Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101/102 Composite for Testing in Bench Scale Steam Reformer

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Book Synopsis Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101/102 Composite for Testing in Bench Scale Steam Reformer by :

Download or read book Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101/102 Composite for Testing in Bench Scale Steam Reformer written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-10-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FB SR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-S.2.1-20 1 0-00 1, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, 'Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.'

Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 Composite for Testing in Bench Scale Steam Reformer

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Book Synopsis Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 Composite for Testing in Bench Scale Steam Reformer by :

Download or read book Cesium Removal from Tanks 241-AN-103 & 241-SX-105 & 241-AZ-101 & 241AZ-102 Composite for Testing in Bench Scale Steam Reformer written by and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This report documents the preparation of three actual Hanford tank waste samples for shipment to the Savannah River National Laboratory (SRNL). Two of the samples were dissolved saltcakes from tank 241-AN-103 (hereafter AN-103) and tank 241-SX-105 (hereafter SX-105); one sample was a supernate composite from tanks 241-AZ-101 and 241-AZ-102 (hereafter AZ-101/102). The preparation of the samples was executed following the test plans LAB-PLAN-10-00006, Test Plan for the Preparation of Samples from Hanford Tanks 241-SX-105, 241-AN-103, 241-AN-107, and LAB-PLN-l0-00014, Test Plan for the Preparation of a Composite Sample from Hanford Tanks 241-AZ-101 and 241-AZ-102 for Steam Reformer Testing at the Savannah River National Laboratory. All procedural steps were recorded in laboratory notebook HNF-N-274 3. Sample breakdown diagrams for AN-103 and SX-105 are presented in Appendix A. The tank samples were prepared in support of a series of treatability studies of the Fluidized Bed Steam Reforming (FBSR) process using a Bench-Scale Reformer (BSR) at SRNL. Tests with simulants have shown that the FBSR mineralized waste form is comparable to low-activity waste glass with respect to environmental durability (WSRC-STI-2008-00268, Mineralization of Radioactive Wastes by Fluidized Bed Steam Reforming (FBSR): Comparisons to Vitreous Waste Forms and Pertinent Durability Testing). However, a rigorous assessment requires long-term performance data from FBSR product formed from actual Hanford tank waste. Washington River Protection Solutions, LLC (WRPS) has initiated a Waste Form Qualification Program (WP-5.2.1-2010-001, Fluidized Bed Steam Reformer Low-level Waste Form Qualification) to gather the data required to demonstrate that an adequate FBSR mineralized waste form can be produced. The documentation of the selection process of the three tank samples has been separately reported in RPP-48824, Sample Selection Process for Bench-Scale Steam Reforming Treatability Studies Using Hanford Waste Samples.

Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102

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Total Pages : 5 pages
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Book Synopsis Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102 by :

Download or read book Intermediate-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102 written by and published by . This book was released on 2001 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ion exchange tests have been completed at the Savannah River Technology Center for British Nuclear Fuels Limited, Inc. as part of the Hanford River Protection Project. Radioactive cesium and technetium (pertechnetate form only) were removed by ion exchange from a sample of Envelope C salt solution from Hanford Tank 241-AN-102 (sample volume: approximately 17 L at 4.8 M Na plus). The original sample was diluted and subjected to strontium/transuranics (Sr/TRU) precipitation and filtration processes before ion exchange processing was performed. Batch contact and column tests for the ion exchange removal of cesium and technetium were then completed on the Sr/TRU-decontaminated product. Previous ion exchange tests were conducted on a smaller portion (0.5 L) of the Tank 241-AN-102 supernate sample, which had been similarly pretreated, and the results were reported in a separate document.

Ion Exchange Removal of Cesium from Simulated and Actual Supernate from Hanford Tanks 241-SY-101 and 241-SY-103

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Book Synopsis Ion Exchange Removal of Cesium from Simulated and Actual Supernate from Hanford Tanks 241-SY-101 and 241-SY-103 by : Garrett N. Brown

Download or read book Ion Exchange Removal of Cesium from Simulated and Actual Supernate from Hanford Tanks 241-SY-101 and 241-SY-103 written by Garrett N. Brown and published by . This book was released on 1995 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

אגרות י"שור

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Book Synopsis אגרות י"שור by :

Download or read book אגרות י"שור written by and published by . This book was released on 1899 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103

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Total Pages : 5 pages
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Book Synopsis Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103 by :

Download or read book Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-103 written by and published by . This book was released on 2000 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low activity and high level waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The ion exchange removal of cesium (Cs) and technetium (Tc) ions is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as pertechnetate), from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Technology Center demonstrated the conceptualized flow sheet parameters with a similar Hanford tank sample (241-AW-101). Those experiments included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Hanford Tank Waste Supernatant Cesium Removal Test Plan

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ISBN 13 :
Total Pages : 57 pages
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Book Synopsis Hanford Tank Waste Supernatant Cesium Removal Test Plan by :

Download or read book Hanford Tank Waste Supernatant Cesium Removal Test Plan written by and published by . This book was released on 1996 with total page 57 pages. Available in PDF, EPUB and Kindle. Book excerpt: This document provides the test plan for the preparation and conduct of a cesium removal test using Hanford DSSF supernatant liquor from tank 241-AW-101 in a bench-scale column. Cesium sorbents to be tested include resorcinol-formaldehyde resin and crystalline silicotitanate.

Evaluating Residence Time for Cesium Removal from Simulated Hanford Tank Wastes Using SuperLig(R) 644 Resin

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Total Pages : 5 pages
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Book Synopsis Evaluating Residence Time for Cesium Removal from Simulated Hanford Tank Wastes Using SuperLig(R) 644 Resin by :

Download or read book Evaluating Residence Time for Cesium Removal from Simulated Hanford Tank Wastes Using SuperLig(R) 644 Resin written by and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Batch contact and column experiments were performed to evaluate the effect of residence time on cesium (Cs) removal from two simulated Hanford tank wastes using SuperLig(R) 644 resin. The two waste simulants mimic the compositions of tanks 241-AZ-102 and 241-AN-107 at the U.S. Department of Energy (DOE) Hanford site. A single column made of glass tube (2.7-cm i.d.), which contained approximately 100 mL of H-form SuperLig(R) 644 resin was used in the column experiments. The experiments each consisted of loading, elution, and regeneration steps were performed at flow rates ranging from 0.64 to 8.2 BV/h for AZ-102 and from 1.5 to 18 BV/h for AN-107 simulant. The lowest flow rates of 0.64 and 1.5 BV/h were selected to evaluate less than optimal flow conditions in the plant. The range of the flow rates is consistent with the River Protection Project design for the waste treatment plant (WTP) columns, which will operate at a flow rate between 1.5 to 3 BV/h. Batch contact experiments were also performed for two batches of SuperLig(R) 644 to determine the equilibrium distribution coefficients (Kds) as a function of Cs concentration.

Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102

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ISBN 13 :
Total Pages : 5 pages
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Book Synopsis Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102 by :

Download or read book Small-Scale Ion Exchange Removal of Cesium and Technetium from Hanford Tank 241-AN-102 written by and published by . This book was released on 2000 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The pretreatment process for BNFL, Inc.'s Hanford River Protection Project is to provide decontaminated low activity waste and concentrated eluate streams for vitrification into low and high activity waste glass, respectively. The pretreatment includes sludge washing, filtration, precipitation, and ion exchange processes to remove entrained solids, cesium, transuranics, technetium, and strontium. The cesium (Cs-137) and technetium (Tc-99) ion exchange removal is accomplished by using SuperLig 644, and 639 resins from IBC Advanced Technologies, American Fork, Utah. The resins were shown to selectively remove cesium and technetium (as anionic pertechnetate) from alkaline salt solutions. The efficiency of ion exchange column loading and elution is a complex function involving feed compositions, equilibrium and kinetic behavior of ion exchange resins, diffusion, and the ionic strength and pH of the aqueous solution. A previous experimental program completed at the Savannah River Tech nology Center2 demonstrated the conceptualized flow sheet parameters with an Envelope C sample from Hanford Tank 241-AN-107. Those experiments also included determination of Cs and Tc batch distribution coefficients by SuperLig 644 and 639 resins and demonstration of small-scale column breakthrough and elution. The experimental findings were used in support of preliminary design bases and pretreatment flow sheet development by BNFL, Inc.

Cesium Ion Exchange Using Tank 241-AN-104 Supernate

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Total Pages : 5 pages
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Book Synopsis Cesium Ion Exchange Using Tank 241-AN-104 Supernate by : K. Adu-Wusu

Download or read book Cesium Ion Exchange Using Tank 241-AN-104 Supernate written by K. Adu-Wusu and published by . This book was released on 2003 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: The River Protection Project is to design and build a high level nuclear waste treatment facility. The waste treatment plant is to process millions of gallons of radioactive waste stored in tanks at the Hanford Site. The high level nuclear waste treatment process includes various unit operations, such as ultrafiltration, precipitation, evaporation, ion exchange, and vitrification. Ion exchange is identified as the optimal treatment method for removal of cesium-137 and Tc-99 from the waste. Extensive ion exchange testing was performed using small-scale columns with actual waste samples. The objectives of this study were to: demonstrate SuperLig 644 ion exchange performance and process steps for the removal of cesium from actual AN-104 tank waste; pretreat actual AN-104 tank waste to reduce the concentration of cesium-137 in the waste below LAW vitrification limit; produce and characterize cesium eluate solutions for use in eluate evaporation tests. The experiments consisted of batch contact and small-scale column tests. The batch contact tests measured sorption partition coefficients Kds. The Kds were used to predict the effective resin capacity. The small-scale column tests, which closely mimic plant conditions, generated loading and elution profile data used to determine whether removal targets and design requirements were met.

Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241-AW-101 DSSF Tank Waste

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Book Synopsis Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241-AW-101 DSSF Tank Waste by :

Download or read book Comparison of Organic and Inorganic Ion Exchangers for Removal of Cesium and Strontium from Simulated and Actual Hanford 241-AW-101 DSSF Tank Waste written by and published by . This book was released on 2001 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: A number of organic and inorganic exchangers are being developed and evaluated for cesium removal from Hanford tank wastes. The exchangers of interest that are investigated in this work include powdered (IONSIV[reg-sign] IE-910; referred to as IE-910) and engineered (IONSIV[reg-sign] IE-911; referred to as IE-911) forms of the crystalline silico-titanate (CST) inorganic sorbent developed by Sandia National Laboratories (SNL)/Texas A and M and prepared by UOP; a phenol-formaldehyde (CS-100) resin developed by Rohm and Haas; a resorcinol-formaldehyde (R-F) polymer developed at the Westinghouse Savannah River Company (WSRC) and produced by Boulder Scientific; an inorganic zeolite exchanger produced by UOP (IONSIV[reg-sign] TIE-96; referred to as TIE-96); an inorganic sodium titanate produced by Allied Signal/Texas A and M (NaTi); and a macrocyclic organic resin developed and produced by IBC Advanced Technologies (SuperLig[reg-sign] 644; referred to as SL-644). Several of these materials are still under development and may not be in the optimal form. The work described in this report involves the direct comparison of the ion exchange materials for the pretreatment of actual and simulated Hanford tank waste. Data on the performance of all of the exchangers with simulated and actual double shell slurry feed (DSSF) is included. The DSSF waste is a mixture of the supernate from tanks 101-AW (70%), 106-AP (20%) and 102-AP (10%). The comparative parameters include radionuclide removal efficiency under a variety of conditions and material properties (e.g., bed density and percent removable water). Cesium and strontium distribution (K[sub d]), lambda ([lambda]= K[sub d][times][rho][sub b]), and decontamination factors (DF) are compared as a function of exchanger contact duration, solution composition (Na and Cs concentration), exchanger/waste phase ratio, and multiple sequential contacts.

Removal of Technetium from Hanford Tank 241-AP-101

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Book Synopsis Removal of Technetium from Hanford Tank 241-AP-101 by : Ingrid E. Burgeson

Download or read book Removal of Technetium from Hanford Tank 241-AP-101 written by Ingrid E. Burgeson and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

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ISBN 13 :
Total Pages : 266 pages
Book Rating : 4.:/5 (163 download)

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Download or read book Contro la soluzione politica written by and published by . This book was released on 1999 with total page 266 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Test Procedures and Instructions for Hanford Complexant Concentrate Supernatant Cesium Removal Using CST.

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Total Pages : 99 pages
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Book Synopsis Test Procedures and Instructions for Hanford Complexant Concentrate Supernatant Cesium Removal Using CST. by :

Download or read book Test Procedures and Instructions for Hanford Complexant Concentrate Supernatant Cesium Removal Using CST. written by and published by . This book was released on 1997 with total page 99 pages. Available in PDF, EPUB and Kindle. Book excerpt: This document provides specific test procedures and instructions to implement the test plan for the preparation and conduct of a cesium removal test, using Hanford Complexant Concentrate supernatant liquor from tank 241-AN-107, in a bench-scale column. The cesium sorbent to be tested is crystalline silicotitanate. The test plan for which this provides instructions is WHC-SD-RE-TP-023, Hanford Complexant Concentrate Supernatant Cesium Removal Test Plan.

Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank Waste 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions

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Book Synopsis Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank Waste 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions by : Ingrid E. Burgeson

Download or read book Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank Waste 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions written by Ingrid E. Burgeson and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Effect of Temperature of SuperLig (R) 644 Cesium Removal from Simulated Hanford Tank Waste Supernate

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Total Pages : 5 pages
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Book Synopsis The Effect of Temperature of SuperLig (R) 644 Cesium Removal from Simulated Hanford Tank Waste Supernate by :

Download or read book The Effect of Temperature of SuperLig (R) 644 Cesium Removal from Simulated Hanford Tank Waste Supernate written by and published by . This book was released on 2002 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Batch kinetic and column experiments have been carried out at 25, 35, and 45 Degrees C to examine the effect of temperature on SuperLig(R) 644 cesium (Cs) removal from simulated Hanford tank waste supernate. The simulated solution mimicked the composition of the low-activity waste supernate from tank 241-AN-105 in the U.S. DOE Hanford site. Small quantities of toxic metals, such as Cd, Cr, Fe, and Pb were spiked into the simulant to evaluate the metal's competitiveness with Cs for sorption on SuperLig(R) 644 resin. The results indicated that the temperature affects the removal of Cs and metal ions, although the effect was not the same for all metal ions. The extent of Cs removal decreased with an increase in temperature. The Cs capacity at breakthrough point was 0.015, 0.013, and 0.011-mmole/g dry resin at 25, 35 and 45 Degrees C, respectively. The column was effectively eluted to less than 1 Percent (0.1 C/Co) of the feed concentration with approximately 10 BVs of 0.5 M nitric acid. The resin showed limited affinity for toxic metal ions (Cr, Cd, Fe, and Pb) as compared to Cs. Based on the batch kinetic data, the Cs uptake of the resin was not hampered by the presence of the toxic metals in solution.

Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions

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Book Synopsis Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions by :

Download or read book Small Column Testing of SuperLig 639 for Removing 99Tc from Hanford Tank 241-AN-102 Supernate (Envelope C) Mixed with Tank 241-C-104 Solids (Envelope D) Wash and Permeate Solutions written by and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: