Charge Transfer Reactions in Electrochemical and Chemical Processes

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 1468487183
Total Pages : 339 pages
Book Rating : 4.4/5 (684 download)

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Book Synopsis Charge Transfer Reactions in Electrochemical and Chemical Processes by : L.I. Krishtalik

Download or read book Charge Transfer Reactions in Electrochemical and Chemical Processes written by L.I. Krishtalik and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 339 pages. Available in PDF, EPUB and Kindle. Book excerpt: The mechanism of an elementary act is undoubtedly one of the most fundamental problems of chemical and, in particular, electro chemical kinetics. Although this problem has fascinated scientists for quite a long time, it was only in the late fifties and early sixties that it began to be actively investigated for charge transfer reactions. Owing to the development of new methods in the analysis of this problem, significant advancements were made in theoretical as well as experimental studies. These investigations showed that the physical mechanism of charge transfer in all processes including heterogeneous electrochemical and homogeneous chemical and bio chemical processes is basically the same. Hence, the results ob tained in the field of electrochemical kinetics are relevant to the understanding of homogeneous chemical reactions as well. This book endeavors to summarize the results of investigations carried out during the last two decades. It is based on the author's monograph "Electrode Reactions: The Mechanism of an Elementary Act" (Nauka, 1979). As compared to the first version, the book has been considerably revised and enlarged not only to include a large body of data published between 1978 and 1982, but also to analyze in detail the links between electrochemical and homogeneous, in particular enzymatic, kinetics. As a result, a new chapter has been added to the book. The change in the title reflects the fact that the material contained in the book is not restricted to an investigation of purely electrochemical problems.

Handbook of Electrochemistry

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Publisher : Elsevier
ISBN 13 : 0444519580
Total Pages : 935 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis Handbook of Electrochemistry by : Cynthia G. Zoski

Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)

Electron Transfer Reactions

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Author :
Publisher : Butterworth-Heinemann
ISBN 13 :
Total Pages : 376 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Electron Transfer Reactions by : Roderick David Cannon

Download or read book Electron Transfer Reactions written by Roderick David Cannon and published by Butterworth-Heinemann. This book was released on 1980 with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Atomic-Scale Modelling of Electrochemical Systems

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Publisher : John Wiley & Sons
ISBN 13 : 1119605636
Total Pages : 372 pages
Book Rating : 4.1/5 (196 download)

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Book Synopsis Atomic-Scale Modelling of Electrochemical Systems by : Marko M. Melander

Download or read book Atomic-Scale Modelling of Electrochemical Systems written by Marko M. Melander and published by John Wiley & Sons. This book was released on 2021-09-09 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt: Atomic-Scale Modelling of Electrochemical Systems A comprehensive overview of atomistic computational electrochemistry, discussing methods, implementation, and state-of-the-art applications in the field The first book to review state-of-the-art computational and theoretical methods for modelling, understanding, and predicting the properties of electrochemical interfaces. This book presents a detailed description of the current methods, their background, limitations, and use for addressing the electrochemical interface and reactions. It also highlights several applications in electrocatalysis and electrochemistry. Atomic-Scale Modelling of Electrochemical Systems discusses different ways of including the electrode potential in the computational setup and fixed potential calculations within the framework of grand canonical density functional theory. It examines classical and quantum mechanical models for the solid-liquid interface and formation of an electrochemical double-layer using molecular dynamics and/or continuum descriptions. A thermodynamic description of the interface and reactions taking place at the interface as a function of the electrode potential is provided, as are novel ways to describe rates of heterogeneous electron transfer, proton-coupled electron transfer, and other electrocatalytic reactions. The book also covers multiscale modelling, where atomic level information is used for predicting experimental observables to enable direct comparison with experiments, to rationalize experimental results, and to predict the following electrochemical performance. Uniquely explains how to understand, predict, and optimize the properties and reactivity of electrochemical interfaces starting from the atomic scale Uses an engaging “tutorial style” presentation, highlighting a solid physicochemical background, computational implementation, and applications for different methods, including merits and limitations Bridges the gap between experimental electrochemistry and computational atomistic modelling Written by a team of experts within the field of computational electrochemistry and the wider computational condensed matter community, this book serves as an introduction to the subject for readers entering the field of atom-level electrochemical modeling, while also serving as an invaluable reference for advanced practitioners already working in the field.

Charge Transfer in Physics, Chemistry and Biology

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Publisher : CRC Press
ISBN 13 : 100010270X
Total Pages : 637 pages
Book Rating : 4.0/5 (1 download)

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Book Synopsis Charge Transfer in Physics, Chemistry and Biology by : A.M. Kuznetrsov

Download or read book Charge Transfer in Physics, Chemistry and Biology written by A.M. Kuznetrsov and published by CRC Press. This book was released on 2020-09-23 with total page 637 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers the various processes of charge transfer in physics, chemistry and biology and shows the similarities and differences between them. It focuses on the physical mechanisms of the elementary processes to demonstrate their common physical nature.

Electron And Ion Transfer In Condensed Media: Theoretical Physics For Reaction Kinetics

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Author :
Publisher : World Scientific
ISBN 13 : 9814546666
Total Pages : 426 pages
Book Rating : 4.8/5 (145 download)

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Book Synopsis Electron And Ion Transfer In Condensed Media: Theoretical Physics For Reaction Kinetics by : Alexei A Kornyshev

Download or read book Electron And Ion Transfer In Condensed Media: Theoretical Physics For Reaction Kinetics written by Alexei A Kornyshev and published by World Scientific. This book was released on 1997-07-15 with total page 426 pages. Available in PDF, EPUB and Kindle. Book excerpt: An elementary act of charge transfer determines a variety of phenomena in physics, chemistry and biology. The study of charge transfer processes has developed together with general progress in theoretical physics and in fast high resolution spectroscopy, so that research deals now with a broad class of systems, materials and environmental conditions. The specific topics covered are: (1) the environment and reactant-environment interaction at bulk and interfaces; (2) the elementary act of electron and proton transfer; homogeneous and heterogeneous processes; (3) processes of ion and heavy group transfer; ion transport in complex systems; (4) artificially and naturally organized charge transfer in physics, chemistry and biology, technological applications (molecular electronics, sensors, modified electrodes, membrane transport).

Rotating Electrode Methods and Oxygen Reduction Electrocatalysts

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Publisher : Elsevier
ISBN 13 : 0444633286
Total Pages : 323 pages
Book Rating : 4.4/5 (446 download)

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Book Synopsis Rotating Electrode Methods and Oxygen Reduction Electrocatalysts by : Wei Xing

Download or read book Rotating Electrode Methods and Oxygen Reduction Electrocatalysts written by Wei Xing and published by Elsevier. This book was released on 2014-03-26 with total page 323 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rotating Electrode Methods and Oxygen Reduction Electrocatalysts provides the latest information and methodologies of rotating disk electrode and rotating ring-disk electrode (RDE/RRDE) and oxygen reduction reaction (ORR). It is an ideal reference for undergraduate and graduate students, scientists, and engineers who work in the areas of energy, electrochemistry science and technology, fuel cells, and other electrochemical systems. - Presents a comprehensive description, from fundamentals to applications, of catalyzed oxygen reduction reaction and its mechanisms - Portrays a complete description of the RDE (Rotating Disc Electrode)/RRDE (Rotating Ring-Disc Electrode) techniques and their use in evaluating ORR (Oxygen Reduction Reaction) catalysts - Provides working examples along with figures, tables, photos and a comprehensive list of references to help understanding of the principles involved

Catenanes, Rotaxanes, and Knots

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Publisher : Elsevier
ISBN 13 : 1483275663
Total Pages : 205 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Catenanes, Rotaxanes, and Knots by : Gottfried Schill

Download or read book Catenanes, Rotaxanes, and Knots written by Gottfried Schill and published by Elsevier. This book was released on 2013-10-22 with total page 205 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organic Chemistry, Volume 22: Catenanes, Rotaxanes, and Knots provides information pertinent to the synthesis of catenanes and rotaxanes. This book discusses the manner of interaction between the molecular subunits in catenanes in the solid, liquid, and gaseous states. Organized into 19 chapters, this volume begins with an overview of the idea of synthesizing molecules composed of separate entities that are mechanically connected to one another. This text then examines the stereochemistry and the other physical and chemical properties related to the mechanical connections in these compounds. Other chapters consider the determination of the absolute configuration of catenanes by extension of the Cahn–Ingold–Prelog rules. This book discusses as well the bond that mechanically connects the catenated rings. The final chapter deals with the model studies of the synthesis of knots, double wound rotaxanes, and higher linear catenanes. This book is a valuable resource for chemists, students, and research workers.

Pulse Voltammetry in Physical Electrochemistry and Electroanalysis

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Publisher : Springer
ISBN 13 : 3319212516
Total Pages : 678 pages
Book Rating : 4.3/5 (192 download)

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Book Synopsis Pulse Voltammetry in Physical Electrochemistry and Electroanalysis by : Ángela Molina

Download or read book Pulse Voltammetry in Physical Electrochemistry and Electroanalysis written by Ángela Molina and published by Springer. This book was released on 2015-11-14 with total page 678 pages. Available in PDF, EPUB and Kindle. Book excerpt: For the first time, the authors provide a comprehensive and consistent presentation of all techniques available in this field. They rigorously analyze the behavior of different electrochemical single and multipotential step techniques for electrodes of different geometries and sizes under transient and stationary conditions. The effects of these electrode features in studies of various electrochemical systems (solution systems, electroactive monolayers, and liquid-liquid interfaces) are discussed. Explicit analytical expressions for the current-potential responses are given for all available cases. Applications of each technique are outlined for the elucidation of reaction mechanisms. Coverage is comprehensive: normal pulse voltammetry, double differential pulse voltammetry, reverse pulse voltammetry and other triple and multipulse techniques, such as staircase voltammetry, differential staircase voltammetry, differential staircase voltcoulommetry, cyclic voltammetry, square wave voltammetry and square wave voltcoulommetry.

Cytochrome Complexes: Evolution, Structures, Energy Transduction, and Signaling

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Publisher : Springer
ISBN 13 : 9401774811
Total Pages : 763 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Cytochrome Complexes: Evolution, Structures, Energy Transduction, and Signaling by : William A. Cramer

Download or read book Cytochrome Complexes: Evolution, Structures, Energy Transduction, and Signaling written by William A. Cramer and published by Springer. This book was released on 2016-06-14 with total page 763 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction that describes the origin of cytochrome notation also connects to the history of the field, focusing on research in England in the pre-World War II era. The start of the modern era of studies on structure-function of cytochromes and energy-transducing membrane proteins was marked by the 1988 Nobel Prize in Chemistry, given to J. Deisenhofer, H. Michel, and R. Huber for determination of the crystal structure of the bacterial photosynthetic reaction center. An ab initio logic of presentation in the book discusses the evolution of cytochromes and hemes, followed by theoretical perspectives on electron transfer in proteins and specifically in cytochromes. There is an extensive description of the molecular structures of cytochromes and cytochrome complexes from eukaryotic and prokaryotic sources, bacterial, plant and animal. The presentation of atomic structure information has a major role in these discussions, and makes an important contribution to the broad field of membrane protein structure-function.

Charge Transfer in Chemical Reaction Kinetics

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Publisher : EPFL Press
ISBN 13 : 9782880743208
Total Pages : 120 pages
Book Rating : 4.7/5 (432 download)

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Book Synopsis Charge Transfer in Chemical Reaction Kinetics by : A. M. Kuznet͡sov (dokt. fiz.-mat. nauk.)

Download or read book Charge Transfer in Chemical Reaction Kinetics written by A. M. Kuznet͡sov (dokt. fiz.-mat. nauk.) and published by EPFL Press. This book was released on 1997-01-01 with total page 120 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Encyclopedia of Electrochemical Power Sources

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Publisher : Elsevier
ISBN 13 : 0323958222
Total Pages : 5674 pages
Book Rating : 4.3/5 (239 download)

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Book Synopsis Encyclopedia of Electrochemical Power Sources by :

Download or read book Encyclopedia of Electrochemical Power Sources written by and published by Elsevier. This book was released on 2024-09-16 with total page 5674 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Encyclopedia of Electrochemical Power Sources, Second Edition, is a comprehensive seven-volume set that serves as a vital interdisciplinary reference for those working with batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. With an increased focus on the environmental and economic impacts of electrochemical power sources, this work not only consolidates extensive coverage of the field but also serves as a gateway to the latest literature for professionals and students alike. The field of electrochemical power sources has experienced significant growth and development since the first edition was published in 2009. This is reflected in the exponential growth of the battery market, the improvement of many conventional systems, and the introduction of new systems and technologies. This completely revised second edition captures these advancements, providing updates on all scientific, technical, and economic developments over the past decade. Thematically arranged, this edition delves into crucial areas such as batteries, fuel cells, electrolyzers, supercapacitors, and photo-electrochemical cells. It explores challenges and advancements in electrode and electrolyte materials, structural design, optimization, application of novel materials, and performance analysis. This comprehensive resource, with its focus on the future of electrochemical power sources, is an essential tool for navigating this rapidly evolving field. - Covers the main types of power sources, including their operating principles, systems, materials, and applications - Serves as a primary source of information for electrochemists, materials scientists, energy technologists, and engineers - Incorporates 365 articles, with timely coverage of environmental and sustainability aspects - Arranged thematically to facilitate easy navigation of topics and easy exploration of the field across its key branches - Follows a consistent structure and features elements such as key objective boxes, summaries, figures, references, and cross-references etc., to help students, faculty, and professionals alike

Oxygenic Photosynthesis: The Light Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 0306481278
Total Pages : 681 pages
Book Rating : 4.3/5 (64 download)

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Book Synopsis Oxygenic Photosynthesis: The Light Reactions by : Donald R. Ort

Download or read book Oxygenic Photosynthesis: The Light Reactions written by Donald R. Ort and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 681 pages. Available in PDF, EPUB and Kindle. Book excerpt: Structure and function of the components of the photosynthetic apparatus and the molecular biology of these components have become the dominant themes in advances in our understanding of the light reactions of oxygenic photosynthesis. Oxygenic Photosynthesis: The Light Reactions presents our current understanding of these reactions in thylakoid membranes. Topics covered include the photosystems, the cytochrome b6-f complex, plastocyanin, ferredoxin, FNR, light-harvesting complexes, and the coupling factor. Chapters are also devoted to the structure of thylakoid membranes, their lipid composition, and their biogenesis. Updates on the crystal structures of cytochrome f, ATP synthase and photosystem I are presented and a section on molecular biology and evolution of the photosynthetic apparatus is also included. The chapters in this book provide a comprehensive overview of photosynthetic reactions in eukaryotic thylakoids. The book is intended for a wide audience, including graduate students and researchers active in this field, as well as those individuals who have interests in plant biochemistry and molecular biology or plant physiology.

Corrosion Mechanisms in Theory and Practice, Third Edition

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Publisher : CRC Press
ISBN 13 : 1420094629
Total Pages : 944 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Corrosion Mechanisms in Theory and Practice, Third Edition by : Philippe Marcus

Download or read book Corrosion Mechanisms in Theory and Practice, Third Edition written by Philippe Marcus and published by CRC Press. This book was released on 2011-08-18 with total page 944 pages. Available in PDF, EPUB and Kindle. Book excerpt: Updated to include recent results from intensive worldwide research efforts in materials science, surface science, and corrosion science, Corrosion Mechanisms in Theory and Practice, Third Edition explores the latest advances in corrosion and protection mechanisms. It presents a detailed account of the chemical and electrochemical surface reactions that govern corrosion as well as the link between microscopic forces and macroscopic behavior. Revised and expanded, this edition includes four new chapters on corrosion fundamentals, the passivity of metals, high temperature corrosion, and the corrosion of aluminum alloys. The first half of the book covers basic aspects of corrosion, such as entry of hydrogen into metals, anodic dissolution, localized corrosion, stress corrosion cracking, and corrosion fatigue. Connecting the theoretical aspects of corrosion mechanisms to practical applications in industry, the second half of the text discusses corrosion inhibition, atmospheric corrosion, microbially induced corrosion, corrosion in nuclear systems, corrosion of microelectronic and magnetic data-storage devices, and organic coatings. With contributions from leading academic and industrial researchers, this bestselling book continues to provide a thorough understanding of corrosion mechanisms—helping you solve existing corrosion challenges and prevent future problems.

Progress in Reaction Kinetics

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Publisher : Elsevier
ISBN 13 : 1483224953
Total Pages : 532 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Progress in Reaction Kinetics by : G. Porter

Download or read book Progress in Reaction Kinetics written by G. Porter and published by Elsevier. This book was released on 2013-09-03 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in Reaction Kinetics, Volume 4 is a 10-chapter text that focuses on the reactions of nitrogen atoms in the gas phase and some chemical factors in the kinetics of processes at electrodes. This volume describes first the free radical reactions dealing with halogenomethyl and alkoxyl radicals. The next chapters deal with electronically excited states, proton transfer, and kinetics of electrode processes. These topics are followed by discussions on the primary processes in the gas phase photochemistry of carbonyl compounds, as well as the mechanisms and rates of radiationless energy transfer. This book also looks into the methods used for the measurement of fluorescence lifetimes of aromatic compounds. A chapter examines the chemiluminescence in the oxidation of organic compounds and for other liquid-phase reactions. The last chapters discuss the role of the solvent in proton transfer reactions and some aspects of developments in the field of electrode processes. This book is of great value to reaction kinetics scientists and researchers.

Handbook of Materials Modeling

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Publisher : Springer Science & Business Media
ISBN 13 : 1402032862
Total Pages : 2903 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Handbook of Materials Modeling by : Sidney Yip

Download or read book Handbook of Materials Modeling written by Sidney Yip and published by Springer Science & Business Media. This book was released on 2007-11-17 with total page 2903 pages. Available in PDF, EPUB and Kindle. Book excerpt: The first reference of its kind in the rapidly emerging field of computational approachs to materials research, this is a compendium of perspective-providing and topical articles written to inform students and non-specialists of the current status and capabilities of modelling and simulation. From the standpoint of methodology, the development follows a multiscale approach with emphasis on electronic-structure, atomistic, and mesoscale methods, as well as mathematical analysis and rate processes. Basic models are treated across traditional disciplines, not only in the discussion of methods but also in chapters on crystal defects, microstructure, fluids, polymers and soft matter. Written by authors who are actively participating in the current development, this collection of 150 articles has the breadth and depth to be a major contributor toward defining the field of computational materials. In addition, there are 40 commentaries by highly respected researchers, presenting various views that should interest the future generations of the community. Subject Editors: Martin Bazant, MIT; Bruce Boghosian, Tufts University; Richard Catlow, Royal Institution; Long-Qing Chen, Pennsylvania State University; William Curtin, Brown University; Tomas Diaz de la Rubia, Lawrence Livermore National Laboratory; Nicolas Hadjiconstantinou, MIT; Mark F. Horstemeyer, Mississippi State University; Efthimios Kaxiras, Harvard University; L. Mahadevan, Harvard University; Dimitrios Maroudas, University of Massachusetts; Nicola Marzari, MIT; Horia Metiu, University of California Santa Barbara; Gregory C. Rutledge, MIT; David J. Srolovitz, Princeton University; Bernhardt L. Trout, MIT; Dieter Wolf, Argonne National Laboratory.

Introduction to Voltammetric Analysis

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Publisher : CSIRO PUBLISHING
ISBN 13 : 0643102647
Total Pages : 268 pages
Book Rating : 4.6/5 (431 download)

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Book Synopsis Introduction to Voltammetric Analysis by : Francis G Thomas

Download or read book Introduction to Voltammetric Analysis written by Francis G Thomas and published by CSIRO PUBLISHING. This book was released on 2001-04-15 with total page 268 pages. Available in PDF, EPUB and Kindle. Book excerpt: Voltammetric methods are among the most sensitive and versatile available to the analytical chemist. They can identify and quantify substances from simple metal ions, through to complex organic molecules. The concentration range spans 9 orders of magnitude and, in many cases, trace level analyses of surface waters and body fluids can be performed with little or no pre-treatment of the sample is required. In this text the basic concepts and principles are presented in an easy-to-read manner. Practical aspects are discussed and an overview of the electrochemistry of the elements and of organic functional groups is interspersed with 27 tested applications described in detail. The techniques covered expand its application out into other disciplines apart from chemistry, such as botany, zoology and soil science.