Electrochemical Reactions And Mechanisms In Organic Chemistry

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Electrochemical Reactions and Mechanisms in Organic Chemistry

Author : J. Grimshaw
Publisher : Elsevier
ISBN 13 : 0080530729
Total Pages : 415 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Electrochemical Reactions and Mechanisms in Organic Chemistry by : J. Grimshaw

Download or read book Electrochemical Reactions and Mechanisms in Organic Chemistry written by J. Grimshaw and published by Elsevier. This book was released on 2000-12-01 with total page 415 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemical reactions make significant contributions to organic synthesis either in the laboratory or on an industrial scale. These methods have the potential for developing more "green" chemical synthesis. Over recent years, modern investigations have clarified the mechanisms of important organic electrochemical reactions. Progress has also been made in controlling the reactivity of intermediates through either radical or ionic pathways. Now is the time to gather all the electrochemical work into a textbook. As an essential addition to the armory of synthetic organic chemists, electrochemical reactions give results not easily achieved by many other chemical routes. This book presents a logical development of reactions and mechanisms in organic electrochemistry at a level suited to research scientists and final year graduate students. It forms an excellent starting point from which synthetic organic chemists, in both academia and industry, can appreciate uses for electrochemical methods in their own work. The book is also a reference guide to the literature.

The Investigation of Organic Reactions and Their Mechanisms

Author : Howard Maskill
Publisher : John Wiley & Sons
ISBN 13 : 0470994169
Total Pages : 392 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis The Investigation of Organic Reactions and Their Mechanisms by : Howard Maskill

Download or read book The Investigation of Organic Reactions and Their Mechanisms written by Howard Maskill and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 392 pages. Available in PDF, EPUB and Kindle. Book excerpt: A range of alternative mechanisms can usually be postulated for most organic chemical reactions, and identification of the most likely requires detailed investigation. Investigation of Organic Reactions and their Mechanisms will serve as a guide for the trained chemist who needs to characterise an organic chemical reaction and investigate its mechanism, but who is not an expert in physical organic chemistry. Such an investigation will lead to an understanding of which bonds are broken, which are made, and the order in which these processes happen. This information and knowledge of the associated kinetic and thermodynamic parameters are central to the development of safe, efficient, and profitable industrial chemical processes, and to extending the synthetic utility of new chemical reactions in chemical and pharmaceutical manufacturing, and academic environments. Written as a coherent account of the principal methods currently used in mechanistic investigations, at a level accessible to academic researchers and graduate chemists in industry, the book is highly practical in approach. The contributing authors, an international group of expert practitioners of the techniques covered, illustrate their contributions by examples from their own research and from the relevant wider chemical literature. The book covers basic aspects such as product analysis, kinetics, catalysis, and investigation of reactive intermediates. It also includes material on significant recent developments, e.g. computational chemistry, calorimetry, and electrochemistry, in addition to topics of high current industrial relevance, e.g. reactions in multiphase systems, and synthetically useful reactions involving free radicals and catalysis by organometallic compounds.

Fundamentals and Applications of Organic Electrochemistry

Author : Toshio Fuchigami
Publisher : John Wiley & Sons
ISBN 13 : 1118653173
Total Pages : 238 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis Fundamentals and Applications of Organic Electrochemistry by : Toshio Fuchigami

Download or read book Fundamentals and Applications of Organic Electrochemistry written by Toshio Fuchigami and published by John Wiley & Sons. This book was released on 2014-11-10 with total page 238 pages. Available in PDF, EPUB and Kindle. Book excerpt: This textbook is an accessible overview of the broad field of organic electrochemistry, covering the fundamentals and applications of contemporary organic electrochemistry. The book begins with an introduction to the fundamental aspects of electrode electron transfer and methods for the electrochemical measurement of organic molecules. It then goes on to discuss organic electrosynthesis of molecules and macromolecules, including detailed experimental information for the electrochemical synthesis of organic compounds and conducting polymers. Later chapters highlight new methodology for organic electrochemical synthesis, for example electrolysis in ionic liquids, the application to organic electronic devices such as solar cells and LEDs, and examples of commercialized organic electrode processes. Appendices present useful supplementary information including experimental examples of organic electrosynthesis, and tables of physical data (redox potentials of various organic solvents and organic compounds and physical properties of various organic solvents).

Basics of Electroorganic Synthesis

Author : Demetrios K. Kyriacou
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Basics of Electroorganic Synthesis by : Demetrios K. Kyriacou

Download or read book Basics of Electroorganic Synthesis written by Demetrios K. Kyriacou and published by John Wiley & Sons. This book was released on 1981 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Trends in Molecular Electrochemistry

Author : Armando J.L. Pombeiro
Publisher : CRC Press
ISBN 13 : 1482276526
Total Pages : 600 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Trends in Molecular Electrochemistry by : Armando J.L. Pombeiro

Download or read book Trends in Molecular Electrochemistry written by Armando J.L. Pombeiro and published by CRC Press. This book was released on 2004-09-13 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemists increasingly apply electrochemical methods to the investigation of their systems, in particular towards a better understanding of molecular properties, the exploration of chemical reactions involving electron-transfer (ET), the initiation of further reactions by ET, the kinetic measurements, and the establishment of the reaction mechanisms

Organic Electrochemistry

Author : Manuel M. Baizer
Publisher :
ISBN 13 :
Total Pages : 1192 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Organic Electrochemistry by : Manuel M. Baizer

Download or read book Organic Electrochemistry written by Manuel M. Baizer and published by . This book was released on 1983 with total page 1192 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Anodic Oxidation

Author : Sidney D. Ross
Publisher : Elsevier
ISBN 13 : 1483219860
Total Pages : 353 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Anodic Oxidation by : Sidney D. Ross

Download or read book Anodic Oxidation written by Sidney D. Ross and published by Elsevier. This book was released on 2013-10-22 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Anodic Oxidation covers the application of the concept, principles, and methods of electrochemistry to organic reactions. This book is composed of two parts encompassing 12 chapters that consider the mechanism of anodic oxidation. Part I surveys the theory and methods of electrochemistry as applied to organic reactions. These parts also present the mathematical equations to describe the kinetics of electrode reactions using both polarographic and steady-state conditions. Part II examines the anodic oxidation of organic substrates by the functional group initially attacked. This part particularly emphasizes the kinds of intermediates generated and the mechanisms leading to final products. This book is intended primarily to organic chemists and physical electrochemists.

Electron Transfer Reactions in Organic Chemistry

Author : Lennart Eberson
Publisher : Springer Science & Business Media
ISBN 13 : 3642725449
Total Pages : 245 pages
Book Rating : 4.6/5 (427 download)

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Book Synopsis Electron Transfer Reactions in Organic Chemistry by : Lennart Eberson

Download or read book Electron Transfer Reactions in Organic Chemistry written by Lennart Eberson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 245 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject of the book is electron transfer reactions in organic chemistry, with the emphasis on mechanistic aspects. The theoretical framework is that of the Marcus theory, well-known from its extensive use in inorganic chemistry. The book deals with definitions of electron transfer, theory of electron transfer reactions (Marcus' and Pross-Shaik's approach) experimental diagnosis of electron transfer reactions, examples from inorganic/organic reactants and purely organic reactants, electro- and photochemical electron transfer, electron transfer catalyzed reactions, connections between electron transfer and polar mechanisms, and applications of electron transfer, such as electrosynthesis of organic chemicals, photochemical energy storage, conducting organic materials and chemiluminescence. The approach is new in so far as no comparable book has been published. The book will be of value to anyone interested in keeping track of developments in physical organic chemistry.

Introduction to Organic Electrochemistry

Author : M. R. Rifi
Publisher :
ISBN 13 :
Total Pages : 442 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Introduction to Organic Electrochemistry by : M. R. Rifi

Download or read book Introduction to Organic Electrochemistry written by M. R. Rifi and published by . This book was released on 1974 with total page 442 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Strategies and Solutions to Advanced Organic Reaction Mechanisms

Author : Andrei Hent
Publisher : Academic Press
ISBN 13 : 0128128232
Total Pages : 884 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Strategies and Solutions to Advanced Organic Reaction Mechanisms by : Andrei Hent

Download or read book Strategies and Solutions to Advanced Organic Reaction Mechanisms written by Andrei Hent and published by Academic Press. This book was released on 2019-06-15 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strategies and Solutions to Advanced Organic Reaction Mechanisms: A New Perspective on McKillop's Problems builds upon Alexander (Sandy) McKillop's popular text, Solutions to McKillop's Advanced Problems in Organic Reaction Mechanisms, providing a unified methodological approach to dealing with problems of organic reaction mechanism. This unique book outlines the logic, experimental insight and problem-solving strategy approaches available when dealing with problems of organic reaction mechanism. These valuable methods emphasize a structured and widely applicable approach relevant for both students and experts in the field. By using the methods described, advanced students and researchers alike will be able to tackle problems in organic reaction mechanism, from the simple and straight forward to the advanced. Provides strategic methods for solving advanced mechanistic problems and applies those techniques to the 300 original problems in the first publication Replaces reliance on memorization with the understanding brought by pattern recognition to new problems Supplements worked examples with synthesis strategy, green metrics analysis and novel research, where available, to help advanced students and researchers in choosing their next research project

Organic Electrochemistry

Author : Ole Hammerich
Publisher : CRC Press
ISBN 13 : 142008402X
Total Pages : 1706 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Organic Electrochemistry by : Ole Hammerich

Download or read book Organic Electrochemistry written by Ole Hammerich and published by CRC Press. This book was released on 2015-09-22 with total page 1706 pages. Available in PDF, EPUB and Kindle. Book excerpt: Praise for the Fourth Edition"Outstanding praise for previous editions.the single best general reference for the organic chemist."-Journal of the Electrochemical Society"The cast of editors and authors is excellent, the text is, in general, easily readable and understandable, well documented, and well indexed those who purchase the book will be sa

Modern Electroorganic Chemistry

Author : Demetrios K. Kyriacou
Publisher : Springer
ISBN 13 :
Total Pages : 250 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Modern Electroorganic Chemistry by : Demetrios K. Kyriacou

Download or read book Modern Electroorganic Chemistry written by Demetrios K. Kyriacou and published by Springer. This book was released on 1994 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthetic Organic Electrochemistry

Author : Albert J. Fry
Publisher : HarperCollins Publishers
ISBN 13 :
Total Pages : 364 pages
Book Rating : 4.:/5 (44 download)

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Book Synopsis Synthetic Organic Electrochemistry by : Albert J. Fry

Download or read book Synthetic Organic Electrochemistry written by Albert J. Fry and published by HarperCollins Publishers. This book was released on 1972 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: An introduction to electrochemical methods and their use in the synthetic laboratory. Covers the major organic electrochemical pathways of synthetic interest, while de-emphasizing the mechanistic literature. For each functional group covered, the essential features of its electrochemical behavior are outlined, including the presumed intermediates. This Second Edition has been revised, covering the literature through early 1988, and presents useful electrochemical reactions superior to, and, in some cases, without counterparts in, conventional chemical methods.

Electrochemical Reactions in Nonaqueous Systems

Author : Charles Kenneth Mann
Publisher :
ISBN 13 :
Total Pages : 584 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Electrochemical Reactions in Nonaqueous Systems by : Charles Kenneth Mann

Download or read book Electrochemical Reactions in Nonaqueous Systems written by Charles Kenneth Mann and published by . This book was released on 1970 with total page 584 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Electrochemistry

Author : Cynthia G. Zoski
Publisher : Elsevier
ISBN 13 : 0444519580
Total Pages : 935 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Handbook of Electrochemistry by : Cynthia G. Zoski

Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS)

Author : Sean James Ashton
Publisher : Springer Science & Business Media
ISBN 13 : 3642305504
Total Pages : 234 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS) by : Sean James Ashton

Download or read book Design, Construction and Research Application of a Differential Electrochemical Mass Spectrometer (DEMS) written by Sean James Ashton and published by Springer Science & Business Media. This book was released on 2012-07-11 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sean Ashton's doctoral thesis, which he finished at the Technical University in Munich, describes the challenge of constructing a Differential Electrochemical Mass Spectrometer instrument (DEMS). DEMS combines an electrochemical cell with mass spectrometry via a membrane interface, allowing gaseous and volatile electrochemical reaction species to be monitored online. The thesis carefully introduces the fuel cell electrocatalyst development concerns before reviewing the pertinent literature on DEMS. This is followed by the presentation and discussion of the new extended design, including a thorough characterization of the instrument. The capabilities of the new setup are demonstrated in two research studies: The methanol oxidation reaction on Pt and PtRu catalysts, and the electrochemical corrosion of fuel cell catalyst supports. Despite both topics having long since been studied, new insights can be obtained through careful investigations with the new DEMS instrument that are of great, general interest. The thesis and the instrument thus show the way for future investigations in the field.

Electrochemistry in Ionic Liquids

Author : Angel A. J. Torriero
Publisher : Springer
ISBN 13 : 3319151320
Total Pages : 275 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Electrochemistry in Ionic Liquids by : Angel A. J. Torriero

Download or read book Electrochemistry in Ionic Liquids written by Angel A. J. Torriero and published by Springer. This book was released on 2015-07-17 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a set of two books dedicated to presenting the latest novel and advanced research from around the world in this exciting area. These books highlight the important properties of electrochemistry in ionic liquids – as opposed to the more commonly used aqueous and organic environments – and the many applications. Readers will find 20 chapters gathered in two books : Electrochemistry in Ionic Liquids – Volume 1, Fundamentals: This book critically discusses electrode-electrolyte interfacial processes, reference electrodes, ultramicroelectrode voltammetry and scanning electrochemical microscopy, semi-integral and convolution voltammetry, and small-angle X-ray scattering coupled with voltammetry. The structure and properties of protic ionic liquids, deep-eutectic solvents, task-specific ionic liquids, polymeric ion gels, and lithium-ion solvation, useful for electrochemical application is also critically discussed. Electrochemistry in Ionic Liquids – Volume 2, Applications: The major topics covered in this book include electrodeposition and electroless deposition, voltammetry of adhered microparticles, electrochemistry of organic and organometallic compounds, electrocatalytic reactions, oxygen reduction reaction, ionic liquids in surface protection and lubrication, current industrial application of ionic liquids, and challenges, issues and recycling methods of ionic liquids in industrial developments.