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Excited State Properties Of Transition Metal Complexes In Solution And The Solid State
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Book Synopsis Excited-state Properties of Transition-metal Complexes in Solution and the Solid State by : Mark David Newsham
Download or read book Excited-state Properties of Transition-metal Complexes in Solution and the Solid State written by Mark David Newsham and published by . This book was released on 1988 with total page 540 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Photochemistry and Photophysics of Coordination Compounds by : Hartmut Yersin
Download or read book Photochemistry and Photophysics of Coordination Compounds written by Hartmut Yersin and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Seventh International Symposium on the Photochemistry and Photophysics of Coordination Compounds Elmau/FRG, March 29-April 2, 1987
Book Synopsis Electronic structure and excited state properties of some transition metal complexes having a lowest energy metal to ligand charge transfer state by : Peter C. Servaas
Download or read book Electronic structure and excited state properties of some transition metal complexes having a lowest energy metal to ligand charge transfer state written by Peter C. Servaas and published by . This book was released on 1991 with total page 101 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Excited States Of Transition Elements - Proceedings Of The 2nd International School by : Strek W
Download or read book Excited States Of Transition Elements - Proceedings Of The 2nd International School written by Strek W and published by World Scientific. This book was released on 1992-09-30 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the recent advances in spectroscopy and theoretical modeling relevant to the interpretation of luminescence and laser phenomena in solid state materials. The available solid state matrices in crystalline and glassy states and the full range of activaters-transition metal ions, rare earth ions and actinides are considered here. Processes of activator excitation, energy transfer between activators and relaxation of excited states are particularly stressed.
Book Synopsis Solid Compounds of Transition Elements by : Jean Louis Bobet
Download or read book Solid Compounds of Transition Elements written by Jean Louis Bobet and published by Trans Tech Publications Ltd. This book was released on 2011-04-19 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume is indexed by Thomson Reuters CPCI-S (WoS). This special collection gathers together the newest results on novel classes of materials which contain transition metals. It covers crystal chemistry, chemical bonding and electronic structure, magnetic and electron transport properties, thermo-electrics, hydrides, borides, carbides, silicides, germanides, pnictides, chalcogenides and complexes, metallic alloys and oxides. It will of interest to all those who work with transition metals.
Book Synopsis Excited State Processes in Transition Metal Complexes by :
Download or read book Excited State Processes in Transition Metal Complexes written by and published by . This book was released on 1992 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: In our research there were two major themes. The first was the continued development of excited states as sensitizers. In one sequence of experiments the synthetic aspects of this area were developed in further detail both by extending the chemistry of the polypyridyl-accepting ligands associated with the excited state and by developing a new procedure for the preparation of unsymmetrical tris-chelate complexes. The second important aspect of this work was the continued investigation of the molecular and electronic structure characteristics of this class of excited states and how those factors determine such properties as photostability and excited state decay. This effort was extended to complexes of Re(I) and an examination of their excited state characteristics, the role of hydride ligand in determining the properties of excited states, the calculation of relative nonradiative decay rate constants for a series of complexes of Ru(II), the participation of higher lying excited states in decay in complexes of Ru(II) and Os(II), and the application of the transient infrared technique to the elucidation of a photochemical intermediate following laser flash excitation. The second area of study involved excited states in soluble polymers to investigate photoinduced electron and energy transfer in multi-component assemblies. This work was based on chemically derivatized polystyrene polymers which contain combinations of chromophores and electron or energy transfer quenchers.
Book Synopsis Organometallic Photochemistry by : Gregory L. Geoffroy
Download or read book Organometallic Photochemistry written by Gregory L. Geoffroy and published by . This book was released on 1979 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic Photochemistry explores the photochemical properties of transition-metal organometallic complexes, such as metal carbonyls, olefin complexes, arene complexes, and cyclopentadienyl complexes. Isocyanide complexes, hydride complexes, and alkyl complexes are also covered. This book consists of eight chapters and begins with an overview of organometallic complexes and their electronic structure, along with the principles of photochemistry. The chapters that follow are detailed reviews of photochemical studies organized according to type of organometallic. Each chapter is organized a ...
Book Synopsis A Textbook of Inorganic Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Book Synopsis Solid-State Properties of Transition Metal Complexes by : L. V. Interrante
Download or read book Solid-State Properties of Transition Metal Complexes written by L. V. Interrante and published by . This book was released on 1975 with total page 69 pages. Available in PDF, EPUB and Kindle. Book excerpt: The report describes the work on solid-state properties of transition metal complexes. Several different types of transition metal complex systems with anisotropic solid-state interactions have been prepared and studied using electrical conductivity, magnetic susceptibility, and spectral measurement methods. The results of these measurements and accompanying x-ray structural studies have been used to derive structure-property relationships and to obtain information regarding the nature of the intermolecular interactions occurring in the solid state.
Book Synopsis Electronic Excited State Properties of Transition-metal Complexes Studied by Time-resolved Raman Spectroscopy and Optical Spectroscopy by : Jing-Huei Perng
Download or read book Electronic Excited State Properties of Transition-metal Complexes Studied by Time-resolved Raman Spectroscopy and Optical Spectroscopy written by Jing-Huei Perng and published by . This book was released on 1989 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transition Metals in Coordination Environments by : Ewa Broclawik
Download or read book Transition Metals in Coordination Environments written by Ewa Broclawik and published by Springer. This book was released on 2019-03-16 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book focuses on the electronic properties of transition metals in coordination environments. These properties are responsible for the unique and intricate activity of transition metal sites in bio- and inorganic catalysis, but also pose challenges for both theoretical and experimental studies. Written by an international group of recognized experts, the book reviews recent advances in computational modeling and discusses their interplay using experiments. It covers a broad range of topics, including advanced computational methods for transition metal systems; spectroscopic, electrochemical and catalytic properties of transition metals in coordination environments; metalloenzymes and biomimetic compounds; and spin-related phenomena. As such, the book offers an invaluable resource for all researchers and postgraduate students interested in both fundamental and application-oriented research in the field of transition metal systems.
Book Synopsis Macromolecules Incorporating Transition Metals by : Alaa S Abd-El-Aziz
Download or read book Macromolecules Incorporating Transition Metals written by Alaa S Abd-El-Aziz and published by Royal Society of Chemistry. This book was released on 2018-02-01 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: New materials are required to solve global challenges such as the growing energy demand and reducing the threat of new and re-emerging diseases and infections. Metallopolymers is an exciting and promising area of research and this book focuses on the strategy of incorporating transition metals into macromolecules to design functional materials for addressing such problems. The book starts with an introduction to current global challenges and the role of materials science in tackling these, it then discusses the fundamentals of metallopolymers and their synthesis. The final chapters look at specific applications of the materials from photovoltaics and light-emitting diodes for energy conservation, to biological sensors and drug delivery platforms. Written by leading experts in the field, this book is an ideal reference for students and researchers working in polymer chemistry, organometallic chemistry and materials science interested in both the polymers and their applications in energy and health.
Book Synopsis Spin States in Biochemistry and Inorganic Chemistry by : Marcel Swart
Download or read book Spin States in Biochemistry and Inorganic Chemistry written by Marcel Swart and published by John Wiley & Sons. This book was released on 2015-09-17 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.
Book Synopsis Spectroscopic Studies of Excited State Potential Energy Surfaces of Transition Metal Complexes by : Randall Brian Wilson
Download or read book Spectroscopic Studies of Excited State Potential Energy Surfaces of Transition Metal Complexes written by Randall Brian Wilson and published by . This book was released on 1979 with total page 712 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Photophysics of Organometallics by : Alistair J. Lees
Download or read book Photophysics of Organometallics written by Alistair J. Lees and published by Springer. This book was released on 2012-05-04 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Arvind Kumar, Shih-Sheng Sun, and Alistair J. Lees: Photophysics and Photochemistry of Organometallic Rhenium Diimine Complexes; Conor Long: Photophysics of CO Loss from Simple Metal Carbonyl Complexes; Antonín Vlcek Jr: Ultrafast Excited-State Processes in Re(I) Carbonyl-Diimine Complexes: From Excitation to Photochemistry; Kenneth Kam-Wing Lo: Exploitation of Luminescent Organometallic Rhenium(I) and Iridium(III) Complexes in Biological Studies; Maria L. Muro , Aaron A. Rachford , Xianghuai Wang, and Felix N. Castellano: Platinum II Acetylide Photophysics; Andreas F. Rausch, Herbert H. H. Homeier, and Hartmut Yersin: Organometallic Pt(II) and Ir(III) Triplet Emitters for OLED Applications and the Role of Spin–Orbit Coupling: A Study Based on High-Resolution Optical Spectroscopy.
Book Synopsis Fundamentals of Inorganic and Organometallic Polymer Science by : Christian Agatemor
Download or read book Fundamentals of Inorganic and Organometallic Polymer Science written by Christian Agatemor and published by Royal Society of Chemistry. This book was released on 2023-09-04 with total page 227 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis An Investigation of the Photochemical and Excited State Properties of Selected Second and Third Row Transition Metal Complexes by : Gregory L. Geoffroy
Download or read book An Investigation of the Photochemical and Excited State Properties of Selected Second and Third Row Transition Metal Complexes written by Gregory L. Geoffroy and published by . This book was released on 1974 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt:
