operations at Los Alamos written by and published by . This book was released on 1986 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Plutonium Metal Technology Group at Los Alamos routinely uses pyrochemical processes to produce and purify plutonium from impure sources. The basic processes (metal production, metal purification, and residue treatment) involve controlling oxidation and reduction reactions between plutonium and its compounds in molten salts. Current production methods are described, as well as traditional approaches and recent developments in the preparation of solvent salts for electrorefining, molten salt extraction, lean metal (pyroredox) purification, and direct oxide reduction.

The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5)

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Publisher : Springer Science & Business Media
ISBN 13 : 1402035985
Total Pages : 4059 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) by : L.R. Morss

Download or read book The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2007-12-31 with total page 4059 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.

Energy Research Abstracts

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ISBN 13 :
Total Pages : 636 pages
Book Rating : 4.:/5 (3 download)

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Book Synopsis Energy Research Abstracts by :

Download or read book Energy Research Abstracts written by and published by . This book was released on 1989 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Proceedings of the International Symposium on Molten Salts

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ISBN 13 :
Total Pages : 632 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Proceedings of the International Symposium on Molten Salts by :

Download or read book Proceedings of the International Symposium on Molten Salts written by and published by . This book was released on 1986 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: