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Composite Metal Membranes For Hydrogen Separation Applications
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Book Synopsis Composite Metal Membranes for Hydrogen Separation Applications by :
Download or read book Composite Metal Membranes for Hydrogen Separation Applications written by and published by . This book was released on 1997 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: A novel multilayer metal membrane has been developed that can be used for the separation of hydrogen from feed streams with near perfect selectivity. The membrane is comprised of very thin layers of fully dense palladium film deposited on both sides of a thin Group V metal foil, ion-milled prior to sputtering of the palladium. Palladium loading are kept low using the thin film deposition technology: 0.0012 grams of palladium per square centimeter of membrane is typically used, although thinner coatings have been employed. This membrane operates at temperatures on the order of 300 C and is capable of high rates of hydrogen flow. Flows are dependent on the pressure differential applied to the membrane, but flows of 105 sccm/cm2 and higher are regularly observed with differentials below one atmosphere. Long term testing of the membrane for a period in excess of 775 hours under constant conditions showed stable flows and an 85% hydrogen recovery efficiency. A system has been successfully applied to the hydrogen handling system of a proton exchange membrane fuel cell and was tested using a pseudo-reformate feed stream without any degradation in performance.
Book Synopsis Pd-based Membranes by : Thijs Peters
Download or read book Pd-based Membranes written by Thijs Peters and published by MDPI. This book was released on 2019-03-26 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: Palladium (Pd)-based membranes have received a great deal of attention from both academia and industry thanks to their ability to selectively separate hydrogen from gas streams. The integration of such membranes with appropriate catalysts in membrane reactors allows for hydrogen production with CO2 capture that can be applied in smaller bioenergy or combined heat and power (CHP) plants, as well as in large-scale power plants. Pd-based membranes are therefore regarded as a Key Enabling Technology (KET) to facilitate the transition towards a knowledge-based, low-carbon, and resource-efficient economy. This Special Issue of the journal Membranes on “Pd-based Membranes: Overview and Perspectives” contains nine peer-reviewed articles. Topics include manufacturing techniques, understanding of material phenomena, module and reactor design, novel applications, and demonstration efforts and industrial exploitation.
Book Synopsis Organic-inorganic Composite Membranes for Molecular Separation by : Wanqin Jin
Download or read book Organic-inorganic Composite Membranes for Molecular Separation written by Wanqin Jin and published by Wspc (Europe). This book was released on 2017-07-15 with total page 301 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives comprehensive information on the design, preparation and application of organic-inorganic composite membranes that are used for molecular separation. Various membrane types with different materials are highlighted, including polymer/ceramic composite membranes, mixed matrix membranes, metal-organic frameworks membranes and graphene-based membranes. Physical and chemical properties, morphologies, interfacial behaviors, transport characteristics and separation performance of the organic-inorganic composite membranes are thoroughly discussed based on advanced characterization techniques. Meanwhile, the book contains several typical applications of the membranes in fields such as bio-fuels production, organic compounds recovery, solvent dehydration, carbon dioxide capture and others. In addition, large-scale production and industrial implementation of the organic-inorganic composite membranes are briefly introduced.
Book Synopsis Membrane Engineering for the Treatment of Gases: Gas-separation problems combined with membrane reactors by : Enrico Drioli
Download or read book Membrane Engineering for the Treatment of Gases: Gas-separation problems combined with membrane reactors written by Enrico Drioli and published by Royal Society of Chemistry. This book was released on 2011 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: This two volume set presents the state-of-the-art, and potential for future developments, in membrane engineering for the separation of gases.
Book Synopsis Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation by : J. Douglas Way
Download or read book Palladium/Copper Alloy Composite Membranes for High Temperature Hydrogen Separation written by J. Douglas Way and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report summarizes progress made during the a three year University Coal Research grant (DEFG26-03NT41792) at the Colorado School of Mines. The period of performance was September 1, 2003 through August of 2006. We made excellent progress toward our goal of contributing to the development of high productivity, sulfur tolerant composite metal membranes for hydrogen production and membrane reactors. Composite Pd and Pd alloy metal membranes with thin metal films (1-7 {micro}m) were prepared on porous stainless steel and ceramic supports that meet or exceed the DOE 2010 and 2015 pure hydrogen flux targets at differential pressure of only 20 psi. For example, a 2 {micro}m pure Pd membrane on a Pall AccuSep{reg_sign} substrate achieved an ideal H{sub 2}/N{sub 2} separation factor of over 6000, with a pure hydrogen flux of 210 SCFH/ft{sup 2} at only 20 psig feed pressure. Similar performance was achieved with a Pd{sub 80}Au{sub 20} composite membrane on a similar stainless steel substrate. Extrapolating the pure hydrogen flux of this PdAu membrane to the DOE Fossil Energy target conditions of 150 psia feed pressure and 50 psia permeate pressure gives a value of 508 SCFH/ft{sup 2}, exceeding the 2015 target. At these thicknesses, it is the support cost that will dominate the cost of a large scale module. In a direct comparison of FCC phase PdCu and PdAu alloys on identical supports, we showed that a Pd{sub 85}Au{sub 15} (mass %) alloy membrane is not inhibited by CO, CO{sub 2}, or steam present in a water-gas shift feed mixture at 400 C, has better resistance to sulfur than a Pd{sub 94}Cu{sub 6} membrane, and has over twice the hydrogen permeance.
Book Synopsis Membranes For Gas Separations by : Moises A Carreon
Download or read book Membranes For Gas Separations written by Moises A Carreon and published by World Scientific. This book was released on 2017-08-11 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book aims at illustrating several examples of different membrane compositions ranging from inorganic, polymeric, metallic, metal organic framework, and composite which have been successfully deployed to separate industrially relevant gas mixtures including hydrogen, nitrogen, methane, carbon dioxide, olefins/parafins among others. Each book chapter highlights some of the current and key fundamental and technological challenges for these membranes that must be overcome in order to envision its application at industrial level.
Book Synopsis Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications by : A Doukelis
Download or read book Palladium Membrane Technology for Hydrogen Production, Carbon Capture and Other Applications written by A Doukelis and published by Elsevier. This book was released on 2014-10-20 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thanks to their outstanding hydrogen selectivity, palladium membranes have attracted extensive R&D interest. They are a potential breakthrough technology for hydrogen production and also have promising applications in the areas of thermochemical biorefining. This book summarises key research in palladium membrane technologies, with particular focus on the scale-up challenges. After an introductory chapter, Part one reviews the fabrication of palladium membranes. Part two then focuses on palladium membrane module and reactor design. The final part of the book reviews the operation of palladium membranes for synthesis gas/hydrogen production, carbon capture and other applications. Review of manufacture and design issues for palladium membranes Discussion of the applications of palladium membrane technology, including solar steam reforming, IGCC plants, NGCC plants, CHP plants and hydrogen production Examples of the technology in operation
Book Synopsis Palladium Composite Membranes for Hydrogen Production and Separation by : Samhun Yun
Download or read book Palladium Composite Membranes for Hydrogen Production and Separation written by Samhun Yun and published by LAP Lambert Academic Publishing. This book was released on 2012-04 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this work, we developed a new preparation technique for palladium composite membranes which results in an ultra-thin and defect-free selective layer with outstanding performance properties and long life. In the method, a palladium precursor and a reducing agent on opposite sides of a substrate of porous alumina hollow fibers were placed and used an electric field to cause migration of metal ions to the outer surface where they are reduced to form seeds at high concentration in a narrow spatial region. The ethanol steam reforming was conducted in a membrane reactor with the Pd membrane and the performance of this reactor was compared with results from a packed bed reactor under identical conditions. For all conditions studied, enhancement of ethanol conversion and hydrogen yield were observed in the membrane reactor compared to the packed bed reactor.
Book Synopsis Membrane Technology and Applications by : Richard W. Baker
Download or read book Membrane Technology and Applications written by Richard W. Baker and published by John Wiley & Sons. This book was released on 2004-04-21 with total page 555 pages. Available in PDF, EPUB and Kindle. Book excerpt: This A to Z guide to membrane science, technology, and applicationsprovides comprehensive coverage of membrane preparation, modules,and transport theory. Highly illustrated with comprehensive andcurrent reference listings, the resource provides practical usesand how-to's for a broad range of application areas. Single author work presenting a unified treatment Comprehensive coverage of membrane preparation, modules andtransport theory A 'how-to' book giving practical advice Highly illustrated with comprehensive and current referencelistings
Book Synopsis Inorganic Membranes for Energy and Environmental Applications by : Arun C. Bose
Download or read book Inorganic Membranes for Energy and Environmental Applications written by Arun C. Bose and published by Springer Science & Business Media. This book was released on 2008-10-08 with total page 318 pages. Available in PDF, EPUB and Kindle. Book excerpt: Research interest in inorganic membrane materials and processes has significantly increased in recent years due to novel, potentially low-cost energy and fuel production applications. This book documents the recent progress in membrane science, especially in advanced materials and novel reaction and separation concepts. The book classifies membranes based on the mechanism of operation, i.e., size exclusion filtration, solution-diffusion, and mixed ion-electron conduction of the permeate streams. This is the first book on the use of inorganic membranes for fuel and energy applications.
Book Synopsis Palladium and Palladium-copper Composite Membranes for Hydrogen Separation by : Stephen Nick Paglieri
Download or read book Palladium and Palladium-copper Composite Membranes for Hydrogen Separation written by Stephen Nick Paglieri and published by . This book was released on 1999 with total page 197 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Preparation of Pd-Ag/PSS Composite Membranes for Hydrogen Separation by :
Download or read book Preparation of Pd-Ag/PSS Composite Membranes for Hydrogen Separation written by and published by . This book was released on 2004 with total page 121 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Inorganic Membranes: Synthesis, Characterization and Applications by : Reyes Mallada
Download or read book Inorganic Membranes: Synthesis, Characterization and Applications written by Reyes Mallada and published by Elsevier. This book was released on 2008-05-01 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Approx.480 pages Approx.480 pages
Book Synopsis Membranes for Membrane Reactors by : Angelo Basile
Download or read book Membranes for Membrane Reactors written by Angelo Basile and published by John Wiley & Sons. This book was released on 2010-12-20 with total page 661 pages. Available in PDF, EPUB and Kindle. Book excerpt: A membrane reactor is a device for simultaneously performing a reaction and a membrane-based separation in the same physical device. Therefore, the membrane not only plays the role of a separator, but also takes place in the reaction itself. This text covers, in detail, the preparation and characterisation of all types of membranes used in membranes reactors. Each membrane synthesis process used by membranologists is explained by well known scientists in their specific research field. The book opens with an exhaustive review and introduction to membrane reactors, introducing the recent advances in this field. The following chapters concern the preparation of both organic and inorganic, and in both cases, a deep analysis of all the techniques used to prepare membrane are presented and discussed. A brief historical introduction for each technique is also included, followed by a complete description of the technique as well as the main results presented in the international specialized literature. In order to give to the reader a summary look to the overall work, a conclusive chapter is included for collecting all the information presented in the previous chapters. Key features: Fills a gap in the market for a scientific book describing the preparation and characterization of all the kind of membranes used in membrane reactors Discusses an important topic - there is increasing emphasis on membranes in general, due to their use as energy efficient separation tools and the ‘green’ chemistry opportunities they offer Includes a review about membrane reactors, several chapters concerning the preparation organic, inorganic, dense, porous, and composite membranes and a conclusion with a comparison among the different membrane preparation techniques
Book Synopsis Selective Hydrogen Separation by Palladium-based Composite Membranes by : Elin Aksnes
Download or read book Selective Hydrogen Separation by Palladium-based Composite Membranes written by Elin Aksnes and published by . This book was released on 1993 with total page 20 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Development of Composite Metal Membrane Using Cold Gas Dynamic Spray for Hydrogen Separation by : Sunday Temitope Oyinbo
Download or read book Development of Composite Metal Membrane Using Cold Gas Dynamic Spray for Hydrogen Separation written by Sunday Temitope Oyinbo and published by . This book was released on 2020 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Development of Palladium Composite Membranes for Hydrogen Separation by :
Download or read book Development of Palladium Composite Membranes for Hydrogen Separation written by and published by . This book was released on 2004 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Two types of palladium composite membrane were investigated for hydrogen separation. A palladium alloy membrane was prepared by electroless plating a layer of palladium (≈20 [mu]m) and then copper onto a commercially available porous (nominal 0.2 [mu]m pores) [alpha]-alumina substrate. The resulting multilayer metal film was annealed at 355 C for several days to promote metallic interdiffusion and alloy formation. During the heat treatment, a maximum hydrogen flux of 0.15 mol (STP)/m2 · s was observed at 355 C and a pressure drop ([Delta]P) across the membrane of 6.8 atm. The H2/Ar ideal separation factor was 68 at these conditions, however, the separation factor decreased upon thermal cycling. The other type of membrane fabricated was a palladium coated vanadium-copper alloy foil where the main advantage is the reduction in palladium film coating thickness to 100 nm per side. New methods are being developed for welding the thin foil into modules for testing. The hydrogen flux through a pinhole-free, 75 [mu]m thick Pd/VCu{sub 1.1}/Pd (atomic %) composite membrane was 0.66 mol (STP)/m2 · at 350 C and [Delta]P = 3.5 atm compared to 0.44 mol (STP)/m2 · s for a 71 [mu]m thick Pd/VCu10/Pd membrane. Vanadium alloy composition was checked using Auger electron spectroscopy (AES).
