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Comprehensive Chemical Kinetics Modern Methods Theory And Data V 25 Diffusion Limited Reactions
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Book Synopsis Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions by : C. H. Bamford
Download or read book Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions written by C. H. Bamford and published by . This book was released on 1969 with total page 428 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions by : C. H. Bamford
Download or read book Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions written by C. H. Bamford and published by . This book was released on 1969 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Kinetics of Homogeneous Multistep Reactions by : Friedrich G. Helfferich
Download or read book Kinetics of Homogeneous Multistep Reactions written by Friedrich G. Helfferich and published by Elsevier Science. This book was released on 2001-01-25 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book addresses primarily the chemist and engineer in industrial research and process development, where competitive pressures put a premium on scale-up by large factors to cut development time. To be safe, such scale-up should be based on "fundamental" kinetics, that is, mathematics that reflect the elementary steps of which the reactions consist. The book forges fundamental kinetics into a practical tool by presenting new effective methods for elucidation of mechanisms and reduction of mathematical complexity without unacceptable sacrifice in accuracy.
Book Synopsis Modeling of Chemical Reactions by : R.W. Carr
Download or read book Modeling of Chemical Reactions written by R.W. Carr and published by Elsevier Science. This book was released on 2007 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modeling of Chemical Reactions covers detailed chemical kinetics models for chemical reactions. Including a comprehensive treatment of pressure dependent reactions, which are frequently not incorporated into detailed chemical kinetic models, and the use of modern computational quantum chemistry, which has recently become an extraordinarily useful component of the reaction kinetics toolkit. It is intended both for those who need to model complex chemical reaction processes but have little background in the area, and those who are already have experience and would benefit from having a wide range of useful material gathered in one volume. The range of subject matter is wider than that found in many previous treatments of this subject. The technical level of the material is also quite wide, so that non-experts can gain a grasp of fundamentals, and experts also can find the book useful.
Book Synopsis Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions by : C. H. Bamford
Download or read book Comprehensive Chemical Kinetics: Modern methods, theory, and data. v. 25. Diffusion-limited reactions written by C. H. Bamford and published by . This book was released on 1969 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Applications of Kinetic Modelling by : G. Hancock
Download or read book Applications of Kinetic Modelling written by G. Hancock and published by Elsevier Science. This book was released on 1999-05-07 with total page 744 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 37 is concerned with the use and role of modelling in chemical kinetics and seeks to show the interplay of theory or simulation with experiment in a diversity of physico-chemical areas in which kinetics measurements provide significant physical insight. Areas of application covered within the volume include electro- and interfacial chemistry, physiology, biochemistry, solid state chemistry and chemical engineering. A leading contributor to this general area has been Professor W. John Albery, FRS, to whom the contributors and editors dedicate this book.
Book Synopsis Comprehensive Chemical Kinetics by : Nicholas Green
Download or read book Comprehensive Chemical Kinetics written by Nicholas Green and published by Elsevier Science. This book was released on 2003 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: Unimolecular reactions are in principle the simplest chemical reactions, because they only involve one molecule. The basic mechanism, in which the competition between the chemical reaction step and a collisional deactivation leads to a pressure-dependent coefficient, has been understood for a long time. However, this is a rapidly developing field, and many new and important discoveries have been made in the past decade. This First Part Part of Two CCK Volumes dealing with Unimolecular Rections, deals with the Reaction Step. The first chapter is an introduction to the whole project, aiming to cover the material necessary to understand the content of the detailed chapters, as well as the history of the development of the area. Chapter 2 is a review of the modern view of the statistical theories, as embodied in the various forms of RRKM theory. Chapter 3 deals with the fully quantum mechanical view of reactive states as resonances.
Download or read book Catastrophe Theory written by A. Okninski and published by Elsevier Science. This book was released on 1992-06-12 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims to provide a straightforward introduction to chemical applications of the catastrophe theory. It is primarily intended for chemists interested in placing chemical reactions in the broader context of non-linear science, but it has a practical relevance for scientists in general. Catastrophe theory deals with those non-linear phenomena in which a continuous change in the control parameters results in a discontinuous alteration of a characteristic quantity of the system. The author discusses the origins of catastrophe theory, giving examples of occurrences in the areas of physics, chemistry and biology. Elementary theory and non-chemical applications are also described. The chemical kinetics and methods of analysis of chemical kinetic equations arising from elementary and generalized catastrophe theories are reviewed. Finally, the theory is applied to analyse and classify phenomena associated with the stability loss that may occur in chemical reactions. The book contains over 100 figures and an extensive subject index.
Book Synopsis Modern Aspects of Diffusion-Controlled Reactions by : E. Kotomin
Download or read book Modern Aspects of Diffusion-Controlled Reactions written by E. Kotomin and published by Elsevier Science. This book was released on 1996-10-24 with total page 644 pages. Available in PDF, EPUB and Kindle. Book excerpt: This monograph deals with the effects of reactant spatial correlations arising in the course of basic bimolecular reactions describing defect recombination, energy transfer and exciton annihilation in condensed matter. These effects lead to the kinetics considered abnormal from the standard chemical kinetics point of view. Numerous bimolecular reaction regimes and conditions are analysed in detail. Special attention is paid to the development and numerous applications of a novel, many-point density (MPD) formalism, which is based on Kirkwood's superposition approximation used for decoupling three-particle correlation functions. The book demonstrates that incorporation of the reaction-induced spatial correlations of similar reactants (e.g., vacancy-vacancy) leads to the development of an essentially non-Poisson spectrum of reactant density fluctuations. This can completely change the kinetics at longer times since it no longer obeys the law of mass action. The language of the correlation lengths and critical exponents similar to physics of critical phenomena is used instead. A relation between MPD theory and synergistics is discussed. The validity of the theorem giving a critical complexity for the two-step reactions exhibiting self-organization phenomena is questioned. Theoretical results are illustrated by numerous experimental data.
Book Synopsis Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents by : Victor L. Cherginets
Download or read book Oxoacidity: Reactions of Oxo-compounds in Ionic Solvents written by Victor L. Cherginets and published by Elsevier Science. This book was released on 2005-06-09 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt: The generally accepted definitions of acids and bases together with the generalized definition for the solvent system introduced by the author for the description of both molecular and ionic solvents are discussed. The oxobasicity index introduced as a measure of relative oxoacidic properties of ionic melts (pIL) and methods of its determination are presented. Moreover, the oxoacidity scales of ionic melts based on alkali metal halides at different temperatures are constructed. The sequential addition method (SAM), proposed by the author to investigate the effect of oxide particle size on oxide solubilities is presented. This book is meant for specialists developing theoretical and applied aspects of molten salt chemistry, acid-base theories and solubility phenomena. It will also be useful for those chemists who wish to extend their knowledge of physical and solution chemistry.
Book Synopsis Modern Methods, Theory, and Data by : Stephen A. Rice
Download or read book Modern Methods, Theory, and Data written by Stephen A. Rice and published by . This book was released on 1985 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Mechanism and Kinetics of Addition Polymerizations by : M. Kucera
Download or read book Mechanism and Kinetics of Addition Polymerizations written by M. Kucera and published by Elsevier Science. This book was released on 1991-11-26 with total page 600 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume presents an up-to-date survey of knowledge concerning addition type polymerizations. It contains nine chapters, each of which covers a particular basic term. Whenever necessary, the phenomena are discussed from the viewpoint of both stationary and non-stationary state of radical, ionic (i.e. anionic and cationic) and coordination polymerization. Special attention has been paid to the propagation process. It provides not only a general overview but also information on important special cases (theoretical conditions of propagation, influence of external factors, controlled propagation, copolymerization, mechanism of various propagation types, etc.). The book is arranged according to the basic steps in chain reactions, which is a novel approach in a monograph on this topic. It facilitates the identification of common features of various polymerization types which may appear quite different. This useful, comprehensive text should prove invaluable to all those involved in the field of macromolecular chemistry. It will also be of interest to all chemists who, beside the profound study of their own field, are looking for interdisciplinary liaison points.
Download or read book Photokinetics written by H. Mauser and published by Elsevier Science. This book was released on 1998-09-02 with total page 586 pages. Available in PDF, EPUB and Kindle. Book excerpt: Many books cover the determination of rate constants under different experimental conditions and different chemical composition of the reaction mixture in their formal treatment of thermal kinetics. However, most textbooks are limited to simple mechanisms. In contrast, analogous treatment of photochemical reactions is limited to the publication of special reactions and investigations. Therefore, this book is aimed at providing an overall description of formal photokinetics covering a wider scope than the usual books on kinetics. This volume attempts to provide a concise treatment of both thermo- and photochemical reactions by means of generalised differential equations, their set-up in matrix notation, and their solution by a formalism using numerical integration. At a first glance this approach might be surprising. However, apart from the argument that the didactics of thermal reactions are easier to handle than those of kinetics, the book provides additional reasons in support of this approach. Therefore, the formalism derived allows the evaluation of photochemical reactions, which are superimposed thermal reactions taking into account that the amount of light absorbed varies during the reaction. Because of this, any approximation, either by using total absorbance or negligible absorbance, will cause considerable errors even for simple reactions. The approach chosen to transform the axis of the radiation time into a new variable that includes the photokinetic factor proves that formal kinetics can be applied to thermal and photochemical reactions as well, and even allows the handling of solutions that cannot be homogenised or solid samples in which the concentration varies locally. By using this approach to introduce partial photochemical quantum yields even complex mechanisms can be determined quantitatively. A large number of examples for different mechanisms and an introduction to many spectroscopic and chromatographic methods suitable for photokinetic analyses are provided to enable the reader to carry out a step-by-step evaluation of his own measurements. To reduce the number of formula in some chapters an appendix has been included which contains a detailed description of the calculus of some essential examples. For the convenience of the reader the following has been included: . A large number of examples describing the use of formula . A detailed description of the procedure for applying photokinetics to complex consecutive photoreactions . An Internet address where the reader can find a tutorial for this procedure: http://www.barolo.ipc.uni-tuebingen.de/tele/photokin/ . A simple macro to help in programming his own evaluation procedure.
Book Synopsis Modern Aspects of Diffusion-controlled Reactions by : Evgeniĭ Alekseevich Kotomin
Download or read book Modern Aspects of Diffusion-controlled Reactions written by Evgeniĭ Alekseevich Kotomin and published by Elsevier Science Limited. This book was released on 1996 with total page 612 pages. Available in PDF, EPUB and Kindle. Book excerpt: Basic methods for describing chemical kinetics in condensed media : continuum models -- From pair kinetics toward the many-reactant problem -- The linear approximation in bimolecular reaction kinetics -- The fluctuation-controlled kinetics : the basic formalism of many-point particle densities -- The many-particle effects in irreversible A + B [yields] 0 reaction -- The many-particle effects in A + B [yields] 0 reaction with particle generation -- Systems under birth and death conditions : Lotka and Lotka-Volterra models -- Catalytic reactions on solid surfaces.
Book Synopsis Comprehensive Chemical Kinetics: Modern methods, theory, and data (vols. 24-37) by : C. H. Bamford
Download or read book Comprehensive Chemical Kinetics: Modern methods, theory, and data (vols. 24-37) written by C. H. Bamford and published by . This book was released on 1969 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Modern Methods in Kinetics by : C.H. Bamford
Download or read book Modern Methods in Kinetics written by C.H. Bamford and published by Elsevier. This book was released on 1983-01-01 with total page 545 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modern Methods in Kinetics
Book Synopsis Diffusion-Limited Reactions by : S.A. Rice
Download or read book Diffusion-Limited Reactions written by S.A. Rice and published by Elsevier. This book was released on 1985-03-01 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diffusion-Limited Reactions