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Formation And Reactions Of Methyl Radicals On Metal Oxides
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Book Synopsis Methane Conversion by Oxidative Processes by : Wolf
Download or read book Methane Conversion by Oxidative Processes written by Wolf and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 556 pages. Available in PDF, EPUB and Kindle. Book excerpt: A reasonable case could be made that the scientific interest in catalytic oxidation was the basis for the recognition of the phenomenon of catalysis. Davy, in his attempt in 1817 to understand the science associated with the safety lamp he had invented a few years earlier, undertook a series of studies that led him to make the observation that a jet of gas, primarily methane, would cause a platinum wire to continue to glow even though the flame was extinguished and there was no visible flame. Dobereiner reported in 1823 the results of a similar investigation and observed that spongy platina would cause the ignition of a stream of hydrogen in air. Based on this observation Dobereiner invented the first lighter. His lighter employed hydrogen (generated from zinc and sulfuric acid) which passed over finely divided platinum and which ignited the gas. Thousands of these lighters were used over a number of years. Dobereiner refused to file a patent for his lighter, commenting that "I love science more than money." Davy thought the action of platinum was the result of heat while Dobereiner believed the ~ffect ~as a manifestation of electricity. Faraday became interested in the subject and published a paper on it in 1834; he concluded that the cause for this reaction was similar to other reactions.
Book Synopsis Metal Oxides in Energy Technologies by : Yuping Wu
Download or read book Metal Oxides in Energy Technologies written by Yuping Wu and published by Elsevier. This book was released on 2018-10-05 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxides in Energy Technologies provides, for the first time, a look at the wide range of energy applications of metal oxides. Topics covered include metal oxides materials and their applications in batteries, supercapacitors, fuel cells, solar cells, supercapacitors, and much more. The book is written by an experienced author of over 240 papers in peer-reviewed journals who was also been recognized as one of Thomson Reuter's "World's Most Influential Scientific Minds in 2015. This book presents a unique work that is ideal for academic researchers and engineers. - Presents an authoritative overview on metal oxides in energy technologies as written by an expert author who has published extensively in the area - Offers up-to-date coverage of a large, rapidly growing and complex literature - Focuses on applications, making it an ideal resource for those who want to apply this knowledge in industry
Book Synopsis Scientific and Technical Aerospace Reports by :
Download or read book Scientific and Technical Aerospace Reports written by and published by . This book was released on 1995 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Looping Partial Oxidation by : Liang-Shih Fan
Download or read book Chemical Looping Partial Oxidation written by Liang-Shih Fan and published by Cambridge University Press. This book was released on 2017-10-12 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first comprehensive guide to chemical looping partial oxidation processes, covering key principles, techniques, and applications.
Book Synopsis Reaction Kinetics and the Development of Catalytic Processes by : G.F. Froment
Download or read book Reaction Kinetics and the Development of Catalytic Processes written by G.F. Froment and published by Elsevier. This book was released on 1999-03-18 with total page 491 pages. Available in PDF, EPUB and Kindle. Book excerpt: The symposium "Reaction Kinetics and the Development of Catalytic Processes" is the continuation of the very successful International Symposium "Dynamics of Surfaces and Reaction Kinetics in Heterogeneous Catalysis", held in September 1997 in Antwerp, Belgium. These proceedings contain a unique series of top level plenary lectures mainly focused on• the dynamics of catalytic surfaces• the interaction of the reacting molecules with the solid catalyst• the elementary steps of reaction pathways and molecular kinetics.Surface science techniques, molecular modeling, transient kinetic studies, sophisticated and specific reactors are included to a growing extent in the kinetic modeling and the development of catalytic processes. How this is practiced today and how it will evolve in the coming years, and what benefit can be expected for a more fundamentally based approach is the aim of the symposium.
Book Synopsis Bimodal Oxidation by : Robert Bakhtchadjian
Download or read book Bimodal Oxidation written by Robert Bakhtchadjian and published by CRC Press. This book was released on 2019-11-15 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is devoted to the problems of oxidation chemical reactions and addresses bimodal reaction sequences. Chemical reactions of oxidation, occurring under certain conditions and in multicomponent systems are complex processes. The process of the oxidation essentially changes in the presence and contact of the solid substances with reactants. The role of solid substances and the appearance of this phenomenon in oxidation reaction are discussed. The reader will understand the "driving forces" of this phenomenon and apply it in practice. Written for chemists, physicists, biologists and engineers working in the domain of oxidation reactions. Key Selling Features: Covers the historical background, modern state of the art, and perspectives in investigations of the coupling between heterogeneous and homogeneous reactions Discusses the feasible pathways of the coupling of heterogeneous and homogeneous reactions in oxidation in man-made and natural chemical systems Addresses the abundance, peculiarities and mechanisms of the bimodal reaction sequences in oxidation with dioxygen in recent decades Discusses the existence of the bimodal reaction sequences in chemical systems investigations in atmospheric chemistry and heterogeneous photocatalysis Presented in a simple concise style, accessible for both specialists and non-specialists
Book Synopsis Oxidation of Organic Compounds by : N. M. Emanuel
Download or read book Oxidation of Organic Compounds written by N. M. Emanuel and published by Elsevier. This book was released on 2013-10-22 with total page 628 pages. Available in PDF, EPUB and Kindle. Book excerpt: Oxidation of Organic Compounds: Medium Effects in Radical Reactions explores the role of solvents and of the composition of phase states in radical-chain processes involved in the oxidation of organic compounds. Organized into 10 chapters, this book begins with a discussion of the basic concepts relating to the mechanism involved in the oxidation of hydrocarbons and other organic compounds in liquid-phase reactions. Subsequent chapters detail some methods for studying the mechanism of oxidation reactions; role of solvation in chemical reaction kinetics; role of the medium in chain-initiation reactions; role of non-specific and specific solvation in chain-propagation and chain-termination reactions; and the role of solvation in chain-termination reactions in inhibitors. The influence of the solvent and the phase state of substances undergoing oxidation on the rates and mechanisms of individual elementary processes are also addressed. The last chapter examines the problem of the influence of the solid state of the polymer on the reactivity of radicals. This monograph will be valuable to scientific research workers, engineers, and engineering technologists specializing in the field of radical reactions and in particular in the oxidation of organic compounds.
Download or read book Catalysis written by James J Spivey and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: There is an increasing challenge for chemical industry and research institutions to find cost-efficient and environmentally sound methods of converting natural resources into fuels chemicals and energy. Catalysts are essential to these processes and the Catalysis Specialist Periodical Report series serves to highlight major developments in this area. This series provides systematic and detailed reviews of topics of interest to scientists and engineers in the catalysis field. The coverage includes all major areas of heterogeneous and homogeneous catalysis and also specific applications of catalysis such as NOx control kinetics and experimental techniques such as microcalorimetry. Each chapter is compiled by recognised experts within their specialist fields and provides a summary of the current literature. This series will be of interest to all those in academia and industry who need an up-to-date critical analysis and summary of catalysis research and applications. Catalysis will be of interest to anyone working in academia and industry that needs an up-to-date critical analysis and summary of catalysis research and applications. Specialist Periodical Reports provide systematic and detailed review coverage in major areas of chemical research. Compiled by teams of leading experts in their specialist fields, this series is designed to help the chemistry community keep current with the latest developments in their field. Each volume in the series is published either annually or biennially and is a superb reference point for researchers. www.rsc.org/spr
Download or read book Radicals on Surfaces written by A. Lund and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: Studies of free radicals on surfaces are of interest for several reasons: the spontaneous or stimulated formation of radicals from adsorbed molecules may represent one possible mechanism for heterogeneous catalysis. In some cases the radicals are ionic, indicating that primary oxidation and reduction reactions occur. Radicals can also be used as probes to investigate diffusion processes on catalytic surfaces. The first direct observations were made more than 30 years ago, but detailed studies of structure, reactions and mobility have only recently become feasible with the advent of powerful spectroscopic techniques, to a great extent developed and used by the contributors to this volume. This comprehensive review describes new trends in the field. Leading experts write about the nature of surface active sites, methods to identify them, and the radicals formed from adsorbed molecules interacting with the surface. The emphasis is on the fundamentals covering thermal, photostimulated and radiation induced reactions as well as diffusion processes. This provides the necessary background for technological applications. This book will be useful to those who are interested in surface chemistry, heterogeneous catalysis as well as those who want to study reactive intermediates in chemical reactions. It is also of interest to scientists in photo and radiation physics and chemistry.
Book Synopsis Nanostructured Catalysts by : Christian Hess
Download or read book Nanostructured Catalysts written by Christian Hess and published by Royal Society of Chemistry. This book was released on 2011-07-22 with total page 453 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a comprehensive up-to-date summary of the existing information on the structural/electronic properties, chemistry and catalytic properties of vanadium and molybdenum containing catalysts. It discusses the importance of nanoscience for the controlled synthesis of catalysts with functional properties and introduces the necessary background regarding surface properties and preparation techniques, leading from a textbook level to the current state of knowledge. Then follows an extensive survey and analysis of the existing open and patent literature - an essential knowledge source for the development of the new generation of partial oxidation catalysts. Important examples from current research on partial oxidation reactions are reviewed from experts in the field. The next chapter discusses the importance of 2- and 3-dimensional model systems for a fundamental understanding of the structure of transition metal oxide catalysts and its correlation to reactivity. Finally, an outlook on research opportunities within the area of partial oxidation reactions is presented.
Download or read book Energy Research Abstracts written by and published by . This book was released on 1994-11 with total page 486 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Catalysis and the Mechanism of Methane Conversion to Chemicals by : Toshihide Baba
Download or read book Catalysis and the Mechanism of Methane Conversion to Chemicals written by Toshihide Baba and published by Springer Nature. This book was released on 2020-04-18 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces various types of reactions to produce chemicals by the direct conversion of methane from the point of view of mechanistic and functional aspects. The chemicals produced from methane are aliphatic and aromatic hydrocarbons such as propylene and benzene, and methanol. These chemicals are created by using homogeneous catalysts, heterogeneous catalysts such as zeolites, and biocatalysts such as enzymes. Various examples of methane conversion reactions that are discussed have been chosen to illustrate how heterogeneous and homogenous catalysts and biocatalysts and/or their reaction environments control the formation of highly energetic species from methane contributing to C-C and C-O bond formation.
Book Synopsis New Frontiers in Catalysis, Parts A-C by : L. Guczi
Download or read book New Frontiers in Catalysis, Parts A-C written by L. Guczi and published by Elsevier. This book was released on 1993-04-20 with total page 2955 pages. Available in PDF, EPUB and Kindle. Book excerpt: These volumes comprise the proceedings of the major international meeting on catalysis which is held at 4 year intervals. The programme focussed on New Frontiers in Catalysis including nontraditional catalytic materials and environmental catalysis. The contributions cover a wide range of fundamental, applied, industrial and engineering aspects of catalysis. The extensive range of highly efficient industrial techniques for observing and characterizing catalytically important surfaces is evident.The programme covered the following sessions: Mechanism, theory, in situ methods; Catalytic reaction on atomically clean surfaces; Catalytic reaction on zeolites and related substances; New methods and principles for catalyst preparation; Hydrotreatment reactions (HDS, HDN); Characterization of catalysts, application of novel techniques; Selective oxidation; New catalytic aspects of heteropoly acids and related compounds; Reaction of hydrocarbons; Nontraditional catalytic materials; Fuel upgrading; Alkane activation; Acid-base catalysis; New selective catalytic reactons, fine chemicals; Environmental catalysis; Industrial catalysis, deactivation, reactivation; Synthesis from syngas; Electrocatalysis; Photocatalysis.The invited lectures and 433 papers included in these volumes present an update on all areas of catalysis and applications.
Book Synopsis Technical Abstract Bulletin by : Defense Documentation Center (U.S.)
Download or read book Technical Abstract Bulletin written by Defense Documentation Center (U.S.) and published by . This book was released on 1963 with total page 1032 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Small-Scale Gas to Liquid Fuel Synthesis by : Nick Kanellopoulos
Download or read book Small-Scale Gas to Liquid Fuel Synthesis written by Nick Kanellopoulos and published by CRC Press. This book was released on 2015-02-23 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt: It is estimated that a large fraction of natural gas reserves are found in locations from where transport is not economical. If these isolated natural gas reserves could be converted to synthetic fuels, they would generate around 250 billion barrels of synthetic oil-a quantity equal to one-third of the Middle East's proven oil reserves. Small-Scale
Book Synopsis Basic Principles in Applied Catalysis by : Manfred Baerns
Download or read book Basic Principles in Applied Catalysis written by Manfred Baerns and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a team of internationally recognized experts, this book addresses the most important types of catalytic reactions and catalysts as used in industrial practice. Both applied aspects and the essential scientific principles are described. The main topics can be summarized as follows: heterogeneous, homogeneous and biocatalysis, catalyst preparation and characterization, catalytic reaction engineering and kinetics, catalyst deactivation and industrial perspective.
Download or read book Catalysis written by James Spivey and published by Royal Society of Chemistry. This book was released on 2020-01-17 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: Catalysts are required for a variety of applications and researchers are increasingly challenged to find cost effective and environmentally benign catalysts to use. This volume looks at modern approaches to catalysis and reviews the extensive literature. Chapters highlight reactions active under oxidative coupling of methane conditions and how they are interlinked, heterogeneous nickel catalysts and their use in laboratory and industry, the reaction mechanism of heterogeneous catalysis with the surface science probe, the concepts of electroless deposition (ED) methods for preparation of true bimetallic catalysts, the general subject of metal-support interactions occurring over ruthenium-based catalysts and benzene as the target volatile organic compound (VOC). Appealing broadly to researchers in academia and industry, these illustrative chapters bridge the gap from academic studies in the laboratory to practical applications in industry not only for catalysis field but also for environmental protection. The book will be of great benefit to any researcher wanting a succinct reference on developments in this area now and looking to the future.
