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Comprehensive Development Of High Performance Solid Oxide Fuel Cells For Intermediate And Low Temperature Applications
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Book Synopsis Comprehensive Development of High Performance Solid Oxide Fuel Cells for Intermediate and Low Temperature Applications by : Kang Taek Lee
Download or read book Comprehensive Development of High Performance Solid Oxide Fuel Cells for Intermediate and Low Temperature Applications written by Kang Taek Lee and published by . This book was released on 2010 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: ABSTRACT: In order to develop high performance solid oxide fuel cells (SOFCs) operating at low to intermediate temperatures, the three main SOFC components--the anode, electrolyte, and cathode--were comprehensively studied. In order to lower anodic polarization losses in anode-supported SOFCs, a novel composite anode functional layer (AFL) having bimodal (nano/micro) structure was developed. Application of this AFL involved a simple process where a precursor solution was coated onto a conventional submicron sized colloidally-deposited Ni-GDC AFL. Cells prepared in this manner yielded maximum power densities (MPD) of 1.29, 1.16, 0.7 and 0.38 W/cm2 at 650, 600, 550 and 500 oC, respectively. Electrochemical impedance results showed a striking decrease in both ohmic and non-ohmic area specific resistances (ASRs) for these cells compared to those with either no AFL, or a conventional AFL. In addition, the effect composition of the conventional submironsized AFL on performance was examined. The highest MPD (1.15 W/cm2 at 650 °C) was achieved at a composition of 60wt% NiO. This composition had the best performance over the intermediate temperature range (450 to 650 °C). For the potentio-static test, the cell exhibited stable performance over 200 hrs of operation at 1.1 W/cm2. It was also revealed that electrode ASR has an inverse linear relationship with maximum power density at 650oC.
Book Synopsis Intermediate Temperature Solid Oxide Fuel Cells by : Gurbinder Kaur
Download or read book Intermediate Temperature Solid Oxide Fuel Cells written by Gurbinder Kaur and published by Elsevier. This book was released on 2019-11-21 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: Intermediate Temperature Solid Oxide Fuel Cells: Electrolytes, Electrodes and Interconnects introduces the fundamental principles of intermediate solid oxide fuel cells technology. It provides the reader with a broad understanding and practical knowledge of the electrodes, pyrochlore/perovskite/oxide electrolytes and interconnects which form the backbone of the Solid Oxide Fuel Cell (SOFC) unit. Opening with an introduction to the thermodynamics, physiochemical and electrochemical behavior of Solid Oxide Fuel Cells (SOFC), the book also discusses specific materials, including low temperature brownmillerites and aurivillius electrolytes, as well as pyrochlore interconnects. This book analyzes the basic concepts, providing cutting-edge information for both researchers and students. It is a complete reference for Intermediate Solid Oxide Fuel Cells technology that will be a vital resource for those working in materials science, fuel cells and solid state chemistry. Provides a single source of information on glass, electrolytes, interconnects, vanadates, pyrochlores and perovskite SOFC Includes illustrations that provide a clear visual explanation of concepts being discussed Progresses from a discussion of basic concepts that will enable readers to easily comprehend the subject matter
Download or read book Solid Oxide Fuel Cells written by Bin Zhu and published by John Wiley & Sons. This book was released on 2020-02-12 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents innovative approaches towards affordable, highly efficient, and reliable sustainable energy systems Written by leading experts on the subject, this book provides not only a basic introduction and understanding of conventional fuel cell principle, but also an updated view of the most recent developments in this field. It focuses on the new energy conversion technologies based on both electrolyte and electrolyte-free fuel cells?from advanced novel ceria-based composite electrolyte low temperature solid oxide fuel cells to non-electrolyte fuel cells as advanced fuel-to-electricity conversion technology. Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyte-Free Devices is divided into three parts. Part I covers the latest developments of anode, electrolyte, and cathode materials as well as the SOFC technologies. Part II discusses the non-electrolyte or semiconductor-based membrane fuel cells. Part III focuses on engineering efforts on materials, technology, devices and stack developments, and looks at various applications and new opportunities of SOFC using both the electrolyte and non-electrolyte principles, including integrated fuel cell systems with electrolysis, solar energy, and more. -Offers knowledge on how to realize highly efficient fuel cells with novel device structures -Shows the opportunity to transform the future fuel cell markets and the possibility to commercialize fuel cells in an extended range of applications -Presents a unique collection of contributions on the development of solid oxide fuel cells from electrolyte based to non-electrolyte-based technology -Provides a more comprehensive understanding of the advances in fuel cells and bridges the knowledge from traditional SOFC to the new concept -Allows readers to track the development from the conventional SOFC to the non-electrolyte or single-component fuel cell Solid Oxide Fuel Cells: From Electrolyte-Based to Electrolyte-Free Devices will serve as an important reference work to students, scientists, engineers, researchers, and technology developers in the fuel cell field.
Book Synopsis Solid Oxide Fuel Cell Technology by : K Huang
Download or read book Solid Oxide Fuel Cell Technology written by K Huang and published by Elsevier. This book was released on 2009-07-30 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: High temperature solid oxide fuel cell (SOFC) technology is a promising power generation option that features high electrical efficiency and low emissions of environmentally polluting gases such as CO2, NOox and SOx. It is ideal for distributed stationary power generation applications where both high-efficiency electricity and high-quality heat are in strong demand. For the past few decades, SOFC technology has attracted intense worldwide R&D effort and, along with polymer electrolyte membrane fuel cell (PEMFC) technology, has undergone extensive commercialization development. This book presents a systematic and in-depth narrative of the technology from the perspective of fundamentals, providing comprehensive theoretical analysis and innovative characterization techniques for SOFC technology. The book initially deals with the basics and development of SOFC technology from cell materials to fundamental thermodynamics, electronic properties of solids and charged particle transport. This coverage is extended with a thorough analysis of such operational features as current flow and energy balance, and on to voltage losses and electrical efficiency. Furthermore, the book also covers the important issues of fuel cell stability and durability with chapters on performance characterization, fuel processing, and electrode poisoning. Finally, the book provides a comprehensive review for SOFC materials and fabrication techniques. A series of useful scientific appendices rounds off the book. Solid oxide fuel cell technology is a standard reference for all those researching this important field as well as those working in the power industry. Provides a comprehensive review of solid oxide fuel cells from history and design to chemistry and materials development Presents analysis of operational features including current flow, energy balance, voltage losses and electrical efficiency Explores fuel cell stability and durability with specific chapters examining performance characterization, fuel processing and electrode poisoning
Book Synopsis Intermediate-Temperature Solid Oxide Fuel Cells by : Zongping Shao
Download or read book Intermediate-Temperature Solid Oxide Fuel Cells written by Zongping Shao and published by Springer. This book was released on 2016-09-12 with total page 271 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book discusses recent advances in intermediate-temperature solid oxide fuel cells (IT-SOFCs), focusing on material development and design, mechanism study, reaction kinetics and practical applications. It consists of five chapters presenting different types of reactions and materials employed in electrolytes, cathodes, anodes, interconnects and sealants for IT-SOFCs. It also includes two chapters highlighting new aspects of these solid oxide fuel cells and exploring their practical applications. This insightful and useful book appeals to a wide readership in various fields, including solid oxide fuel cells, electrochemistry, membranes and ceramics. Zongping Shao is a Professor at the State Key Laboratory of Materials-Oriented Chemical Engineering and the College of Energy, Nanjing University of Technology, China. Moses O. Tade is a Professor at the Department of Chemical Engineering, Curtin University, Australia.
Book Synopsis High-Temperature Solid Oxide Fuel Cells for the 21st Century by : Kevin Kendall
Download or read book High-Temperature Solid Oxide Fuel Cells for the 21st Century written by Kevin Kendall and published by Elsevier. This book was released on 2015-11-21 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt: High-temperature Solid Oxide Fuel Cells, Second Edition, explores the growing interest in fuel cells as a sustainable source of energy. The text brings the topic of green energy front and center, illustrating the need for new books that provide comprehensive and practical information on specific types of fuel cells and their applications. This landmark volume on solid oxide fuel cells contains contributions from experts of international repute, and provides a single source of the latest knowledge on this topic. A single source for all the latest information on solid oxide fuel cells and their applications Illustrates the need for new, more comprehensive books and study on the topic Explores the growing interest in fuel cells as viable, sustainable sources of energy
Book Synopsis Hybrid Systems Based on Solid Oxide Fuel Cells by : Mario L. Ferrari
Download or read book Hybrid Systems Based on Solid Oxide Fuel Cells written by Mario L. Ferrari and published by John Wiley & Sons. This book was released on 2017-08-14 with total page 341 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive guide to the modelling and design of solid oxide fuel cell hybrid power plants This book explores all technical aspects of solid oxide fuel cell (SOFC) hybrid systems and proposes solutions to a range of technical problems that can arise from component integration. Following a general introduction to the state-of-the-art in SOFC hybrid systems, the authors focus on fuel cell technology, including the components required to operate with standard fuels. Micro-gas turbine (mGT) technology for hybrid systems is discussed, with special attention given to issues related to the coupling of SOFCs with mGTs. Throughout the book emphasis is placed on dynamic issues, including control systems used to avoid risk conditions. With an eye to mitigating the high costs and risks incurred with the building and use of prototype hybrid systems, the authors demonstrate a proven, economically feasible approach to obtaining important experimental results using simplified plants that simulate both generic and detailed system-level behaviour using emulators. Computational models and experimental plants are developed to support the analysis of SOFC hybrid systems, including models appropriate for design, development and performance analysis at both component and system levels. Presents models for a range of size units, technology variations, unit coupling dynamics and start-up and shutdown behaviours Focuses on SOFCs integration with mGTs in light of key constraints and risk avoidance issues under steady-state conditions and during transient operations Identifies interaction and coupling problems within the GT/SOFC environment, including exergy analysis and optimization Demonstrates an economical approach to obtaining important experimental results while avoiding high-cost components and risk conditions Presents analytical/computational and experimental tools for the efficient design and development of hardware and software systems Hybrid Systems Based on Solid Oxide Fuel Cells: Modelling and Design is a valuable resource for researchers and practicing engineers involved in fuel cell fundamentals, design and development. It is also an excellent reference for academic researchers and advanced-level students exploring fuel cell technology.
Book Synopsis Solid Oxide Fuels Cells: Facts and Figures by : John T.S. Irvine
Download or read book Solid Oxide Fuels Cells: Facts and Figures written by John T.S. Irvine and published by Springer Science & Business Media. This book was released on 2012-11-02 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid Oxide Fuel Cells (SOFCs) operate at high temperatures allowing more fuel flexibility and also useful heat output and so increase total efficiency, but does give some interesting engineering challenges. Solid Oxide Fuels Cells: Facts and Figures provides clear and accurate data for a selection of SOFC topics from the specific details of Ni cermet anodes, chemical expansion in materials, and the measuring and modelling of mechanical stresses, to the broader scope of the history and present design of cells, to SOFC systems and the future of SOFC. Celebrating Ulf Bossel’s work on Solid Oxide Fuel Cells, and especially his running of the European Fuel Cell Forum, Solid Oxide Fuels Cells: Facts and Figures covers important topics on the way including intermediate temperature fuel cells, metal supported fuel cells and both new materials and engineering solutions to some of the challenges of getting SOFC to market. The chapters are based on the special plenary talks given by some of the most respected and talented people in the field at the 2010 European SOFC Forum in Luzern and the title for this book comes from the report produced by Ulf for the IEA “Final Report on SOFC Data, Facts and Figures”, Swiss Federal Office of Energy, Berne, 1992. The comprehensive nature of Solid Oxide Fuels Cells: Facts and Figures makes it a key resource of SOFC topics for students, lecturers, researchers and industry practitioners alike.
Book Synopsis Solid Oxide Fuel Cells by : Jeffrey Fergus
Download or read book Solid Oxide Fuel Cells written by Jeffrey Fergus and published by CRC Press. This book was released on 2016-04-19 with total page 314 pages. Available in PDF, EPUB and Kindle. Book excerpt: The First Book Centered on Materials Issues of SOFCsAlthough the high operating temperature of solid oxide fuel cells (SOFCs) creates opportunities for using a variety of fuels, including low-grade hydrogen and those derived from biomass, it also produces difficulties in materials performance and often leads to materials degradation during operatio
Book Synopsis High-temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications by : S.C. Singhal
Download or read book High-temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications written by S.C. Singhal and published by Elsevier. This book was released on 2003-12-08 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: High Temperature Solid Oxide Fuel Cells: Fundamentals, Design and Applications provides a comprehensive discussion of solid oxide fuel cells (SOFCs). SOFCs are the most efficient devices for the electrochemical conversion of chemical energy of hydrocarbon fuels into electricity, and have been gaining increasing attention for clean and efficient distributed power generation. The book explains the operating principle, cell component materials, cell and stack designs and fabrication processes, cell and stack performance, and applications of SOFCs. Individual chapters are written by internationally renowned authors in their respective fields, and the text is supplemented by a large number of references for further information. The book is primarily intended for use by researchers, engineers, and other technical people working in the field of SOFCs. Even though the technology is advancing at a very rapid pace, the information contained in most of the chapters is fundamental enough for the book to be useful even as a text for SOFC technology at the graduate level.
Book Synopsis Solid Oxide Fuels Cells: Facts and Figures by : John T.S. Irvine
Download or read book Solid Oxide Fuels Cells: Facts and Figures written by John T.S. Irvine and published by Springer. This book was released on 2012-11-02 with total page 232 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid Oxide Fuel Cells (SOFCs) operate at high temperatures allowing more fuel flexibility and also useful heat output and so increase total efficiency, but does give some interesting engineering challenges. Solid Oxide Fuels Cells: Facts and Figures provides clear and accurate data for a selection of SOFC topics from the specific details of Ni cermet anodes, chemical expansion in materials, and the measuring and modelling of mechanical stresses, to the broader scope of the history and present design of cells, to SOFC systems and the future of SOFC. Celebrating Ulf Bossel’s work on Solid Oxide Fuel Cells, and especially his running of the European Fuel Cell Forum, Solid Oxide Fuels Cells: Facts and Figures covers important topics on the way including intermediate temperature fuel cells, metal supported fuel cells and both new materials and engineering solutions to some of the challenges of getting SOFC to market. The chapters are based on the special plenary talks given by some of the most respected and talented people in the field at the 2010 European SOFC Forum in Luzern and the title for this book comes from the report produced by Ulf for the IEA “Final Report on SOFC Data, Facts and Figures”, Swiss Federal Office of Energy, Berne, 1992. The comprehensive nature of Solid Oxide Fuels Cells: Facts and Figures makes it a key resource of SOFC topics for students, lecturers, researchers and industry practitioners alike.
Book Synopsis Advances in Solid Oxide Fuel Cells by : Narottam P. Bansal
Download or read book Advances in Solid Oxide Fuel Cells written by Narottam P. Bansal and published by John Wiley & Sons. This book was released on 2009-09-28 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to its many potential benefits, including high electrical efficiency and low environmental emissions, solid oxide fuel cell (SOFC) technology is the subject of extensive research and development efforts by national laboratories, universities, and private industries. This collection of papers provides valuable insights on materials-related aspects of fuel cells such as SOFC component materials, materials processing, and cell/stack design, performance, and stability. Emerging trends in electrochemical materials, electrodics, interface engineering, long-term chemical interactions are also covered.
Book Synopsis Design and Operation of Solid Oxide Fuel Cells by : Mahdi Sharifzadeh
Download or read book Design and Operation of Solid Oxide Fuel Cells written by Mahdi Sharifzadeh and published by Academic Press. This book was released on 2019-10-31 with total page 648 pages. Available in PDF, EPUB and Kindle. Book excerpt: Design and Operation of Solid Oxide Fuel Cells: The Systems Engineering Vision for Industrial Application presents a comprehensive, critical and accessible review of the latest research in the field of solid oxide fuel cells (SOFCs). As well as discussing the theoretical aspects of the field, the book explores a diverse range of power applications, such as hybrid power plants, polygeneration, distributed electricity generation, energy storage and waste management—all with a focus on modeling and computational skills. Dr. Sharifzadeh presents the associated risks and limitations throughout the discussion, providing a very complete and thorough analysis of SOFCs and their control and operation in power plants. The first of its kind, this book will be of particular interest to energy engineers, industry experts and academic researchers in the energy, power and transportation industries, as well as those working and researching in the chemical, environmental and material sectors. Closes the gap between various power engineering disciples by considering a diverse variety of applications and sectors Presents and reviews a variety of modeling techniques and considers regulations throughout Includes CFD modeling examples and process simulation and optimization programming guidance
Book Synopsis Solid Oxide Fuel Cells by : Radenka Maric
Download or read book Solid Oxide Fuel Cells written by Radenka Maric and published by CRC Press. This book was released on 2020-12-08 with total page 257 pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid Oxide Fuel Cells: From Fundamental Principles to Complete Systems is a valuable resource for beginners, experienced researchers, and developers of solid oxide fuel cells (SOFCs). It provides a fundamental understanding of SOFCs by covering the present state-of-the-art as well as ongoing research and future challenges to be solved. It discusses current and future materials, and provides an overview of development activities with a more general system approach toward fuel cell plant technology, including plant design and economics, industrial data, and advances in technology. Provides an understanding of the operating principles of SOFCs Discusses state-of-the-art materials, technologies, and processes Includes a review of the current industry and lessons learned Offers a more general system approach toward fuel cell plant technology, including plant design and economics of SOFC manufacture Covers significant technical challenges that remain to be solved Presents the status of government activities, industry, and market This book is aimed at electrochemists, batteries and fuel cell engineers, alternative energy scientists, and professionals in materials science.
Book Synopsis Advances in Solid Oxide Fuel Cells VIII, Volume 33, Issue 4 by : Prabhakar Singh
Download or read book Advances in Solid Oxide Fuel Cells VIII, Volume 33, Issue 4 written by Prabhakar Singh and published by John Wiley & Sons. This book was released on 2012-11-27 with total page 174 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Ninth International Symposium on Solid Oxide Fuel Cells: Materials, Science, and Technology was held in January 2012 as part of the 36th International Conference on Advanced Ceramics and Composites (ICACC). This symposium provided an international forum for scientists, engineers, and technologists from around the world to present and discuss the latest advances in solid oxide fuel cells. This issue features fourteen papers selected from the symposium, offering readers a broad panorama of the current status of solid oxide fuel cells technology, as well as emerging issues and future directions in the field.
Book Synopsis Intermediate Temperature Solid Oxide Fuel Cell Development by :
Download or read book Intermediate Temperature Solid Oxide Fuel Cell Development written by and published by . This book was released on 2008 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Solid oxide fuel cells (SOFCs) are high efficiency energy conversion devices. Present materials set, using yttria stabilized zirconia (YSZ) electrolyte, limit the cell operating temperatures to 800 C or higher. It has become increasingly evident however that lowering the operating temperature would provide a more expeditious route to commercialization. The advantages of intermediate temperature (600 to 800 C) operation are related to both economic and materials issues. Lower operating temperature allows the use of low cost materials for the balance of plant and limits degradation arising from materials interactions. When the SOFC operating temperature is in the range of 600 to 700 C, it is also possible to partially reform hydrocarbon fuels within the stack providing additional system cost savings by reducing the air preheat heat-exchanger and blower size. The promise of Sr and Mg doped lanthanum gallate (LSGM) electrolyte materials, based on their high ionic conductivity and oxygen transference number at the intermediate temperature is well recognized. The focus of the present project was two-fold: (a) Identify a cell fabrication technique to achieve the benefits of lanthanum gallate material, and (b) Investigate alternative cathode materials that demonstrate low cathode polarization losses at the intermediate temperature. A porous matrix supported, thin film cell configuration was fabricated. The electrode material precursor was infiltrated into the porous matrix and the counter electrode was screen printed. Both anode and cathode infiltration produced high performance cells. Comparison of the two approaches showed that an infiltrated cathode cells may have advantages in high fuel utilization operations. Two new cathode materials were evaluated. Northwestern University investigated LSGM-ceria composite cathode while Caltech evaluated Ba-Sr-Co-Fe (BSCF) based pervoskite cathode. Both cathode materials showed lower polarization losses at temperatures as low as 600 C than conventional manganite or cobaltite cathodes.
Book Synopsis Perovskite Oxide for Solid Oxide Fuel Cells by : Tatsumi Ishihara
Download or read book Perovskite Oxide for Solid Oxide Fuel Cells written by Tatsumi Ishihara and published by Springer Science & Business Media. This book was released on 2009-06-12 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fuel cell technology is quite promising for conversion of chemical energy of hydrocarbon fuels into electricity without forming air pollutants. There are several types of fuel cells: polymer electrolyte fuel cell (PEFC), phosphoric acid fuel cell (PAFC), molten carbonate fuel cell (MCFC), solid oxide fuel cell (SOFC), and alkaline fuel cell (AFC). Among these, SOFCs are the most efficient and have various advantages such as flexibility in fuel, high reliability, simple balance of plant (BOP), and a long history. Therefore, SOFC technology is attracting much attention as a power plant and is now close to marketing as a combined heat and power generation system. From the beginning of SOFC development, many perovskite oxides have been used for SOFC components; for example, LaMnO -based oxide for the cathode and 3 LaCrO for the interconnect are the most well known materials for SOFCs. The 3 current SOFCs operate at temperatures higher than 1073 K. However, lowering the operating temperature of SOFCs is an important goal for further SOFC development. Reliability, durability, and stability of the SOFCs could be greatly improved by decreasing their operating temperature. In addition, a lower operating temperature is also beneficial for shortening the startup time and decreasing energy loss from heat radiation. For this purpose, faster oxide ion conductors are required to replace the conventional Y O -stabilized ZrO 2 3 2 electrolyte. A new class of electrolytes such as LaGaO is considered to be 3 highly useful for intermediate-temperature SOFCs.
