Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions

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Book Synopsis Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions by :

Download or read book Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions written by and published by . This book was released on 1985 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A technique is described for the simultaneous separation and determination of the cyanide complexes of copper, nickel, cobalt, iron, and gold. The separation procedure utilizes the principles of ion-pair chromatography, i.e. the partitioning of ion pairs between a hydrophilic mobile phase and a hydrophobic column surface. The cyanide complexes are detected spectrophotometrically or, after the solution has passed through a suppressor, by conductivity measurement. The method is applied to gold solutions from the carbon-in-pulp process. The precision (relative standard deviation) was found to be better than 0,0201 for all complexes at concentrations of 5 mg/l and better than 0,0138 at concentrations of 10 mg/l.

Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions

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Book Synopsis Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions by :

Download or read book Chromatographic Separation and Determination of Stable Metal Cyanide Complexes in Gold Processing Solutions written by and published by . This book was released on 1986 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Classical analytical chemistry relied to a large extent on the physical separation of the individual elements or radicals prior to their identification and quantitative determination. With the advent of instrumental methods of analysis it became possible in many instances to detect and measure the concentration of elements by physical means without prior separation. Optical emission spectrometry, X-ray-fluorescence spectrometry, polarography, and activation analysis are examples of such techniques. In recent years, much effort has been directed towards 'speciation': the identification of the state of combination of the elements and their complexes as they exist in a sample, followed by quantitative estimation. This is of importance, for example, in the electroplating, electrowinning, water-treatment, and hydrometallurgical fields. Ion chromatography is a technique that can be used with success for some of this work. Chromatography as a method of separating species was first employed in 1906 by the botanist Tswett to separate plant pigments. The early chromatographic columns consisted of inorganic adsorbents such as alumina. Paper pulp was also used, to be followed by synthetic organic ion-exchange materials for chemical chromatographic separations. By the suitable choice of solvents and eluting agents, it has now become possible to separate certain chemical complexes with relative ease. It then remains to find a suitable method for the determination of the eluted species. Spectrophotometric or conductivity measurements are usually employed. The technique has been developed to such an extent that it can be used for small volumes of samples. The procedure has great potential in the South African mining context, not only for the better understanding and control of hydrometallurgical processes, but also for the analysis and monitoring of effluents. Pioneering work has been done at Mintek on the development and application of this technique in South Africa. Already several laboratories serving the mining industry have acquired similar equipment, and ion chromatography is becoming one of the accepted analytical procedures. Work on the determination of complexes other than cyanides is already in progress.

The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide

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Total Pages : 11 pages
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Book Synopsis The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide by : Christel Pohlandt

Download or read book The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide written by Christel Pohlandt and published by . This book was released on 1989 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt: The determination of a variety of metal complexes, typically occurring in solutions and effluents derived from the processing of gold, is described. The method makes use of reverse-phase ion-interaction chromatography, with an acetonitrile eluent containing tetrabutylammonium hydroxide as the pairing reagent and a neutral phosphate buffer as the inorganic modifier. Individual metal complexes occurring in a process or tailings solution can be identified and their cyanide content reliably estimated. The simultaneous determination of 'free' cyanide in waste waters, which allows an estimate of the 'total' cyanide concentration, was achieved by the conversion of the cyanide to the silver cyanide complex, chromatographic separation, and the use of calibration graphs.

The Determination of 'total' Cyanide by the Ion-interaction Chromatographic Separation of Individual Metal Cyanide Complexes

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Book Synopsis The Determination of 'total' Cyanide by the Ion-interaction Chromatographic Separation of Individual Metal Cyanide Complexes by :

Download or read book The Determination of 'total' Cyanide by the Ion-interaction Chromatographic Separation of Individual Metal Cyanide Complexes written by and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A method is described for the determination of a variety of metal cyanide complexes occurring typically in solutions and effluents derived from the processing of gold. The method employs reverse-phase ion-interaction chromatography using an acetonitrile eluent containing tetrabutylammonium hydroxide as the pairing reagent and a neutral phosphate buffer as the inorganic modifier. Individual metal complexes occurring in a process or tailings solution can be identified, and their cyanide content reliably estimated. The simultaneous determination of 'free' cyanide in waste waters, which allows the 'total' cyanide concentration to be estimated, is achieved by the conversion of the cyanide to the silver cyanide complex, followed by chromatographic separation. The precision of the procedure (relative standard deviation) for most of the complexes is acceptable, even at submicrogram-per-litre levels.

The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide

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Total Pages : 11 pages
Book Rating : 4.:/5 (46 download)

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Book Synopsis The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide by : Christel Pohlandt

Download or read book The Separation, by Ion-interaction Chromatography, of Metal Cyanide Complexes, and the Application of the Technique to the Determination of 'total' Cyanide written by Christel Pohlandt and published by . This book was released on 1989 with total page 11 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Chemistry of Gold Extraction

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Publisher : SME
ISBN 13 : 9780873352406
Total Pages : 688 pages
Book Rating : 4.3/5 (524 download)

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Book Synopsis The Chemistry of Gold Extraction by : John Marsden

Download or read book The Chemistry of Gold Extraction written by John Marsden and published by SME. This book was released on 2006 with total page 688 pages. Available in PDF, EPUB and Kindle. Book excerpt: Extensively revised and updated, this edition provides the broad base of knowledge required by all working in the gold extraction and gold processing industries. It bridges the gap between research and industry by emphasizing practical applications of chemical principles and techniques.

A Revised Ion-chromatographic Method for the Determination of Free Cyanide

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ISBN 13 : 9780869997741
Total Pages : 3 pages
Book Rating : 4.9/5 (977 download)

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Book Synopsis A Revised Ion-chromatographic Method for the Determination of Free Cyanide by : Christel Pohlandt-Watson

Download or read book A Revised Ion-chromatographic Method for the Determination of Free Cyanide written by Christel Pohlandt-Watson and published by . This book was released on 1986 with total page 3 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Randol at Minexpo '92

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ISBN 13 :
Total Pages : 372 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Randol at Minexpo '92 by :

Download or read book Randol at Minexpo '92 written by and published by . This book was released on 1992 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Journal of Chromatography

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ISBN 13 :
Total Pages : 356 pages
Book Rating : 4.5/5 (315 download)

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Book Synopsis Journal of Chromatography by :

Download or read book Journal of Chromatography written by and published by . This book was released on 1998 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Unrestricted Mintek Publications

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ISBN 13 :
Total Pages : 236 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis Unrestricted Mintek Publications by :

Download or read book Unrestricted Mintek Publications written by and published by . This book was released on 1966 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Management of Cyanide in Gold Extraction

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ISBN 13 :
Total Pages : 56 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis The Management of Cyanide in Gold Extraction by : Mark J. Logsdon

Download or read book The Management of Cyanide in Gold Extraction written by Mark J. Logsdon and published by . This book was released on 1999 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Capsule Report

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ISBN 13 :
Total Pages : 36 pages
Book Rating : 4.:/5 (31 download)

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Book Synopsis Capsule Report by :

Download or read book Capsule Report written by and published by . This book was released on 2000 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Determination of Cyanide in Hydrometallurgical Process Solutions and Effluents by Ion Chromatography

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ISBN 13 : 9780869996478
Total Pages : 31 pages
Book Rating : 4.9/5 (964 download)

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Book Synopsis The Determination of Cyanide in Hydrometallurgical Process Solutions and Effluents by Ion Chromatography by : Christel Pohlandt-Watson

Download or read book The Determination of Cyanide in Hydrometallurgical Process Solutions and Effluents by Ion Chromatography written by Christel Pohlandt-Watson and published by . This book was released on 1984 with total page 31 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Extraction Metallurgy '85

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ISBN 13 :
Total Pages : 1144 pages
Book Rating : 4.:/5 (41 download)

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Book Synopsis Extraction Metallurgy '85 by :

Download or read book Extraction Metallurgy '85 written by and published by . This book was released on 1985 with total page 1144 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chromatographic Analysis of Precious Metals in Gold-processing Solutions

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ISBN 13 :
Total Pages : 114 pages
Book Rating : 4.:/5 (226 download)

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Book Synopsis Chromatographic Analysis of Precious Metals in Gold-processing Solutions by : Damien Francis Hilton

Download or read book Chromatographic Analysis of Precious Metals in Gold-processing Solutions written by Damien Francis Hilton and published by . This book was released on 1985 with total page 114 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Ion Chromatography

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Publisher : John Wiley & Sons
ISBN 13 : 3527626883
Total Pages : 394 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Ion Chromatography by : James S. Fritz

Download or read book Ion Chromatography written by James S. Fritz and published by John Wiley & Sons. This book was released on 2009-03-09 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt: This completely revised and updated fourth edition of the best-selling classic is a thorough treatment of the subject while remaining concise and readable. New additions include capillary electrophoresis, monolithic columns, zwitterion colums, DNA/RNA analysis, fundamentals of the science of IC, and micro methods. The whole is rounded off by handy tables with details on detection or elution conditions, among others.

Ion Chromatography

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Publisher : John Wiley & Sons
ISBN 13 : 3527615628
Total Pages : 476 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Ion Chromatography by : Joachim Weiss

Download or read book Ion Chromatography written by Joachim Weiss and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 476 pages. Available in PDF, EPUB and Kindle. Book excerpt: This all-new edition of the highly successful first edition contains a wealth of up-to-date information on this major analytical technique. Ion-exchange, ion-exclusion, and ion-pair chromatography are treated together with their detection methods, and a discussion of quantitative analysis is also given. The complete range of application possibilities of this technique is described and illustrated with numerous chromatograms. Special chapters are featured on applications in environmental analysis, clinical chemistry as well as in the food and beverage industry. From reviews of previous editions: This volume can be highly recommended to both the experienced user and the newcomer in the field of ion chromatography. Zeitschrift fuer Wasser- und Abwasserforschung Everybody who is actively dealing with ion chromatography cannot afford to miss this book. Laborpraxis This book is a valuable aid to all scientists wishing to work confidently with these different methods, as well as practitioners who employ these techniques on a day-to-day basis.