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Chemistry Of Hydrocarbon Combustion
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Book Synopsis Chemistry of Hydrocarbon Combustion by : David. Hucknall
Download or read book Chemistry of Hydrocarbon Combustion written by David. Hucknall and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: The scientific and economic importance of the high-temperature reactions of hydrocarbons in both the presence and absence of oxygen cannot be overemphasized. A vast chemical industry exists based on feedstocks produced by the controlled pyrolysis of hydrocarbons, while uncontrolled combustion in air is still among the most important sources of heat and mechanical energy. The detonation and explosion of hydrocarbon-oxidant mixtures can however, be a highly dangerous phenomenon which destroys lives and equipment. In order that control can be exerted over combustion processes, a complete description of hydrocarbon oxidation and pyrolysis is required. A major contribution to this is an understanding of the unstable intermediates involved and their reactions. The aim of this book is to review our knowledge of the chemistry of hydrocarbon combustion and to consider the data which are available for relevant reactions. Chapter 1 describes early studies in which the apparent complexity of the chemistry was established and the type of information required for a better understanding was defined. Experimental studies of the overall process which were carried out with the aim of establishing the sequence of stable chemical intermediates and some of the unstable species are described in Chapter 2. The limited nature of the information thus obtained showed that independent studies of individual reactions involving the unstable species were required. In Chapter 3 investigations specifically aimed at the determination of the kinetics of elementary reactions are discussed.
Book Synopsis Handbook of Industrial Hydrocarbon Processes by : James G. Speight
Download or read book Handbook of Industrial Hydrocarbon Processes written by James G. Speight and published by Gulf Professional Publishing. This book was released on 2010-12-24 with total page 657 pages. Available in PDF, EPUB and Kindle. Book excerpt: Written by an author with over 38 years of experience in the chemical and petrochemical process industry, this handbook will present an analysis of the process steps used to produce industrial hydrocarbons from various raw materials. It is the first book to offer a thorough analysis of external factors effecting production such as: cost, availability and environmental legislation. An A-Z list of raw materials and their properties are presented along with a commentary regarding their cost and availability. Specific processing operations described in the book include: distillation, thermal cracking and coking, catalytic methods, hydroprocesses, thermal and catalytic reforming, isomerization, alkylation processes, polymerization processes, solvent processes, water removal, fractionation and acid gas removal. - Flow diagrams and descriptions of more than 250 leading-edge process technologies - An analysis of chemical reactions and process steps that are required to produce chemicals from various raw materials - Properties, availability and environmental impact of various raw materials used in hydrocarbon processing
Book Synopsis The Chemistry of Hydrocarbon Fuels by : Harold H. Schobert
Download or read book The Chemistry of Hydrocarbon Fuels written by Harold H. Schobert and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 361 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Hydrocarbon Fuels is concerned with the chemical aspects of hydrofuels such as coal, petroleum, and natural gas. Topics covered include diagenesis and catagenesis, processing of natural gas and petroleum fractions, coal combustion, and chemicals that can be obtained from fuels. This book is comprised of 14 chapters and begins with a comprehensive treatment of the formation of fuels from accumulated organic matter, along with the organic geochemistry of coal, oil, and gas. The following chapters focus on the composition of hydrocarbon fuels and some of their important physical properties. Production and use of synthesis gas, alternate fuels from coal, and oxygenated fuels are considered. The remaining chapters deal with some of the chemistry of separation, refining, and use of hydrocarbon fuels. This monograph is written primarily for practicing scientists and engineers, fuel scientists, petroleum chemists, and those who are new to the field of fuel science and seek an introduction to fuel chemistry.
Book Synopsis Detailed and Reduced Chemical-kinetic Descriptions for Hydrocarbon Combustion by : Maria V. Petrova
Download or read book Detailed and Reduced Chemical-kinetic Descriptions for Hydrocarbon Combustion written by Maria V. Petrova and published by . This book was released on 2005 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Chemistry of Hydrocarbon Fuel Combustion by : Walter R. May
Download or read book The Chemistry of Hydrocarbon Fuel Combustion written by Walter R. May and published by . This book was released on 2013-04 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book was written to bring together under one cover a detailed look at the chemistry (and some physics) of combustion of hydrocarbon fuels that will satisfy experts in the field, and at the same time allow the less well prepared student to understand the basic principles involved.
Book Synopsis Hydrocarbon Combustion Reaction Models from Both Ends--the Foundational Fuels and JP10 by : Yujie Tao
Download or read book Hydrocarbon Combustion Reaction Models from Both Ends--the Foundational Fuels and JP10 written by Yujie Tao and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Due to the hierarchical nature of high-temperature hydrocarbon oxidation, modeling the combustion chemistry of higher hydrocarbon fuels typically requires a fuel-specific reaction model that describes the fragmentation of the fuel to small species, and a foundational fuel chemistry model that describes the oxidation of these species. Shared by the combustion of large hydrocarbons, the foundational fuel chemistry is also the rate-limiting step and therefore a crucial part for constructing reliable combustion models for any higher hydrocarbons. The dissertation studies the aforementioned problems from both ends. A detailed reaction kinetic model of the foundational fuel combustion is comprised of elementary chemical reactions and their associated rate coefficients. Each of the rate coefficients comes with some uncertainty. The inherent uncertainties of the rate parameters propagate into model predictions and need to be properly quantified. Without characterizing the uncertainty, a reaction model merely represents a feasible combination of rate parameters within a high-dimensional uncertainty space. The Foundational Fuel Chemistry Model (FFCM) is an effort directed at developing a reliable combustion model for the foundational fuels with rate parameters optimized and uncertainty minimized. The first version, FFCM-1, optimized for H2, H2/CO, CH2O and CH4 combustion was constrained with carefully evaluated fundamental combustion data that includes laminar flame speeds, shock tube ignition delay times, shock tube species profiles, and flow reactor species profiles. It has been shown that the model reconciles all the experimental targets chosen and has significantly reduced prediction uncertainties. The remaining kinetic uncertainties in FFCM-1 were further analyzed with extinction and ignition residence time predictions in perfectly-stirred reactor conditions. The reactions that were responsible for the remaining prediction uncertainties were studied with an impact factor analysis over a wide range of temperature, pressure and equivalence ratio. The optimization and uncertainty quantification procedure was then extended to also include temperature dependency by considering the joint optimization of pre-exponential factors and activation energies. An effective temperature was defined for every target and utilized in the response surface derivation. The resulting temperature-dependent uncertainties of key reactions in H2/CO flames in a test problem were discussed. JP10 was studied as a single-component large-fuel example, using the Hybrid Chemistry (HyChem) approach. The HyChem approach assumes a decoupled fuel pyrolysis and oxidation of pyrolysis products. The pyrolysis model is described with highly-lumped steps and optimized against experimental data from shock tube and flow reactor species profiles and shock tube ignition delay. Special attention was paid to the unique molecular structure of the fuel in the lumped pyrolysis reactions, and the overall performance of the model is shown to be satisfactory.
Author :W.C., Jr. Gardiner Publisher :Springer Science & Business Media ISBN 13 :9780387988610 Total Pages :564 pages Book Rating :4.9/5 (886 download)
Book Synopsis Gas-Phase Combustion Chemistry by : W.C., Jr. Gardiner
Download or read book Gas-Phase Combustion Chemistry written by W.C., Jr. Gardiner and published by Springer Science & Business Media. This book was released on 1999-12-10 with total page 564 pages. Available in PDF, EPUB and Kindle. Book excerpt: Superseding Gardiner's "Combustion Chemistry", this is an updated, comprehensive coverage of those aspects of combustion chemistry relevant to gas-phase combustion of hydrocarbons. The book includes an extended discussion of air pollutant chemistry and aspects of combustion, and reviews elementary reactions of nitrogen, sulfur and chlorine compounds that are relevant to combustion. Methods of combustion modeling and rate coefficient estimation are presented, as well as access to databases for combustion thermochemistry and modeling.
Book Synopsis First-principles Chemistry for Combustion of Hydrocarbon Fuels by : Lam Kim Huynh
Download or read book First-principles Chemistry for Combustion of Hydrocarbon Fuels written by Lam Kim Huynh and published by . This book was released on 2007 with total page 177 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chapter 1 is an overview on the main challenges in building complete kinetic mechanisms for combustion of hydrocarbon fuels. The suggested solutions to address these challenges are also introduced in this chapter. Chapter 2 presents the RC-TST methodology. Several applications of the RC-TST are presented in Chapter 3. Chapter 4 is about the implementation of the ME methodology in calculating the pressure-dependent rate constants for complex reactions on multiple, interconnected potential energy surface. An illustration is given as "Kinetics of Enol Formation from Reaction of OH with Propene."
Book Synopsis Basic Principles of Organic Chemistry by : John D. Roberts
Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.
Book Synopsis Chemistry of Hydrocarbon Fuels by : Harold H. Schobert
Download or read book Chemistry of Hydrocarbon Fuels written by Harold H. Schobert and published by Butterworth-Heinemann. This book was released on 1990 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Hydrocarbon Fuels by : E. M. Goodger
Download or read book Hydrocarbon Fuels written by E. M. Goodger and published by . This book was released on 1975 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis HYDROCARBON COMBUSTION CHEMISTRY- PREPRINTS OF A SYMPOSIUM PRESENTED TO THE DIVISION OF PETROLEUM CHEMISTRY- ACS. by :
Download or read book HYDROCARBON COMBUSTION CHEMISTRY- PREPRINTS OF A SYMPOSIUM PRESENTED TO THE DIVISION OF PETROLEUM CHEMISTRY- ACS. written by and published by . This book was released on with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Combustion Chemistry of Chain Hydrocarbons by : Frederick L. Dryer
Download or read book Combustion Chemistry of Chain Hydrocarbons written by Frederick L. Dryer and published by . This book was released on 1977 with total page 63 pages. Available in PDF, EPUB and Kindle. Book excerpt: The current understanding of the combustion chemistry of paraffin hydrocarbons is summarized. Emphasis is placed on reviewing the semiempirical methods presently available for modelling alkyl hydrocarbon combustion. The anomalies inherent in some of the existing models and approaches to improve both qualitative and quantitative predictive capabilities are discussed. Modelling alkane combustion chemistry over extended ranges of equivalence ratio, pressure, and temperature, requires the consideration of sequential but partially overlapping processes: an initial period of induction phase chemistry; conversion of primary aliphatics to olefins, oxidation of the resulting oelfins to carbon monoxide, and simultaneous oxidation of hydrogen produced in the hydrocarbon destruction. The conditions under which the induction phase chemistry can be neglected in modelling efforts is explored. HO2 chemistry is found to be required in order to extend the applicability of detailed hydrogen/carbon monoxide/oxygen mechanisms to ranges of pressure and temperature normally used in practical combustion system modelling. Functional quasi-global kinetic expressions for alkane oxidation are discussed and errors in some published results on overall rate coefficients are clarified. Stress is given to the advantages of quasi-global kinetic modelling and the additional modifications required for these models to have greater applicability.
Book Synopsis Hydrocarbon Combustion Chemistry by : D.I. MacLean
Download or read book Hydrocarbon Combustion Chemistry written by D.I. MacLean and published by . This book was released on 1973 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Chemical Kinetics of the Gas Phase Combustion of Fuels by : Francis Westley
Download or read book Chemical Kinetics of the Gas Phase Combustion of Fuels written by Francis Westley and published by . This book was released on 1976 with total page 148 pages. Available in PDF, EPUB and Kindle. Book excerpt: Work supported by the Office of Standard Reference Data, National Bureau of Standards, Naval Sea Systems Command, Department of the Navy, and Division of Conservation, Research and Technology, Energy Research and Development Administration.
Book Synopsis The Chemistry of Combustion by : John Newton Friend
Download or read book The Chemistry of Combustion written by John Newton Friend and published by . This book was released on 1922 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Tackling Turbulent Flows in Engineering by : Anupam Dewan
Download or read book Tackling Turbulent Flows in Engineering written by Anupam Dewan and published by Springer Science & Business Media. This book was released on 2010-10-23 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: The emphasis of this book is on engineering aspects of fluid turbulence. The book explains for example how to tackle turbulence in industrial applications. It is useful to several disciplines, such as, mechanical, civil, chemical, aerospace engineers and also to professors, researchers, beginners, under graduates and post graduates. The following issues are emphasized in the book: - Modeling and computations of engineering flows: The author discusses in detail the quantities of interest for engineering turbulent flows and how to select an appropriate turbulence model; Also, a treatment of the selection of appropriate boundary conditions for the CFD simulations is given. - Modeling of turbulent convective heat transfer: This is encountered in several practical situations. It basically needs discussion on issues of treatment of walls and turbulent heat fluxes. - Modeling of buoyancy driven flows, for example, smoke issuing from chimney, pollutant discharge into water bodies, etc
