Effects of Heterogeneity on Reactive Transport in Geologic Media

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ISBN 13 :
Total Pages : 414 pages
Book Rating : 4.:/5 (64 download)

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Book Synopsis Effects of Heterogeneity on Reactive Transport in Geologic Media by : Christopher Terry Green

Download or read book Effects of Heterogeneity on Reactive Transport in Geologic Media written by Christopher Terry Green and published by . This book was released on 2002 with total page 414 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Reactive Transport in Natural Porous Media

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (844 download)

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Book Synopsis Reactive Transport in Natural Porous Media by : Babak Shafei

Download or read book Reactive Transport in Natural Porous Media written by Babak Shafei and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Reactive Transport Models (RTMs) provide quantitative tools to analyze the interaction between transport and biogeochemical processes in subsurface environments such as aquatic sediments and groundwater flow. A tremendous amount of research has shown the role and impact of scaling behavior of the reactive systems which stems from geologic heterogeneity. Depending on the kinetics of the reactions, different types of formulations have been proposed to describe reactions in RTMs. We introduce a novel quantitative criteria on the range of validity of local equilibrium assumption (LEA) in aquatic sediments with irreversible heterogeneous sorption reactions. Then we present a one-dimensional (1-D) early diagenetic module, MATSEDLAB, developed in MATLAB. The module provides templates for representing the reaction network, boundary conditions and transport regime, which the user can modify to fit the particular early diagenetic model configuration of interest. We describe the theoretical background of the model and introduce the MATLAB pdepe solver, followed by calibration and validation of the model by a number of theoretical and empirical applications. Finally, we introduce a new pore-scale model using lattice Boltzmann (LB) approach. It uses an iterative scheme for the chemical transport-reaction part and recent advances in the development of optimal advection-diffusion solvers within the lattice Boltzmann method framework. We present results for the dissolution and precipitation of a porous medium under different dynamical conditions, varying reaction rates and the ratio of advective to diffusive transport (Pe, Peclet number) for linear reactions. The final set of calculations considers sorption reactions on a heterogeneous porous medium. We use our model to investigate the effect of heterogeneity on the pore-scale distribution of sorption sites and the competition between three different sorption reactions.

Reactive Transport in Porous Media

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501509799
Total Pages : 452 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Reactive Transport in Porous Media by : Peter C. Lichtner

Download or read book Reactive Transport in Porous Media written by Peter C. Lichtner and published by Walter de Gruyter GmbH & Co KG. This book was released on 2018-12-17 with total page 452 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 34 of Reviews in Mineralogy focuses on methods to describe the extent and consequences of reactive flow and transport in natural subsurface systems. Since the field of reactive transport within the Earth Sciences is a highly multidisciplinary area of research, including geochemistry, geology, physics, chemistry, hydrology, and engineering, this book is an attempt to some extent bridge the gap between these different disciplines. This volume contains the contributions presented at a short course held in Golden, Colorado, October 25-27, 1996 in conjunction with the Mineralogical Society of America's (MSA) Annual Meeting with the Geological Society of America in Denver, Colorado.

Reactive Transport in Natural and Engineered Systems

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501512005
Total Pages : 514 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Reactive Transport in Natural and Engineered Systems by : Jennifer Druhan

Download or read book Reactive Transport in Natural and Engineered Systems written by Jennifer Druhan and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-03-04 with total page 514 pages. Available in PDF, EPUB and Kindle. Book excerpt: Open system behavior is predicated on a fundamental relationship between the timescale over which mass is transported and the timescale over which it is chemically transformed. This relationship describes the basis for the multidisciplinary field of reactive transport (RT). In the 20 years since publication of Review in Mineralogy and Geochemistry volume 34: Reactive Transport in Porous Media, RT principles have expanded beyond early applications largely based in contaminant hydrology to become broadly utilized throughout the Earth Sciences. RT is now employed to address a wide variety of natural and engineered systems across diverse spatial and temporal scales, in tandem with advances in computational capability, quantitative imaging and reactive interface characterization techniques. The present volume reviews the diversity of reactive transport applications developed over the past 20 years, ranging from the understanding of basic processes at the nano- to micrometer scale to the prediction of Earth global cycling processes at the watershed scale. Key areas of RT development are highlighted to continue advancing our capabilities to predict mass and energy transfer in natural and engineered systems.

An Introduction to Solute Transport in Heterogeneous Geologic Media

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Publisher : Cambridge University Press
ISBN 13 : 1316511189
Total Pages : 365 pages
Book Rating : 4.3/5 (165 download)

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Book Synopsis An Introduction to Solute Transport in Heterogeneous Geologic Media by : Tian-Chyi Jim Yeh

Download or read book An Introduction to Solute Transport in Heterogeneous Geologic Media written by Tian-Chyi Jim Yeh and published by Cambridge University Press. This book was released on 2023-02-28 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a unified and comprehensive overview of physical explanations of the stochastic concepts of solute transport processes, important scaling issues, and practical tools for the analysis of solute transport.

Non Fickian Solute Transport

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Publisher :
ISBN 13 : 9781632403872
Total Pages : 0 pages
Book Rating : 4.4/5 (38 download)

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Book Synopsis Non Fickian Solute Transport by : William Taylor

Download or read book Non Fickian Solute Transport written by William Taylor and published by . This book was released on 2015-02-12 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This research-based book provides a mathematical approach based on stochastic calculus which describes state-of-the-art information regarding porous media science and engineering - prediction of dispersivity from covariance of hydraulic conductivity (velocity). The complication is of great significance for tracer examination, for improved recovery by injection of miscible gases, etc. The book elucidates a generalized mathematical model and efficient numerical methodologies that may greatly affect the stochastic porous media hydrodynamics. It begins with a descriptive basic analysis of the complication of scale dependence of the dispersion coefficient in porous media. Furthermore, relevant topics of stochastic calculus which would be helpful in modeling are discussed subsequently. An in-depth elaborative discussion regarding the development of a generalized stochastic solute transport model for any provided velocity covariance without conferring to fickian expectations from laboratory scale to field scale is also illustrated in this book. The mathematical approaches described in this book will serve as useful solutions for several other complications associated with chemical dispersion in porous media.

Geologic Carbon Sequestration

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Publisher : Springer
ISBN 13 : 3319270192
Total Pages : 336 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Geologic Carbon Sequestration by : V. Vishal

Download or read book Geologic Carbon Sequestration written by V. Vishal and published by Springer. This book was released on 2016-05-11 with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: This exclusive compilation written by eminent experts from more than ten countries, outlines the processes and methods for geologic sequestration in different sinks. It discusses and highlights the details of individual storage types, including recent advances in the science and technology of carbon storage. The topic is of immense interest to geoscientists, reservoir engineers, environmentalists and researchers from the scientific and industrial communities working on the methodologies for carbon dioxide storage. Increasing concentrations of anthropogenic carbon dioxide in the atmosphere are often held responsible for the rising temperature of the globe. Geologic sequestration prevents atmospheric release of the waste greenhouse gases by storing them underground for geologically significant periods of time. The book addresses the need for an understanding of carbon reservoir characteristics and behavior. Other book volumes on carbon capture, utilization and storage (CCUS) attempt to cover the entire process of CCUS, but the topic of geologic sequestration is not discussed in detail. This book focuses on the recent trends and up-to-date information on different storage rock types, ranging from deep saline aquifers to coal to basaltic formations.

Chemical Heterogeneity of Glaciofluvial Deposits

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ISBN 13 :
Total Pages : 426 pages
Book Rating : 4.:/5 (611 download)

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Book Synopsis Chemical Heterogeneity of Glaciofluvial Deposits by : Gordon M. Sturgeon

Download or read book Chemical Heterogeneity of Glaciofluvial Deposits written by Gordon M. Sturgeon and published by . This book was released on 2004 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Numerical Methods

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110571064
Total Pages : 467 pages
Book Rating : 4.1/5 (15 download)

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Book Synopsis Numerical Methods by : George Em Karniadakis

Download or read book Numerical Methods written by George Em Karniadakis and published by Walter de Gruyter GmbH & Co KG. This book was released on 2019-04-15 with total page 467 pages. Available in PDF, EPUB and Kindle. Book excerpt: This multi-volume handbook is the most up-to-date and comprehensive reference work in the field of fractional calculus and its numerous applications. This third volume collects authoritative chapters covering several numerical aspects of fractional calculus, including time and space fractional derivatives, finite differences and finite elements, and spectral, meshless, and particle methods.

Scale-up of Reactive Processes in Heterogeneous Media

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ISBN 13 :
Total Pages : 438 pages
Book Rating : 4.:/5 (93 download)

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Book Synopsis Scale-up of Reactive Processes in Heterogeneous Media by : Harpreet Singh

Download or read book Scale-up of Reactive Processes in Heterogeneous Media written by Harpreet Singh and published by . This book was released on 2014 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical and chemical heterogeneities cause the porous media transport parameters to vary with scale, and between these two types of heterogeneities geological heterogeneity is considered to be the most important source of scale-dependence of transport parameters. Subsurface processes associated with chemical alterations result in changing reservoir properties with interlinked spatial and temporal scale, and there is uncertainty in the evolution of those properties and the chemical processes. This dissertation provides a framework and procedures to quantify the spatiotemporal scaling characteristics of reservoir attributes and transport processes in heterogeneous media accounting for chemical alterations in the reservoir. Conventional flow scaling groups were used to assess their applicability in scaling of recovery and Mixing Zone Length (MZL) in presence of chemical reactivity and permeability heterogeneity through numerical simulations of CO2 injection. It was found out that these scaling groups are not adequate enough to capture the scaling of recovery and transport parameters in the combined presence of chemical reactivity and physical heterogeneity. In this illustrative example, MZL was investigated as a function of spatial scale, temporal scale, multi-scale heterogeneity, and chemical reactivity; key conclusions are that 1) the scaling characteristics of MZL distinctly differ for low permeability and high permeability media, 2) heterogeneous media with spatial arrangements of both high and low permeability regions exhibit scaling characteristics of both high and low permeability media, 3) reactions affect scaling characteristics of MZL in heterogeneous media, 4) a simple rescaling can combine various MZL curves by merging them into a single MZL curve irrespective of the correlation length of heterogeneity, and 5) estimates of MZL (and consequently predictions of oil recovery) will fluctuate corresponding to displacements in a permeable medium whose lateral length is smaller than the correlation length of geological formation. We illustrate and extend the procedure of estimating Representative Elementary Volume (REV) to include temporal scale by coupling it with spatial scale. The current practice is to perform spatial averaging of attributes and account for residual variability by calibration and history matching. This results in poor predictions of future reservoir performance. The proposed semi-analytical technique to scale-up in both space and time provides guidance for selection of spatial and temporal discretizations that takes into account the uncertainties due to sub-processes. Finally, a probabilistic particle tracking (PT) approach is proposed to scale-up flow and transport of diffusion-reaction (DR) processes while addressing multi-scale and multi-physics nature of DR mechanisms and also maintaining consistent reservoir heterogeneity at different levels of scales. This multi-scale modeling uses a hierarchical approach which is based on passing the macroscopic subsurface heterogeneity down to the finer scales and then returning more accurate reactive flow response. This PT method can quantify the impact of reservoir heterogeneity and its uncertainties on statistical properties such as reaction surface area and MZL, at various scales.

Dispersion in Heterogeneous Geological Formations

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Publisher : Springer Science & Business Media
ISBN 13 : 9401712786
Total Pages : 261 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Dispersion in Heterogeneous Geological Formations by : Brian Berkowitz

Download or read book Dispersion in Heterogeneous Geological Formations written by Brian Berkowitz and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt: In spite of many years of intensive study, our current abilities to quantify and predict contaminant migration in natural geological formations remain severely limited. The heterogeneity of these formations over a wide range of scales necessitates consideration of sophisticated transport theories. The evolution of such theories has escalated to the point that a review of the subject seems timely. While conceptual and mathematical developments were crucial to the introduction of these new approaches, there are now too many publications that contain theoretical abstractions without regard to real systems, or incremental improvements to existing theories which are known not to be applicable. This volume brings together articles representing a broad spectrum of state-of-the-art approaches for characterization and quantification of contaminant dispersion in heterogeneous porous media. Audience: The contributions are intended to be as accessible as possible to a wide readership of academics and professionals with diverse backgrounds such as earth sciences, subsurface hydrology, petroleum engineering, and soil physics.

Applied Stochastic Hydrogeology

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Publisher : Oxford University Press
ISBN 13 : 9780198031543
Total Pages : 416 pages
Book Rating : 4.0/5 (315 download)

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Book Synopsis Applied Stochastic Hydrogeology by : Yoram Rubin

Download or read book Applied Stochastic Hydrogeology written by Yoram Rubin and published by Oxford University Press. This book was released on 2003-03-27 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: Stochastic Subsurface Hydrogeology is the study of subsurface, geological heterogeneity, and its effects on flow and transport process, using probabilistic and geostatistical concepts. This book presents a rational, systematic approach for analyzing and modeling subsurface heterogeneity, and for modeling flow and transport in the subsurface, and for prediction and decision-making under uncertainty. The book covers the fundamentals and practical aspects of geostatistics and stochastic hydrogeology, coupling theoretical and practical aspects, with examples, case studies and guidelines for applications, and provides a summary and review of the major developments in these areas.

Transport & Fate of Chemicals in Soils

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Publisher : CRC Press
ISBN 13 : 146655794X
Total Pages : 356 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Transport & Fate of Chemicals in Soils by : H. Magdi Selim

Download or read book Transport & Fate of Chemicals in Soils written by H. Magdi Selim and published by CRC Press. This book was released on 2014-09-17 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last four decades, tremendous advances have been made towards the understanding of transport characteristics of contaminants in soils, solutes, and tracers in geological media. Transport & Fate of Chemicals in Soils: Principles & Applications offers a comprehensive treatment of the subject complete with supporting examples of mathematical models that describe contaminants reactivity and transport in soils and aquifers. This approach makes it a practical guide for designing experiments and collecting data that focus on characterizing retention as well as release kinetic reactions in soils and contaminant transport experiments in the laboratory, greenhouse), and in the field. The book provides the basic framework of the principals governing the sorption and transport of chemicalsin soils. It focuses on physical processes such as fractured media, multiregion, multiple porosities, and heterogeneity and effect of scale as well as chemical processes such as nonlinear kinetics, release and desorption hysteresis, multisite and multireaction reactions, and competitive-type reactions. The coverage also includes details of sorption behavior of chemicals with soil matrix surfaces as well the integration of sorption characteristics with mechanisms that govern solute transport in soils. The discussions of applications of the principles of sorption and transport are not restricted to contaminants, but also include nitrogen, phosphorus, and trace elements including essential micronutrients, heavy metals, military explosives, pesticides, and radionuclides. Written in a very clear and easy-to-follow language by a pioneer in soil science, this book details the basic framework of the physical and chemical processes governing the transport of contaminants, trace elements, and heavy metals in soils. Highly practical, it includes laboratory methods, examples, and empirical formulations. The approach taken by the author gives you not only the fundamentals of understanding of reactive chemicals retention and their transport in soils and aquifers, but practical guidance you can put to immediate use in designing experiments and collecting data.

Proceedings

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ISBN 13 :
Total Pages : 790 pages
Book Rating : 4.:/5 (318 download)

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Book Synopsis Proceedings by :

Download or read book Proceedings written by and published by . This book was released on 1998 with total page 790 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Pore Scale Geochemical Processes

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 1501502077
Total Pages : 496 pages
Book Rating : 4.5/5 (15 download)

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Book Synopsis Pore Scale Geochemical Processes by : Carl Steefel

Download or read book Pore Scale Geochemical Processes written by Carl Steefel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2015-09-25 with total page 496 pages. Available in PDF, EPUB and Kindle. Book excerpt: This RiMG (Reviews in Mineralogy & Geochemistry) volume includes contributions that review experimental, characterization, and modeling advances in our understanding of pore-scale geochemical processes. The volume had its origins in a special theme session at the 2015 Goldschmidt Conference in Prague. From a diversity of pore-scale topics that ranged from multi-scale characterization to modeling, this work summarizes the state-of-the-science in this subject. Topics include: modification of thermodynamics and kinetics in small pores. chemo-mechanical processes and how they affect porosity evolution in geological media. small angle neutron scattering (SANS) techniques. how isotopic gradients across fluid–mineral boundaries can develop and how these provide insight into pore-scale processes. Information on an important class of models referred to as "pore network" and much more. The material in this book is accessible for graduate students, researchers, and professionals in the earth, material, environmental, hydrological, and biological sciences. The pore scale is readily recognizable to geochemists, and yet in the past it has not received a great deal of attention as a distinct scale or environment that is associated with its own set of questions and challenges. Is the pore scale merely an environment in which smaller scale (molecular) processes aggregate, or are there emergent phenomena unique to this scale? Is it simply a finer-grained version of the "continuum" scale that is addressed in larger-scale models and interpretations? The scale is important because it accounts for the pore architecture within which such diverse processes as multi-mineral reaction networks, microbial community interaction, and transport play out, giving rise to new geochemical behavior that might not be understood or predicted by considering smaller or larger scales alone.

Fundamentals of Geoenvironmental Engineering

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Publisher : Butterworth-Heinemann
ISBN 13 : 0128051450
Total Pages : 710 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Fundamentals of Geoenvironmental Engineering by : Abdel-Mohsen O. Mohamed

Download or read book Fundamentals of Geoenvironmental Engineering written by Abdel-Mohsen O. Mohamed and published by Butterworth-Heinemann. This book was released on 2017-10-31 with total page 710 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fundamentals of Geoenvironmental Engineering: Understanding Soil, Water, and Pollutant Interaction and Transport examines soil-water-pollutant interaction, including physico-chemical processes that occur when soil is exposed to various contaminants. Soil characteristics relevant to remedial techniques are explored, providing foundations for the correct process selection. Built upon the authors' extensive experience in research and practice, the book updates and expands the content to include current processes and pollutants. The book discusses propagation of soil pollution and soil characteristics relevant to remedial techniques. Practicing geotechnical and environmental engineers can apply the theory and case studies in the book directly to current projects. The book first discusses the stages of economic development and their connections to the sustainability of the environment. Subsequent chapters cover waste and its management, soil systems, soil-water and soil-pollutant interactions, subsurface transport of pollutants, role of groundwater, nano-, micro- and biologic pollutants, soil characteristics that impact pollution diffusion, and potential remediation processes like mechanical, electric, magnetic, hydraulic and dielectric permittivity of soils. Presents a clear understanding of the propagation of pollutants in soils Identifies the physico-chemical processes in soils Covers emerging pollutants (nano-, micro- and biologic contaminants) Features in-depth coverage of hydraulic, electrical, magnetic and dielectric permittivity characteristics of soils and their impact on remedial technologies

Heterogeneity and Scaling in Geologic Media

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Publisher :
ISBN 13 :
Total Pages : 5 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis Heterogeneity and Scaling in Geologic Media by : Stephen R. Brown

Download or read book Heterogeneity and Scaling in Geologic Media written by Stephen R. Brown and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The DOE National Laboratories have extensive environmental remediation and operations centers as well as research teams specializing in environmental problems. These organizations are concerned largely with pollution prevention, safe disposal of hazardous materials, polluted site identification and characterization, and cleanup of polluted sites. These organizations, and the private-industry subcontractors they hire, require state of the art tools and techniques for characterization and monitoring. Our research will contribute to this effort by providing descriptions of heterogeneities and scaling properties in the vadose and saturated zones with particular emphasis on flow and transport. This work will also provide an important link between some geophysical measurements and fluid transport characteristics.