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Author : Glenn Richard Wilkes
Publisher :
ISBN 13 :
Total Pages : 356 pages
Book Rating : 4.:/5 (89 download)
Download or read book Chemistry and Structures of Some Polynuclear Metal Carbonyl Complexes written by Glenn Richard Wilkes and published by . This book was released on 1965 with total page 356 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Mandeep Dalal
Publisher : Dalal Institute
ISBN 13 : 8193872002
Total Pages : 480 pages
Book Rating : 4.1/5 (938 download)
Download or read book A Textbook of Inorganic Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2017-01-01 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of inorganic chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Inorganic Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Stereochemistry and Bonding in Main Group Compounds: VSEPR theory, dπ -pπ bonds, Bent rule and energetic of hybridization. Chapter 2. Metal-Ligand Equilibria in Solution: Stepwise and overall formation constants and their interactions, Trends in stepwise constants, Factors affecting stability of metal complexes with reference to the nature of metal ion and ligand, Chelate effect and its thermodynamic origin, Determination of binary formation constants by pH-metry and spectrophotometry. Chapter 3. Reaction Mechanism of Transition Metal Complexes – I: Inert and labile complexes, Mechanisms for ligand replacement reactions, Formation of complexes from aquo ions, Ligand displacement reactions in octahedral complexes- acid hydrolysis, Base hydrolysis, Racemization of tris chelate complexes, Electrophilic attack on ligands. Chapter 4. Reaction Mechanism of Transition Metal Complexes – II: Mechanism of ligand displacement reactions in square planar complexes, The trans effect, Theories of trans effect, Mechanism of electron transfer reactions – types; Outer sphere electron transfer mechanism and inner sphere electron transfer mechanism, Electron exchange. Chapter 5. Isopoly and Heteropoly Acids and Salts: Isopoly and Heteropoly acids and salts of Mo and W: structures of isopoly and heteropoly anions. Chapter 6. Crystal Structures: Structures of some binary and ternary compounds such as fluorite, antifluorite, rutile, antirutile, crystobalite, layer lattices- CdI2, BiI3; ReO3, Mn2O3, corundum, pervoskite, Ilmenite and Calcite. Chapter 7. Metal-Ligand Bonding: Limitation of crystal field theory, Molecular orbital theory, octahedral, tetrahedral or square planar complexes, π-bonding and molecular orbital theory. Chapter 8. Electronic Spectra of Transition Metal Complexes: Spectroscopic ground states, Correlation and spin-orbit coupling in free ions for Ist series of transition metals, Orgel and Tanabe-Sugano diagrams for transition metal complexes (d1 – d9 states), Calculation of Dq, B and β parameters, Effect of distortion on the d-orbital energy levels, Structural evidence from electronic spectrum, John-Tellar effect, Spectrochemical and nephalauxetic series, Charge transfer spectra, Electronic spectra of molecular addition compounds. Chapter 9. Magantic Properties of Transition Metal Complexes: Elementary theory of magneto - chemistry, Guoy’s method for determination of magnetic susceptibility, Calculation of magnetic moments, Magnetic properties of free ions, Orbital contribution, effect of ligand-field, Application of magneto-chemistry in structure determination, Magnetic exchange coupling and spin state cross over. Chapter 10. Metal Clusters: Structure and bonding in higher boranes, Wade’s rules, Carboranes, Metal Carbonyl Clusters - Low Nuclearity Carbonyl Clusters, Total Electron Count (TEC). Chapter 11. Metal-π Complexes: Metal carbonyls, structure and bonding, Vibrational spectra of metal carbonyls for bonding and structure elucidation, Important reactions of metal carbonyls; Preparation, bonding, structure and important reactions of transition metal nitrosyl, dinitrogen and dioxygen complexes; Tertiary phosphine as ligand.
Author : Duward F. Shriver
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 456 pages
Book Rating : 4.3/5 (91 download)
Download or read book The Chemistry of Metal Cluster Complexes written by Duward F. Shriver and published by Wiley-VCH. This book was released on 1990 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: Seven chapters summarize the current status of organometallic cluster chemistry from the viewpoints of synthesis, structure and bonding, ligand substitution reactions, ligand transformations, polyhedral rearrangement, cluster fragmentation reactions, and metal clusters as homogeneous catalysts. An eighth provides an extensive bibliography of reviews for the period from 1965 to 1988. Annotation copyrighted by Book News, Inc., Portland, OR
Author : Eugene R. Corey
Publisher :
ISBN 13 :
Total Pages : 228 pages
Book Rating : 4.:/5 (89 download)
Download or read book The Crystal and Molecular Structures of Some Polynuclear Metal Carbonyls written by Eugene R. Corey and published by . This book was released on 1963 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Michael John Bennett
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (27 download)
Download or read book The Structure of Some Substituted Transition Metal Carbonyl Complexes written by Michael John Bennett and published by . This book was released on 1965 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Paul J Dyson
Publisher : CRC Press
ISBN 13 : 9780367397913
Total Pages : 180 pages
Book Rating : 4.3/5 (979 download)
Download or read book Transition Metal Carbonyl Cluster Chemistry written by Paul J Dyson and published by CRC Press. This book was released on 2019-08-30 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition metal carbonyl clusters (TMCCs) continue to inspire great interest in chemical research, as much for their fascinating structures as for potential industrial applications conferred by their unique properties. This highly accessible book introduces the bonding, structure, spectroscopic properties, and characterization of clusters, and then explores their synthesis, reactivity, reaction mechanisms and use in organic synthesis and catalysis. Transition Metal Carbonyl Cluster Chemistry describes models and rules that correlate cluster structure with electron count, which are then applied in worked examples. Subsequent chapters explain how bonding relates to molecular structure, demonstrate the use of spectroscopic techniques such as NMR, IR and MS in cluster chemistry, and outline the factors contributing to the stability, dynamics and reactivity of clusters. The second part of this book discusses the synthesis and applications of TMCCs. It emphasizes the differences between the reactivities of clusters vs. mononuclear metal complexes, contingent to the availability of multiple-bonding sites and heterosite reactivity. The final chapters discuss reactions in which clusters act as homogeneous catalysts; including discussion on the use of solid and biphasic liquid-liquid supported clusters in heterogeneous catalysts. A useful reference for those commencing further research or post-graduate study on metal carbonyl clusters and advanced organometallic chemistry, this book is also a cornerstone addition to academic and libraries as well as private collections.
Author : Pierre Braunstein
Publisher : Wiley-VCH
ISBN 13 :
Total Pages : 568 pages
Book Rating : 4.:/5 ( download)
Download or read book Metal Clusters in Chemistry written by Pierre Braunstein and published by Wiley-VCH. This book was released on 2000-01-11 with total page 568 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal cluster chemistry is at the cutting edge between molecular and solid-state chemistry and has therefore had a great impact on the researchers working on organic, coordination, and solid-state chemistry, catalysis, physics, and materials science. The development of new sophisticated synthetic techniques has led to enormous progress in the synthesis of this diverse class of compounds. The number of clusters is growing rapidly, since the possible variations in the metal and ligand sphere are numerous. Modern bonding theories, such as the isolobal principle, have allowed a better understanding of the structures and properties of metal clusters, and thus paved the way for the usage of these versatile materials. Catalysis and nanomaterials are just two of the very promising application-oriented fields. Seventy six contributions, written by world experts in this research field, provide extensive coverage of different aspects of cluster chemistry, ranging from synthesis, structure determination, and dynamics to applications. Up-to-date information, including an impressive collection of structural data and illustrations, extensive coverage of the most important publications of the last decade, and many more features make this three-volume set a complete single-source guide for all researchers working in the area of cluster chemistry.
Author : Madan R.L.
Publisher : S. Chand Publishing
ISBN 13 : 9352535855
Total Pages : 336 pages
Book Rating : 4.3/5 (525 download)
Download or read book Chemistry for Degree Students (B.Sc. Elective Semester-V/VI - Elective-I) (As per CBCS) written by Madan R.L. and published by S. Chand Publishing. This book was released on with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: The subject matter has been divided into twelve chapters written in lucid language. Great care has been taken to explain the topics in such a simple way that it should be possible for the students to understand the various topics easily.
Author : Lawrence Frederick Dahl
Publisher :
ISBN 13 :
Total Pages : 350 pages
Book Rating : 4.:/5 (245 download)
Download or read book Structures of Some Polynuclear Metal Carbonyls ... written by Lawrence Frederick Dahl and published by . This book was released on 1957 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : James Patrick Nice
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (643 download)
Download or read book Crystal and Molecular Structures of Some Transition Metal Carbonyl Complexes written by James Patrick Nice and published by . This book was released on 1966 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : D. A. Brown
Publisher : Butterworth-Heinemann
ISBN 13 : 1483155765
Total Pages : 131 pages
Book Rating : 4.4/5 (831 download)
Download or read book Coordination Chemistry—XVI written by D. A. Brown and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 131 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination Chemistry XVI is a compendium of papers that deals with structured absorption band, intra-molecular electron transfer, and the influence of natural and synthetic ligands on the transport and function of metal ions in the environment. Experiments show that the chemical, spectral and kinetic results of the physical state of an enzyme can be a significant experimental variable that will change function-related-conformations. Another paper points out the dangers of assigning weakly structured bands to partially resolved vibrations, to lower symmetry, to spin-orbit coupling, and to the Jahn-Teller effects. One paper deals with intra-molecular electron transfer in three manifestations: 1) in traditional oxidation-reduction reactions; 2) in induced electron transfer; and 3) in mixed valence complexes. Another paper discusses the reactivity of polynuclear metal complexes involving metal-metal bonds with simple inorganic and organic molecules, particularly, polynuclear aggregates' basic structural forms and polynuclear's fluxional nature. One paper investigates the environmental effects of coordination compounds that disturb the natural balance and levels of metal ions and metal complexes in the ecosystem. The paper cites examples of pollutions caused by abnormal amounts of metal salts and metal complexes introduced in the ecosystem, and the presence of synthetic ligands or abnormal levels of natural ligands in the environment. The compendium is suitable for analytical and organic chemists, chemical engineers, environmentalists, and students of biochemistry.
Author :
Publisher : Laxmi Publications
ISBN 13 : 9788170087526
Total Pages : 1820 pages
Book Rating : 4.0/5 (875 download)
Download or read book Comprehensive Chemistry XII written by and published by Laxmi Publications. This book was released on with total page 1820 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Houghton
Publisher : Cambridge University Press
ISBN 13 : 9780521219921
Total Pages : 324 pages
Book Rating : 4.2/5 (199 download)
Download or read book Metal Complexes-Organic Chemistry written by Houghton and published by Cambridge University Press. This book was released on 1979-07-12 with total page 324 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Madan R.L.
Publisher : S. Chand Publishing
ISBN 13 : 819477179X
Total Pages : 939 pages
Book Rating : 4.1/5 (947 download)
Download or read book Chemistry for Degree Students B.Sc. Third Year written by Madan R.L. and published by S. Chand Publishing. This book was released on 2022 with total page 939 pages. Available in PDF, EPUB and Kindle. Book excerpt: For B.Sc 3rd year students of all Indian Universities. The book has been prepared keeping view the syllabi prepared by different universities on the basis of Model UGC Curriculum. A large number of illustrations, pictures and interesting examples have been provided to make the reading interesting and understandable. The question that have been provided in the Exercise are in tune with the latest pattern of examination.
Author : Lawrence F. Dahl
Publisher :
ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.:/5 (227 download)
Download or read book Structural Chemistry and Bonding in Inorganic Compounds written by Lawrence F. Dahl and published by . This book was released on 1968 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: Systematic structural investigations not only have led to the characterization of new general types of organometallic complexes but also have provided new structural and bonding principles. These investigations have included studies on a wide variety of unusual organo (transition metal sulfur complexes). It has been shown that a sulfur atom can function as a doubly-bridging two-electron donating group, a triply-bridging four-electron donating group, a quadruply bridging four-electron donating group, and a quadruply bridging six-electron donating group in organometallic complexes. This work has also uncovered the fact that disulfide groups can be coordinated to one, two, or four transition metals. In addition, several new kinds of metal atom cluster systems have been uncovered, and the importance of metal-metal interactions on the molecular geometries of polynuclear metal carbonyl and cyclopentadienyl complexes has been assessed for several complexes. A brief summary of this work is given. (Author).
Author : Federation of European Chemical Societies. Working Party on Organometallic Chemistry
Publisher :
ISBN 13 :
Total Pages : 140 pages
Book Rating : 4.:/5 (318 download)
Download or read book Organometallic Research Centres in Europe written by Federation of European Chemical Societies. Working Party on Organometallic Chemistry and published by . This book was released on 1990 with total page 140 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : J. N. Nicholls
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (535 download)
Download or read book Further Studies on the Chemistry of Polynuclear Transition Metal Carbonyl Complexes written by J. N. Nicholls and published by . This book was released on 1982 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
