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Effect Of Chemical Solvents On Rheological Properties Of Recovered Asphalt Binders
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Book Synopsis Effect of Chemical Solvents on Rheological Properties of Recovered Asphalt Binders by : Yazeed Abu Hassan
Download or read book Effect of Chemical Solvents on Rheological Properties of Recovered Asphalt Binders written by Yazeed Abu Hassan and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Extraction and recovery of asphalt binders is an important procedure, although the rheological properties of the recovered binder may vary from the actual values due to many factors. This study has been conducted to evaluate the effect of different chemical solvents on the rheological properties of the recovered asphalt binder at high, intermediate, and low temperatures excluding the other factors that may affect the results. Five different binders were taken into consideration when this study was conducted, PG 58-28, PG 64-22, PG 64-28, PG 70-22, and PG 76-28, along with three different types of chemical solvents largely used as an industrial solvent, which are Trycoloroethelene (TCE), N-Propyl Bromide (nPB) brand called Entron-AE and Toluene.To catch the effect left by these solvents on the recovered binders, each binder has been dissolved in a specific amount of each of the three chemical solvents individually, the proportions of the solvent to the asphalt binder used was almost equal to the amount of the solvent needed to extract the same amount of binder out of a mixtures using a centrifuge. After leaving it for a while and making sure that the binder is totally dissolved, the binder is then recovered using a normal distillation process called the Abson method. In order to determine whether the age of the binder affects the results obtained from the recovered binders or not, testing has been done on unaged binders, short term aged binders, and long term aged binders, and in order to do that, short term aging has been simulated using the Rolling Thin Film Oven Test (RTFO), and the long term aging has been simulated using the Pressurized Aging Vessel (PAV).Finally, both original and recovered binders were tested at different aging conditions using the Dynamic Shear Rheometer (DSR), and the Bending Beam Rheometer (BBR). Data were used to obtain a full continuous grading of both the original (base) binder and the recovered binder for the five different binders used in this study using the three chemical solvents. Direct Comparisons were also made to compare the results of the original binder to the recovered binders using Trichloroethylene (TCE), Normal Propyl Bromide (nPB), and Toluene. Results showed that TCE will exhibit high softening effect unlike the Toluene which showed reasonable and representative data compared to the base binder, while nPB kept on giving un consistent data without a specific pattern.
Book Synopsis Binder Characterization and Evaluation: Test methods by :
Download or read book Binder Characterization and Evaluation: Test methods written by and published by . This book was released on 1994 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Rheological, Chemical and Microstructural Characterization of Asphalt Binders Aged at Different Conditions and Evaluation of the Use of Antioxidants and Copolymers to Retard Aging by : Mohammad Solaiman Khan
Download or read book Rheological, Chemical and Microstructural Characterization of Asphalt Binders Aged at Different Conditions and Evaluation of the Use of Antioxidants and Copolymers to Retard Aging written by Mohammad Solaiman Khan and published by . This book was released on 2017 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: The rheological, chemical and microstructural properties of asphalt binders change with oxidative aging which is accelerated at elevated temperatures. Aging stiffens asphalt binders and increases the embrittlement of asphalt mixtures which would lead to fatigue cracking and eventually pavement failure under repetitive traffic loading. This study explored the feasibility of using antioxidant additives and copolymers with antioxidant agents to retard oxidative aging of asphalt binders. The performance of the additives was evaluated at the binder and mastic levels. The laboratory experiments included two unmodified binders, various antioxidant additives and copolymers, and three aggregate types. The fatigue characteristics of asphalt binders and mastic were determined before and after aging and an aging index was defined to evaluate the effect of the additives on aging. The results demonstrated that certain antioxidants and copolymers such as Redicote AP, Solprene, and Calprene may retard the aging and improve the rheological properties of the asphalt binders. In addition, the results of mastic testing confirmed the favorable effect of certain antioxidants on improving the resistance to fatigue cracking. Furthermore, the type of aggregate was found to influence the rate of aging of asphalt mixtures. Based on the rheological and fracture test results on asphalt binders and mastic, the effect of antioxidants was further investigated and validated at spectroscopic, chemical and microstructural level using Fourier-transform infrared spectroscopy (FTIR), Gel-permeation chromatography (GPC) and Atomic Force Microscopy (AFM), respectively. The spectroscopic analysis with FTIR supported the efficacy of the additives in retarding aging by reducing the carbonyl growth in aged binders. The chemical analysis with GPC confirmed that both Redicote and Solprene were capable of reducing the large molecular size fraction in binders subjected to long-term aging. The image analysis with AFM provided insight on the spatial distribution, surface roughness parameters and micromechanical properties (i.e., adhesion, stiffness) of various phases and the effect of aging on the micro-rheology of antioxidant-modified binders. The last part of this study examined the effect of aging on the viscoelastic response of asphalt mixture using the Prony series representation and a newly developed parameter called aging state variable 'A'. The dynamic modulus test data was used for the analysis. The aging state variable 'A' was found to capture the effect of aging temperature and duration of aging on the viscoelastic properties of asphalt mixtures.
Book Synopsis Investigation of Binder Rheology and Performance Outcomes of Recycled Hot-mix Asphalt Using Different Rejuvenation Agents by : Kerry Jean King
Download or read book Investigation of Binder Rheology and Performance Outcomes of Recycled Hot-mix Asphalt Using Different Rejuvenation Agents written by Kerry Jean King and published by . This book was released on 2015 with total page 252 pages. Available in PDF, EPUB and Kindle. Book excerpt: The research presented in this thesis investigated the effect of various rejuvenation agents on the performance of hot-mix asphalt (HMA) surfacing mixes containing high levels of recycled asphalt pavement (RAP) material (30%). The research aimed to develop testing methodologies for evaluating the mechanical performance properties of HMA mixes and for the characterisation of extracted binder properties. The methodologies were used determine the effects of various rejuvenators on the mechanical performance properties and binder properties fundamental to the long-term performance of pavement surfaces. A testing methodology was developed to investigate the performance properties of five HMA mixes including four mixes that were rejuvenated using different rejuvenation agents and one control. The mechanical testing methodology provided a comprehensive assessment of mix properties that are fundamental to the long-term performance of recycled pavements. A methodology for the characterisation of extracted binders was developed to evaluate properties that had a significant effect on the performance of the binder and therefore the overall mix. The binder properties were compared to results obtained from mechanical performance tests to establish a relationship between binder rejuvenation and performance observations. The results obtained from mechanical testing demonstrated that the cracking resistance of recycled mixes could be significantly improved through the use of rejuvenation agents. Rejuvenation also decreased the stiffness of the mix and had a negative effect on the resistance of a mix to permanent deformation. From the characterisation of the binder, it was found that rejuvenation agents altered the rheological properties of the binder but did not have a notable effect on chemical composition. The rheological performance parameters of the binder correlated to the mix performance observed from mechanical tests. Overall this research has shown that rejuvenation agents can be utilised to enhance the performance of recycled mixes by restoring binder properties.
Download or read book ICCOEE2020 written by Bashar S. Mohammed and published by Springer Nature. This book was released on 2020-12-31 with total page 1147 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book contains papers presented in the 6th International Conference on Civil, Offshore & Environmental Engineering (ICCOEE2020) under the banner of World Engineering, Science & Technology Congress (ESTCON2020) will be held from 13th to 15th July 2021 at Borneo Convention Centre, Kuching, Sarawak, Malaysia. This proceeding contains papers presented by academics and industrial practitioners showcasing the latest advancements and findings in civil engineering areas with an emphasis on sustainability and the Industrial Revolution 4.0. The papers are categorized under the following tracks and topics of research: 1. Resilient Structures and Smart Materials 2. Advanced Construction and Building Information Modelling 3. Smart and Sustainable Infrastructure 4. Advanced Coastal and Offshore Engineering 5. Green Environment and Smart Water Resource Management Systems
Book Synopsis Characteristics of Asphalt Binders by :
Download or read book Characteristics of Asphalt Binders written by and published by . This book was released on 1996 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Laboratory Characterization of Asphalt Binders Containing a Chemical-Based Warm Mix Asphalt Additive by : Shivani Rani
Download or read book Laboratory Characterization of Asphalt Binders Containing a Chemical-Based Warm Mix Asphalt Additive written by Shivani Rani and published by . This book was released on 2020 with total page 16 pages. Available in PDF, EPUB and Kindle. Book excerpt: Different technologies, namely foamed asphalt, synthetic waxes, zeolites, and chemical additives, are used to produce warm mix asphalt (WMA). This study was undertaken to evaluate the effect of using different amounts of an amine-based chemical WMA additive on the rheology, performance grade (PG), and moisture-induced damage potential of an asphalt binder (PG 58-28). Superpave specifications were used to evaluate the rheological properties and PG of the asphalt binder. Also, a mechanistic approach-based on the surface free energy (SFE) method was used to evaluate the moisture-induced damage potential of the asphalt binder combined with commonly used aggregates in an asphalt mix. It was found that the dynamic viscosity of the asphalt binder was not significantly affected after blending it with the WMA additive. It was also observed that the Superpave high-temperature PG and the rutting factor did not reduce by an increase in the WMA additive content. However, the continuous low-temperature PG of the asphalt binder decreased with an increase in the amount of WMA additive. Furthermore, it was found that the fatigue resistance increased after blending the binder with the WMA additive. The SFE results of the asphalt binder revealed that the WMA additive used in this study reduced the moisture-induced damage potential of the asphalt mixes. However, the extent of this improvement was found to largely depend on the aggregate type. The outcomes of this study are expected to help better understand the influence of amine-based chemical WMA additives on rheological and long-term performance of asphalt mix.
Book Synopsis Shell Bitumen Handbook by : Robert Hunter
Download or read book Shell Bitumen Handbook written by Robert Hunter and published by ICE Publishing. This book was released on 2015-01-28 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Shell has been at the forefront of bitumen technology for over 90 years, and continues to play a leading role in global bitumen research and development. The Shell Bitumen Handbook is an authoritative source of information on bitumen use in road pavements around the world.
Book Synopsis Chemical Properties of Asphalts and Their Effects on Pavement Performance by : Raymond E. Robertson
Download or read book Chemical Properties of Asphalts and Their Effects on Pavement Performance written by Raymond E. Robertson and published by . This book was released on 2000 with total page 52 pages. Available in PDF, EPUB and Kindle. Book excerpt: The purpose of this Circular is to familiarize the asphalt user with the source of asphalt, the variable chemistry of asphalt, why variable performance should be expected when asphalt is used in roadways and what is currently missing from the specification process. Several areas are identified where refinements in the specification process would improve the ability to classify asphalts by their expected performance. This Circular summarizes more than 2,500 pages written during the past 20 years on the effects of fundamental chemistry on the rheological properties of asphalt. This Circular should be especially useful to civil engineering students who intend to work in some highway construction-related business.
Book Synopsis Rheological Properties of Polymer and RAP Modified Asphalt Binders Using Multiple Stress Creep and Recovery Method by : Syed Ashik Ali
Download or read book Rheological Properties of Polymer and RAP Modified Asphalt Binders Using Multiple Stress Creep and Recovery Method written by Syed Ashik Ali and published by . This book was released on 2016 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Influence of Rheological Properties of Modified Asphalt Binders on the Load-deformation Characteristics of the Binder-aggregate Mixtures by : Akhtarhusein Asgarali Tayebali
Download or read book Influence of Rheological Properties of Modified Asphalt Binders on the Load-deformation Characteristics of the Binder-aggregate Mixtures written by Akhtarhusein Asgarali Tayebali and published by . This book was released on 1990 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Influence of Laboratory Aging Method on the Rheological Properties of Asphalt Binders by : A. Abbas
Download or read book The Influence of Laboratory Aging Method on the Rheological Properties of Asphalt Binders written by A. Abbas and published by . This book was released on 2002 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Asphalt binders used in asphalt concrete roadway pavements experience aging during construction and subsequently during their service lives. Aging is the combined effect of the evaporation of volatile compounds and the chemical reaction of residual compounds with oxygen. This aging affects the rheological properties of asphalt binders. The SuperpaveTM testing and specification system uses two laboratory procedures for aging of binders prior to measuring their rheological properties, namely the rolling thin film oven (RTFO) and the pressure aging vessel (PAV). These two procedures are used to simulate the aging that takes place during construction and during service, respectively. This paper examines whether the SuperpaveTM prescribed sequence of binder aging procedures (i.e., the RTFO followed by the PAV) is necessary, or whether similar binder rheological properties are obtained using the PAV procedure only. For this purpose, three binders were tested, namely an unmodified PG 64-28, an SBS polymer-modified binder of the same grade, and an SBS polymer-modified PG 76-28. The low temperature and fatigue rheological properties were measured by a bending beam rheometer (BBR) and a dynamic shear rheometer (DSR), respectively. The findings of the study suggest that, with a few exceptions, the rheological properties measured after aging with the RTFO followed by PAV are significantly different than those obtained after PAV aging only.
Book Synopsis Chemical, Morphological, and Rheological Properties of Various Rejuvenated Asphalt Binders by : Rayhan Bin Ahmed
Download or read book Chemical, Morphological, and Rheological Properties of Various Rejuvenated Asphalt Binders written by Rayhan Bin Ahmed and published by . This book was released on 2020 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Reclaimed asphalt pavement (RAP) material is considered as an economical approach for sustainable pavement construction. However, usage of higher RAP binder content is more susceptible to pavement cracking. Using rejuvenators with RAP binder is a widely used approach to address the issues related to RAP binder. This study used thin film oven test (TFOT) aged binder with three types of rejuvenators including waste cooking oil (UT/R1), modified waste cooking oil (TR/R2), and Hydrolene (HL/R3). Also, in some cases, styrene butadiene styrene (SBS) polymer was added with UT/R1 and TR/R2 rejuvenated binders to compare the performances. To understand the behavior and the performance of these rejuvenators, three sets of characterization tests were conducted: chemical, morphological, and rheological. Gas Chromatography-Mass Spectroscopy (GC-MS) and Fourier Transformed Infrared Spectroscopy (FTIR) was employed for chemical characterization, while Atomic Force Microscopy (AFM) was used for morphological analysis. Later, a frequency sweep test and surface free energy (SFE) test was conducted to understand the rheological performances and moisture damage resistance of rejuvenated asphalt binders respectively. Based on the experimentation, the study reveals that UT/R1 softens the binders most, whereas TR/R2 rejuvenator eliminates these issues and showed better rheological performances of the binder. However, in case of moisture susceptibility, TR/R2 rejuvenated binder seems to have poor resistance and the highest resistance was recorded for UT/R1 rejuvenated binders. This study observes a good correlation between chemical, morphological and rheological performances of binders which are expected to contribute to the performance evaluation and characterization of rejuvenated asphalt mixes.
Book Synopsis Effects of Asphamin® and Sasobit® on Rheological Properties of Asphalt Binders by : Justin Michael Sneed
Download or read book Effects of Asphamin® and Sasobit® on Rheological Properties of Asphalt Binders written by Justin Michael Sneed and published by . This book was released on 2008 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Effects of Waste Polyethylene on the Rheological Properties of Asphalt Binder by : Qunshan Ye
Download or read book Effects of Waste Polyethylene on the Rheological Properties of Asphalt Binder written by Qunshan Ye and published by . This book was released on 2020 with total page 12 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recycling of waste plastic is an issue of great concern worldwide because of its considerable quantity and growth. The effects of waste polyethylene (PE) on the rheological properties of asphalt binder were investigated in this research. Three types of PE were adopted to prepare modified binders with contents ranging from 2 to 6 %. A viscosity test, performance grade test, frequency sweep test, amplitude sweep test, and linear amplitude sweep test are conducted to study rheological properties of PE modified binders, compared with base binder and binders modified with styrene-butadiene-styrene and crumb rubber modifier. The test results indicated that the high temperature properties of asphalt binders could be effectively improved by the PE modifiers with different types and contents. The high temperature grade and rutting resistance factor of PE modified binder can be increased significantly when compared with the base binder. With the increased PE content, the complex modulus increased, whereas the phase angle values decreased in most test frequencies and shear strain, which implied that the usage of PE not only reinforced the viscosity of binders but also enhanced the elasticity. The fatigue properties of PE modified binders were improved, especially at the lower shear strain range. However, PE modifier had a negative effect for asphalt binder on low temperature property.
Book Synopsis Interaction Between New and Age-hardened Binders in Asphalt Mixes Containing High Quantities of Reclaimed Asphalt Pavement and Reclaimed Asphalt Shingles by : Yuan He
Download or read book Interaction Between New and Age-hardened Binders in Asphalt Mixes Containing High Quantities of Reclaimed Asphalt Pavement and Reclaimed Asphalt Shingles written by Yuan He and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: As virgin pavement material sources become scarcer and costlier the use of higher quantities of reclaimed asphalt pavement (RAP) and reclaimed asphalt shingles (RAS) in the production of new asphalt mixes becomes increasingly desirable. RAP/RAS binder in the mix has different levels of aging. Through oxidation, the binder becomes stiffer and more rigid than virgin binder, and thus results in a pavement material that is more brittle and susceptible to fatigue and thermal cracking. The purpose of this dissertation study was to investigate the interactions between new and age binders and evaluate asphalt mixes performance. A major concern associated with the use of high percentages of RAP and/or RAS is the level of blending between virgin and age-hardened binders, because the performance of the mix can be highly influenced by the properties of the composite binder. The blending between new binder and age-hardened RAP binder can be explained through diffusion mechanisms. This research used asphalt binder testing and diffusion and aging theory to investigate the evolution of blending between virgin and RAP binders during asphalt mix production, storage, and placement. The rheological properties of a two-layer asphalt binder sample composed of virgin and simulated RAP binder were measured using a dynamic shear rheometer (DSR) after conditioning following hot mix asphalt (HMA) and warm mix asphalt (WMA) time-temperature paths during mixing and placement. The diffusion and aging coefficients for the composite binder were estimated by comparing measured shear stiffness values with those predicted using a diffusion model and considering asphalt binder aging over time. The diffusion model is solved numerically based on the finite control volume approach. Results show that the HMA results in nearly full blending of the new and aged binders following the time-temperature paths used in this study; while the WMA results in only partial blending. Traditionally, the properties of blended binders in asphalt mixes containing RAP and RAS are evaluated through rheological testing of the binder extracted and recovered from a mix. However, this approach has long been criticized for being labor intensive, for potentially altering the chemistry of the binder and consequently changing the binder rheology, for forcing blending of binders that may not have been present in the mix, and for creating hazardous material disposal issues. The research presented in this dissertation proposes an alternative approach for characterizing blended binders by testing the linear viscoelastic properties of a fine aggregate matrix (FAM) asphalt mix using a torsion bar fixture in a DSR. A procedure has been developed for preparation and testing of small FAM cylindrical FAM specimens. The results demonstrated that this testing is sensitive to FAM mixes made of different virgin binders, RAP/RAS contents, with and without rejuvenating agent. More importantly, FAM mix testing shows similar results as that from DSR binder testing and full mix testing in terms of rankings of master curves and Black diagrams. Statistical analysis (ANOVA) on stiffness values from FAM testing also provides the same conclusion to that at binder and mix levels. Therefore, FAM approach has the potential to be used as a substitute to stiffness testing for mix comparison purposes. It is also a less expensive and more efficient testing approach than the full mix testing.The combined effect of RAP, RAS, and different virgin binder sources and grades on performance of the blended binders and asphalt mixes was also investigated. Previous studies have indicated that RAP, RAS, and virgin binder grades each has certain effects on performance of the mix. The addition of RAP/RAS undermines fatigue and thermal performance and improves rutting resistance. The virgin binder grade should be carefully chosen based on the percentages of RAP/RAS in the mix. Results from unconfined RLT appears to show that reducing the binder grade when using more than 25 percent RAP results in rutting performance similar to the original grade. Therefore, it is likely safe for high temperatures if the binder grade is reduced to meet the low and intermediate temperature requirements. Asphalt binders contain different organic molecules, and thus their chemical compositions vary according to the source of the oil used in their production. Virgin binders from different sources blend differently with the age-harden oxidized binder in RAP/RAS. Therefore, depending on the level of blending between virgin and oxidized binders, the performance of the mixes could vary substantially. Findings from this work indicated that virgin binder source had some effect on the blended materials. Additional research that came from the testing approaches to complete the investigation of RAP/RAS with this dissertation were also investigated. All the asphalt mixes used in this study were designed following Caltrans modified Superpave mix design procedure and tested using an Asphalt Mixture Performance Tester (AMPT). The effects of specimen preparation variables in terms of compaction method, compaction level, test temperature, stress state, and deformation measurement location when using the AMPT to predict mix stiffness and permanent deformation were evaluated. The best approach using Superpave testing equipment that appears to best characterize expected rutting performance as defined by previous calibrated RSCH results were also investigated.
Book Synopsis Rheological Properties of Asphalt Binders by : Ali Behnood
Download or read book Rheological Properties of Asphalt Binders written by Ali Behnood and published by . This book was released on 2016 with total page 197 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Superpave specifications and equipment, introduced in 1993, represented a major advancement with respect to offering a better understanding of the behavior and characteristics of asphalt binders based on their rheological properties. However, the Superpave high-temperature test protocol has been shown to be inadequate for characterizing the high-temperature behavior (rutting resistance) of asphalt binders, particularly polymer modified ones. Recently, a specification based on the Multiple Stress Creep Recovery (MSCR) test has been proposed to address the shortcomings of the Superpave high-temperature binder specifications. This study aims to investigate the merits of implementing the MSCR test and specification as a replacement for the conventional high-temperature testing in the Performance Graded (PG) system.
