Classical Nucleation Theory In Multicomponent Systems

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Classical Nucleation Theory in Multicomponent Systems

Author : Hanna Vehkamäki
Publisher : Springer Science & Business Media
ISBN 13 : 3540312188
Total Pages : 189 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis Classical Nucleation Theory in Multicomponent Systems by : Hanna Vehkamäki

Download or read book Classical Nucleation Theory in Multicomponent Systems written by Hanna Vehkamäki and published by Springer Science & Business Media. This book was released on 2006-03-22 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nucleation is the initial step of every first-order phase transition, and most phase transitions encountered both in everyday life and industrial processes are of the first-order. Using an elegant classical theory based on thermodynamics and kinetics, this book provides a fully detailed picture of multi-component nucleation. As many of the issues concerning multi-component nucleation theory have been solved during the last 10-15 years, it also thoroughly integrates both fundamental theory with recent advances presented in the literature. Classical Nucleation Theory in Multicomponent Systems serves as a textbook for advanced thermodynamics courses, as well as an important reference for researchers in the field. The main topics covered are: the basic relevant thermodynamics and statistical physics; modelling a molecular cluster as a spherical liquid droplet; predicting the size and composition of the nucleating critical clusters; kinetic models for cluster growth and decay; calculating nucleation rates; and a full derivation and application of nucleation theorems that can be used to extract microscopic cluster properties from nucleation rate measurements. The assumptions and approximations needed to build the classical theory are described in detail, and the reasons why the theory fails in certain cases are explained. Relevant problems are presented at the end of each chapter.

Classical Nucleation Theory in Multicomponent Systems

Author : Hanna Vehkamäki
Publisher : Springer Science & Business Media
ISBN 13 : 3540292136
Total Pages : 189 pages
Book Rating : 4.5/5 (42 download)

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Book Synopsis Classical Nucleation Theory in Multicomponent Systems by : Hanna Vehkamäki

Download or read book Classical Nucleation Theory in Multicomponent Systems written by Hanna Vehkamäki and published by Springer Science & Business Media. This book was released on 2006-01-12 with total page 189 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nucleation is the initial step of every first-order phase transition, and most phase transitions encountered both in everyday life and industrial processes are of the first-order. Using an elegant classical theory based on thermodynamics and kinetics, this book provides a fully detailed picture of multi-component nucleation. As many of the issues concerning multi-component nucleation theory have been solved during the last 10-15 years, it also thoroughly integrates both fundamental theory with recent advances presented in the literature. Classical Nucleation Theory in Multicomponent Systems serves as a textbook for advanced thermodynamics courses, as well as an important reference for researchers in the field. The main topics covered are: the basic relevant thermodynamics and statistical physics; modelling a molecular cluster as a spherical liquid droplet; predicting the size and composition of the nucleating critical clusters; kinetic models for cluster growth and decay; calculating nucleation rates; and a full derivation and application of nucleation theorems that can be used to extract microscopic cluster properties from nucleation rate measurements. The assumptions and approximations needed to build the classical theory are described in detail, and the reasons why the theory fails in certain cases are explained. Relevant problems are presented at the end of each chapter.

The Validity of Classical Nucleation Theory and Its Application to Dislocation Nucleation

Author : Seunghwa Ryu
Publisher : Stanford University
ISBN 13 :
Total Pages : 240 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis The Validity of Classical Nucleation Theory and Its Application to Dislocation Nucleation by : Seunghwa Ryu

Download or read book The Validity of Classical Nucleation Theory and Its Application to Dislocation Nucleation written by Seunghwa Ryu and published by Stanford University. This book was released on 2011 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nucleation has been the subject of intense research because it plays an important role in the dynamics of most first-order phase transitions. The standard theory to describe the nucleation phenomena is the classical nucleation theory (CNT) because it correctly captures the qualitative features of the nucleation process. However potential problems with CNT have been suggested by previous studies. We systematically test the individual components of CNT by computer simulations of the Ising model and find that it accurately predicts the nucleation rate if the correct droplet free energy computed by umbrella sampling is provided as input. This validates the fundamental assumption of CNT that the system can be coarse grained into a one dimensional Markov chain with the largest droplet size as the reaction coordinate. Employing similar simulation techniques, we study the dislocation nucleation which is essential to our understanding of plastic deformation, ductility, and mechanical strength of crystalline materials. We show that dislocation nucleation rates can be accurately predicted over a wide range of conditions using CNT with the activation free energy determined by umbrella sampling. Our data reveal very large activation entropies, which contribute a multiplicative factor of many orders of magnitude to the nucleation rate. The activation entropy at constant strain is caused by thermal expansion, with negligible contribution from the vibrational entropy. The activation entropy at constant stress is significantly larger than that at constant strain, as a result of thermal softening. The large activation entropies are caused by anharmonic effects, showing the limitations of the harmonic approximation widely used for rate estimation in solids. Similar behaviors are expected to occur in other nucleation processes in solids.

Nucleation Theory

Author :
Publisher : Springer
ISBN 13 : 9789048136483
Total Pages : 334 pages
Book Rating : 4.1/5 (364 download)

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Book Synopsis Nucleation Theory by :

Download or read book Nucleation Theory written by and published by Springer. This book was released on 2012-11-26 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Nucleation Theory

Author : V.I. Kalikmanov
Publisher : Springer
ISBN 13 : 9048136431
Total Pages : 319 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Nucleation Theory by : V.I. Kalikmanov

Download or read book Nucleation Theory written by V.I. Kalikmanov and published by Springer. This book was released on 2012-11-28 with total page 319 pages. Available in PDF, EPUB and Kindle. Book excerpt: One of the most striking phenomena in condensed matter physics is the occurrence of abrupt transitions in the structure of a substance at certain temperatures or pressures. These are first order phase transitions, and examples such as the freezing of water are familiar in everyday life. The conditions at which the transformation takes place can sometimes vary. For example, the freezing point of water is not always 0°C, but the liquid can be supercooled considerably if it is pure enough and treated carefully. The reason for this phenomenon is nucleation. This monograph covers all major available routes of theoretical research of nucleation phenomena (phenomenological models, semi-phenomenological theories, density functional theories, microscopic and semi-microscopic approaches), with emphasis on the formation of liquid droplets from a metastable vapor. Also, it illustrates the application of these various approaches to experimentally relevant problems. In spite of the familiarity of the involved phenomena, it is still impossible to calculate nucleation accurately, as the properties and the kinetics of the daughter phase are insufficiently well known. Existing theories based upon classical nucleation theory have on the whole explained the trends in behavior correctly. However they often fail spectacularly to account for new data, in particular in the case of binary or, more generally, multi-component nucleation. The current challenge of this book is to go beyond such classical models and provide a more satisfactory theory by using density functional theory and microscopic computer simulations in order to describe the properties of small clusters. Also, semi-phenomenological models are proposed, which attempt to relate the properties of small clusters to known properties of the bulk phases. This monograph is an introduction as well as a compendium to researchers in soft condensed matter physics and chemical physics, graduate and post-graduate students in physics and chemistry starting on research in the area of nucleation, and to experimentalists wishing to gain a better understanding of the efforts being made to account for their data.

Nucleation Theory and Applications

Author : Jürn W. P. Schmelzer
Publisher : John Wiley & Sons
ISBN 13 : 3527604766
Total Pages : 472 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Nucleation Theory and Applications by : Jürn W. P. Schmelzer

Download or read book Nucleation Theory and Applications written by Jürn W. P. Schmelzer and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: An overview of recent developments in the field of first-order phase transitions, which may be considered a continuation of the previous work 'Aggregation Phenomena in Complex Systems', covering work done and discussed since then. Each chapter features a different aspect of the field written by international specialists, and covers such topics as nucleation and crystallization kinetic of silicate glasses, nucleation in concentration gradients, the determination of coefficients of emission of nucleation theory, diamonds from vitreous carbon.

Physics and Chemistry of Interfaces

Author : Hans-Jürgen Butt
Publisher : John Wiley & Sons
ISBN 13 : 3527836160
Total Pages : 485 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Physics and Chemistry of Interfaces by : Hans-Jürgen Butt

Download or read book Physics and Chemistry of Interfaces written by Hans-Jürgen Butt and published by John Wiley & Sons. This book was released on 2023-02-07 with total page 485 pages. Available in PDF, EPUB and Kindle. Book excerpt: Physics and Chemistry of Interfaces Comprehensive textbook on the interdisciplinary field of interface science, fully updated with new content on wetting, spectroscopy, and coatings Physics and Chemistry of Interfaces provides a comprehensive introduction to the field of surface and interface science, focusing on essential concepts rather than specific details, and on intuitive understanding rather than convoluted math. Numerous high-end applications from surface technology, biotechnology, and microelectronics are included to illustrate and help readers easily comprehend basic concepts. The new edition contains an increased number of problems with detailed, worked solutions, making it ideal as a self-study resource. In topic coverage, the highly qualified authors take a balanced approach, discussing advanced interface phenomena in detail while remaining comprehensible. Chapter summaries with the most important equations, facts, and phenomena are included to aid the reader in information retention. A few of the sample topics included in Physics and Chemistry of Interfaces are as follows: Liquid surfaces, covering microscopic picture of a liquid surface, surface tension, the equation of Young and Laplace, and curved liquid surfaces Thermodynamics of interfaces, covering surface excess, internal energy and Helmholtz energy, equilibrium conditions, and interfacial excess energies Charged interfaces and the electric double layer, covering planar surfaces, the Grahame equation, and limitations of the Poisson-Boltzmann theory Surface forces, covering Van der Waals forces between molecules, macroscopic calculations, the Derjaguin approximation, and disjoining pressure Physics and Chemistry of Interfaces is a complete reference on the subject, aimed at advanced students (and their instructors) in physics, material science, chemistry, and engineering. Researchers requiring background knowledge on surface and interface science will also benefit from the accessible yet in-depth coverage of the text.

Atmospheric Chemistry

Author : Detlev Möller
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110732513
Total Pages : 1132 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Atmospheric Chemistry by : Detlev Möller

Download or read book Atmospheric Chemistry written by Detlev Möller and published by Walter de Gruyter GmbH & Co KG. This book was released on 2022-05-09 with total page 1132 pages. Available in PDF, EPUB and Kindle. Book excerpt: The work in your hand contains three main chapters, covering the chemistry of the condensed phase in the atmosphere, first, the different forms of atmospheric waters (precipitation, fog and clouds, dew), and secondly dust, now mostly termed particulate matter and, more scientifically, atmospheric aerosol. A third section treats the gases in the atmosphere. An introductory chapter covers the roots of the term atmospheric chemistry in its relations to chemistry in general and biogeochemistry as the chemistry of the climate system. Furthermore, a brief overview of understanding chemical reactions in aqueous and gaseous phase is given. It is my aim to pay respect to all persons who studied the substances in the air, to those who made small, and to them who made giant contributions for the progress in atmospheric science. I’m not a historian who is able to present the past from a true perspective of their time – this also would not be my aim. If possible, however, I try to interpret the past – almost limited to experimental fi ndings in the nineteenth century – through current values, without dismissal of the problems and ideas of earlier scientists. In this way it is possible to draw some ideas on the historical chemical state of the air. Hence, I name this voyage critical. However, nowhere in this book it is my attention to express my criticism to colleagues and scientifi c ancestors. Great scientists too were subject to errors; doing science consists from the permanent loop observation, interpretation, conclusion, and again testing against new observation. If this volume can contribute more than to be “a nice story” on atmospheric chemistry, then hopefully it inspires the reader to more critical reading of scientifi c publications, and, not to forget the older one. 2022 ASLI Choice Awards Winner! The book won the annual Atmospheric Science Librarians International (ASLI) award. For details see here: https://www.aslionline.org/wp/2022-asli-choice-awards-winners/

Carbon Nanomaterials Sourcebook

Author : Klaus D. Sattler
Publisher : CRC Press
ISBN 13 : 148225705X
Total Pages : 1066 pages
Book Rating : 4.4/5 (822 download)

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Book Synopsis Carbon Nanomaterials Sourcebook by : Klaus D. Sattler

Download or read book Carbon Nanomaterials Sourcebook written by Klaus D. Sattler and published by CRC Press. This book was released on 2018-09-03 with total page 1066 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Carbon Nanomaterials Sourcebook contains extensive, interdisciplinary coverage of carbon nanomaterials, encompassing the full scope of the field—from physics, chemistry, and materials science to molecular biology, engineering, and medicine—in two comprehensive volumes. Written in a tutorial style, this second volume of the sourcebook: Focuses on nanoparticles, nanocapsules, nanofibers, nanoporous structures, and nanocomposites Describes the fundamental properties, growth mechanisms, and processing of each nanomaterial discussed Explores functionalization for electronic, energy, biomedical, and environmental applications Showcases materials with exceptional properties, synthesis methods, large-scale production techniques, and application prospects Provides the tools necessary for understanding current and future technology developments, including important equations, tables, and graphs Each chapter is dedicated to a different type of carbon nanomaterial and addresses three main areas: formation, properties, and applications. This setup allows for quick and easy search, making the Carbon Nanomaterials Sourcebook: Nanoparticles, Nanocapsules, Nanofibers, Nanoporous Structures, and Nanocomposites a must-have reference for scientists and engineers.

Thermal analysis of Micro, Nano- and Non-Crystalline Materials

Author : Jaroslav Šesták
Publisher : Springer Science & Business Media
ISBN 13 : 9048131502
Total Pages : 498 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis Thermal analysis of Micro, Nano- and Non-Crystalline Materials by : Jaroslav Šesták

Download or read book Thermal analysis of Micro, Nano- and Non-Crystalline Materials written by Jaroslav Šesták and published by Springer Science & Business Media. This book was released on 2012-10-28 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: Thermal Analysis of Micro-, Nano- and Non-Crystalline Materials: Transformation, Crystallization, Kinetics, and Thermodynamics complements and adds to volume 8 Glassy, Amorphous and Nano-Crystalline Materials by providing a coherent and authoritative overview of cutting-edge themes in this field. In particular, the book focuses on reaction thermodynamics and kinetics applied to solid-state chemistry and thermal physics of various states of materials. Written by an international array of distinguished academics, the book deals with fundamental and historical aspects of phenomenological kinetics, equilibrium background of processes, crystal defects, non-stoichiometry and nano-crystallinity, reduced glass-transition temperatures and glass-forming coefficients, determination of the glass transition by DSC, the role of heat transfer and phase transition in DTA experiments, explanation of DTA/DSC methods used for the estimation of crystal nucleation, structural relaxation and viscosity behaviour in glass and associated relaxation kinetics, influence of preliminary nucleation and coupled phenomenological kinetics, nucleation on both the strongly curved surfaces and nano-particles, crystallization of glassy and amorphous materials including oxides, chalcogenides and metals, non-parametric and fractal description of kinetics, disorder and dimensionality in nano-crystalline diamond, thermal analysis of waste glass batches, amorphous inorganic polysialates and bioactivity of hydroxyl groups as well as reaction kinetics and unconventional glass formability of oxide superconductors. Thermal Analysis of Micro-, Nano- and Non-Crystalline Materials: Transformation, Crystallization, Kinetics, and Thermodynamics is a valuable resource to advanced undergraduates, postgraduates, and researches working in the application fields of material thermodynamics, thermal analysis, thermophysical measurements, and calorimetry.

Nucleation in Condensed Matter

Author : Ken Kelton
Publisher : Elsevier
ISBN 13 : 0080912648
Total Pages : 759 pages
Book Rating : 4.0/5 (89 download)

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Book Synopsis Nucleation in Condensed Matter by : Ken Kelton

Download or read book Nucleation in Condensed Matter written by Ken Kelton and published by Elsevier. This book was released on 2010-03-19 with total page 759 pages. Available in PDF, EPUB and Kindle. Book excerpt: In Nucleation in Condensed Matter, key theoretical models for nucleation are developed and experimental data are used to discuss their range of validity. A central aim of this book is to enable the reader, when faced with a phenomenon in which nucleation appears to play a role, to determine whether nucleation is indeed important and to develop a quantitative and predictive description of the nucleation behavior. The third section of the book examines nucleation processes in practical situations, ranging from solid state precipitation to nucleation in biological systems to nucleation in food and drink. Nucleation in Condensed Matter is a key reference for an advanced materials course in phase transformations. It is also an essential reference for researchers in the field. Unified treatment of key theories, experimental evaluations and case studies Complete derivation of key models Detailed discussion of experimental measurements Examples of nucleation in diverse systems

New Perspectives on Mineral Nucleation and Growth

Author : Alexander E.S. Van Driessche
Publisher : Springer
ISBN 13 : 3319456695
Total Pages : 380 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis New Perspectives on Mineral Nucleation and Growth by : Alexander E.S. Van Driessche

Download or read book New Perspectives on Mineral Nucleation and Growth written by Alexander E.S. Van Driessche and published by Springer. This book was released on 2016-12-20 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade, numerous studies have demonstrated the existence of alternative pathways to nucleation and crystallisation that oppose the classical view. Such proposed scenarios include multistage reactions proceeding via various precursor species and/or intermediate phases. The aim of this book is to review and discuss these recent advances in our understanding of the early stages of mineralisation through a series of contributions that address both experimental and theoretical studies about the formation and nature of initial precursor species (e.g., prenucleation clusters, dense liquid phases, amorphous nanoparticles, etc.) as well as their transformations leading to the stable mineral phase. Several chapters are devoted to cutting-edge analytical techniques used for investigating the above processes in situ, in real time and at conditions relevant to both natural and industrial processes. At the end of the book, the editors summarize the key questions that still need to be addressed in order to establish a complete picture of the nucleation and growth processes involved during the formation of minerals

Nucleation of Water

Author : Ari Laaksonen
Publisher : Elsevier
ISBN 13 : 0128143223
Total Pages : 296 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Nucleation of Water by : Ari Laaksonen

Download or read book Nucleation of Water written by Ari Laaksonen and published by Elsevier. This book was released on 2021-11-25 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nucleation of Water: From Fundamental Science to Atmospheric and Additional Applications provides a comprehensive accounting of the current state-of-the-art regarding the nucleation of water. It covers vapor-liquid, liquid-vapor, liquid-ice and vapor-ice transitions and describes basic kinetic and thermodynamic concepts in a manner understandable to researchers working on specific applications. The main focus of the book lies in atmospheric phenomena, but it also describes engineering and biological applications. Bubble nucleation, although not of major atmospheric relevance, is included for completeness. This book presents a single, go-to resource that will help readers understand the breadth and depth of nucleation, both in theory and in real-world examples. Offers a single, comprehensive work on water nucleation, including cutting- edge research on ice, cloud and bubble nucleation Written primarily for atmospheric scientists, but it also presents the theories in such a way that researchers in other disciplines will find it useful Written by one of the world’s foremost experts on ice nucleation

Light Metals 2016

Author : The Minerals, Metals & Materials Society (TMS)
Publisher : John Wiley & Sons
ISBN 13 : 111927477X
Total Pages : 1083 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Light Metals 2016 by : The Minerals, Metals & Materials Society (TMS)

Download or read book Light Metals 2016 written by The Minerals, Metals & Materials Society (TMS) and published by John Wiley & Sons. This book was released on 2016-02-09 with total page 1083 pages. Available in PDF, EPUB and Kindle. Book excerpt: The 2016 collection will include papers from the following symposia: Alumina and Bauxite Aluminum Alloys, Processing, and Characterization Aluminum Reduction Technology Cast Shop Technology Electrode Technology Strip Casting

Environmental Chemistry of Aerosols

Author : Ian Colbeck
Publisher : John Wiley & Sons
ISBN 13 : 1405139196
Total Pages : 276 pages
Book Rating : 4.4/5 (51 download)

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Book Synopsis Environmental Chemistry of Aerosols by : Ian Colbeck

Download or read book Environmental Chemistry of Aerosols written by Ian Colbeck and published by John Wiley & Sons. This book was released on 2008-03-24 with total page 276 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aerosol particles are ubiquitous in the Earth’s atmosphere and are central to many environmental issues such as climate change, stratospheric ozone depletion and air quality. In urban environments, aerosol particles can affect human health through their inhalation. Atmospheric aerosols originate from naturally occurring processes, such as volcanic emissions, sea spray and mineral dust emissions, or from anthropogenic activity such as industry and combustion processes. Aerosols present pathways for reactions, transport, and deposition that would not occur in the gas phase alone. Understanding the ways in which aerosols behave, evolve, and exert these effects requires knowledge of their formation and removal mechanism, transport processes, as well as their physical and chemical characteristics. Motivated by climate change and adverse health effects of traffic-related air pollution, aerosol research has intensified over the past couple of decades, and recent scientific advances offer an improved understanding of the mechanisms and factors controlling the chemistry of atmospheric aerosols. Environmental Chemistry of Aerosols brings together the current state of knowledge of aerosol chemistry, with chapters written by international leaders in the field. It will serve as an authoritative and practical reference for scientists studying the Earth’s atmosphere and as an educational and training resource for both postgraduate students and professional atmospheric scientists.

Light Metals 2016

Author : Edward Williams
Publisher : Springer
ISBN 13 : 3319482513
Total Pages : 983 pages
Book Rating : 4.3/5 (194 download)

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Book Synopsis Light Metals 2016 by : Edward Williams

Download or read book Light Metals 2016 written by Edward Williams and published by Springer. This book was released on 2016-12-20 with total page 983 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Light Metals symposia are a key part of the TMS Annual Meeting & Exhibition, presenting the most recent developments, discoveries, and practices in primary aluminum science and technology. Publishing the proceedings from these important symposia, the Light Metals volume has become the definitive reference in the field of aluminum production and related light metal technologies. The 2016 collection includes papers from the following symposia: 1.Alumina and Bauxite 2.Aluminum Alloys, Processing, and Characterization 3.Aluminum Reduction Technology 4.Cast Shop Technology 5.Electrode Technology 6.Strip Casting

Kinetics of First Order Phase Transitions

Author : Vitaly V. Slezov
Publisher : John Wiley & Sons
ISBN 13 : 9783527627776
Total Pages : 429 pages
Book Rating : 4.6/5 (277 download)

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Book Synopsis Kinetics of First Order Phase Transitions by : Vitaly V. Slezov

Download or read book Kinetics of First Order Phase Transitions written by Vitaly V. Slezov and published by John Wiley & Sons. This book was released on 2009-07-10 with total page 429 pages. Available in PDF, EPUB and Kindle. Book excerpt: Filling a gap in the literature, this crucial publication on the renowned Lifshitz-Slezov-Wagner Theory of first-order phase transitions is authored by one of the scientists who gave it its name. Prof Slezov spent decades analyzing this topic and obtained a number of results that form the cornerstone of this rapidly developing branch of science. Following an analysis of unresolved problems together with proposed solutions, the book develops a theoretical description of the overall course of first-order phase transformations, starting from the nucleation state right up to the late stages of coarsening. In so doing, the author illustrates the results by way of numerical computations and experimental applications. The outline of the general results is performed for segregation processes in solutions and the results used in the analysis of a variety of different topics, such as phase formation in multi-component solutions, boiling in one- and multi-component liquids, vacancy cluster evolution in solids with and without influence of radiation, as well as phase separation in helium at low temperatures. The result is a detailed overview of the theoretical description of the whole course of nucleation-growth processes and applications for a wide audience of scientists and students.