Controlled Surface Modifications of Synthetic Polymers Via Radical Graft Polymerization

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Publisher :
ISBN 13 : 9781085746236
Total Pages : pages
Book Rating : 4.7/5 (462 download)

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Book Synopsis Controlled Surface Modifications of Synthetic Polymers Via Radical Graft Polymerization by : Maryam Tamizifar

Download or read book Controlled Surface Modifications of Synthetic Polymers Via Radical Graft Polymerization written by Maryam Tamizifar and published by . This book was released on 2019 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Synthetic polymers such as polyethylene terephthalate (PET), polyamide (PA), polyacrylonitrile (PAN) and polypropylene (PP) possess many advantages such as high mechanical strength and elasticity, good chemical and abrasion resistance, however, also exhibit hydrophobic behavior and poor wettability, causing them limitations in comfort and application properties. Radical graft polymerization has been considered as a possible and effective method for surface modification of the synthetic polymers to improve surface properties or introduce new functionalities. However, having proper control of conventional free-radical polymerization to increase the grafting efficiency is challenging and critical due to the nature of radical reactions, limited fiber surface area, and lack of surface reactive groups. Therefore, having an appropriate method of control is critically important to achieve high grafting yields on synthetic fiber surfaces. As an effort to control radical graft polymerization on surfaces of synthetic fibers with focus on PET fibers, the Hansen Solubility Parameter (HSP) has been successfully employed to quantify mutual affinities of different reaction components in the grafting reaction system (vinyl monomers, radical initiators, solvents, crosslinkers, and fiber) through calculation of distances between different materials. Calculated HSP distance (R) values can serve as an effective measure to predict, increase and in other words to control the fate of the graft polymerization reaction on polymer (PET) surfaces. The competency of HSP in this regard has been investigated using several different vinyl monomers, initiators, solvents, and crosslinkers on PET surfaces. Successful graft polymerizations on PET surfaces were confirmed by FTIR analysis, and supported quantitatively by different measures such as gravimetric analysis (grafting yield), surface elemental analyses, relative moisture regain values, active chlorine content of grafted samples with N-H containing monomers, and dye uptake of the grafted products. Scanning electron microscope (SEM) was employed to examine surface morphologies of the grafted PET samples. Results indicate that for the selected grafting systems, in general, hydrophilic functional monomers show higher grafting values on PET surfaces compared to hydrophobic vinyl monomers without any crosslinkers. Disregarding the nature and properties of monomers (and other reaction components) HSP can successfully justify grafting values based on mutual affinities (HSP distances) between reaction components and provides effective control on surface radical graft polymerization of PET fibers. HSP can inform selection of solvents and initiators with suitable affinities between monomers and PET polymer. It appears that four major distances, initiator-PET, initiator-solvent, monomer-PET, and monomer-solvent, in the grafting reaction system have major roles in the fate and result of the grafting reaction efficiency.In order to increase the grafting values for hydrophobic monomers studied in the research, another component, a multi-vinyl crosslinker (CL), was added to the graft polymerization reaction system and the new interaction system was analyzed using HSP. As expected, results indicate addition of crosslinkers increased the grafting values of all six different monomers including hydrophobic monomers that had significantly low grafting values in absence of a crosslinker. Using HSP it was enlightened that although the monomer-PET, crosslinker-PET, and monomer-crosslinker interactions impart significant roles in controlling the radical graft polymerization on PET surfaces, monomer/crosslinker-solvent and monomer/crosslinker-initiator interactions are determining factors and affect the grafting values. Dyeing properties and active chlorine contents of the grafted samples with N-H containing monomers in presence of crosslinkers, show increased values that confirm positive control of the crosslinker in enhancing the grafting efficiency. Obvious morphological alteration in surface structure of grafted PET surfaces in presence of PEGDIA crosslinker is observed for all monomers by scanning electron microscopy. The significance of this research lies in the fact that, HSP can be an efficient tool to analyze different interactions (affinities) in the grafting system which enables one to effectively control (enhance) surface modification of inert polymers such as PET.

An Approach to Surface Modifications with Polymer Brushes Using Aqueous Synthetic Techniques and Characterization

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Publisher :
ISBN 13 :
Total Pages : 488 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis An Approach to Surface Modifications with Polymer Brushes Using Aqueous Synthetic Techniques and Characterization by : Roselynn Cordero

Download or read book An Approach to Surface Modifications with Polymer Brushes Using Aqueous Synthetic Techniques and Characterization written by Roselynn Cordero and published by . This book was released on 2018 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis introduces a new emulsion polymerization technique called mini monomer encapsulated emulsion polymerization (mini ME emulsion) using activators regenerated by electron transfer (ARGET) atom transfer radical polymerization (ATRP) to form narrow dispersity poly(methyl methacrylate), PMMA and polystyrene, PS. Subsequent chapters discuss use of this method to create polymer brushes on silica nanoparticles to form "hairy" nanoparticles, and the use of polymer brushes on silica and cellulose substrates to serve as an antibody sensor. "Hairy nanoparticles" use a combination of a polymer brush and an inorganic nanoparticle core to improve the mechanical and thermal properties of a film. Mini ME emulsion polymerization was created for the controlled polymerization of PMMA and PS in an aqueous medium. By guiding reaction localization with a phase transfer agent, tetrabutylammonium bromide (TBAB) and with acetone to control their diffusion rate, continuous feeding of the reaction loci with monomer was employed to keep a constant concentration of propagating radicals. This reaction process leads to low dispersity polymers with a predetermined molecular weight in an emulsion polymerization. Once mini ME emulsion polymerization was established in aqueous media, the polymerization method was modified to grow polymer chains on a nanoparticle surface to obtain hairy nanoparticles. Within recent years, the study of polymer brushes, which is broadly defined as polymer chains bound to a surface, has enabled ground-breaking materials with tailored interfaces, finding applications in nonfouling biosurfaces and creating novel mechanical and optical nanocomposite materials. The particles were functionalized with a hydrophobic initiator to control the polymerization loci forcing initiation to occur only within the organic phase surrounding the nanoparticle and minimizing reaction in the aqueous medium. Results of the new reaction route are described. This technique was also employed to generate polymer brushes on surfaces such as those suitable for biosensing devices and is discussed. Reaction conditions and the results of preliminary testing to these new structures for antibody sensing are described. A poly(oligoethylene glycol) methacrylate (POEGMA) polymer brush, which is used to prevent non-specific adsorption of biomolecules, was grown from cellulose or silica microparticles under aqueous conditions. These brushes were then post-modified with a model antigen, dinitrophenyl (DNP) to increase the specificity of the sensor via specific antibody-antigen recognition. Preliminary results suggest that polymer brushes are needed to increase the sensitivity of the sensor by repelling molecules that would lead to a false positive result. A sensor based on the antibody catalyzed water oxidation pathway (ACWOP) eliminates the need for a secondary antibody, thus further increasing both the specificity and sensitivity of the device and is described in this thesis.

Controlled and Living Polymerizations

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Publisher : John Wiley & Sons
ISBN 13 : 9783527324927
Total Pages : 640 pages
Book Rating : 4.3/5 (249 download)

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Book Synopsis Controlled and Living Polymerizations by : Krzysztof Matyjaszewski

Download or read book Controlled and Living Polymerizations written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by a highly prestigious and knowledgeable team of top scientists in the field, this book provides an overview of the current status of controlled/living polymerization, combining the synthetic, mechanistic and application-oriented aspects. From the contents: * Anionic Vinyl Polymerization * Carbocationic Polymerization * Radical Polymerization * Coordinative Polymerization of Olefins * Ring-Opening Polymerization of Heterocycles * Ring-Opening Metathesis Polymerization * Macromolecular Architectures * Complex Functional Macromolecules * Synthesis of Block and Graft Copolymers * Bulk and Solution Structures of Block Copolymers * Industrial Applications While some of the material is based on chapters taken from the four-volume work "Macromolecular Engineering", it is completely updated and rewritten to reflect the focus of this monograph. Must-have knowledge for polymer and organic chemists, plastics technologists, materials scientists and chemical engineers.

Surface Modification of Polyolefins Using New Synthetic Techniques

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Publisher :
ISBN 13 :
Total Pages : 306 pages
Book Rating : 4.:/5 (313 download)

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Book Synopsis Surface Modification of Polyolefins Using New Synthetic Techniques by : Jing Zhou

Download or read book Surface Modification of Polyolefins Using New Synthetic Techniques written by Jing Zhou and published by . This book was released on 1992 with total page 306 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Controlled/living Radical Polymerization

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Publisher : Academic
ISBN 13 :
Total Pages : 444 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Controlled/living Radical Polymerization by : Krzysztof Matyjaszewski

Download or read book Controlled/living Radical Polymerization written by Krzysztof Matyjaszewski and published by Academic. This book was released on 2009 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent progress in the field of controlled/living radical polymerization.

Biopolymer Grafting: Applications

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Publisher : Elsevier
ISBN 13 : 0128104635
Total Pages : 542 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Biopolymer Grafting: Applications by : Vijay Kumar Thakur

Download or read book Biopolymer Grafting: Applications written by Vijay Kumar Thakur and published by Elsevier. This book was released on 2017-09-19 with total page 542 pages. Available in PDF, EPUB and Kindle. Book excerpt: Biopolymer Grafting: Applications presents the latest research and developments in the practical application of these methods in industry, both to enable polymer scientists and engineers to keep up with the latest research trends, as well as to propose ideas for further research and application. Research into bio-based polymers has become increasingly prevalent. However, due to challenges related to the properties of these materials compared to synthetic polymers—such as their resistance to chemicals or weather—uptake has not dramatically increased yet. As a result, improvements in surface modification of bio-polymers through graft copolymerization are enormously important, because they will widen the scope of their applications. Relevant industries for application of these methods include automotive, construction, food, packaging, agriculture, textiles and paper. This book provides an overview of the developments made in the area of biopolymer-based graft polymers. Advantages, disadvantages and suggestions for future works are discussed, assisting materials scientists and researchers in mapping out the future of these new "green" materials through value addition to enhance their use. Helps researchers and product developers understand the applications and limitations of biopolymer copolymers or copolymers of natural polymers Offers a roadmap to future applications development in a range of different industries, including automotive, biomedical and packaging Increases familiarity with a range of biopolymer grafting processes, enabling materials scientists and engineers to improve material properties and widen the range of potential biopolymer applications

Anionic Polymerization

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Publisher : CRC Press
ISBN 13 : 9780824795238
Total Pages : 748 pages
Book Rating : 4.7/5 (952 download)

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Book Synopsis Anionic Polymerization by : Henry Hsieh

Download or read book Anionic Polymerization written by Henry Hsieh and published by CRC Press. This book was released on 1996-03-15 with total page 748 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work introduces the basic theories and experimental methods of anionic polymerization as well as the synthesis, analysis and characteristics of anionic polymerized products. It details the creation of linear and branched polymers, random and block copolymers, graft and macromonomers, and many other substances. The work emphasizes the relationship between fundamental principles and commercial applications.;College or university bookstores may purchase five or more copies at a special student price, available on request from Marcel Dekker, Inc.

Polysaccharide Based Graft Copolymers

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Publisher : Springer Science & Business Media
ISBN 13 : 3642365663
Total Pages : 358 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Polysaccharide Based Graft Copolymers by : Susheel Kalia

Download or read book Polysaccharide Based Graft Copolymers written by Susheel Kalia and published by Springer Science & Business Media. This book was released on 2013-05-23 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Renowned experts give all essential aspects of the techniques and applications of graft copolymers based on polysaccharides. Polysaccharides are the most abundant natural organic materials and polysaccharide based graft copolymers are of great importance and widely used in various fields. Natural polysaccharides have recently received more attention due to their advantages over synthetic polymers by being non-toxic, biodegradable and available at low cost. Modification of polysaccharides through graft copolymerization improves the properties of polysaccharides. Grafting is known to improve the characteristic properties of the backbones. Such properties include water repellency, thermal stability, flame resistance, dye-ability and resistance towards acid-base attack and abrasion. Polysaccharides and their graft copolymers find extensive applications in diversified fields. Applications of modified polysaccharides include drug delivery devices, controlled release of fungicides, selective water absorption from oil-water emulsions, purification of water etc.

Surface Modification of Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527345418
Total Pages : 458 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Surface Modification of Polymers by : Jean Pinson

Download or read book Surface Modification of Polymers written by Jean Pinson and published by John Wiley & Sons. This book was released on 2020-02-18 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to modifying and functionalizing the surfaces of polymers Surface Modification of Polymers is an essential guide to the myriad methods that can be employed to modify and functionalize the surfaces of polymers. The functionalization of polymer surfaces is often required for applications in sensors, membranes, medicinal devices, and others. The contributors?noted experts on the topic?describe the polymer surface in detail and discuss the internal and external factors that influence surface properties. This comprehensive guide to the most important methods for the introduction of new functionalities is an authoritative resource for everyone working in the field. This book explores many applications, including the plasma polymerization technique, organic surface functionalization by initiated chemical vapor deposition, photoinduced functionalization on polymer surfaces, functionalization of polymers by hydrolysis, aminolysis, reduction, oxidation, surface modification of nanoparticles, and many more. Inside, readers will find information on various applications in the biomedical field, food science, and membrane science. This important book: -Offers a range of polymer functionalization methods for biomedical applications, water filtration membranes, and food science -Contains discussions of the key surface modification methods, including plasma and chemical techniques, as well as applications for nanotechnology, environmental filtration, food science, and biomedicine -Includes contributions from a team of international renowned experts Written for polymer chemists, materials scientists, plasma physicists, analytical chemists, surface physicists, and surface chemists, Surface Modification of Polymers offers a comprehensive and application-oriented review of the important functionalization methods with a special focus on biomedical applications, membrane science, and food science.

Handbook of Green Analytical Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 111994094X
Total Pages : 569 pages
Book Rating : 4.1/5 (199 download)

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Book Synopsis Handbook of Green Analytical Chemistry by : Miguel de la Guardia

Download or read book Handbook of Green Analytical Chemistry written by Miguel de la Guardia and published by John Wiley & Sons. This book was released on 2012-02-23 with total page 569 pages. Available in PDF, EPUB and Kindle. Book excerpt: The emerging field of green analytical chemistry is concerned with the development of analytical procedures that minimize consumption of hazardous reagents and solvents, and maximize safety for operators and the environment. In recent years there have been significant developments in methodological and technological tools to prevent and reduce the deleterious effects of analytical activities; key strategies include recycling, replacement, reduction and detoxification of reagents and solvents. The Handbook of Green Analytical Chemistry provides a comprehensive overview of the present state and recent developments in green chemical analysis. A series of detailed chapters, written by international specialists in the field, discuss the fundamental principles of green analytical chemistry and present a catalogue of tools for developing environmentally friendly analytical techniques. Topics covered include: Concepts: Fundamental principles, education, laboratory experiments and publication in green analytical chemistry. The Analytical Process: Green sampling techniques and sample preparation, direct analysis of samples, green methods for capillary electrophoresis, chromatography, atomic spectroscopy, solid phase molecular spectroscopy, derivative molecular spectroscopy and electroanalytical methods. Strategies: Energy saving, automation, miniaturization and photocatalytic treatment of laboratory wastes. Fields of Application: Green bioanalytical chemistry, biodiagnostics, environmental analysis and industrial analysis. This advanced handbook is a practical resource for experienced analytical chemists who are interested in implementing green approaches in their work.

Antioxidant Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 1118445511
Total Pages : 601 pages
Book Rating : 4.1/5 (184 download)

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Book Synopsis Antioxidant Polymers by : Giuseppe Cirillo

Download or read book Antioxidant Polymers written by Giuseppe Cirillo and published by John Wiley & Sons. This book was released on 2012-06-07 with total page 601 pages. Available in PDF, EPUB and Kindle. Book excerpt: Antioxidant Polymers is an exhaustive overview of the recent developments in the field of polymeric materials showing antioxidant properties. This research area has grown rapidly in the last decade because antioxidant polymers have wide industry applications ranging from materials science to biomedical, pharmaceuticals and cosmetics.

Living and Controlled Polymerization

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Publisher : Nova Publishers
ISBN 13 : 9781594543302
Total Pages : 398 pages
Book Rating : 4.5/5 (433 download)

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Book Synopsis Living and Controlled Polymerization by : Joseph Jagur-Grodzinski

Download or read book Living and Controlled Polymerization written by Joseph Jagur-Grodzinski and published by Nova Publishers. This book was released on 2006 with total page 398 pages. Available in PDF, EPUB and Kindle. Book excerpt: The living/controlled polymerisation techniques opened new vistas in polymer chemistry. The leading authorities in this field and its pioneers contributed chapters to this collective volume. The controlled polymerisation techniques have enabled preparation of polymers, copolymers, and block copolymers with predetermined molecular weights and narrow polydispersity, in which functional groups or biologically active molecules could be placed at well defined locations. They have also enabled preparation of advanced polymeric structures with precisely determined architectures and improved properties. Moreover, they have provided opportunities for preparation of novel polymeric materials from monomers, which before have not been suitable or accessible for such purposes. Properties of some of these polymeric materials may be significantly different from those of the existing ones. They provide opportunities for new applications. Several patents have already been approved for such speciality applications as, drug delivery, biocompatible surfaces, thermoplastic elastomers, moisture curable sealants, and so on. Many more products, based on polymers fabricated by the living/ controlled polymerisation techniques, will certainly emerge in such specialised areas as, nanotechnology, medical devices, "smart polymers", sensors , smart separation technologies, optical fibres and other optical applications, various biomaterials, etc.

Surface Modification of Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527819231
Total Pages : 510 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Surface Modification of Polymers by : Jean Pinson

Download or read book Surface Modification of Polymers written by Jean Pinson and published by John Wiley & Sons. This book was released on 2019-12-04 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to modifying and functionalizing the surfaces of polymers Surface Modification of Polymers is an essential guide to the myriad methods that can be employed to modify and functionalize the surfaces of polymers. The functionalization of polymer surfaces is often required for applications in sensors, membranes, medicinal devices, and others. The contributors?noted experts on the topic?describe the polymer surface in detail and discuss the internal and external factors that influence surface properties. This comprehensive guide to the most important methods for the introduction of new functionalities is an authoritative resource for everyone working in the field. This book explores many applications, including the plasma polymerization technique, organic surface functionalization by initiated chemical vapor deposition, photoinduced functionalization on polymer surfaces, functionalization of polymers by hydrolysis, aminolysis, reduction, oxidation, surface modification of nanoparticles, and many more. Inside, readers will find information on various applications in the biomedical field, food science, and membrane science. This important book: -Offers a range of polymer functionalization methods for biomedical applications, water filtration membranes, and food science -Contains discussions of the key surface modification methods, including plasma and chemical techniques, as well as applications for nanotechnology, environmental filtration, food science, and biomedicine -Includes contributions from a team of international renowned experts Written for polymer chemists, materials scientists, plasma physicists, analytical chemists, surface physicists, and surface chemists, Surface Modification of Polymers offers a comprehensive and application-oriented review of the important functionalization methods with a special focus on biomedical applications, membrane science, and food science.

Self-Healing Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 3527670203
Total Pages : 638 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Self-Healing Polymers by : Wolfgang H. Binder

Download or read book Self-Healing Polymers written by Wolfgang H. Binder and published by John Wiley & Sons. This book was released on 2013-03-29 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Self-healing is a well-known phenomenon in nature: a broken bone merges after some time and if skin is damaged, the wound will stop bleeding and heals again. This concept can be mimicked in order to create polymeric materials with the ability to regenerate after they have suffered degradation or wear. Already realized applications are used in aerospace engineering, and current research in this fascinating field shows how different self-healing mechanisms proven successful by nature can be adapted to produce even more versatile materials. The book combines the knowledge of an international panel of experts in the field and provides the reader with chemical and physical concepts for self-healing polymers, including aspects of biomimetic processes of healing in nature. It shows how to design self-healing polymers and explains the dynamics in these systems. Different self-healing concepts such as encapsulated systems and supramolecular systems are detailed. Chapters on analysis and friction detection in self-healing polymers and on applications round off the book.

Polymer Nanocomposites

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Publisher : American Chemical Society
ISBN 13 :
Total Pages : 266 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Polymer Nanocomposites by : Ramanan Krishnamoorti

Download or read book Polymer Nanocomposites written by Ramanan Krishnamoorti and published by American Chemical Society. This book was released on 2002-01-17 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer Nanocomposites: Synthesis, Characterization, and Modeling examines the unique chemical and physical aspects associated with polymer based nanocomposite materials. The volume discusses the latest fundamental and applied research in the field of polymer nanocomposites as well as future directions for the development of high performance materials.

Reversible Deactivation Radical Polymerization

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110640171
Total Pages : 400 pages
Book Rating : 4.1/5 (16 download)

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Book Synopsis Reversible Deactivation Radical Polymerization by : Nikhil K. Singha

Download or read book Reversible Deactivation Radical Polymerization written by Nikhil K. Singha and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-01-20 with total page 400 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book describes strategies and mechanism of reversible deactivation radical polymerization (RDRP) to synthesize functional polymers. Several approaches such as atom transfer radical polymerization and the combination of click chemistry and RDRP are summarized. Contributors from interdisciplinary fields highlight applications in nanotechnology, self-healing materials, oil and water resistant coatings and controlled drug delivery systems.

Advanced Polymer Nanoparticles

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Publisher : CRC Press
ISBN 13 : 9781439814437
Total Pages : 0 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Advanced Polymer Nanoparticles by : Vikas Mittal

Download or read book Advanced Polymer Nanoparticles written by Vikas Mittal and published by CRC Press. This book was released on 2010-07-13 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymer latex particles continue to become increasingly important in numerous commercial applications. Advanced synthesis techniques are the key to developing new functionality for nanoparticles. These methods make it possible to tailor the size, chemical composition, or properties of these particles, as well as the molecular weight of the polymer chain as a whole, based on given requirements. Advanced Polymer Nanoparticles: Synthesis and Surface Modifications summarizes important developments in the advanced synthesis and surface modification techniques used to generate and mold polymer particles. This book explores the evolution and enhancement of processes such as emulsion, mini-emulsion, micro-emulsion, dispersion, suspension, inverse emulsion (in organic phase), and polymerization. Understanding these developments will enable the reader to optimize particle system design, giving rise to a greater application spectrum. This book: Focuses on synthesis and characterization of particles with core-shell morphologies Details generation of nonspherical polymer particles using different synthetic routes Explores generation of specific architectures, such as block, star, graft, and gradient copolymer particles The authors describe pH-responsive nanoparticles and smart, thermally responsive particles. They also cover surface tailoring of various organic and inorganic nanoparticles by polymers, as well as theoretical studies on the kinetics of controlled radical polymerization techniques. Condensing and evaluating current knowledge of the development of polymer nanoparticles, this reference will prove a valuable addition to the area of polymer latex technology.