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Dissociation Constants Of Organic Bases In Aqueous Solution
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Book Synopsis Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution by : D. D. Perrin
Download or read book Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution written by D. D. Perrin and published by Elsevier. This book was released on 2016-09-14 with total page 195 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ionisation Constants of Inorganic Acids and Bases in Aqueous Solution, Second Edition provides a compilation of tables that summarize relevant data recorded in the literature up to the end of 1980 for the ionization constants of inorganic acids and bases in aqueous solution. This book includes references to acidity functions for strong acids and bases, as well as details about the formation of polynuclear species. This text then explains the details of each column of the tables, wherein column 1 gives the name of the substance and the negative logarithm of the ionization constant and column 2 gives the temperature of measurements in degree Celsius. This book presents as well the method of measurement and the literature references that are listed alphabetically at the end of the tables. Chemists will find this book useful.
Book Synopsis The Determination of Ionization Constants by : Adrien Albert
Download or read book The Determination of Ionization Constants written by Adrien Albert and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: This practical manual is devised for organic chemists and biochemists who, in the course of their researches and without previous experience, need to determine an ionization constant. We are gratified that earlier editions were much used for this purpose and that they also proved adequate for the in service training of technicians and technical officers to provide a Department with a pK service. The features of previous editions that gave this wide appeal have been retained, but the subject matter has been revised, extended, and brought up to date. We present two new chapters, one of which describes the determination of the stability constants of the complexes which organic ligands form with metal cations. The other describes the use of more recently introduced techniques for the determination of ionization constants, such as Raman and nuclear magnetic resonance spectroscopy, thermometric titrations, and paper electro phoresis. Chapter 1 gives enhanced help in choosing between alternative methods for determining ionization constants. The two chapters on potentiometric methods have been extensively revised in the light of newer understanding of electrode processes and of the present state of the art in instrumen tation.
Book Synopsis Dissociation Constants of Organic Bases in Aqueous Solution by : Douglas Dalzell Perrin
Download or read book Dissociation Constants of Organic Bases in Aqueous Solution written by Douglas Dalzell Perrin and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Physical Methods in Heterocyclic Chemistry by : A. R. Katritzky
Download or read book Physical Methods in Heterocyclic Chemistry written by A. R. Katritzky and published by Elsevier. This book was released on 2013-10-22 with total page 497 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physical Methods in Heterocyclic Chemistry, Volume IV, discusses the application of physical methods to organic chemistry, and in particular to heterocyclic chemistry. Since the publication in 1963 of the first two volumes of this treatise, the application of physical methods to organic chemistry, and in particular to heterocyclic chemistry, has proceeded apace. The importance of physical methods to structure determination and to the understanding of inter- and intramolecular interactions has increased no less than the flood of new work. Heterocyclic chemists are thus faced with the necessity of having more to comprehend for the efficient execution of their own work. The present volume includes chapters on electric dipole moments and heteroaromatic reactivity, which originally appeared in Volume I, and chapters on nuclear quadrupole resonance, nuclear magnetic resonance, and infrared spectra, which originally formed part of Volume II. Also included is one new topic: dielectric absorption.
Book Synopsis Thermodynamic and Transport Properties of Organic Salts by : Paolo Franzosini
Download or read book Thermodynamic and Transport Properties of Organic Salts written by Paolo Franzosini and published by Elsevier. This book was released on 2013-10-22 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermodynamic and Transport Properties of Organic Salts is concerned with the thermodynamic and transport properties of organic salts, namely, pure salts, mixtures, and solutions. The transport properties of pure molten salts and binary mixtures of molten salts with organic ions are given, along with the transport properties of organic salts in aqueous solutions. This book is divided into three sections and opens with a discussion on the statistical treatment and of computer simulation methods for molten salts as well as their results for pressure-volume-temperature (PVT) data. The PVT data for organic molten salts determined experimentally are considered, and the thermal properties as well as the melting mechanism of pure salts are described. A method by which PVT data at high pressure can be estimated from those at low pressure with sufficiently high accuracy is also outlined. The next section deals with salt mixtures, their phase diagrams, and their transport properties. The final section looks at the transport properties of organic salts in aqueous solutions; thermodynamic quantities of micelle formation; and formation of lyotropic liquid crystals by organic salts. Two appendixes showing the structure of the pure solids and the use of the melts in electrochemical studies are included. This monograph will be a useful resource for organic chemists.
Book Synopsis CRC Handbook of Chemistry and Physics by : William M. Haynes
Download or read book CRC Handbook of Chemistry and Physics written by William M. Haynes and published by CRC Press. This book was released on 2011-06-06 with total page 2624 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mirroring the growth and direction of science for a century, the CRC Handbook of Chemistry and Physics, now in its 92nd edition, continues to be the most accessed and respected scientific reference in the world, used by students and Nobel Laureates. Available in its traditional print format, the Handbook is also available as an innovative interactive product on DVD and online. Among a wealth of enhancements, this edition analyzes, updates, and validates molecular formulas and weights, boiling and melting points, densities, and refractive indexes in the Physical Constants of Organic Compounds Table through comparisons with critically evaluated data from the NIST Thermodynamics Research Center. New Tables: Analytical Chemistry Abbreviations Used In Analytical Chemistry Basic Instrumental Techniques of Analytical Chemistry Correlation Table for Ultraviolet Active Functionalities Detection of Outliers in Measurements Polymer Properties Second Virial Coefficients of Polymer Solutions Updated Tables: Properties of the Elements and Inorganic Compounds Update of the Melting, Boiling, Triple, and Critical Points of the Elements Fluid Properties Major update and expansion of Viscosity of Gases table Major update and expansion of Thermal Conductivity of Gases table Major update of Properties of Cryogenic Fluids Major update of Recommended Data for Vapor-Pressure Calibration Expansion of table on the Viscosity of Liquid Metals Update of Permittivity (Dielectric Constant) of Gases table Added new refrigerant R-1234yf to Thermophysical Properties of Selected Fluids at Saturation table Molecular Structure and Spectroscopy Major update of Atomic Radii of the Elements Update of Bond Dissociation Energies Update of Characteristic Bond Lengths in Free Molecules Atomic, Molecular, and Optical Physics Update of Electron Affinities Update of Atomic and Molecular Polarizabilities Nuclear and Particle Physics Major update of the Table of the Isotopes Properties of Solids Major update and expansion of the Electron Inelastic Mean Free Paths table Update of table on Semiconducting Properties of Selected Materials Geophysics, Astronomy, and Acoustics Update of the Global Temperature Trend table to include 2010 data Health and Safety Information Major update of Threshold Limits for Airborne Contaminants The Handbook is also available as an eBook.
Book Synopsis CRC Handbook of Chemistry and Physics, 96th Edition by : William M. Haynes
Download or read book CRC Handbook of Chemistry and Physics, 96th Edition written by William M. Haynes and published by CRC Press. This book was released on 2015-06-09 with total page 2652 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proudly serving the scientific community for over a century, this 96th edition of the CRC Handbook of Chemistry and Physics is an update of a classic reference, mirroring the growth and direction of science. This venerable work continues to be the most accessed and respected scientific reference in the world. An authoritative resource consisting of tables of data and current international recommendations on nomenclature, symbols, and units, its usefulness spans not only the physical sciences but also related areas of biology, geology, and environmental science. The 96th edition of the Handbook includes 18 new or updated tables along with other updates and expansions. A new series highlighting the achievements of some of the major historical figures in chemistry and physics was initiated with the 94th edition. This series is continued with this edition, which is focused on Lord Kelvin, Michael Faraday, John Dalton, and Robert Boyle. This series, which provides biographical information, a list of major achievements, and notable quotations attributed to each of the renowned chemists and physicists, will be continued in succeeding editions. Each edition will feature two chemists and two physicists. The 96th edition now includes a complimentary eBook with purchase of the print version. This reference puts physical property data and mathematical formulas used in labs and classrooms every day within easy reach. New Tables: Section 1: Basic Constants, Units, and Conversion Factors Descriptive Terms for Solubility Section 8: Analytical Chemistry Stationary Phases for Porous Layer Open Tubular Columns Coolants for Cryotrapping Instability of HPLC Solvents Chlorine-Bromine Combination Isotope Intensities Section 16: Health and Safety Information Materials Compatible with and Resistant to 72 Percent Perchloric Acid Relative Dose Ranges from Ionizing Radiation Updated and Expanded Tables Section 6: Fluid Properties Sublimation Pressure of Solids Vapor Pressure of Fluids at Temperatures Below 300 K Section 7: Biochemistry Structure and Functions of Some Common Drugs Section 9: Molecular Structure and Spectroscopy Bond Dissociation Energies Section 11: Nuclear and Particle Physics Summary Tables of Particle Properties Table of the Isotopes Section 14: Geophysics, Astronomy, and Acoustics Major World Earthquakes Atmospheric Concentration of Carbon Dioxide, 1958-2014 Global Temperature Trend, 1880-2014 Section 15: Practical Laboratory Data Dependence of Boiling Point on Pressure Section 16: Health and Safety Information Threshold Limits for Airborne Contaminants
Book Synopsis International Thermodynamic Tables of the Fluid State by : S. Angus
Download or read book International Thermodynamic Tables of the Fluid State written by S. Angus and published by Elsevier. This book was released on 2013-10-22 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: International Thermodynamic Tables of the Fluid State - 7 Propylene (Propene) is a compilation of internationally agreed values of the equilibrium thermodynamic properties of propylene. This book is composed of three chapters, and begins with the presentation of experimental result of thermodynamic studies compared with the equations used to generate the tables. The succeeding chapter deals with correlating equations for thermodynamic property determination of propylene. The last chapter provides the tabulations of the propylene's thermodynamic properties and constants. This book will prove useful to physical chemists.
Book Synopsis Organic Chemist's Desk Reference by : Caroline Cooper
Download or read book Organic Chemist's Desk Reference written by Caroline Cooper and published by CRC Press. This book was released on 2010-07-23 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt: CHOICE Award Winner Since the first publication in 1995, the Organic Chemist’s Desk Reference has been essential reading for laboratory chemists who need a concise guide to the essentials of organic chemistry — the literature, nomenclature, stereochemistry, spectroscopy, hazard information, and laboratory data. The past fifteen years have witnessed immense growth in the field of chemistry and new discoveries have continued to shape its progress. In addition, the distinction between organic chemistry and other disciplines such as biochemistry and materials science has become increasingly blurred. Extensively revised and updated, this new edition contains the very latest data that chemists need access to for experimentation and research. New in the Second Edition: Rearranged content placed in a logical progressive order, making subjects easier to find Expanded topics from the glossary now presented as separate chapters Updated information on many classic subjects such as mass spectrometry and infrared, ultraviolet, and nuclear magnetic resonance spectroscopy New sections on chiral separations and crystallography Cross references to a plethora of web information Reflecting a 75% revision since the last edition, this volume is a must-have for organic chemists and those in related fields who need quick and easy access to vital information in the lab. It is also a valuable companion to the Dictionary of Organic Compounds, enabling readers to easily focus in on critical data.
Book Synopsis pKa Prediction for Organic Acids and Bases by : D. Perrin
Download or read book pKa Prediction for Organic Acids and Bases written by D. Perrin and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 154 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many chemists and biochemists require to know the ionization constants of organic acids and bases. This is evident from the Science Citation Index which lists The Determination of Ionization Constants by A. Albert and E. P. Serjeant (1971) as one of the most widely quoted books in the chemical literature. Although, ultimately, there is no satisfactory alternative to experimental measurement, it is not always convenient or practicable to make the necessary measure ments and calculations. Moreover, the massive pK. compilations currently available provide values for only a small fraction of known or possible acids or bases. For example, the compilations listed in Section 1. 3 give pK. data for some 6 000--8 000 acids, whereas if the conservative estimate is made that there are one hundred different substituent groups available to substitute in the benzene ring of benzoic acid, approximately five million tri-substituted benzoic acids are theoretically possible. Thus we have long felt that it is useful to consider methods by which a pK. value might be predicted as an interim value to within several tenths of a pH unit using arguments based on linear free energy relationships, by analogy, by extrapolation, by interpolation from existing data, or in some other way. This degree of precision may be adequate for many purposes such as the recording of spectra of pure species (as anion, neutral molecule or cation), for selection of conditions favourable to solvent extraction, and for the interpretation of pH-profiles for organic reactions.
Book Synopsis March's Advanced Organic Chemistry by : Michael B. Smith
Download or read book March's Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 2379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations
Book Synopsis Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates by : J. Stary
Download or read book Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates written by J. Stary and published by Elsevier. This book was released on 2013-10-22 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt: Critical Evaluation of Equilibrium Constants Involving 8-Hydroxyquinoline and Its Metal Chelates presents and evaluates the published data on the solubility, dissociation, and liquid–liquid distribution of oxine and its metal chelates to recommend the most reliable numerical data. This book explores the dissociation constants of oxine in aqueous solutions. Organized into four chapters, this book begins with an overview of the characteristics of 8-hydroxyquinoline (oxine). This text then examines the total solubility of oxine in aqueous solution at different pH values. Other chapters consider the distribution of oxine between an aqueous phase and an organic solvent, which can be generally described by an equation where the bar indicates the organic phase species. This book discusses as well the overall extraction constant involving metal chelate formation. The final chapter deals with the overall stability constants of metal oxinate. This book is a valuable resource for geochemists, chemists, scientists, and research workers.
Book Synopsis Strategies and Solutions to Advanced Organic Reaction Mechanisms by : Andrei Hent
Download or read book Strategies and Solutions to Advanced Organic Reaction Mechanisms written by Andrei Hent and published by Academic Press. This book was released on 2019-06-26 with total page 884 pages. Available in PDF, EPUB and Kindle. Book excerpt: Strategies and Solutions to Advanced Organic Reaction Mechanisms: A New Perspective on McKillop's Problems builds upon Alexander (Sandy) McKillop's popular text, Solutions to McKillop's Advanced Problems in Organic Reaction Mechanisms, providing a unified methodological approach to dealing with problems of organic reaction mechanism. This unique book outlines the logic, experimental insight and problem-solving strategy approaches available when dealing with problems of organic reaction mechanism. These valuable methods emphasize a structured and widely applicable approach relevant for both students and experts in the field. By using the methods described, advanced students and researchers alike will be able to tackle problems in organic reaction mechanism, from the simple and straight forward to the advanced.
Book Synopsis Progress in Physical Organic Chemistry by : Robert W. Taft
Download or read book Progress in Physical Organic Chemistry written by Robert W. Taft and published by John Wiley & Sons. This book was released on 2009-09-17 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Physical Organic Chemistry is dedicated to reviewing the latest investigations into organic chemistry that use quantitative and mathematical methods. These reviews help readers understand the importance of individual discoveries and what they mean to the field as a whole. Moreover, the authors, leading experts in their fields, offer unique and thought-provoking perspectives on the current state of the science and its future directions. With so many new findings published in a broad range of journals, Progress in Physical Organic Chemistry fills the need for a central resource that presents, analyzes, and contextualizes the major advances in the field. The articles published in Progress in Physical Organic Chemistry are not only of interest to scientists working in physical organic chemistry, but also scientists working in the many subdisciplines of chemistry in which physical organic chemistry approaches are now applied, such as biochemistry, pharmaceutical chemistry, and materials and polymer science. Among the topics explored in this series are reaction mechanisms; reactive intermediates; combinatorial strategies; novel structures; spectroscopy; chemistry at interfaces; stereochemistry; conformational analysis; quantum chemical studies; structure-reactivity relationships; solvent, isotope and solid-state effects; long-lived charged, sextet or open-shell species; magnetic, non-linear optical and conducting molecules; and molecular recognition.
Book Synopsis Mechanisation and Automation in Dairy Technology by : Chemical Rubber Company
Download or read book Mechanisation and Automation in Dairy Technology written by Chemical Rubber Company and published by CRC Press. This book was released on 1976 with total page 580 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Environmental Organic Chemistry by : René P. Schwarzenbach
Download or read book Environmental Organic Chemistry written by René P. Schwarzenbach and published by John Wiley & Sons. This book was released on 2005-06-24 with total page 1329 pages. Available in PDF, EPUB and Kindle. Book excerpt: Environmental Organic Chemistry focuses on environmental factors that govern the processes that determine the fate of organic chemicals in natural and engineered systems. The information discovered is then applied to quantitatively assessing the environmental behaviour of organic chemicals. Now in its 2nd edition this book takes a more holistic view on physical-chemical properties of organic compounds. It includes new topics that address aspects of gas/solid partitioning, bioaccumulation, and transformations in the atmosphere. Structures chapters into basic and sophisticated sections Contains illustrative examples, problems and case studies Examines the fundamental aspects of organic, physical and inorganic chemistry - applied to environmentally relevant problems Addresses problems and case studies in one volume
Book Synopsis CRC Handbook of Chemistry and Physics, 93rd Edition by : William M. Haynes
Download or read book CRC Handbook of Chemistry and Physics, 93rd Edition written by William M. Haynes and published by CRC Press. This book was released on 2012-06-22 with total page 2657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mirroring the growth and direction of science for a century, the Handbook, now in its 93rd edition, continues to be the most accessed and respected scientific reference in the world. An authoritative resource consisting tables of data, its usefulness spans every discipline. This edition includes 17 new tables in the Analytical Chemistry section, a major update of the CODATA Recommended Values of the Fundamental Physical Constants and updates to many other tables. The book puts physical formulas and mathematical tables used in labs every day within easy reach. The 93rd edition is the first edition to be available as an eBook.
