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Author :
Publisher :
ISBN 13 :
Total Pages : 288 pages
Book Rating : 4.F/5 ( download)
Download or read book Uranium: Coordination compounds (including organouranium compounds) written by and published by . This book was released on 1980 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : L.R. Morss
Publisher : Springer Science & Business Media
ISBN 13 : 1402035985
Total Pages : 4059 pages
Book Rating : 4.4/5 (2 download)
Download or read book The Chemistry of the Actinide and Transactinide Elements (3rd ed., Volumes 1-5) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2007-12-31 with total page 4059 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of the Actinide and Transactinide Elements is a contemporary and definitive compilation of chemical properties of all of the actinide elements, especially of the technologically important elements uranium and plutonium, as well as the transactinide elements. In addition to the comprehensive treatment of the chemical properties of each element, ion, and compound from atomic number 89 (actinium) through to 109 (meitnerium), this multi-volume work has specialized and definitive chapters on electronic theory, optical and laser fluorescence spectroscopy, X-ray absorption spectroscopy, organoactinide chemistry, thermodynamics, magnetic properties, the metals, coordination chemistry, separations, and trace analysis. Several chapters deal with environmental science, safe handling, and biological interactions of the actinide elements. The Editors invited teams of authors, who are active practitioners and recognized experts in their specialty, to write each chapter and have endeavoured to provide a balanced and insightful treatment of these fascinating elements at the frontier of the periodic table. Because the field has expanded with new spectroscopic techniques and environmental focus, the work encompasses five volumes, each of which groups chapters on related topics. All chapters represent the current state of research in the chemistry of these elements and related fields.
Author : Ionel Haiduc
Publisher : Walter de Gruyter
ISBN 13 : 3110847884
Total Pages : 517 pages
Book Rating : 4.1/5 (18 download)
Download or read book Basic Organometallic Chemistry written by Ionel Haiduc and published by Walter de Gruyter. This book was released on 2011-06-01 with total page 517 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : L.R. Morss
Publisher : Springer Science & Business Media
ISBN 13 : 9400702116
Total Pages : 4511 pages
Book Rating : 4.4/5 (7 download)
Download or read book The Chemistry of the Actinide and Transactinide Elements (Set Vol.1-6) written by L.R. Morss and published by Springer Science & Business Media. This book was released on 2010-10-21 with total page 4511 pages. Available in PDF, EPUB and Kindle. Book excerpt: The fourth edition of "The Chemistry of the Actinide and Transactinide Elements" comprises all chapters in volumes 1 through 5 of the third edition (published in 2006) plus a new volume 6. To remain consistent with the plan of the first edition, “ ... to provide a comprehensive and uniform treatment of the chemistry of the actinide [and transactinide] elements for both the nuclear technologist and the inorganic and physical chemist,” and to be consistent with the maturity of the field, the fourth edition is organized in three parts. The first group of chapters follows the format of the first and second editions with chapters on individual elements or groups of elements that describe and interpret their chemical properties. A chapter on the chemical properties of the transactinide elements follows. The second group, chapters 15-26, summarizes and correlates physical and chemical properties that are in general unique to the actinide elements, because most of these elements contain partially-filled shells of 5f electrons whether present as isolated atoms or ions, as metals, as compounds, or as ions in solution. The third group, chapters 27-39, focuses on specialized topics that encompass contemporary fields related to actinides in the environment, in the human body, and in storage or wastes. Two appendices at the end of volume 5 tabulate important nuclear properties of all actinide and transactinide isotopes. Volume 6 (Chapters 32 through 39) consists of new chapters that focus on actinide species in the environment, actinide waste forms, nuclear fuels, analytical chemistry of plutonium, actinide chalcogenide and hydrothermal synthesis of actinide compounds. The subject and author indices and list of contributors encompass all six volumes.
Author :
Publisher :
ISBN 13 :
Total Pages : 134 pages
Book Rating : 4.:/5 (321 download)
Download or read book Gmelin Handbook of Inorganic Chemistry, Including Organometallic Compounds. Complete Catalog written by and published by . This book was released on 1990 with total page 134 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kenneth W. Bagnall
Publisher : Springer
ISBN 13 : 9783540935155
Total Pages : 352 pages
Book Rating : 4.9/5 (351 download)
Download or read book Coordination Compounds written by Kenneth W. Bagnall and published by Springer. This book was released on 1984-12-21 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kenneth W. Bagnall
Publisher : Springer Science & Business Media
ISBN 13 : 3662063158
Total Pages : 177 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium written by Kenneth W. Bagnall and published by Springer Science & Business Media. This book was released on 2013-12-12 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume of the Gmelin thorium series describes the solid thorium-carbon compounds with the exception of the carbides and coordination compounds of the type 4 ThAn· X B, where B is a neutral ligand. The complex equilibria of the Th + ion with C-containing complexing agents are treated in the ThD1 volume. A first look into this volume demonstrates that a very large number of ThlV complexes has 4 been prepared. This may be explained by the fact that the Th + ion is the largest tetravalent ion of the periodic table. Therefore, the preparation of complexes with, e. g. , multidentate ligands can give a well-established picture of the coordination number as a function of charge and ionic radius. However, there are very few modern and updated comprehensive treatments of such data. Many compounds described in this volume are characterized by no other means than analytical composition and IR spectra (whereby IR spectra of organic ThlV salts mostly give information only on the ligand). Besides thorium carbonate and carbonato complexes, which are relevant for the environmental behaviour of this radioactive element and some organic complexes like oxalates, which are used in the field of analytical and separation chemistry nearly all other compounds described here are practically only of scientific interest. On the other hand in order to have scientifically reliable data, a very large part of these compounds needs further investigation and characterization.
Author : Reiner Ditz
Publisher : Springer Science & Business Media
ISBN 13 : 3662089106
Total Pages : 406 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium written by Reiner Ditz and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 406 pages. Available in PDF, EPUB and Kindle. Book excerpt: In connection with the recent treatment of radium and the actinides, the Gmelin Institute is carrying out the description of thorium and its compounds. The Supplement Volumes A 2, A 3, A 4, and A 5 with the history, isotopes, uses, the recovery of thorium and general properties of thorium atom and ions, the thermodynamics of its compounds and solutions, spectroscopic data and analytical chemistry, biological behavior, health protection and safety control have already been published. The Supplement Volumes C 1, C 2 and C 3 describing the compounds with the noble gases, hydrogen, oxygen compounds and nitrogen compounds are also available; also have been published Supplement Volumes C 5 and C 7 describing the compounds with sulfur, selenium, tellurium, and boron, carbonates, thiocynates, alkoxides, and carboxylates. The Supplement Volumes D 1, D 2, and D 3 describing the properties of thorium ions in solution and the solvent extraction of thorium as well as Supplement Volume E describing the coordination compounds also have been published. The present volume begins, in a summary fashion, with a description of the natural occurrence of the element Th. Especially stressed are those facts that are most important in understanding its geological distribution on Earth (as, e.g., mode of occurrence and distribution among minerals) and its behavior in minerals (as, e.g., mode of occurrence and distribution among minerals) and its behavior in minerals (as, e.g., diadochy and metamictization of minerals). Attached is a tabulation of the highest reported Th or ThO2 content in minerals that normally (by their crystal-chemical formula) do not contain Th. The main part of the present volume describes the minerals of Th. As can be seen from the crystal-chemical formulas, there are, in addition to a few minerals containing Th as the sole cation, a number of minerals that contain Th as an additional cation or as a diadochic element. In the case of diadochic substitution the mineral may represent a Th-rich end member of a solid-solution series and, therefore, is described as a separate Th mineral, or may only sporadically contain higher amounts of Th (no mineral description is given). The mineral descriptions, in this volume including oxides, carbonates and phosphates/siliconphosphates of Th, comprise the following topics: occurence; chemistry; crystal form and structure; optical and other physical properties; and chemical and thermal behavior. The silicates of Th and the deposits of Th will be described in the volume "Thorium" Suppl. Vol. A 1b, that also contains a mineral index for both volumes.
Author : Hans U. Borgstedt
Publisher : Springer Science & Business Media
ISBN 13 : 3662056712
Total Pages : 354 pages
Book Rating : 4.6/5 (62 download)
Download or read book U Uranium written by Hans U. Borgstedt and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 354 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alloys of Uranium with Alkali Metals, Alkaline Earths, and Elements of Main Groups III and IV. The description of uranium and its compounds, for which the Gmelin Institute has started a series of volumes supplementing the main volume of 1936, follows in its arrangement closely the order chosen for the transuranium volumes. Part A treats "The Element", Part B "The Metal and its Alloys", Part C "The Compounds", Part D "The Chemistry in Solution", and finally Part E "The Coordination Compounds". Part E, "The Coordination Compounds" comprises two volumes which already have been finished and are available - completely written in English. Series A comprises 7 volumes which are all available. Series C will comprise 14 volumes of which only volume 6 is missing. Series D consists of 4 volumes dealing with the chemistry in solution, which already have been finished and are available. The present volume describes the alloys and the intermetallic compounds with the metals of main groups I to IV - those systems with semimetals such as boron and germanium are to be found in corresponding volumes in Uranium C series. In the volume B 2 main emphasis is given to the binary systems. The most frequently investigated systems are uranium-beryllium and uranium-aluminium because of their special scientific (U-Be) and technological (U-Al) importance.
Author : Heiko Kleykamp
Publisher : Springer
ISBN 13 : 9783540936459
Total Pages : 160 pages
Book Rating : 4.9/5 (364 download)
Download or read book Thorium Carbides written by Heiko Kleykamp and published by Springer. This book was released on 1992 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: The volume comprises an updated and critical description of the binary and ternary thorium carbides. These compounds are of technological interest because of their possible use as fertile materials in advanced nuclear power reactors. The fuel for the Thermal Breeder consists of a ThC-UC solid solution and that for the Thorium High Temperature Reactor of coated ThC2-UC2 particles. The binary Th-C system and ternary carbides were intensively investigated worldwide for nearly 20 years. Because of general discussions on the use of nuclear technology, interest in advanced nuclear reactors declined in recent years. Nevertheless, the research activity in the solid state science of binary and ternary thorium carbides increased and the Th-C system became one of the best known binary systems. At high temperatures there exists a series of solid solutions ranging from Th metal to the hypostoichiometric cubic ThC1.96' including the monocarbide ThC. A body-centered cubic Th2C3 of the Pu2C3 structure type only exists at pressures above 30 kbar. The Th carbides are refractory compounds with high melting points, e.g., 2500° C for the composition ThC0.97. Ternary carbides are either stoichiometric compounds, like ThAl4C4, ThAlC2, and Th4Al2C5 in the Th-Al-C system, or they form solid solutions with more or less broad ranges of composition. On the other hand, ThC is immiscible with group IV and V transition metal carbides because of its large unit cell. The normally metastable Th2C3 can be stabilized by forming solid solutions like (Th, La)2C3 with other sesquicarbides. Some ternary phases are superconductors with transition temperatures as high as 17 K.
Author : H. Holleck
Publisher : Springer Science & Business Media
ISBN 13 : 3662107163
Total Pages : 295 pages
Book Rating : 4.6/5 (621 download)
Download or read book U Uranium written by H. Holleck and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume Uranium C12 covers the binary and polynary carbides of uranium, including ternary carbides with nonmetals like the carbide oxides and carbide nitrides U(C,O) and U(C,N). The binary carbide UC and especially the mixed carbide (UO.80PUO.20)C are of special importance due to their potential as the fuel for advanced .. Fast Breeder Reactors" because of properties such as the short doubling time, the high fissionable material density, and the good thermal conductivity. On the other hand, the dicarbide UC is of interest for .. High 2 Temperature Reactors", especially in the form of the mixed carbide (U . Th . )C . For O80 o20 2 the first time, India used mixed uranium-plutonium carbide (U . PU .)C as the fuel for its O3 O7 own newly developed 15 MW Fast Breeder Reactor at Kalpakkam, south of Madras. el Because of the technological importance of the uranium carbides a lot of data were published only in reports. In most cases, it was the aim of these less-scientifically based studies to promote the carbide fuel development on an economical basis. The lack of analyti cal data on the purity of the samples, missing characterization of the present phases, etc., hQINever, does not allow the discussion of the results of such references in this handbook. Therefore, only reliable publications were cited. For the technical fabrication of uranium carbides and their irradiation behavior, see Volumes A3 and A4 of this Handbook.
Author : R. Benz
Publisher : Springer Science & Business Media
ISBN 13 : 3662063301
Total Pages : 141 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium written by R. Benz and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 141 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume C 3, as a part of the Gmelin "Thorium" Handbook, Series C, describes the thorium-nitrogen compounds. Included are compounds both of technological importance like the nitrides and the nitrates and those of merely scientific interest, such as amides and related compounds. However, due to the decreasing technical importance of the nuclear thorium fuel cycle, especially with the advanced fuels like the nitride ThN, in recent years, the thorium compounds with nitrogen have been investigated much less extensively than the correspond ing uranium compounds. In order to have the data for the Th-N-X systems accumulated in one specific volume, the decision was made to publish this volume without incorporating other Th systems. ThN is the compound with the lowest N :Th ratio. In addition to its (former) nuclear interest due to its thermal and radiation stability, it has many very interesting physicochemical properties. Thorium nitrate, the other well-investigated compound, is of importance because it is (in the form of an adduct with tri-n-butylphosphate) the extracted compound when burnt-up thorium fuels are reprocessed. Despite the wealth of accumulated data on the chemical and physicochemical properties of the compounds discussed, the knowledge of the compounds and of the systems is far from satisfactory - it must be deepened and improved in further studies. I would like to thank the competent authors for their critical contributions as well as the Gmelin-Institute for the excellent cooperation provided, especially Prof. Dr. Fluck and Dr. Keim, the editor-in-chief of this volume.
Author : Robert G. Behrens
Publisher : Springer Science & Business Media
ISBN 13 : 3662074109
Total Pages : 263 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium written by Robert G. Behrens and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 263 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume describes the general properties of the thorium atom and ions, the thermodynamics of its compounds and solutions, the behavior of solutions and solid com pounds under the influence of its own radiation as well as an external radiation field, and spectroscopic data in great detail. The different chapters are of special interest to scientists who work in these fields, and also in the corresponding fields of other elements. In some special fields there exists a detailed knowledge of this radioelement whereas in other fields, such as M6Bbauer spectra, lower oxidation states, or radiation stability, there are large gaps. Due to the fact that the significance 23 of thorium as a breeder fuel ( 2"fh to be converted to fissile 233U after thermal neutron capture) has decreased within the last decade, the behavior of thorium is not as yet so thoroughly investigated as the heavier radioactive element uranium. Many of these data, however, are not only of academic interest, e.g., the knowledge of atomic spectra is needed for some analytical methods, especially in the trace concentration region. Due to the noble gaS-like electronic configuration of the tetravalent ion, there are no absorption bands in the visible region so that in general spectra and data are very scarce. This volume is a very detailed and critically reviewed compilation, written by experts from the Federal Republic of Germany, Belgium, and the United States.
Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3662107198
Total Pages : 334 pages
Book Rating : 4.6/5 (621 download)
Download or read book U Uranium written by and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume Uranium C5 covers the physical properties of U0 - the production 2 and preparation of U0 were already treated in Uranium C4, whereas the chemical proper 2 ties will be the subject of the forthcoming part C6. U0 is the most important chemical compound in all aspects of nuclear technology. 2 It is and will be for the foreseeable future the fuel for all light and heavy water reactors as well as (in the mixed crystal with Pu0 ) for the fast breeder reactors. Therefore, the 2 nuclear engineer has to understand the behavior of U0 under all conditions existing during 2 operational (and possibly failure) states of a nuclear reactor, e. g. , not only in the solid state but also to some extent in the liquid and gaseous states. Besides high scientific interest in the sometimes unique or unusual properties, e. g. , at low temperatures, a lot of data and physical properties which are critical for its use as a nuclear fuel have been determined more or less accurately. Creep, swelling, irradiation densification, and fission gas behavior in the fuel are properties which have been evaluated up to the high temperatu res (near the melting point) which may exist in U0 fuel due to its low thermal conductivity. 2 Besides these more technical data there have been accumulated a lot of important physical data, e. g.
Author : Michael Bickel
Publisher : Springer Science & Business Media
ISBN 13 : 3662063484
Total Pages : 324 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium Supplement Volume C 8 written by Michael Bickel and published by Springer Science & Business Media. This book was released on 2013-04-17 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume comprises the compounds of thorium with the 4th main group elements silicon and germanium and all 5th main group elements except nitrogen. On the subject of ternary and polynary compounds containing oxygen, only those compounds with phosphorus are included (e.g., phosphates, hypophosphates, or phosphinates). Similar compounds of the other ele ments like silicates, arsenates, etc. were already treated in "Thorium" Suppl. Vol. C 2, 1976. Most of the compounds in the different systems treated in this volume are of scientific interest because of their special physical and chemical properties. On the other hand, there are also many compounds wh ich are of specific technological interest, mainly in the nuclear field. Refractory compounds like ThSi or ThP have potential interest as nuclear fuel for special reactors due to their physical properties like good heat conductivity and their chemical stability, e.g., against the corrosion of cladding alloys for nuclear fuel elements. Due to the present situation in the further development of the thorium nuclear fuel cycle, their large potential has not yet been fully investigated. For most of the binary and ternary phases in these systems, we presently have good knowledge about the preparation of the compounds and their physical and chemical properties. But nevertheless, there are still a lot of open questions concerning phase equilibria, solid solutions, and homogeneity of some of the phases described in this volume.
Author :
Publisher :
ISBN 13 :
Total Pages : 422 pages
Book Rating : 4.F/5 ( download)
Download or read book Uranium: The compounds. sect. 1. Compounds with noble gases and hydrogen. The uranium-oxygen system written by and published by . This book was released on 1983 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : David Brown
Publisher : Springer Science & Business Media
ISBN 13 : 3662063425
Total Pages : 170 pages
Book Rating : 4.6/5 (62 download)
Download or read book Th Thorium written by David Brown and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt: The present volume, Thorium C5, deals with the compounds of thorium and sulfur, selenium, tellurium, and boron, as well as with oxoacid compounds of the three chalcogen elements. Thorium borates have already been treated in Thorium C2. In contrast to the corresponding compounds of uranium the thorium sulfides, etc. , do not show any nuclear or other technological application; they are only of academic interest, despite some very interest ing electronic properties, especially of the 1 : 1 compounds. The thorium-sulfur and the thorium boron systems in particular were studied in detail, so that we have a clear picture of them, whereas there are still a lot of open questions in the systems Th-Se and Th-Te - not very different from other metal chalcogenide systems. Thorium sulfates are of some technological importance because they are formed in solution during recovery of thorium from monazite by sulfuric acid leaching. The very detailed and critical treatment of the chemical and physical properties of the compounds discussed also enables us to find gaps still remaining in our knowledge and thus to initiate new research in this field. I want to thank the two authors, Dr. Horst Wedemeyer (Karlsruhe) and Dr. David Brown (Harwell), for their excellent contributions, the "Literaturabteilung" of the Karlsruhe Nuclear Research Center for its help in providing reports and other documents difficult to procure, as well as the staff of the Gmelin-Institute, especially to Dr. K. -C.
