Design, Synthesis and Study of Photophysical Properties of Re(I) and Ru(II) Metal Center Organometallic Complexes as Dyes for Harvesting Sunlight

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ISBN 13 :
Total Pages : 166 pages
Book Rating : 4.:/5 (19 download)

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Book Synopsis Design, Synthesis and Study of Photophysical Properties of Re(I) and Ru(II) Metal Center Organometallic Complexes as Dyes for Harvesting Sunlight by : Venugopal R. Komreddy

Download or read book Design, Synthesis and Study of Photophysical Properties of Re(I) and Ru(II) Metal Center Organometallic Complexes as Dyes for Harvesting Sunlight written by Venugopal R. Komreddy and published by . This book was released on 2018 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Dyes and Photoactive Molecules in Microporous Systems

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Publisher : Springer Nature
ISBN 13 : 303056634X
Total Pages : 411 pages
Book Rating : 4.0/5 (35 download)

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Book Synopsis Dyes and Photoactive Molecules in Microporous Systems by : Virginia Martínez-Martínez

Download or read book Dyes and Photoactive Molecules in Microporous Systems written by Virginia Martínez-Martínez and published by Springer Nature. This book was released on 2020-12-15 with total page 411 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides an overview of the design, synthesis, and characterization of different photoactive hybrid organic-inorganic materials, based on the combination of mainly organic molecules and inorganic nanostructures, tackling their uses in different scientific fields from photonics to biomedicine. There are many examples extensively describing how the confinement of organic compounds (i.e. chromophores, photochromic molecules or photoreactants), or other photoactive compounds (i.e.metal clusters) into several microporous systems can modulate the photophysical properties and photochemical reactions leading to interesting applications. Among (ordered)-hosts, different systems of diverse nature are widely used, such as the, the 1D- or 3D- channels of zeolitic frameworks, interlayer space of 2D-clays, the organic nanospace of curcubituril and cyclodextrins or the organo-inorganic porous crystalline MOFs systems. This volume highlights the advances of these photoactive materials and aims to be an inspiration for researchers working in materials science and photochemistry, including chemists, material engineers, physicists, biologists, and medical researchers.

"Design, Synthesis, and Photophysical Properties of Novel Chalcogenorhodamine Dyes for Various Applications"

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ISBN 13 :
Total Pages : 346 pages
Book Rating : 4.:/5 (1 download)

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Book Synopsis "Design, Synthesis, and Photophysical Properties of Novel Chalcogenorhodamine Dyes for Various Applications" by : Mark William Kryman

Download or read book "Design, Synthesis, and Photophysical Properties of Novel Chalcogenorhodamine Dyes for Various Applications" written by Mark William Kryman and published by . This book was released on 2015 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract: Chalcogenorhodamine dyes bearing thioamide or amide moieties are transported at different rates by P-gp, with amide-containing dyes being transported more rapidly than the analogous thioamide derivatives. Additionally, thiorhodamine dyes with fused ring moieties at the 3-amino position have shown decreased ATPase stimulation and increased binding affinity for P-gp relative to the analogous dimethylamino dyes. Based on these results, a synthetic route toward a new rhodamine precursor with fused ring moieties at both 3- and 6- amino positions, the bis(julolidyl) xanthone (57-E), was developed. The two julolidyl moieties impart added rigidity, increased lipophilicity, and bathochromic shifts in the wavelength of maximum absorption in the resulting dyes. The thioamide- and amide-containing bis(julolidyl) selenorhodamines are more effective photosensitizers in the PDT of P-gp-expressing cancer cells, with EC50 values an order of magnitude lower than previously reported selenium-containing photosensitizers. The bis(julolidyl) selenorhodamine 6 is rapidly transported by P-gp, localizes in the mitochondria of cancer cells, and selectively photodepletes malignant T cells while sparing T cells necessary for healthy immune function. Several tellurorhodamines with phenyl, 2-methylphenyl, and 2,4,6-trimethylphenyl substituents at the 9-position were prepared and evaluated for their potential use as reversible fluorescence probes based on a Te(II)/Te(IV) redox cycle. While the tellurides were essentially nonfluorescent ([phi]FL

Design, Synthesis, Photochromic and Photophysical Studies of Dithienylethene-Containing Heteroacenes, Alkynyls, Diimines and Their Metal Complexes

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ISBN 13 : 9781361273081
Total Pages : pages
Book Rating : 4.2/5 (73 download)

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Book Synopsis Design, Synthesis, Photochromic and Photophysical Studies of Dithienylethene-Containing Heteroacenes, Alkynyls, Diimines and Their Metal Complexes by : Hok-Lai Wong

Download or read book Design, Synthesis, Photochromic and Photophysical Studies of Dithienylethene-Containing Heteroacenes, Alkynyls, Diimines and Their Metal Complexes written by Hok-Lai Wong and published by . This book was released on 2017-01-26 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Design, Synthesis, Photochromic and Photophysical Studies of Dithienylethene-containing Heteroacenes, Alkynyls, Diimines and Their Metal Complexes" by Hok-lai, Wong, 黃學禮, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b4587474 Subjects: Metal complexes - Synthesis Photochromism Photochemistry

Design, Synthesis, and Application of Photoactive Complexes of Biologically Relevant Metals

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ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (862 download)

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Book Synopsis Design, Synthesis, and Application of Photoactive Complexes of Biologically Relevant Metals by : Celina Gwizdala

Download or read book Design, Synthesis, and Application of Photoactive Complexes of Biologically Relevant Metals written by Celina Gwizdala and published by . This book was released on 2013 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synthesis and Characterization of Dyes with Solar Energy Applications

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ISBN 13 :
Total Pages : 172 pages
Book Rating : 4.:/5 (834 download)

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Book Synopsis Synthesis and Characterization of Dyes with Solar Energy Applications by : Bradley J. Brennan

Download or read book Synthesis and Characterization of Dyes with Solar Energy Applications written by Bradley J. Brennan and published by . This book was released on 2012 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt: The sun provides Earth with a virtually limitless source of energy capable of sustaining all of humanity's needs. Photosynthetic organisms have exploited this energy for eons. However, efficiently converting solar radiation into a readily available and easily transportable form is complex. New materials with optimized physical, electrochemical, and photophysical properties are at the forefront of organic solar energy conversion research. In the work presented herein, porphyrin and organometallic dyes with widely-varied properties were studied for solar energy applications. In one project, porphyrins and porphyrin-fullerene dyads with aniline-like features were polymerized via electrochemical methods into semiconductive thin films. These were shown to have high visible light absorption and stable physical and electrochemical properties. However, experimentation using porphyrin polymer films as both the light absorber and semiconductor in a photoelectrochemical cell showed relatively low efficiency of converting absorbed solar energy into electricity. In separate work, tetra-aryl porphyrin derivatives were examined in conjunction with wide-bandgap semiconductive oxides TiO2 and SnO2. Carboxylic acid-, phosphonic acid-, and silatrane-functionalized porphyrins were obtained or synthesized for attachment to the metal oxide species. Electrochemical, photophysical, photoelectrochemical, and surface stability studies of the porphyrins were performed for comparative purposes. The order of surface linkage stability on TiO2 in alkaline conditions, from most stable to least, was determined to be siloxane> phosphonate> carboxylate. Finally, porphyrin dimers fused via their meso and beta positions were synthesized using a chemical oxidative synthesis with a copper(II) oxidant. The molecules exhibit strong absorption in the visible and near-infrared spectral regions as well as interesting electrochemical properties suggesting possible applications in light harvesting and redox catalysis.

Design, Synthesis, Photophysics and Photochromic Study of Dithienylethene-containing N-heterocycles and Their D8 and D10 Metal Complexes

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ISBN 13 :
Total Pages : 716 pages
Book Rating : 4.:/5 (228 download)

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Book Synopsis Design, Synthesis, Photophysics and Photochromic Study of Dithienylethene-containing N-heterocycles and Their D8 and D10 Metal Complexes by : Ka-wai Lee (Chemist.)

Download or read book Design, Synthesis, Photophysics and Photochromic Study of Dithienylethene-containing N-heterocycles and Their D8 and D10 Metal Complexes written by Ka-wai Lee (Chemist.) and published by . This book was released on 2007 with total page 716 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Design, Synthesis, and Evaluation of Manganese(I) Photoinduced CO-releasing Molecules and Water-soluble Lanthanide Cages

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (137 download)

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Book Synopsis Design, Synthesis, and Evaluation of Manganese(I) Photoinduced CO-releasing Molecules and Water-soluble Lanthanide Cages by : Shabnam Pordel

Download or read book Design, Synthesis, and Evaluation of Manganese(I) Photoinduced CO-releasing Molecules and Water-soluble Lanthanide Cages written by Shabnam Pordel and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon monoxide (CO) is a toxic gas that has been known as the “silent killer” for decades. At high concentrations, CO reacts with hemoglobin, impairing its ability to transfer oxygen throughout the body. At low concentrations, however, CO has anti-cancer and anti-inflammatory effects. CO has also been shown to increase the sensitivity of certain types of cancer cells to the reactive oxygen species (ROS) produced by chemotherapeutics, thereby reducing drug resistance. One way to deliver CO in a controlled and safe manner is through the use of photoCORMs, or photoactivated CO releasing molecules. Transition metal-based photoCORMs are a class of molecules that release CO by breaking the M-CO bond upon exposure to light. In Chapters 2 and 3, my research study the effect of ligand set variation (both electronically and sterically) around the Mn(I) metal center on the photophysical and photochemical properties, as well as the assignment of photochemical intermediate formation during visible light irradiation. In Chapter 4, we designed a system that combined photo-activated CO delivery and singlet oxygen (1O2). The photophysical and photochemical properties of two Mn(I)-based photoCORMs sensitized with a luminescent BODIPY, as well as their ability to generate singlet oxygen during visible light irradiation were investigated.iv In Chapter 5, my focus was on water-soluble 3D supramolecular coordination cages (SCCs). The internal cavity incorporated in these structures allows them to encapsulate various guest molecules. Water-soluble Ln(III)-based SCCs are scarce, and the arrangement of water molecules inside the cavity, as well as the recognition properties of the latter, are mostly unknown. The study of such interactions would be of interest to the growing field of SCCs. To this end, we designed and synthesized a water-soluble Eu(III)-based supramolecular coordination cage with the general formula of Eu2L3 and a triplestranded helicate structure. The guest binding properties of the Eu2L3 cage were studied with smaller mono- and di-cationic organic guests through 1H NMR titration in D2O

Periodic Mesoporous Organosilicas

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Publisher : Springer
ISBN 13 : 9811329591
Total Pages : 333 pages
Book Rating : 4.8/5 (113 download)

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Book Synopsis Periodic Mesoporous Organosilicas by : Chang-Sik Ha

Download or read book Periodic Mesoporous Organosilicas written by Chang-Sik Ha and published by Springer. This book was released on 2018-11-07 with total page 333 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive overview of the fundamental properties, preparation routes and applications of a novel class of organic–inorganic nanocomposites known as periodic mesoporous organosilicas (PMOs). Mesoporous silicas are amorphous inorganic materials which have silicon and oxygen atoms in their framework with pore size ranging from 2 to 50 nm. They can be synthesized from surfactants as templates for the polycondensation of various silicon sources such as tetraalkoxysilane. In general, mesoporous silica materials possess high surface areas, tunable pore diameters, high pore volumes and well uniformly organized porosity. The stable chemical property and the variable ability for chemical modification makes them ideal for many applications such as drug carrier, sensor, separation, catalyst, and adsorbent. Among such mesoporous silicas, in 1999, three groups in Canada, Germany, and Japan independently developed a novel class of organic–inorganic nanocomposites known as periodic mesoporous organosilicas (PMOs). The organic functional groups in the frameworks of these solids allow tuning of their surface properties and modification of the bulk properties of the material. The book discusses the properties of PMOs, their preparation, different functionalities and morphology, before going on to applications in fields such as catalysis, drug delivery, sensing, optics, electronic devices, environmental applications (gas sensing and gas adsorption), biomolecule adsorption and chromatography. The book provides fundamental understanding of PMOs and their advanced applications for general materials chemists and is an excellent guide to these promising novel materials for graduate students majoring in chemical engineering, chemistry, polymer science and materials science and engineering.

Applied Photochemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 9048138302
Total Pages : 619 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Applied Photochemistry by : Rachel C. Evans

Download or read book Applied Photochemistry written by Rachel C. Evans and published by Springer Science & Business Media. This book was released on 2014-07-08 with total page 619 pages. Available in PDF, EPUB and Kindle. Book excerpt: Applied Photochemistry encompasses the major applications of the chemical effects resulting from light absorption by atoms and molecules in chemistry, physics, medicine and engineering, and contains contributions from specialists in these key areas. Particular emphasis is placed both on how photochemistry contributes to these disciplines and on what the current developments are. The book starts with a general description of the interaction between light and matter, which provides the general background to photochemistry for non-specialists. The following chapters develop the general synthetic and mechanistic aspects of photochemistry as applied to both organic and inorganic materials, together with types of materials which are useful as light absorbers, emitters, sensitisers, etc. for a wide variety of applications. A detailed discussion is presented on the photochemical processes occurring in the Earth’s atmosphere, including discussion of important current aspects such as ozone depletion. Two important distinct, but interconnected, applications of photochemistry are in photocatalytic treatment of wastes and in solar energy conversion. Semiconductor photochemistry plays an important role in these and is discussed with reference to both of these areas. Free radicals and reactive oxygen species are of major importance in many chemical, biological and medical applications of photochemistry, and are discussed in depth. The following chapters discuss the relevance of using light in medicine, both with various types of phototherapy and in medical diagnostics. The development of optical sensors and probes is closely related to diagnostics, but is also relevant to many other applications, and is discussed separately. Important aspects of applied photochemistry in electronics and imaging, through processes such as photolithography, are discussed and it is shown how this is allowing the increasing miniaturisation of semiconductor devices for a wide variety of electronics applications and the development of nanometer scale devices. The final two chapters provide the basic ideas necessary to set up a photochemical laboratory and to characterise excited states. This book is aimed at those in science, engineering and medicine who are interested in applying photochemistry in a broad spectrum of areas. Each chapter has the basic theories and methods for its particular applications and directs the reader to the current, important literature in the field, making Applied Photochemistry suitable for both the novice and the experienced photochemist.

Bioinorganic Photochemistry

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Publisher : John Wiley & Sons
ISBN 13 : 9781405193276
Total Pages : 398 pages
Book Rating : 4.1/5 (932 download)

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Book Synopsis Bioinorganic Photochemistry by : Grazyna Stochel

Download or read book Bioinorganic Photochemistry written by Grazyna Stochel and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: Bioinorganic photochemistry is a rapidly evolving field integrating inorganic photochemistry with biological, medical and environmental sciences. The interactions of light with inorganic species in natural systems, and the applications in artificial systems of medical or environmental importance, form the basis of this challenging inter-disciplinary research area. Bioinorganic Photochemistry provides a comprehensive overview of the concepts and reactions fundamental to the field, illustrating important applications in biological, medical and environmental sciences. Topics covered include: Cosmic and environmental photochemistry Photochemistry of biologically relevant nanoassemblies Molecular aspects of photosynthesis Photoinduced electron transfer in biosystems Modern therapeutic strategies in photomedicine The book concludes with an outlook for the future of environmental protection, discussing emerging techniques in the field of pollution abatement, and the potential for bioinorganic photochemistry as a pathway to developing cheap, environmentally friendly sources of energy. Written as an authoritative guide for researchers involved in the development of bioinorganic photochemical processes, Bioinorganic Photochemistry is also accessible to scientists new to the field, and will be a key reference source for advanced courses in inorganic, and bioinorganic chemistry.

Heterogeneous Photocatalysis

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Publisher : Springer
ISBN 13 : 3662487195
Total Pages : 419 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Heterogeneous Photocatalysis by : Juan Carlos Colmenares

Download or read book Heterogeneous Photocatalysis written by Juan Carlos Colmenares and published by Springer. This book was released on 2015-12-24 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book explains the principles and fundamentals of photocatalysis and highlights the current developments and future potential of the green-chemistry-oriented applications of various inorganic, organic, and hybrid photocatalysts. The book consists of eleven chapters, including the principles and fundamentals of heterogeneous photocatalysis; the mechanisms and dynamics of surface photocatalysis; research on TiO2-based composites with unique nanostructures; the latest developments and advances in exploiting photocatalyst alternatives to TiO2; and photocatalytic materials for applications other than the traditional degradation of pollutants, such as carbon dioxide reduction, water oxidation, a complete spectrum of selective organic transformations and water splitting by photocatalytic reduction. In addition, heterogeneized polyoxometalate materials for photocatalytic purposes and the proper design of photocatalytic reactors and modeling of light are also discussed. This book appeals to a wide readership of the academic and industrial researchers and it can also be used in the classroom for undergraduate and graduate students focusing on heterogeneous photocatalysis, sustainable chemistry, energy conversion and storage, nanotechnology, chemical engineering, environmental protection, optoelectronics, sensors, and surface and interface science. Juan Carlos Colmenares is a Professor at the Institute of Physical Chemistry, Polish Academy of Sciences, Poland. Yi-Jun Xu is a Professor at the State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, China.

Handbook of Photochemistry

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Publisher : CRC Press
ISBN 13 : 1420015192
Total Pages : 662 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Handbook of Photochemistry by : Marco Montalti

Download or read book Handbook of Photochemistry written by Marco Montalti and published by CRC Press. This book was released on 2006-02-21 with total page 662 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of the second edition of this handbook in 1993, the field of photochemical sciences has continued to expand across several disciplines including organic, inorganic, physical, analytical, and biological chemistries, and, most recently, nanosciences. Emphasizing the important role light-induced processes play in all of these fie

Nanoenergy

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Publisher : Springer
ISBN 13 : 3319628003
Total Pages : 338 pages
Book Rating : 4.3/5 (196 download)

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Book Synopsis Nanoenergy by : Flavio L Souza

Download or read book Nanoenergy written by Flavio L Souza and published by Springer. This book was released on 2017-08-30 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discuss the recent advances and future trends of nanoscience in solar energy conversion and storage. This second edition revisits and updates all the previous book chapters, adding the latest advances in the field of Nanoenergy. Four new chapters are included on the principles and fundamentals of artificial photosynthesis using metal transition semiconductors, perovskite solar cells, hydrogen storage and neutralization batteries. More fundamental aspects can be found in this book, increasing the comparison between theory-experimental achievements and latest developments in commercial devices.

Photochemistry and Photophysics of Coordination Compounds I

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Publisher : Springer
ISBN 13 : 3540733477
Total Pages : 282 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis Photochemistry and Photophysics of Coordination Compounds I by : Vincenzo Balzani

Download or read book Photochemistry and Photophysics of Coordination Compounds I written by Vincenzo Balzani and published by Springer. This book was released on 2007-07-31 with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents critical reviews of the current position and future trends in modern chemical research. It offers short and concise reports on chemistry, each written by world renowned experts.

Perovskite and Piezoelectric Materials

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Publisher : BoD – Books on Demand
ISBN 13 : 1789856655
Total Pages : 230 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Perovskite and Piezoelectric Materials by : Someshwar Pola

Download or read book Perovskite and Piezoelectric Materials written by Someshwar Pola and published by BoD – Books on Demand. This book was released on 2021-01-27 with total page 230 pages. Available in PDF, EPUB and Kindle. Book excerpt: Investigating in the area of perovskite materials and the fabrication of devices for properties in optoelectronics, we have presented a brief outline of perovskite materials. The authors present a fairly comprehensive arrangement of this very active area of research, with its past changes and present position and outlooks. Discussions are presented regarding photocatalysis, fabrication of solar cell devices and their stability, lead-free materials, as well as thermoelectric and piezoelectric applications. In view of the present status of perovskite materials, I am assured that each chapter of the book will be of boundless encouragement for researchers, scientists, and academicians working in this field.

Photon Upconversion Nanomaterials

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Publisher : Springer
ISBN 13 : 3662455978
Total Pages : 428 pages
Book Rating : 4.6/5 (624 download)

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Book Synopsis Photon Upconversion Nanomaterials by : Fan Zhang

Download or read book Photon Upconversion Nanomaterials written by Fan Zhang and published by Springer. This book was released on 2014-12-11 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the latest advances made in both fundamental studies and potential applications of upconversion nanomaterials, particularly in the field of high-resolution in vitro bioanalysis and in vivo imaging. This book starts with the synthesis and characterization, and focuses on applications ranging from materials science to biology. Above all, it describes cutting-edge advances in upconversion nanophosphor (UCNP)-based applications in multiplexed encoding, guest delivery and release systems, photodynamic therapy (PDT), solar cells, photocatalysis and so on. The major barriers that currently prevent UCNPs from being used in mainstream applications are also presented in detail.