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Fabrication And Characterization Of In Plane Aligned Nanotube Composites With Magnetically Aligned Carbon Nanotube Bucky Papers
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Book Synopsis Fabrication and Characterization of In-Plane Aligned Nanotube Composites with Magnetically Aligned Carbon Nanotube Bucky Papers by : Ben Wang
Download or read book Fabrication and Characterization of In-Plane Aligned Nanotube Composites with Magnetically Aligned Carbon Nanotube Bucky Papers written by Ben Wang and published by . This book was released on 2000 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Aligned Carbon Nanotubes by : Zhifeng Ren
Download or read book Aligned Carbon Nanotubes written by Zhifeng Ren and published by Springer Science & Business Media. This book was released on 2012-09-05 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a survey of the physics and fabrication of carbon nanotubes and their applications in optics, electronics, chemistry and biotechnology. It focuses on the structural characterization of various carbon nanotubes, fabrication of vertically or parallel aligned carbon nanotubes on substrates or in composites, physical properties for their alignment, and applications of aligned carbon nanotubes in field emission, optical antennas, light transmission, solar cells, chemical devices, bio-devices, and many others. Major fabrication methods are illustrated in detail, particularly the most widely used PECVD growth technique on which various device integration schemes are based, followed by applications such as electrical interconnects, nanodiodes, optical antennas, and nanocoax solar cells, whereas current limitations and challenges are also be discussed to lay the foundation for future developments.
Book Synopsis Characterization of Carbon Nanotube Based Composites under Consideration of Defects by : Moones Rahmandoust
Download or read book Characterization of Carbon Nanotube Based Composites under Consideration of Defects written by Moones Rahmandoust and published by Springer. This book was released on 2015-10-14 with total page 246 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents the characterization methods involved with carbon nanotubes and carbon nanotube-based composites, with a more detailed look at computational mechanics approaches, namely the finite element method. Special emphasis is placed on studies that consider the extent to which imperfections in the structure of the nanomaterials affect their mechanical properties. These defects may include random distribution of fibers in the composite structure, as well as atom vacancies, perturbation and doping in the structure of individual carbon nanotubes.
Book Synopsis Carbon Nanotube-Polymer Composites by : Brian P. Grady
Download or read book Carbon Nanotube-Polymer Composites written by Brian P. Grady and published by John Wiley & Sons. This book was released on 2011-07-08 with total page 505 pages. Available in PDF, EPUB and Kindle. Book excerpt: The accessible compendium of polymers in carbon nanotubes (CNTs) Carbon nanotubes (CNTs)—extremely thin tubes only a few nanometers in diameter but able to attain lengths thousands of times greater—are prime candidates for use in the development of polymer composite materials. Bringing together thousands of disparate research works, Carbon Nanotube-Polymer Composites: Manufacture, Properties, and Applications covers CNT-polymers from synthesis to potential applications, presenting the basic science and engineering of this dynamic and complex area in an accessible, readable way. Designed to be of use to polymer scientists, engineers, chemists, physicists, and materials scientists, the book covers carbon nanotube fundamentals to help polymer experts understand CNTs, and polymer physics to help those in the CNT field, making it an invaluable resource for anyone working with CNT-polymer composites. Detailed chapters describe the mechanical, rheological, electrical, and thermal properties of carbon nanotube-polymer composites. Including a glossary that defines key terms, Carbon Nanotube-Polymer Composites is essential reading for anyone looking to gain a fundamental understanding of CNTs and polymers, as well as potential and current applications, including electronics (shielding and transparent electrodes), flame retardants, and electromechanics (sensors and actuators), and their challenges.
Book Synopsis Carbon Nanotubes: Synthesis, Characterization and Applications by : Kamal K. Kar
Download or read book Carbon Nanotubes: Synthesis, Characterization and Applications written by Kamal K. Kar and published by Research Publishing Service. This book was released on 2011 with total page 15 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Characterization of Aligned Carbon Nanotube/polymer Composites by : Sumanth Banda
Download or read book Characterization of Aligned Carbon Nanotube/polymer Composites written by Sumanth Banda and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The main objective of this thesis is to efficiently disperse and align SWNTs in two different polymer matrices to obtain an orthotropic composite whose strength, stiffness and electrical properties depend on the orientation of the SWNTs. The SWNTs are successfully dispersed and aligned in a polyimide matrix and a polymer blend of UDMA/HDDMA. In-situ polymerization under sonication is used to disperse the SWNTs in polyimide matrix and sonication is used to disperse SWNTs in the UDMA/HDDMA matrix. In both cases, an electric field is used to align the SWNTs in the polymer matrices. In the polyimide, the SWNTs are aligned by electrospinning technique, and in (UDMA/HDDMA) the SWNTs are aligned by applying an AC electric field, while the composite is cured. The electrical and mechanical properties of randomly dispersed SWNT polyimide composites and SWNT/UDMA/HDDMA composite are measured. The dielectric constant and storage modulus of SWNT polyimide composite increased with SWNT concentration. Low percolation (0.06 wt%) and an increase of 113% in storage modulus with 0.2 wt% SWNTs, both indicate good dispersion of SWNTs in the polyimide matrix. The dielectric constants, conductivity for the unaligned SWNT/UDMA/HDDMA composite are isotropic. The electrical and mechanical properties of the randomly dispersed SWNT polyimide composite and SWNT/UDMA/HDDMA composite are used as references when analyzing the aligned counter parts. Different characterization methods are used to assess the alignment of the SWNTs in the polyimide and (UDMA/HDDMA) matrices. A variety of characterization techniques, i.e. microscopy, Raman spectroscopy, electrical conductivity, dynamic dielectric spectroscopy and dynamic mechanical analysis, indicate preferential alignment of SWNTs in two types of polymers: Polyimide and (UDMA/HDDMA). Optical microscope images showed alignment of the SWNTs in the UDMA/HDDMA composite. Inspection of the Raman spectra on aligned SWNT polyimide composite fibers and aligned SWNT/UDMA/HDDMA composite indicates a decrease in the intensity of the tangential peak of the SWNT with increase in the polarizer angle. The difference in the perpendicular and parallel Raman peaks indicate preferential alignment of SWNTs in both the polymer matrices. In the aligned polyimide composite, percolation transition is at 0.2 wt% SWNT concentrations when dielectric constant is measured parallel to the aligned SWNTs. But percolation transition is at 0.65 wt% SWNT concentrations when dielectric constant is measured perpendicular to the aligned SWNTs. Electrical measurements on aligned SWNT polyimide and UDMA/HDDMA composite are highly anisotropic. In both cases, the dielectric constant values parallel to the direction of SWNT alignment are higher than the values perpendicular to the direction of SWNT alignment. To analyze the resulting anisotropy in the dielectric constant, Bruggeman's effective medium approach is used. The effective medium theory predicts the effective dielectric constant of a composite with aligned anisotropic inclusions. The effective dielectric constant, perpendicular to the aligned inclusions and parallel to the aligned inclusions is estimated. The dielectric constant values of aligned SWNT polyimide and aligned SWNT/UDMA/HDDMA composites are compared to the experimental results. Both the values from the theory and experiment show anisotropy in dielectric constant. The theory indicated that the dielectric constant parallel to the aligned inclusions is highly influenced by the dielectric constant of the inclusion and the dielectric constant perpendicular to the aligned inclusions is highly influenced by the dielectric constant of the polymer matrix. Results from the different characterizing techniques indicate that SWNTs are successfully aligned in the polyimide matrix and (UDMA/HDDMA) matrix by electrospinning technique and by an AC electric field respectively.
Book Synopsis Synthesis and Mechanical Characterization of Aligned Carbon Nanotube Metal- and Carbon-matrix Nanocomposites by : Amy Ruth Vanderhout
Download or read book Synthesis and Mechanical Characterization of Aligned Carbon Nanotube Metal- and Carbon-matrix Nanocomposites written by Amy Ruth Vanderhout and published by . This book was released on 2020 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotube (CNT) assemblies are seeing increasing use in engineering applications due to their advantaged, mass-specific physical properties. The high strength-to-weight ratio, electrical and thermal conductivity, and elastic properties make CNTs ideal for many aerospace, automotive, and electrical applications. In structural materials, CNTs are an outstanding candidate to provide nano-reinforcement, both in hybrid composites and nanocomposites, and they have been found to improve the hardness, yield strength, and conductivity of their matrix material. Additional enhancement of these matrices can be realized by using aligned CNTs (A-CNTs) of increased volume fraction, as explored in this work. In this thesis, ceramic matrix nanocomposites (CMNCs), specifically A-CNT/carbon matrix nanocomposites (A/C-NCs), are synthesized by first infusing a carbon precursor resin into A-CNT arrays with CNT volume fractions (v[subscript f]) ranging from 1-30 vol%, and then pyrolyzing the resin to create a carbon matrix around the A-CNTs. Previous work with A/C-NC hardness suggests that such a lightweight, superhard material may rival the density-normalized hardness of diamond at high v[subscript f]. Various processes were refined and tested in this work, yielding microscale void-free A/CNCs up to 30% v[subscript f], with an ~7% improvement in hardness over baseline pyrolytic carbon (PyC) for 1% v[subscript f] A/C-NCs and ∼10% improvement in hardness for 5% v[subscript f] A-CNTs. A reinfusion (i.e. an initial infusion/pyrolysis cycle with three additional reinfusion/pyrolysis cycles) procedure was developed and implemented, and testing is recommended as immediate future work. Although hardness determination of these reinfused samples is left for future work, the X-ray CT images of the final A/C-NCs after the fourth infusion show excellent infusion and few voids, suggesting that high hardness will be achieved. This thesis also explores and develops synthesis techniques for metal matrix nanocomposites (MMNCs), focusing on an aluminum matrix. As the surface energy of ACNTs is not conducive to wetting by Al (and many other metals), this surface energy must first be altered to allow Al matrix infusion for consistent composite fabrication. TiO2 is conformally decorated onto ~100 [mu]m-tall A-CNT arrays via atomic layer deposition (ALD). A reduction process for the TiO2 coating was developed, and a reduction to TiH2 was determined to be promising, as the TiH2 will not oxidize prior to Al infusion but can easily be reduced in a vacuum oven apparatus designed specifically to meet the needs of Al infusion. Towards MMNCs, both solder and aluminum matrices are infused into the TiO2-decorated A-CNTs. The solder experiments yielded mixed success, as the results suggest that both the reduction and the vacuum infusion steps are important factors determining successful wetting. Although Al infusion into an A-CNT array was unsuccessful without a dedicated Al infusion apparatus, molten Al was found to wet Ti well, which suggests that the Ti coating may allow for successful A-CNT wetting. Additional recommendations are provided to further refine the A/Al-NC fabrication process to improve Al infusion.
Book Synopsis Controlled Fabrication of Aligned Carbon Nanotube Architectures for Microelectronics Packaging Applications by : Lingbo Zhu
Download or read book Controlled Fabrication of Aligned Carbon Nanotube Architectures for Microelectronics Packaging Applications written by Lingbo Zhu and published by . This book was released on 2007 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis is devoted to the fabrication of carbon nanotube structures for microelectronics packaging applications with an emphasis on fundamental studies of nanotube growth and assembly, wetting of nanotube structures, and nanotube-based composites. A CVD process is developed that allows controlled growth of a variety of CNT structures, such as CNT films, bundles, and stacks. Use of an Al2O3 support enhances the Fe catalyst activity by increasing the CNT growth rate by nearly two orders of magnitude under the same growth conditions. By introducing a trace amount of weak oxidants into the CVD chamber during CNT growth, aligned CNT ends can be opened and/or functionalized, depending on the selection of oxidants. By varying the growth temperature, CNT growth can be performed in a gas diffusion- or kinetics-controlled regime. To overcome the challenges that impede implementation of CNTs in circuitry, a CNT transfer process was proposed to assemble aligned CNT structures (films, stacks & bundles) at low temperature which ensures compatibility with current microelectronics fabrication sequences and technology. Field emission and electrical testing of the as-assembled CNT devices indicate good electrical contact between CNTs and solder and a very low contact resistance across CNT/solder interfaces. For attachment of CNTs and other applications (e.g. composites), wetting of nanotube structures was studied. Two model surfaces with two-tier scale roughness were fabricated by controlled growth of CNT arrays followed by coating with fluorocarbon layers formed by plasma polymerization to study roughness geometric effects on superhydrophobicity. Due to the hydrophobicity of nanotube structures, electrowetting was investigated to reduce the hydrophobicity of aligned CNTs by controllably reducing the interfacial tension between carbon nanotubes (CNTs) and liquids. Electrowetting can greatly reduce the contact angle of liquids on the surfaces of aligned CNT films. However, contact angle saturation still occurs.
Book Synopsis Carbon Nanotubes by : Siva Yellampalli
Download or read book Carbon Nanotubes written by Siva Yellampalli and published by BoD – Books on Demand. This book was released on 2011-08-17 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer nanocomposites are a class of material with a great deal of promise for potential applications in various industries ranging from construction to aerospace. The main difference between polymeric nanocomposites and conventional composites is the filler that is being used for reinforcement. In the nanocomposites the reinforcement is on the order of nanometer that leads to a very different final macroscopic property. Due to this unique feature polymeric nanocomposites have been studied exclusively in the last decade using various nanofillers such as minerals, sheets or fibers. This books focuses on the preparation and property analysis of polymer nanocomposites with CNTs (fibers) as nano fillers. The book has been divided into three sections. The first section deals with fabrication and property analysis of new carbon nanotube structures. The second section deals with preparation and characterization of polymer composites with CNTs followed by the various applications of polymers with CNTs in the third section.
Book Synopsis Carbon Nanotube Based Composites by : Antonio Pantano
Download or read book Carbon Nanotube Based Composites written by Antonio Pantano and published by Smithers Rapra. This book was released on 2012-09-28 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotubes (CNTs) have amazing properties and a key way to take advantage of this is by incorporating nanotubes into a matrix to build composite materials. The best candidates for this task are undoubtedly polymers. Almost every characteristic of a polymer can be significantly enhanced by adding carbon nanotubes and as a result, new potential applications of carbon nanotube enhanced polymer composites are discovered every day. However, before carbon nanotube enhanced polymer composites become commonplace there are some tough challenges that need to be overcome. This book reviews the status of worldwide research in both single-walled and multi-walled carbon nanotube based composites. It serves as a practical guide on carbon nanotube based composites and a reference to students and researchers from the academia and industry.
Book Synopsis Carbon Nanotube-Polymer Composites by : Dimitrios Tasis
Download or read book Carbon Nanotube-Polymer Composites written by Dimitrios Tasis and published by Royal Society of Chemistry. This book was released on 2015-11-09 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemically-modified carbon nanotubes (CNTs) exhibit a wide range of physical and chemical properties which makes them an attractive starting material for the preparation of super-strong and highly-conductive fibres and films. Much information is available across the primary literature, making it difficult to obtain an overall picture of the state-of-the-art. This volume brings together some of the leading researchers in the field from across the globe to present the potential these materials have, not only in developing and characterising novel materials but also the devices which can be fabricated from them. Topics featured in the book include Raman characterisation, industrial polymer materials, actuators and sensors and polymer reinforcement, with chapters prepared by highly-cited authors from across the globe. A valuable handbook for any academic or industrial laboratory, this book will appeal to newcomers to the field and established researchers alike.
Book Synopsis Growth of Vertically Aligned Carbon Nanotubes by RF-DC Plasma Chemical Vapor Deposition by : Yasuaki Hayashi
Download or read book Growth of Vertically Aligned Carbon Nanotubes by RF-DC Plasma Chemical Vapor Deposition written by Yasuaki Hayashi and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Carbon Nanotubes by : Arvind Agarwal
Download or read book Carbon Nanotubes written by Arvind Agarwal and published by CRC Press. This book was released on 2018-09-03 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the Foreword, written by legendary nano pioneer M. Meyyappan, Chief Scientist for Exploration Technology NASA Ames Research Center, Moffett Field, California, USA: "...there is critical need for a book to summarize the status of the field but more importantly to lay out the principles behind the technology. This is what Professor Arvind Agarwal and his co-workers ... have done here." Carbon Nanotubes: Reinforced Metal Matrix Composites reflects the authors’ desire to share the benefits of nanotechnology with the masses by developing metal matrix carbon nanotube (MM-CNT) composites for large-scale applications. Multiwall carbon nanotubes can now be produced on a large scale and at a significantly reduced cost. The book explores potential applications and applies the author’s own research to highlight critical developmental issues for different MM-CNT composites—and then outline novel solutions. With this problem-solving approach, the book explores: Advantages, limitations, and the evolution of processing techniques used for MM-CNT composites Characterization techniques unique to the study of MM-CNT composites—and the limitations of these methods Existing research on different MM-CNT composites, presented in useful tables that include composition, processing method, quality of CNT dispersion, and properties The micro-mechanical strengthening that results from adding CNT The applicability of micro-mechanics models in MM-CNT composites Significance of chemical stability for carbon nanotubes in the metal matrix as a function of processing, and its impact on CNT/metal interface and mechanical properties Computational studies that have not been sufficiently covered although they are essential to research and development The critical issue of CNT dispersion in the metal matrix, as well as a unique way to quantify CNT distribution and subsequently improve control of the processing parameters for obtaining improved properties Carbon Nanotubes: Reinforced Metal Matrix Composites paints a vivid picture of scientific and application achievements in this field. Exploring the mechanisms through which CNTs are enhancing the properties of different metal-based composites, the authors provide a roadmap to help researchers develop MM-CNT composites and choose potential materials for use in emerging areas of technology.
Book Synopsis Hierarchical Carbon Fiber Composites with Radially Aligned Carbon Nanotubes by : Richard Li (S.M.)
Download or read book Hierarchical Carbon Fiber Composites with Radially Aligned Carbon Nanotubes written by Richard Li (S.M.) and published by . This book was released on 2013 with total page 94 pages. Available in PDF, EPUB and Kindle. Book excerpt: Hierarchical carbon-nanotube (CNT)-based composites have significant potential to expand the performance and functionality of aerospace composite structures. Notably, circumferentially aligned CNT arrays have previously been grown on woven alumina filaments to form a "fuzzy fiber" reinforced plastic (FFRP) architecture with demonstrated improvements in inter- and intra-ply mechanical properties as well as multifunctional enhancement via tailorable electrical and thermal conductivities. However, thus far, the development of fuzzy carbon fiber reinforced plastics (fuzzy CFRP) with all-around enhanced mechanical properties has been elusive. In particular, prior work attaining growth of CNTs on carbon fibers (CF) have resulted in drastic reductions in fiber tensile strength (e.g., 55% loss), thereby compromising in-plane tensile properties of the resultant fuzzy CFRP. In this thesis, a novel method for high-yield growth of carbon nanotubes on carbon fiber is refined and implemented in the fabrication of unidirectional fuzzy CFRP plies with preserved tensile properties: Non-covalent functionalization of the CF surface coupled with a low temperature thermal chemical vapor deposition process enable high density catalyst adhesion and CNT growth below critical temperatures that would result in fiber strength loss. Successful scale-up to unidirectional fuzzy CFRP specimens with high (67%) and low (32%) CF volume fractions is presented. Testing results indicate that longitudinal elastic properties are retained for all fuzzy CFRP samples consistent with micromechanical analyses. Unexpectedly, the high fiber volume fraction fuzzy CFRP specimens show a 12% decrease in mean tensile strength that was hypothesized to be due to fiber damage introduced through transverse compression during processing of the fuzzy carbon fiber tows. As such, lower fiber volume fraction fuzzy CFRP specimens were subsequently tested and observed to retain strength. These advances pave the way for scale-up to fuzzy CFRP laminates with integrated multifunctionality and improved interlaminar performance without compromising in-plane mechanical properties critical to aerospace-grade composite materials.
Book Synopsis The Design, Fabrication, and Characterization of Polymer-carbon Nanotube Composites by : LaNetra Clayton
Download or read book The Design, Fabrication, and Characterization of Polymer-carbon Nanotube Composites written by LaNetra Clayton and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ABSTRACT: The design, fabrication, and characterization of polymer-carbon nanotube (CNT) composites have generated a significant amount of attention in the fields of materials science and polymer chemistry. The challenge in fabricating composites that exploit the unique properties of the CNT and the ideal processing ability and low cost of the polymer is in achieving a uniform dispersion of the filler in the polymer matrix. This body of work focuses on (1) techniques employed to disperse CNTs into a polymer matrix and (2) the effects of CNTs on the mechanical and electrical properties of the polymer. Poly (methyl methacrylate) (PMMA), an amorphous polymer, and poly (4-methyl-1-pentene) (P4M1P), a semi crystalline polymer, were chosen as the matrices. Non-functionalized single-walled carbon nanotubes and soot (unpurified carbon nanotubes) were chosen as the filler material.
Book Synopsis Multiwalled Carbon Nanotube Films by : John Lucien Rigueur
Download or read book Multiwalled Carbon Nanotube Films written by John Lucien Rigueur and published by . This book was released on 2012 with total page 133 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbon Nanotubes written by Andy Nieto and published by CRC Press. This book was released on 2021-05-18 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt: This discovery of carbon nanotubes (CNT) three decades ago ushered in the technological era of nanotechnology. Among the most widely studied areas of CNT research is their use as structural reinforcements in composites. This book describes the development of CNT reinforced metal matrix composites (CNT-MMCs) over the last two decades. The field of CNT-MMCs is abundant in fundamental science, rich in engineering challenges and innovations and ripe for technological maturation and commercialization. The authors have sought to present the current state of the-art in CNT-MMC technology from their synthesis to their myriad potential end-use applications. Specifically, topics explored include: • Advantages, limitations, and evolution of processing techniques used to synthesize and fabricate CNT-MMCs • Emphasizes dispersion techniques of CNTs in metallic systems, a key challenge to the successful and widespread implementation of CNT-MMCs. Methods for quantification and improved control of CNT distributions are presented • Methods for quantification and improved control of CNT distributions are presented • Characterization techniques uniquely suited for charactering these nanoscale materials and their many chemical and physical interactions with the metal matrix, including real-time in-situ characterization of deformation mechanisms • Electron microscope images from premier studies enrich discussions on micro-mechanical modeling, interfacial design, mechanical behavior, and functional properties • A chapter is dedicated to the emergence of dual reinforcement composites that seek to enhance the efficacy of CNTs and lead to material properties by design This book highlights seminal findings in CNT-MMC research and includes several tables listing processing methods, associated CNT states, and resulting properties in order to aid the next generation of researchers in advancing the science and engineering of CNT-MMCs. In addition, a survey of the patent literature is presented in order to shed light on what the first wave of CNT-MMC commercialization may look like and the challenges that will have to be overcome, both technologically and commercially.
