Contribution à l'étude de l'adsorption physique de gaz sur les nanotubes de carbone mono- et multiparois

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ISBN 13 :
Total Pages : 164 pages
Book Rating : 4.:/5 (492 download)

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Book Synopsis Contribution à l'étude de l'adsorption physique de gaz sur les nanotubes de carbone mono- et multiparois by : Moulay-Rachid Babaa

Download or read book Contribution à l'étude de l'adsorption physique de gaz sur les nanotubes de carbone mono- et multiparois written by Moulay-Rachid Babaa and published by . This book was released on 2004 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ce travail porte sur l'étude de l'adsorption de Kr, Xe et CCl4 sur des nanotubes de carbone mono- et multiparois. La comparaison des isothermes et des énergies d'adsorption de molécules simples avec celles obtenues sur le graphite nous a permis de préciser les différents sites d'adsorption et l'influence de la courbure des plans de graphène. Nous avons caractérisé l'effet de deux techniques d'ouverture des nanotubes sur leurs propriétés et leurs capacités d'adsorption. L'efficacité de la technique mécanique a été étudiée. Nous avons estimé la fraction de la surface interne accessible et la proportion des impuretés introduites par ce procédé. Différents modes d'arrangement des molécules des trois gaz à l'intérieur des tubes monoparois en fonction de leurs diamètres moléculaires ont été mis en évidence. Les nanotubes multiparois ouverts aux extrémités par une oxydation sélective, ont été également caractérisés. La comparaison des isothermes d'adsorption avant et après traitement et l'analyse par MET nous ont permis de déterminer le mécanisme de l'oxydation, son efficacité ainsi que l'influence de ce traitement sur la surface et la structure des nanotubes.

Gas Adsorption on Suspended Carbon Nanotubes and Graphene

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Publisher : Boris Dzyubenko
ISBN 13 :
Total Pages : pages
Book Rating : 4./5 ( download)

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Book Synopsis Gas Adsorption on Suspended Carbon Nanotubes and Graphene by : Boris Dzyubenko

Download or read book Gas Adsorption on Suspended Carbon Nanotubes and Graphene written by Boris Dzyubenko and published by Boris Dzyubenko. This book was released on 2017-08-18 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare gas adsorption was studied on suspended individual single walled carbon nanotubes and graphene. The devices were fabricated as field effect transistors. Adsorption of N2 and CO, which formed a Root 3 X Root 3 commensurate solid monolayer, produced a dramatic reduction of the two-terminal conductance of graphene by as much as a factor of three. This effect is possibly connected with the opening of a band gap expected to occur in such structures.

Carbon Nanomaterials for Gas Adsorption

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Publisher : CRC Press
ISBN 13 : 9814316431
Total Pages : 500 pages
Book Rating : 4.8/5 (143 download)

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Book Synopsis Carbon Nanomaterials for Gas Adsorption by : Maria Letizia Terranova

Download or read book Carbon Nanomaterials for Gas Adsorption written by Maria Letizia Terranova and published by CRC Press. This book was released on 2012-11-27 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research in adsorption of gases by carbon nanomaterials has experienced considerable growth in recent years, with increasing interest for practical applications. Many research groups are now producing or using such materials for gas adsorption, storage, purification, and sensing. This book provides a selected overview of some of the most interesting scientific results regarding the outstanding properties of carbon nanomaterials for gas adsorption and of interest both for basic research and technological applications. Topics receiving special attention in this book include storage of H, purification of H, storage of rare gases, adsorption of organic vapors, gas trapping and separation, and metrology of gas adsorption.

Gas Adsorption on Suspended Carbon Nanotubes and Graphene

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ISBN 13 :
Total Pages : 167 pages
Book Rating : 4.:/5 (12 download)

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Book Synopsis Gas Adsorption on Suspended Carbon Nanotubes and Graphene by : Boris Dzyubenko

Download or read book Gas Adsorption on Suspended Carbon Nanotubes and Graphene written by Boris Dzyubenko and published by . This book was released on 2017 with total page 167 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare gas adsorption was studied on suspended individual single walled carbon nanotubes and graphene. The devices were fabricated as field effect transistors. Adsorption on graphene was studied through two-terminal conductance. On nanotube devices adsorption was studied through conductance while the coverage (density) of the adsorbates was determined from the mechanical resonance frequency shifts. The adsorbed atoms modified the conductance of the nanotube field effect transistors, in part through charge transfer from the adsorbates to the nanotube. By tracking the shifts of conductance as a function of gate voltage, G=G(Vg), and comparing these shifts with the periodicity of the Coulomb blockade oscillations we quantified the charge transfer to the nanotubes with high accuracy. For all studied gases (He, Ar, Kr, Xe, N2, CO, and O2) the charge transfer had a similar magnitude and was rather small, on the order of 10^-5 to 10^-3 electrons per adsorbed atom. The nanotube devices displayed two classes of adsorption behavior. On some devices the monolayers exhibited first-order phase transitions analogous to those that occur in adsorbed monolayers on graphite. On other devices phase transitions within the adsorbed monolayers were absent. We present evidence that a highly uniform layer of contaminants deposits on the surface of suspended nanotube devices either upon cooldown in the cryostat or at room temperature from air. These contaminants modify the adsorption behavior preventing the adsorbed monolayers from exhibiting the first order phase transitions expected to occur on a clean surface. A similar type of contamination leading to virtually identical effects occurs on suspended graphene. In the low coverage regions of isotherms on nanotubes we observe Henry's law behavior, demonstrating a high uniformity of the surface and allowing us to accurately determine the single particle binding energy to this surface. The determined binding energies were 776+-10 K for Ar, and 997+-37 K for Kr. In the second part of the dissertation we present the first measurements of adsorption on a pristine graphene surface, exposed through aggressive electric current annealing. On graphene the rare gas adsorbates form monolayers with phases analogous to those on graphite, but with phase transitions occurring at slightly higher pressures due to a reduction of binding energy. The condensations of monolayers with phases not commensurate with the graphene lattice resulted in a slight shift of the charge neutrality point of monolayer graphene corresponding to a change of carrier concentration on the order of 10^9 e/cm^2. Adsorption of N2 and CO, which formed a Root 3 X Root 3 commensurate solid monolayer, produced a dramatic reduction of the two-terminal conductance of graphene by as much as a factor of three. This effect is possibly connected with the opening of a band gap expected to occur in such structures. We observe hysteretic behavior in the adsorbed Root 3 X Root 3 commensurate monolayers on freestanding graphene, which is likely due to the interaction of two adsorbed monolayers on opposite surfaces of the graphene sheet.

Etude thermodynamique et structurale de l'adsorption de gaz sur les nanotubes de carbone monoparois

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ISBN 13 :
Total Pages : 248 pages
Book Rating : 4.:/5 (49 download)

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Book Synopsis Etude thermodynamique et structurale de l'adsorption de gaz sur les nanotubes de carbone monoparois by : Muris

Download or read book Etude thermodynamique et structurale de l'adsorption de gaz sur les nanotubes de carbone monoparois written by Muris and published by . This book was released on 2001 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications

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Publisher : Springer
ISBN 13 : 3319188755
Total Pages : 126 pages
Book Rating : 4.3/5 (191 download)

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Book Synopsis Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications by : Carlos P. Bergmann

Download or read book Carbon Nanomaterials as Adsorbents for Environmental and Biological Applications written by Carlos P. Bergmann and published by Springer. This book was released on 2015-06-01 with total page 126 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents a summary of the current use of carbon nanomaterials for water treatment, drug delivery, systems and nanosensors. The first chapter elucidates the adsorption process phenomenon. Also, the properties of different carbon nanomaterials for adsorption applications are covered. The third chapter presents the kinetic and equilibrium models of adsorption, processing of experimental data and adsorption process peculiarities. Environmental and biological applications of carbon nanomaterials are listed in the last chapter. This book is written from an application-oriented perspective and is useful for all those interested in nanoadsorbents.

Contribution à l'étude de l'adsorption dynamique et de la désorption sélective d'un mélange binaire de gaz

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ISBN 13 :
Total Pages : 96 pages
Book Rating : 4.:/5 (26 download)

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Book Synopsis Contribution à l'étude de l'adsorption dynamique et de la désorption sélective d'un mélange binaire de gaz by : Joseph-Marie de Kalbermatten

Download or read book Contribution à l'étude de l'adsorption dynamique et de la désorption sélective d'un mélange binaire de gaz written by Joseph-Marie de Kalbermatten and published by . This book was released on 1953 with total page 96 pages. Available in PDF, EPUB and Kindle. Book excerpt:

CONTRIBUTION A L'ETUDE DE L'ADSORPTION ET DE LA COADSORPTION DES MOLECULES H#2 ET D#2 DANS LA ZEOLITHE NAA PAR MICROGRAVIMETRIE ET PAR SPECTROMETRIE INFRAROUGE

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ISBN 13 :
Total Pages : pages
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Book Synopsis CONTRIBUTION A L'ETUDE DE L'ADSORPTION ET DE LA COADSORPTION DES MOLECULES H#2 ET D#2 DANS LA ZEOLITHE NAA PAR MICROGRAVIMETRIE ET PAR SPECTROMETRIE INFRAROUGE by : EL HABIB.. IBNASS

Download or read book CONTRIBUTION A L'ETUDE DE L'ADSORPTION ET DE LA COADSORPTION DES MOLECULES H#2 ET D#2 DANS LA ZEOLITHE NAA PAR MICROGRAVIMETRIE ET PAR SPECTROMETRIE INFRAROUGE written by EL HABIB.. IBNASS and published by . This book was released on 1991 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: CE TRAVAIL EST UNE CONTRIBUTION A L'ETUDE DE L'ADSORPTION PHYSIQUE ET DE LA COADSORPTION DES MOLECULES H#2 ET D#2 DANS UN CRISTAL MICROPOREUX LA ZEOLITHE NAA, PAR MICROGRAVIMETRIE ET SPECTROMETRIE INFRAROUGE. LA BANDE DE VIBRATION FONDAMENTALE DE CES MOLECULES DIATOMIQUES HOMOPOLAIRES, INTERDITE EN IR POUR LA PHASE GAZEUSE, APPARAIT LORSQUE CES MOLECULES SONT ADSORBEES A L'INTERIEUR DES CAVITES. LA COMPARAISON DES ISOTHERMES DES GAZ PURS A MONTRE QUE LE RAPPORT DES TAUX D'ADSORPTION DE D#2 SUR H#2 EST EGAL A 1.1. CECI EST EXPLIQUE PAR LA DIFFERENCE DES COVOLUMES DE CES DEUX MOLECULES. LA MESURE DES INTENSITES DES BANDES INFRAROUGES CONDUIT A LA DETERMINATION DE LA VALEUR DU CHAMP ELECTRIQUE DANS LA CAVITE ZEOLITHIQUE. DANS LE CAS DE LA COADSORPTION D'UN MELANGE GAZEUX EQUIMOLAIRE H#2-D#2, NOUS AVONS MESURE LE FACTEUR DE SEPARATION ALPHA EN FONCTION DE LA PRESSION ET DE LA TEMPERATURE A PARTIR DE LA SURFACE DES BANDES INFRAROUGES DES MOLECULES ADSORBEES. ON CONSTATE QUE ALPHA EST SUPERIEUR AU RAPPORT DES ISOTHERMES DES GAZ PURS, ET PASSE DE 1.5 A 3 QUAND ON ABAISSE LA TEMPERATURE DE 120 A 77 K

Adsorption by Carbons

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Publisher : Elsevier
ISBN 13 : 0080559425
Total Pages : 773 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Adsorption by Carbons by : Eduardo J. Bottani

Download or read book Adsorption by Carbons written by Eduardo J. Bottani and published by Elsevier. This book was released on 2011-10-10 with total page 773 pages. Available in PDF, EPUB and Kindle. Book excerpt: Adsorption by Carbons covers the most significant aspects of adsorption by carbons, attempting to fill the existing gap between the fields of adsorption and carbonaceous materials. Both basic and applied aspects are presented. The first section of the book introduces physical adsorption and carbonaceous materials, and is followed by a section concerning the fundamentals of adsorption by carbons. This leads to development of a series of theoretical concepts that serve as an introduction to the following section in which adsorption is mainly envisaged as a tool to characterize the porous texture and surface chemistry of carbons. Particular attention is paid to some novel nanocarbons, and the electrochemistry of adsorption by carbons is also addressed. Finally, several important technological applications of gas and liquid adsorption by carbons in areas such as environmental protection and energy storage constitute the last section of the book. The first book to address the interplay between carbonaceous materials and adsorption Includes important environmental applications, such as the removal of volatile organic compounds from polluted atmospheres Covers both gas-solid and liquid-solid adsorption

Contribution à l'étude de la diffusion et de l'adsorption de gaz dans les solides ultramicroporeux

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ISBN 13 :
Total Pages : 288 pages
Book Rating : 4.:/5 (49 download)

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Book Synopsis Contribution à l'étude de la diffusion et de l'adsorption de gaz dans les solides ultramicroporeux by : Michel Roques

Download or read book Contribution à l'étude de la diffusion et de l'adsorption de gaz dans les solides ultramicroporeux written by Michel Roques and published by . This book was released on 1974 with total page 288 pages. Available in PDF, EPUB and Kindle. Book excerpt: L'ETUDE DES TEXTURES ULTRAMICROPOREUSES PAR ADSORPTION ET DIFFUSION DE N::(2), O::(2) ET CO::(2) A PRINCIPALEMENT PORTE SUR LES ADSORBANTS QUI ONT LA PARTICULARITE DE NE PAS ADSORBER L'AZOTE A -195**(O)C (CARBONES OU TAMIS MOLECULAIRE 4A)

Contribution à l'étude de l'influence de l'adsorption des gaz sur la conductibilité électrique de couches métalliques très minces

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ISBN 13 :
Total Pages : 39 pages
Book Rating : 4.:/5 (25 download)

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Book Synopsis Contribution à l'étude de l'influence de l'adsorption des gaz sur la conductibilité électrique de couches métalliques très minces by : Suzanne Offret

Download or read book Contribution à l'étude de l'influence de l'adsorption des gaz sur la conductibilité électrique de couches métalliques très minces written by Suzanne Offret and published by . This book was released on 1961 with total page 39 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Contribution à l'étude structurale des charbons actifs

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ISBN 13 :
Total Pages : 222 pages
Book Rating : 4.E/5 ( download)

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Book Synopsis Contribution à l'étude structurale des charbons actifs by : Jean-Philippe Houriet

Download or read book Contribution à l'étude structurale des charbons actifs written by Jean-Philippe Houriet and published by . This book was released on 1978 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:

CONTRIBUTION A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (49 download)

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Book Synopsis CONTRIBUTION A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ by : Lian-Ming Sun

Download or read book CONTRIBUTION A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ written by Lian-Ming Sun and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ETUDE DE LA CINETIQUE D'ABSORPTION SOUS DES CONDITIONS NONISOTHERMES DANS LES ADSORBANTS DONT LA STRUCTURE DE PORE EST A POROSITE MULTIPLE. ETUDE THEORIQUE A PARTIR D'UN MODELE MATHEMATIQUE CONSIDERANT SIMULTANEMENT LES RESISTANCES AUX TRANSFERTS DE MASSE ET CHALEUR. VERIFICATION EXPERIMENTALE SUR DEUX SYSTEMES CHARBON ACTIF-CH#2CL#2 ET ZEOLITE NAX-H#2O

Contribution à l'étude de l'adsorption de molecules simples (H2, N2, NH3, O2, CO, NO) sur monocristal de tungstene {100} par la technique des faisceaux moléculaires et d'échange isotopique

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (464 download)

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Book Synopsis Contribution à l'étude de l'adsorption de molecules simples (H2, N2, NH3, O2, CO, NO) sur monocristal de tungstene {100} par la technique des faisceaux moléculaires et d'échange isotopique by : Patrick Alnot

Download or read book Contribution à l'étude de l'adsorption de molecules simples (H2, N2, NH3, O2, CO, NO) sur monocristal de tungstene {100} par la technique des faisceaux moléculaires et d'échange isotopique written by Patrick Alnot and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ETUDE DE LA CINETIQUE D'ADSORPTION, DE DESORPTION OU DE DECOMPOSITION DES MOLECULES SIMPLES (H::(2), N::(2), NH::(3), O::(2), CO ET NO) SUR UN MONOCRISTAL DE W(100) EN EXAMINANT L'INTERACTION DE CE PLAN DE W AVEC DES FAISCEAUX MOLECULAIRES COMPOSES D'UN OU DE PLUSIEURS GAZ (SOIT DES GAZ DIFFERENTS, SOIT UN MELANGE ISOTOPIQUE D'UN GAZ). L'ADSORPTION DE N::(2), NH::(3), O::(2), CO ET NO SE FAIT AVEC PRECURSEUR (CE QUE MONTRENT LES COURBES D'ADSORPTION AVEC LE DEGRE DE RECOUVREMENT, OU LES RENDEMENTS DE CHOC INITIAL AVEC LA TEMPERATURE DE LA SURFACE OU DU GAZ), CELLE DE L'HYDROGENE PROCEDE D'UN MECANISME DIFFERENT (PIEGEAGE PAR ELECTRON-TROU). ON OBSERVE UN EFFET ISOTOPIQUE ENTRE LA DECOMPOSITION DE NH::(3) ET DE ND::(3) ET PROPOSE DES EXPLICATIONS.

CONTRIBUTION A L'ETUDE DE L'ADSORPTION DE GAZ SUR DES SURFACES MONOCRISTALLINES DE NICKEL ET DE PLATINE

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ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (49 download)

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Book Synopsis CONTRIBUTION A L'ETUDE DE L'ADSORPTION DE GAZ SUR DES SURFACES MONOCRISTALLINES DE NICKEL ET DE PLATINE by : P.. LEGARE

Download or read book CONTRIBUTION A L'ETUDE DE L'ADSORPTION DE GAZ SUR DES SURFACES MONOCRISTALLINES DE NICKEL ET DE PLATINE written by P.. LEGARE and published by . This book was released on 1975 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: RESULTATS DE L'ETUDE A L'AIDE DE LA DIFFRACTION DES ELECTRONS LENTS ET DE LA SPECTROSCOPIE DES ELECTRONS AUGER DE L'ADSORPTION D'O::(2) ET DES HYDROCARBURES SUR LES FACES CRISTALLINES DU NI ET DU PT DANS DES CONDITIONS EXPERIMENTALES PROCHES DE CELLES UTILISEES EN CATALYSE HETEROGENE

Contribution à l'étude de l'absorption du gaz carbonique par les amines

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ISBN 13 :
Total Pages : 346 pages
Book Rating : 4.:/5 (46 download)

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Book Synopsis Contribution à l'étude de l'absorption du gaz carbonique par les amines by : Jacques Fournier

Download or read book Contribution à l'étude de l'absorption du gaz carbonique par les amines written by Jacques Fournier and published by . This book was released on 1963 with total page 346 pages. Available in PDF, EPUB and Kindle. Book excerpt:

CONTRIBUTION EXPERIMENTALE A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ

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ISBN 13 :
Total Pages : 113 pages
Book Rating : 4.:/5 (863 download)

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Book Synopsis CONTRIBUTION EXPERIMENTALE A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ by : KHODR.. ABDALLAH

Download or read book CONTRIBUTION EXPERIMENTALE A L'ETUDE DE LA CINETIQUE D'ADSORPTION DE GAZ written by KHODR.. ABDALLAH and published by . This book was released on 1989 with total page 113 pages. Available in PDF, EPUB and Kindle. Book excerpt: UNE NOUVELLE TECHNIQUE EXPERIMENTALE A ETE MISE AU POINT POUR ETUDIER LA CINETIQUE D'ADSORPTION DUE AUX TRANSFERTS DE MASSE ET DE CHALEUR. APPLICATION A L'ADSORPTION DU METHANOL SUR LA ZEOLITE X ET LE CHARBON ACTIF