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Author : Nicolae Avram
Publisher :
ISBN 13 : 9780080451480
Total Pages : pages
Book Rating : 4.4/5 (514 download)
Download or read book Crystal Field Analysis written by Nicolae Avram and published by . This book was released on 2008-08 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J. Mulak
Publisher : Elsevier
ISBN 13 : 0080530710
Total Pages : 319 pages
Book Rating : 4.0/5 (85 download)
Download or read book The Effective Crystal Field Potential written by J. Mulak and published by Elsevier. This book was released on 2000-06-22 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: As it results from the very nature of things, the spherical symmetry of the surrounding of a site in a crystal lattice or an atom in a molecule can never occur. Therefore, the eigenfunctions and eigenvalues of any bound ion or atom have to differ from those of spherically symmetric respective free ions. In this way, the most simplified concept of the crystal field effect or ligand field effect in the case of individual molecules can be introduced. The conventional notion of the crystal field potential is narrowed to its non-spherical part only through ignoring the dominating spherical part which produces only a uniform energy shift of gravity centres of the free ion terms. It is well understood that the non-spherical part of the effective potential "seen" by open-shell electrons localized on a metal ion plays an essential role in most observed properties. Light adsorption, electron paramagnetic resonance, inelastic neutron scattering and basic characteristics derived from magnetic and thermal measurements, are only examples of a much wider class of experimental results dependent on it. The influence is discerned in all kinds of materials containing unpaired localized electrons: ionic crystals, semiconductors and metallic compounds including materials as intriguing as high-Tc superconductors, or heavy fermion systems. It is evident from the above that we deal with a widespread effect relative to all free ion terms except those which can stand the lowered symmetry, e.g. S-terms. Despite the universality of the phenomenon, the available handbooks on solid state physics pay only marginal attention to it, merely making mention of its occurrence. Present understanding of the origins of the crystal field potential differs essentially from the pioneering electrostatic picture postulated in the twenties. The considerable development of the theory that has been put forward since then can be traced in many regular articles scattered throughout the literature. The last two decades have left their impression as well but, to the authors' best knowledge, this period has not been closed with a more extended review. This has also motivated us to compile the main achievements in the field in the form of a book.
Author : D. J. Newman
Publisher : Cambridge University Press
ISBN 13 : 0521591244
Total Pages : 306 pages
Book Rating : 4.5/5 (215 download)
Download or read book Crystal Field Handbook written by D. J. Newman and published by Cambridge University Press. This book was released on 2000-09-21 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, first published in 2000, is based on the modern conceptual understanding of crystal fields.
Author : Nicolae M. Avram
Publisher : Springer Science & Business Media
ISBN 13 : 3642308384
Total Pages : 278 pages
Book Rating : 4.6/5 (423 download)
Download or read book Optical Properties of 3d-Ions in Crystals written by Nicolae M. Avram and published by Springer Science & Business Media. This book was released on 2013-05-13 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Optical Properties of 3d-Ions in Crystals: Spectroscopy and Crystal Field Analysis" discusses spectral, vibronic and magnetic properties of 3d-ions in a wide range of crystals, used as active media for solid state lasers and potential candidates for this role. Crystal field calculations (including first-principles calculations of energy levels and absorption spectra) and their comparison with experimental spectra, the Jahn-Teller effect, analysis of vibronic spectra, materials science applications are systematically presented. The book is intended for researchers and graduate students in crystal spectroscopy, materials science and optical applications. Dr. N.M. Avram is an Emeritus Professor at the Physics Department, West University of Timisoara, Romania; Dr. M.G. Brik is a Professor at the Institute of Physics, University of Tartu, Estonia.
Author : Li Wang
Publisher :
ISBN 13 :
Total Pages : 188 pages
Book Rating : 4.:/5 (13 download)
Download or read book A crystal field analysis of CeF3 and CaF2:Yb written by Li Wang and published by . This book was released on 1995 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Satoru Sugano
Publisher : Elsevier
ISBN 13 : 0323154794
Total Pages : 348 pages
Book Rating : 4.3/5 (231 download)
Download or read book Multiplets of Transition-Metal Ions in Crystals written by Satoru Sugano and published by Elsevier. This book was released on 2012-12-02 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Multiplets of Transition-Metal Ions in Crystals provides information pertinent to ligand field theory. This book discusses the fundamentals of quantum mechanics and the theory of atomic spectra. Comprised of 10 chapters, this book starts with an overview of the qualitative nature of the splitting of the energy level as well as the angular behavior of the wavefunctions. This text then examines the problem of obtaining the energy eigenvalues and eigenstates of the two-electron systems, in which two electrons are accommodated in the t2g and eg shells in a variety of ways. Other chapters discuss the ligand-field potential, which is invariant to any symmetry operation in the group to which symmetry of the system belongs. This book discusses as well the approximate method of expressing molecular orbitals (MO) by a suitable linear combination of atomic orbitals (AO). The final chapter discusses the MO in molecules and the self-consistent field theory of Hartree–Fock. This book is a valuable resource for research physicists, chemists, electronic engineers, and graduate students.
Author : Roger G. Burns
Publisher : Cambridge University Press
ISBN 13 : 0521430771
Total Pages : 563 pages
Book Rating : 4.5/5 (214 download)
Download or read book Mineralogical Applications of Crystal Field Theory written by Roger G. Burns and published by Cambridge University Press. This book was released on 1993-09-16 with total page 563 pages. Available in PDF, EPUB and Kindle. Book excerpt: The second edition of this classic book provides an updated look at crystal field theory and its applications.
Author : M. Gerloch
Publisher : CUP Archive
ISBN 13 : 9780521249393
Total Pages : 616 pages
Book Rating : 4.2/5 (493 download)
Download or read book Magnetism and Ligand-Field Analysis written by M. Gerloch and published by CUP Archive. This book was released on 1983 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book, a synthesis of old and new notions straddling the disciplines of physics and chemistry is described.
Author : Andrzej Murasik
Publisher :
ISBN 13 :
Total Pages : 17 pages
Book Rating : 4.:/5 (249 download)
Download or read book Analysis of Crystal Field Splitting in TmIn 3 by Means of Powder Neutron Spectroscopy written by Andrzej Murasik and published by . This book was released on 2001 with total page 17 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Wayne M. Saslow
Publisher : Elsevier
ISBN 13 : 008050521X
Total Pages : 809 pages
Book Rating : 4.0/5 (85 download)
Download or read book Electricity, Magnetism, and Light written by Wayne M. Saslow and published by Elsevier. This book was released on 2002-07-19 with total page 809 pages. Available in PDF, EPUB and Kindle. Book excerpt: A very comprehensive introduction to electricity, magnetism and optics ranging from the interesting and useful history of the science, to connections with current real-world phenomena in science, engineering and biology, to common sense advice and insight on the intuitive understanding of electrical and magnetic phenomena. This is a fun book to read, heavy on relevance, with practical examples, such as sections on motors and generators, as well as `take-home experiments' to bring home the key concepts. Slightly more advanced than standard freshman texts for calculus-based engineering physics courses with the mathematics worked out clearly and concisely. Helpful diagrams accompany the discussion. The emphasis is on intuitive physics, graphical visualization, and mathematical implementation. Electricity, Magnetism, and Light is an engaging introductory treatment of electromagnetism and optics for second semester physics and engineering majors. Focuses on conceptual understanding, with an emphasis on relevance and historical development. Mathematics is specific and avoids unnecessary technical development. Emphasis on physical concepts, analyzing the electromagnetic aspects of many everyday phenomena, and guiding readers carefully through mathematical derivations. Provides a wealth of interesting information, from the history of the science of electricity and magnetism, to connections with real world phenomena in science, engineering, and biology, to common sense advice and insight on the intuitive understanding of electrical and magnetic phenomena
Author : Heidi Wines
Publisher :
ISBN 13 :
Total Pages : 162 pages
Book Rating : 4.:/5 (382 download)
Download or read book Reservoir Characterization of Crystal Field and Analysis of the Tow#1-3, HD-1 Well, Montcalm County, Michigan written by Heidi Wines and published by . This book was released on 1997 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : Henry Goldberg
Publisher :
ISBN 13 :
Total Pages : 102 pages
Book Rating : 4.:/5 (31 download)
Download or read book On the Nature of the Crystal Field Approximation written by Henry Goldberg and published by . This book was released on 1960 with total page 102 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert R. Crichton
Publisher : Elsevier
ISBN 13 : 0080556221
Total Pages : 383 pages
Book Rating : 4.0/5 (85 download)
Download or read book Biological Inorganic Chemistry written by Robert R. Crichton and published by Elsevier. This book was released on 2007-12-11 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: The importance of metals in biology, the environment and medicine has become increasingly evident over the last twenty five years. The study of the multiple roles of metal ions in biological systems, the rapidly expanding interface between inorganic chemistry and biology constitutes the subject called Biological Inorganic Chemistry. The present text, written by a biochemist, with a long career experience in the field (particularly iron and copper) presents an introduction to this exciting and dynamic field. The book begins with introductory chapters, which together constitute an overview of the concepts, both chemical and biological, which are required to equip the reader for the detailed analysis which follows. Pathways of metal assimilation, storage and transport, as well as metal homeostasis are dealt with next. Thereafter, individual chapters discuss the roles of sodium and potassium, magnesium, calcium, zinc, iron, copper, nickel and cobalt, manganese, and finally molybdenum, vanadium, tungsten and chromium. The final three chapters provide a tantalising view of the roles of metals in brain function, biomineralization and a brief illustration of their importance in both medicine and the environment. Relaxed and agreeable writing style. The reader will not only fiind the book easy to read, the fascinating anecdotes and footnotes will give him pegs to hang important ideas on.Written by a biochemist. Will enable the reader to more readily grasp the biological and clinical relevance of the subject.Many colour illustrations. Enables easier visualization of molecular mechanismsWritten by a single author. Ensures homgeneity of style and effective cross referencing between chapters
Author : M. Date
Publisher : Elsevier
ISBN 13 : 0444599193
Total Pages : 359 pages
Book Rating : 4.4/5 (445 download)
Download or read book High Field Magnetism written by M. Date and published by Elsevier. This book was released on 2012-12-02 with total page 359 pages. Available in PDF, EPUB and Kindle. Book excerpt: High Field Magnetism presents the proceedings of the International Symposium on High Field Magnetism held at the Osaka University and Hotel Plaza in Osaka on September 13-14, 1982 as a satellite symposium of the International Conference on Magnetism-1982-Kyoto. The symposium tackled a wide variety of high field generation methods and material systems, with magnetism orientation as the main objective. A special Technical Exposition was held in the poster session where representatives from MIT, Grenoble, and other high field facilities were invited to give a descriptive review of each laboratory. This book is divided into eight parts, beginning with an introductory chapter into the subject of high field magnetism. The succeeding parts focus on magnetic interactions and phase transitions in high magnetic fields; metals and alloys in high magnetic fields; high field superconductivity; spin and charge fluctuations in high magnetic fields; high field magneto-optics; high field magnetic resonance; and high magnetic field facilities and techniques. This book will be of interest to practitioners in the fields of cryogenic engineering and applied physics.
Author :
Publisher : North Holland
ISBN 13 : 9780444634832
Total Pages : 0 pages
Book Rating : 4.6/5 (348 download)
Download or read book Handbook on the Physics and Chemistry of Rare Earths written by and published by North Holland. This book was released on 2015-11-18 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook on the Physics and Chemistry of Rare Earths is a continuous series of books covering all aspects of rare earth science, including chemistry, life sciences, materials science, and physics. The main emphasis of the handbook is on rare earth elements [Sc, Y and the lanthanides (La through Lu)], but whenever relevant, information is also included on the closely related actinide elements. The individual chapters are comprehensive, broad, up-to-date, critical reviews written by highly experienced invited experts. The series, which was started in 1978 by Professor Karl A. Gschneidner Jr., combines and integrates both the fundamentals and applications of these elements, now publishing two volumes a year.
Author : M. Gerloch
Publisher : Cambridge University Press
ISBN 13 : 9780521201377
Total Pages : 256 pages
Book Rating : 4.2/5 (13 download)
Download or read book Ligand-Field Parameters written by M. Gerloch and published by Cambridge University Press. This book was released on 1973-08-02 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume was originally published in 1973. The nature of the non-symmetry determined aspects of ligand-field theory receives inadequate treatment in most texts. This book is concerned with the nature of the ligand-field parameters used to describe the electronic properties of transition metal complexes having cubic and lower symmetries. These radial parameters constitute the non-symmetry-determined part of ligand-field theory. Symmetry-based properties are discussed here only to emphasize the separate roles of splitting factors and symmetry. The reader is assumed to be familiar with the usual approach to ligand-field theory and with elementary group theory.
