Emulsions: Structure, Stability and Interactions

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Author :
Publisher : Elsevier
ISBN 13 : 9780080472652
Total Pages : 780 pages
Book Rating : 4.4/5 (726 download)

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Book Synopsis Emulsions: Structure, Stability and Interactions by : Dimiter N. Petsev

Download or read book Emulsions: Structure, Stability and Interactions written by Dimiter N. Petsev and published by Elsevier. This book was released on 2004-10-14 with total page 780 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions: Structure, Stability and Interactions is the perfect handbook for scientists looking to obtain up-to-date knowledge about the fundamentals of emulsion science, and those looking to familiarize themselves with the subject in greater detail. As a ‘stand-alone’ source of information, it is also ideal for solving the practical issues encountered daily in the field of emulsion science. While each chapter presents a concise review on a specific topic, the book offers a consistent presentation of the important physical concepts relevant to emulsions. Some of the topics covered include statistical mechanics of fluid interfaces, the structure of fluid interfaces determined by neutron scattering, hydrodynamic interactions and stability of emulsion films, theory of emulsion flocculation, coalescence kinetics of Brownian emulsions, and Brownian dynamics simulation of emulsion stability. Full and comprehensive presentations Rigorous approach to each topic, providing in-depth information Acts as a 'stand-alone' source of information

Modern Aspects of Emulsion Science

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 0854044396
Total Pages : 56 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis Modern Aspects of Emulsion Science by : Bernard P. Binks

Download or read book Modern Aspects of Emulsion Science written by Bernard P. Binks and published by Royal Society of Chemistry. This book was released on 1998 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions occur either as end products or during the processing of products in various areas, including the food, agrochemical, pharmaceutical, paint & oil industries. Despite over one hundred years of research in the subject, however, a quantitative understanding of emulsions has been lacking. Modern Aspects of Emulsion Science presents a comprehensive description of the scientific principles in the field & the very latest advances in research in this important area of surface & colloid science. Topics covered include emulsion formation, type, stability (creaming, flocculation, ripening, coalescence), monodisperse & gel emulsions, & applications. Emphasis has been placed on relating the chemistry of the surfactant or protein adsorbed at the oil-water interface to the principles of the physics involved in the bulk emulsion property. The book has been written by leading experts in the field & covers both experimental & theoretical approaches. The only book in print on this topic, it will prove essential reading for graduate students & researchers in industry. Contents: Emulsions - Recent Advances in Understanding.- Emulsion Formation.- Emulsion Formation by Nucleation & Growth Mechanisms.- Emulsion Flocculation & Creaming.- Rheology of Emulsions - The Relationship to Structure & Stability.- Phase Inversion & Drop Formation in Agitated Liquid-Liquid Dispersions in the Presence of Nonionic Surfactants.- Coalescence in Emulsions.- Lifetime & Destruction of Concentrated Emulsions Undergoing Coalescence.- Molecular Diffusion in Emulsions & Emulsion Mixtures.- Interactions & Macroscopic Properties of Emulsions & Microemulsions.- Gel Emulsions - Relationship between Phase Behaviour & Formation.- Applications of Emulsions.- Subject Index.

Emulsions

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110452243
Total Pages : 242 pages
Book Rating : 4.1/5 (14 download)

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Book Synopsis Emulsions by : Tharwat F. Tadros

Download or read book Emulsions written by Tharwat F. Tadros and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-03-21 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chapter 1 General Introduction Definition of emulsions and the role of the emulsifier. Classification based on the nature of the emulsifier. Classification based on the structure of the system. General instability problems with emulsions : creaming/sedimentation, flocculation, Ostwald ripening, coalescence and phase inversion. Importance of emulsions in various industrial applications. Chapter 2 Thermodynamics of Emulsion Formation and Breakdown Application of the second law of thermodynamics for emulsion formation : Balance of energy and entropy and non-spontaneous formation of emulsions. Breakdown of the emulsion by flocculation and coalescence in the absence of an emulsifier. Role of the emulsifier in preventing flocculation and coalescence by creating an energy barrier resulting from the repulsive energies between the droplets. Chapter 3 Interaction Forces between Emulsion Droplets Van der Waals attraction and its dependence on droplet size, Hamaker constant and separation distance between the droplets. Electrostatic repulsion resulting from the presence of electrical double layers and its dependence on surface (or zeta) potential and electrolyte concentration and valency. Combination of the van der Waals attraction with double layer repulsion and the theory of colloid stability. Steric repulsion resulting from the presence of adsorbed non-ionic surfactants and polymers. Combination of van der Waals attraction with steric repulsion and the theory of steric stabilisation. Chapter 4 Adsorption of Surfactants at the Oil/Water Interface Thermodynamic analysis of surfactant adsorption and the Gibbs adsorption isotherm. Calculation of the amount of surfactant adsorption and area per surfactant molecule at the interface. Experimental techniques for measuring the interfacial tension. Chapter 5 Mechanism of Emulsification and the Role of the Emulsifier Description of the factors responsible for droplet deformation and its break-up. Role of surfactant in preventing coalescence during emulsification. Definition of the Gibbs dilational elasticity and the Marangoni effect in preventing coalescence. Chapter 6 Methods of Emulsification Pipe flow, static mixers and high speed stirrers (rotor-stator mixer). Laminar and turbulent flow. Membrane emulsification. High pressure homogenisers and ultrasonic methods. Chapter 7 Selection of Emulsifiers The hydrophilic-lipophilic-balance (HLB) and its application in surfactant selection. Calculation of HLB numbers and the effect of the nature of the oil phase. The phase inversion temperature (PIT) method for emulsifier selection. The cohesive energy ratio method for emulsifier selection. Chapter 8 Creaming/Sedimentation of Emulsions and its prevention Driving force for creaming/sedimentation: effect of gravity, droplet size and density difference between the oil and continuous phase. Calculation of the rate of creaming/sedimentation in dilute emulsions. Influence of increase of the volume fraction of the disperse phase on the rate of creaming/sedimentation. Reduction of creaming/sedimentation: Balance of the density of the two phases, reduction of droplet size and effect of addition of ''thickeners'. Chapter 9 Flocculation of Emulsions and its Prevention Factors affecting flocculation. Calculation of fast and slow flocculation rate. Definition of stability ratio and its dependence on electrolyte concentration and valency. Definition of the critical coagulation concentration and its dependence on electrolyte valency. Reduction of flocculation by enhancing the repulsive forces. Chapter 10 Ostwald Ripening and its Reduction Factors responsible for Ostwald ripening : difference in solubility between small and large droplets and the Kelvin equation. Calculation of the rate of Ostwald ripening. Reduction of Ostwald ripening by incorporation of a small amount of highly insoluble oil. Reduction of Ostwald ripening by the use of strongly adsorbed polymeric surfactant and enhancement of the Gibbs elasticity. Chapter 11 Emulsion Coalescence and its Prevention Driving force for emulsion coalescence : Thinning and disruption of the liquid film between the droplets. The concept of disjoining pressure for prevention of coalescence. Methods for reduction or elimination of coalescence : Use of mixed surfactant films, use of lamellar liquid crystalline phases and use of polymeric surfactants. Chapter 12 Phase Inversion and its Prevention Distinction between catastrophic and transient phase inversion. Influence of the disperse volume fraction and surfactant HLB number. Explanation of the factors responsible for phase inversion. Chapter 13 Characterisation of Emulsions Measurement of droplet size distribution : Optical microscopy and image analysis. Phase contrast and polarising microscopyDiffraction methods. Confocal laser microscopy. Back scattering methods Chapter 14 Industrial Application of Emulsions 14.1 Application in Pharmacy 14.2 Application in Cosmetics 14.3 Application in Agrochemicals 14.4 Application in Paints 14.5 Application in the Oil Industry

Emulsion Formation and Stability

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527647961
Total Pages : 283 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Emulsion Formation and Stability by : Tharwat F. Tadros

Download or read book Emulsion Formation and Stability written by Tharwat F. Tadros and published by John Wiley & Sons. This book was released on 2013-06-04 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of emulsification techniques, their use in the production of nanoparticles for biomedical applications as well as application of rheological techniques for studying the interaction between the emulsion droplets is gathered in this reference work. Written by some of the top scientists within their respective fields, this book covers such topics as emulsions, nano-emulsions, nano-dispersions and novel techniques for their investigation. It also considers the fundamental approach in areas such as controlled release, drug delivery and various applications of nanotechnology.

Emulsions

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311045226X
Total Pages : 242 pages
Book Rating : 4.1/5 (14 download)

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Book Synopsis Emulsions by : Tharwat F. Tadros

Download or read book Emulsions written by Tharwat F. Tadros and published by Walter de Gruyter GmbH & Co KG. This book was released on 2016-03-21 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions provides a general introduction, the industrial role of emulsifiers and addresses different problems such as creaming/sedimentation, flocculation, Ostwald ripening, coalescence and phase inversion. Thermodynamics, adsorption and interaction forces between emulsion droplets are thoroughly explained. Supplemented by many figures and tables, it helps to characterize and select the right emulsifier for various industrial applications.

Emulsions and Emulsion Stability

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Author :
Publisher : CRC Press
ISBN 13 : 1420028081
Total Pages : 684 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Emulsions and Emulsion Stability by : Johan Sjoblom

Download or read book Emulsions and Emulsion Stability written by Johan Sjoblom and published by CRC Press. This book was released on 2005-11-21 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions and Emulsion Stability, Second Edition provides comprehensive coverage of both theoretical and practical aspects of emulsions. The book presents fundamental concepts and processes in emulsified systems, such as flocculation, coalescence, stability, precipitation, deposition, and the evolution of droplet size distribution. The bo

Multiple Emulsion

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Publisher : John Wiley & Sons
ISBN 13 : 047017093X
Total Pages : 352 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Multiple Emulsion by : Abraham Aserin

Download or read book Multiple Emulsion written by Abraham Aserin and published by John Wiley & Sons. This book was released on 2007-11-12 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Comprehensive, Single-Source Reference on Multiple Emulsions In theory, multiple emulsions have significant potential for breakthrough applications in food, agricultural, pharmaceutical, nutraceutical, and cosmetic industries in which they can facilitate the sustained release and transport of active material. However, in practice, multiple emulsions are thermodynamically unstable. This book presents recent findings that can help formulators understand how to enhance their stability. With chapters contributed by leading experts from around the world, it covers the definition and properties of multiple emulsions, their formation and stability, and potential applications, with an emphasis on medical and pharmaceutical applications. In one definitive resource, it presents recent findings and achievements in the field, including: New theoretical approaches and modeling to characterize the transport mechanism Droplet size reduction and increased shelf life stability through the use of polymeric amphiphiles and complex adducts The use of new emulsification techniques to enhance the monodispersibility of the droplets Potential applications in drug delivery systems where clinical studies have proven their efficacy This is a core, hands-on reference for surface and colloid scientists, physical chemists, chemical engineers, soft materials scientists, food chemists, controlled release scientists, and pharmaceutical scientists in drug delivery applications, as well as for graduate students in these disciplines. The editor and contributors hope this logical consolidation of current information will further the understanding of multiple emulsions and lead to new, practical applications.

Supercooling, Crystallization and Melting within Emulsions and Divided Systems

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Author :
Publisher : Bentham Science Publishers
ISBN 13 : 168108130X
Total Pages : 300 pages
Book Rating : 4.6/5 (81 download)

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Book Synopsis Supercooling, Crystallization and Melting within Emulsions and Divided Systems by : Danièle Clausse

Download or read book Supercooling, Crystallization and Melting within Emulsions and Divided Systems written by Danièle Clausse and published by Bentham Science Publishers. This book was released on 2016-04-26 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions (simple, mixed or multiple) are essentially pure substances, aqueous or organic binary solutions. The have a wide range of uses, including industrial cooling and heat transfer processes. This monograph gives a brief overview of supercooling, crystallization and melting processes within emulsions. Differential scanning calorimetrey (DSC) coupled with RX is the main technique used to demonstrate these processes. Temperature readings in this work have been defined taking into account known nucleation laws. These results have been used to show mass transfers occurring within mixed emulsions (solid ripening) or multiple emulsions (composition ripening), gas hydrate formation due to a chemical reaction between water and a diffuse specific compound, these phenomena being described by diffusive models. Other aspects of heat transfer process covered in this book include the latent energy released at crystallizations or absorbed at the melting (which alters the temperature field through emulsions), the kinetics of phase transformations and self-regulation of temperature in nodules containing phase changing materials. This monograph is intended for advanced chemistry graduates as well as industrial and chemical engineers working with cooling and heat transfer systems.

Emulsions and Emulsion Stability

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Author :
Publisher : CRC Press
ISBN 13 : 9780824726959
Total Pages : 0 pages
Book Rating : 4.7/5 (269 download)

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Book Synopsis Emulsions and Emulsion Stability by : Johan Sjoblom

Download or read book Emulsions and Emulsion Stability written by Johan Sjoblom and published by CRC Press. This book was released on 2005-11-21 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Emulsions and Emulsion Stability, Second Edition provides comprehensive coverage of both theoretical and practical aspects of emulsions. The book presents fundamental concepts and processes in emulsified systems, such as flocculation, coalescence, stability, precipitation, deposition, and the evolution of droplet size distribution. The book explains how to predict emulsion stability and determine droplet sizes in a variety of emulsion systems. It discusses spontaneous emulsification and the formation of “nanoemulsions” as well as droplet-droplet interactions in different electrical fields (electrocoalescence), and the formulation, composition, and preparation variables that contribute to the inversion in emulsion systems. Several chapters emphasize applications such as emulsification encountered in oil spills, asphalt, chemical flooding, acid crude oils, and large-scale industrial wastewater treatment. The survey of experimental characterization methods highlights the importance of thin liquid films in colloidal systems and assesses different NMR applications, ultrasound characterization, video microscopy, and other on-line instrumentation. The last chapter in the book deals with obtaining conductivity measurements as an alternative to online instrumentation. Completely revised and expanded, this second edition of Emulsions and Emulsion Stability offers a well-rounded collection of knowledge that is applicable to all academic and industrial scientists and researchers in the fields of surfactant and emulsion science.

Surface Complexation Modelling

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Publisher : Elsevier
ISBN 13 : 0080467784
Total Pages : 653 pages
Book Rating : 4.0/5 (84 download)

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Book Synopsis Surface Complexation Modelling by : Johannes Lutzenkirchen

Download or read book Surface Complexation Modelling written by Johannes Lutzenkirchen and published by Elsevier. This book was released on 2006-09-02 with total page 653 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface Complexation Modelling deals with various aspects associate to the modelling of solutes adsorption from of solutes from aqueous solutions to minerals. The individual contributions cover fundamental aspects and applications. Applications cover case studies and present consistent surface complexation parameter sets. The model approaches range from simplistic to mechanistic. More fundamental contributions address underlying phenomena or stress the opportunities of modern computational methods. Several mineral systems are covered, including goethite, gibbsite, clay minerals etc.Surface Complexation Modelling presents the state-of-the-art of surface complexation modelling and suggests ideas for further model development. A number of chapters are authored by scientists working on nuclear waste storage, where the retention of radionuclides contributes to preventing radionuclide migration from the repository to the biosphere. Other contributions come from soil and environmental chemists with an interest in reactive transport of pollutants in soils or aquifers. Covering a wide range of disciplines Bringing together contributions from experts in the field Providing a balance between the theoretical and applied aspects

Rheology of Emulsions

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Publisher : Academic Press
ISBN 13 : 0128138378
Total Pages : 188 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Rheology of Emulsions by : Aleksandar M. M. Spasic

Download or read book Rheology of Emulsions written by Aleksandar M. M. Spasic and published by Academic Press. This book was released on 2018-04-26 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rheology of Emulsions, Volume 22: Electrohydrodynamics Principles studies phenomena at liquid-liquid interfaces, including finely dispersed particles or structures, in particular emulsions, double emulsions and biological cells. The book considers the forces of electrical origin that participate in the physical events at liquid-liquid interfaces, taking into account electron transfer phenomenon and electrodynamics principles. Topics covered are of interest to a broad range of scientists, researchers and graduate students with a basic knowledge of physical chemistry, electromagnetism, fluid mechanics, classical and quantum electrodynamics. The implications and applications of the material presented in the book contribute to the advanced fundamental, applied and engineering research of interfacial electroviscoelastic phenomena. Features a multidisciplinary approach to electron transfer phenomena Introduces a new constitutive model of liquids and a theory of electroviscoelasticity Addresses a broad range of subject field examples that make it useful to various research communities

Emulsions

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Publisher : Springer Science & Business Media
ISBN 13 : 9780792316183
Total Pages : 322 pages
Book Rating : 4.3/5 (161 download)

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Book Synopsis Emulsions by : Johan Sjöblom

Download or read book Emulsions written by Johan Sjöblom and published by Springer Science & Business Media. This book was released on 1992 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fundamental side of this book covers general aspects of stability, interfacial adsorption mechanisms, interfacial rheology, direct measurements of surface forces and the bulk rheological properties of emulsions, and self-diffusion properties as measured by NMR. The applications side covers the fields of food, crude oil and pharmaceutical emulsions. A central topic in the study of food emulsions is the role played by proteins at the water/oil interface, their conformations, and the mechanism by which they can be replaced at the interface (competitive adsorption).

Surface Chemistry in Biomedical and Environmental Science

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Publisher : Springer Science & Business Media
ISBN 13 : 140204741X
Total Pages : 459 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Surface Chemistry in Biomedical and Environmental Science by : Jonathan P. Blitz

Download or read book Surface Chemistry in Biomedical and Environmental Science written by Jonathan P. Blitz and published by Springer Science & Business Media. This book was released on 2006-09-09 with total page 459 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume holds a special niche in describing the current state of the art in the fundamentals and applications of a variety of nanomaterials. A common theme throughout much of this volume involves adsorption and interfacial behavior of nanomaterials. The book provides a useful mixture of reviews and primary research from leading laboratories and offers a unique blend of East European and Western contributors.

Colloid and Interface Chemistry for Nanotechnology

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Publisher : CRC Press
ISBN 13 : 1466569069
Total Pages : 560 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Colloid and Interface Chemistry for Nanotechnology by : Peter Kralchevsky

Download or read book Colloid and Interface Chemistry for Nanotechnology written by Peter Kralchevsky and published by CRC Press. This book was released on 2016-04-19 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Colloid and interface science dealt with nanoscale objects for nearly a century before the term nanotechnology was coined. An interdisciplinary field, it bridges the macroscopic world and the small world of atoms and molecules. Colloid and Interface Chemistry for Nanotechnology is a collection of manuscripts reflecting the activities of research te

Analytical Techniques for Studying the Physical Properties of Lipid Emulsions

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Publisher : Springer Science & Business Media
ISBN 13 : 1461432553
Total Pages : 68 pages
Book Rating : 4.4/5 (614 download)

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Book Synopsis Analytical Techniques for Studying the Physical Properties of Lipid Emulsions by : Maria Herrera

Download or read book Analytical Techniques for Studying the Physical Properties of Lipid Emulsions written by Maria Herrera and published by Springer Science & Business Media. This book was released on 2012-03-07 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book will review old and new methods to study emulsion stability and structure. Examples of emulsion-based foods include ice cream, yoghurt, and mayonnaise. The physicochemical properties of emulsions play an important role in food systems, as they directly contribute to the texture, sensory and nutritional properties of foods. One of the main properties is stability, which refers to the ability of an emulsion to resist physical changes over time. The development of an effective strategy to prevent undesirable changes in the properties of a particular food emulsion depends on the dominant physicochemical mechanism(s) responsible for the changes. In practice, two or more of these mechanisms may operate in concert. It is therefore important for food scientists to identify the relative importance of each mechanism, the relationship between them, and the factors that influence them, so that effective means of controlling the stability and physicochemical properties of emulsions can be established. Several techniques are used to study the physical behavior and structure of emulsions. Each technique has its advantages and disadvantages and provides different insights into the destabilization mechanisms. Among the oldest methods used to study emulsion stability is visual observation and small deformation rheometry. More recently, other techniques, such as ultrasound profiling, microscopy, droplet size distribution, and measurement of surface concentration to characterize adsorbed protein at the interface, have also been employed. Some of these techniques, such as droplet size distribution, involve some form of dilution. However, dilution disrupts some structures that play an important role in stability. The ability to study the stability of food emulsions in their undiluted form may reveal subtle nuances about their stability. Diffusing wave spectroscopy (DWS), laser scanning confocal microscopy (LSCM), nuclear magnetic resonance (NMR), and Turbiscan are among the more powerful, non-perturbing techniques used to characterized emulsions.

Self-Assembly and Nanotechnology

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Publisher : John Wiley & Sons
ISBN 13 : 0470292512
Total Pages : 362 pages
Book Rating : 4.4/5 (72 download)

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Book Synopsis Self-Assembly and Nanotechnology by : Yoon S. Lee

Download or read book Self-Assembly and Nanotechnology written by Yoon S. Lee and published by John Wiley & Sons. This book was released on 2008-06-16 with total page 362 pages. Available in PDF, EPUB and Kindle. Book excerpt: Delivers comprehensive coverage of key subjects in self-assembly and nanotechnology, approaching these and related topics with one unified concept. Designed for students and professionals alike, it explores a variety of materials and situations in which the importance of self-assembly nanotechnology is growing tremendously. Provides clear schematic illustrations to represent the mainstream principles behind each topic.

Surfactants in Personal Care Products and Decorative Cosmetics

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Author :
Publisher : CRC Press
ISBN 13 : 1420016121
Total Pages : 504 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Surfactants in Personal Care Products and Decorative Cosmetics by : Linda D. Rhein

Download or read book Surfactants in Personal Care Products and Decorative Cosmetics written by Linda D. Rhein and published by CRC Press. This book was released on 2006-11-14 with total page 504 pages. Available in PDF, EPUB and Kindle. Book excerpt: From anti-aging creams to make-up, surfactants play a key role as delivery systems for skin care and decorative cosmetic products. Surfactants in Personal Care Products and Decorative Cosmetics, Third Edition presents a scientific basis in surfactant science and recent advances in the industry necessary for understanding, formulating, and te