Carbonyl Compounds Chemistry And Synthetic Applications

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Carbonyl Compounds - Chemistry and Synthetic Applications

Author : Kuriya Madavu Lokanatha Rai
Publisher : Notion Press
ISBN 13 : 9781647608552
Total Pages : 254 pages
Book Rating : 4.6/5 (85 download)

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Book Synopsis Carbonyl Compounds - Chemistry and Synthetic Applications by : Kuriya Madavu Lokanatha Rai

Download or read book Carbonyl Compounds - Chemistry and Synthetic Applications written by Kuriya Madavu Lokanatha Rai and published by Notion Press. This book was released on 2020-01-28 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, Carbonyl Compounds - Chemistry and Synthetic Applications, is meant for M. Sc., Chemistry, M. Sc, Organic Chemistry as well as B. Sc., graduates. The chemistry of the carbonyl compound is virtually the backbone of synthetic organic chemistry. Carbonyl compounds serve as the starting material for the synthesis of various naturally occurring molecules viz., cholesterol, caryophyllene, santonin, reserpine, etc. In the present book, I am concentrating more on mechanistic aspects of the reactions involving carbonyl compounds, which are not discussed in detail in other textbooks. This book provides insight in many areas of carbonyl compounds which includes nomenclature, identification, preparation, structure, reactions, estimations and their synthetic applications.

Carbonyl Compounds

Author : Feng Shi
Publisher : John Wiley & Sons
ISBN 13 : 3527347364
Total Pages : 38 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Carbonyl Compounds by : Feng Shi

Download or read book Carbonyl Compounds written by Feng Shi and published by John Wiley & Sons. This book was released on 2021-11-08 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbonyl Compounds Discover how carbonyl compounds bridge reactants, catalysts, and specific products Carbonyl-containing molecules represent some of the most versatile functionalities in organic chemistry, with applications in a wide variety of areas. In Carbonyl Compounds: Reactants, Catalysts and Products, accomplished chemists and authors Feng Shi, Hongli Wang, and Xingchao Dai deliver a comprehensive treatment of these multi-functional compounds. You’ll discover how to build carbonyl molecules with traditional and non-traditional methods, how to transform carbonyl-containing molecules into fine chemicals, and how to use carbonyl-containing molecules as catalytic materials for the synthesis of fine chemicals. The book is a comprehensive and systematic treatment of carbonyl compounds as reactants, catalysts, and products. From the use of carbon monoxide in the hydroformylation of alkenes and alkynes to the reactions via carbonyl and hydroxyl groups recycling, you’ll find everything you need to know about these versatile compounds. Readers will also benefit from the inclusion of: A thorough introduction to carbonyl molecules as reactants, including treatments of carbon monoxide, carbon dioxide, HCHO, HCOOH, and CO surrogates An exploration of carbonyl compounds as catalysts, including acid catalyzed reactions with -CO2H and reactions via carbonyl and hydroxyl groups recycling A practical discussion of the synthetic applications of carbonyl compounds, including the synthesis of functional molecules and the synthesis of functional materials A concise treatment of future perspectives and potential research trends for carbonyl molecules Perfect for organic, catalytic, pharmaceutical, and physical chemists, Carbonyl Compounds will also earn a place in the libraries of chemical engineers and materials scientists seeking a one-stop reference for up-to-date information about the building, transformation, and applications of carbonyl-containing molecules.

Organic Reactions, Volume 73

Author : Dennis G. Hall
Publisher : John Wiley & Sons
ISBN 13 : 1118344456
Total Pages : 6 pages
Book Rating : 4.1/5 (183 download)

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Book Synopsis Organic Reactions, Volume 73 by : Dennis G. Hall

Download or read book Organic Reactions, Volume 73 written by Dennis G. Hall and published by John Wiley & Sons. This book was released on 2012-05-29 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: Allylic boron compounds have gained a prominent position as a truly practical class of synthetic reagents in the past twenty-five years. Their main application as a method for the stereoselective synthesis of homoallylic alcohols by allyl-transfer to carbonyl compounds is essentially unmatched. In this process, a new carbon-carbon bond is formed, and up to two new stereogenic centers are created in a predictably controlled manner. Highly effective and general enantioselective variants are available, with countless applications in the total syntheses of polyacetate and polypropionate natural products. Furthermore, the residual allylic unit can be manipulated through a number of different transformations such as oxidative cleavage, olefin metathesis, hydrometalations, and many others. The discovery of Lewis and Brønsted acid catalyzed manifolds recently, has opened new doors for further development of this important reaction. This book provides an up-to-date, comprehensive survey of the literature of this rich chemistry as it pertains to organic synthesis. Consistent with the goal of Organic Reactions, the content and presentation emphasize the preparative aspects of the reactions, giving considerable attention to the scope and limitations of the individual transformations along with detailed experimental procedures. A tabular survey of all examples of carbonyl allylboration used in organic synthesis is presented in nine tables organized by type of allylic boron reagent with listings within each table according to increasing carbon number of the carbonyl substrates. The literature is covered through December 2010, including a new listing of nearly 200 literature citations that supplement the original coverage of 834 references used in the earlier hard cover version of the chapter. Allylboration of Carbonyl Compounds is intended to be a useful, easily read reference book for all practitioners of synthetic organic chemistry working in academic and industrial laboratories.

Chemistry of the Carbonyl Group

Author : Timothy K. Dickens
Publisher : John Wiley & Sons
ISBN 13 : 1119459532
Total Pages : 183 pages
Book Rating : 4.1/5 (194 download)

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Book Synopsis Chemistry of the Carbonyl Group by : Timothy K. Dickens

Download or read book Chemistry of the Carbonyl Group written by Timothy K. Dickens and published by John Wiley & Sons. This book was released on 2018-04-09 with total page 183 pages. Available in PDF, EPUB and Kindle. Book excerpt: Teaches and enables students to build confidence in drawing and manipulating curly arrows, a fundamental skill for all organic chemists This book is an interactive approach to learning about chemistry of the carbonyl group—inviting students to work through its pages with pencil and paper in hand. It educates with the belief that the most effective way to learn is by practice and interaction. With this in mind, the reader is asked to predict what would happen under a specific set of reaction conditions. The book is divided into frames: each frame poses a question and invites the reader to predict what will happen. Subsequent frames give the solution but then pose more questions to develop a theme further. Chemistry of the Carbonyl Group: A Programmed Approach to Organic Reaction Mechanisms, Revised Edition provides a solid grounding in the fundamental reactions of carbonyls. Presented in full colour to enhance the understanding of mechanisms within chemistry, the chapters of this step-by-step guide cover: nucleophilic addition to the carbonyl group; nucleophilic substitution; nucleophilic substitution at the carbonyl group with complete removal of carbonyl oxygen; carbanions and enolisation; and building organic molecules from carbonyl compounds. A must-have book for undergraduate chemists to emphasise understanding in carbonyl group chemistry Goes through all the stages of basic carbonyl chemistry, detailing even the simplest mechanisms A step-by-step learning guide to synthetic chemistry for the first year of a chemistry degree, with all the information needed for independent learning Provides a solid grounding in the fundamental reactions of carbonyls which will inform the understanding of many other organic chemistry reactions Chemistry of the Carbonyl Group: A Programmed Approach to Organic Reaction Mechanisms - Revised Edition is packed with all the information on synthetic chemistry that every first-year student will need in order to learn independently.

Organic Chemistry

Author : Open University. Organic Chemistry Course Team
Publisher :
ISBN 13 : 9780749280000
Total Pages : 172 pages
Book Rating : 4.2/5 (8 download)

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Book Synopsis Organic Chemistry by : Open University. Organic Chemistry Course Team

Download or read book Organic Chemistry written by Open University. Organic Chemistry Course Team and published by . This book was released on 1996 with total page 172 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Carbonylation

Author : H.M. Colquhoun
Publisher : Springer Science & Business Media
ISBN 13 : 1475795769
Total Pages : 295 pages
Book Rating : 4.4/5 (757 download)

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Book Synopsis Carbonylation by : H.M. Colquhoun

Download or read book Carbonylation written by H.M. Colquhoun and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since the publication of our earlier book on transition metal mediated organic synthesis, * there has been a widespread increase of interest in this topic, and transition metal based methodology has become firmly established in many areas of organic chemistry. The direct, catalytic formation of organic carbonyl compounds using carbon monoxide as the source of the carbonyl group has seen exceptional progress, and this carbonylation chemistry is being used increasingly in research and on a larger scale for fine chemicals production. In view of these developments, there is a need for a modem, practi cally oriented book dealing with transition metal based carbonylation chemistry. The present monograph should help fulfill this need, since it is intended specifically to foster the adoption of catalytic carbonylation as a general tool in synthetic organic chemistry. It deals exclusively with reactions involving the interconversion of carbon monoxide and organic carbonyl compounds, and although the majority of the reactions discussed involve catalytic formation of carbonyl compounds, potentially valuable syntheses requiring stoichiometric quantities of transition metal are also included. In addition, a chapter is devoted to the remarkably useful reverse transformation (decarbonylation), in which an organic carbonyl group is eliminated in the form of carbon monoxide.

Modern Carbonyl Chemistry

Author : Junzo Otera
Publisher : John Wiley & Sons
ISBN 13 : 3527613277
Total Pages : 632 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Carbonyl Chemistry by : Junzo Otera

Download or read book Modern Carbonyl Chemistry written by Junzo Otera and published by John Wiley & Sons. This book was released on 2008-11-21 with total page 632 pages. Available in PDF, EPUB and Kindle. Book excerpt: The carbonyl group is undoubtedly one of the most important functional groups in organic chemistry, both in its role as reactive center for synthesis or derivatisation and as crucial feature for special structural or physiological properties. Vast and profound progress has been made in all aspects modern carbonyl chemistry. These achievements are, however, rather dispersed in the literature and it is often not easy for the researcher obtain a comprehensive overview of a relevant topic. Modern Carbonyl Chemistry overcomes this inconvenience by collating the information for appropriate themes. In this work internationally renowned experts and leaders in the field have surveyed recent aspects and modern features in carbonyl chemistry, such as cascade-reactions, one-pot-syntheses, recognition, or site differentiation.

Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, Volume 59

Author : Albert Padwa
Publisher : John Wiley & Sons
ISBN 13 : 0471461369
Total Pages : 952 pages
Book Rating : 4.4/5 (714 download)

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Book Synopsis Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, Volume 59 by : Albert Padwa

Download or read book Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products, Volume 59 written by Albert Padwa and published by John Wiley & Sons. This book was released on 2003-04-14 with total page 952 pages. Available in PDF, EPUB and Kindle. Book excerpt: Dipolar cycloaddition reactions have found many useful applications in chemistry, particularly with respect to the synthesis of compounds with new chiral centers. Synthetic Applications of 1,3-Dipolar Cycloaddition Chemistry Toward Heterocycles and Natural Products updates the popular 1984 edition, featuring the advances made over the past twenty years and focusing on synthetic applications.

Advances in the Use of Synthons in Organic Chemistry

Author : Alessandro Dondoni
Publisher : Elsevier
ISBN 13 : 1483100944
Total Pages : 240 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Advances in the Use of Synthons in Organic Chemistry by : Alessandro Dondoni

Download or read book Advances in the Use of Synthons in Organic Chemistry written by Alessandro Dondoni and published by Elsevier. This book was released on 2013-10-22 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in the Use of Synthons in Organic Chemistry: A Research Annual, Volume 1 provides information pertinent to a useful reagent that can perform a certain chemical operation that is otherwise impossible or difficult to carry out. This book presents the developments on established synthons. Organized into four chapters, this volume begins with an overview of the significant role of the formyl group in synthetic methodologies, which has stimulated the search for other reagents. This text then describes trimethysilyldiazomethane as a stable and safe substitute for hazardous diazomethane. Other chapters consider the usefulness of trimethysilyldiazomethane in organic syntheses. This book discusses as well that malonic amides, silylenol ethers, malonic esters, and tetra-donor-substituted allenes serve as synthetic equivalents for the dianions of malonic esters, ketones, and malonic amides. The final chapter deals with the synthesis of biologically-active compounds, which has been one of the major challenges for organic chemists. This book is a valuable resource for practicing synthetic chemists.

Piperidine

Author : M. Rubiralta
Publisher : Elsevier
ISBN 13 : 148329093X
Total Pages : 460 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Piperidine by : M. Rubiralta

Download or read book Piperidine written by M. Rubiralta and published by Elsevier. This book was released on 2013-10-22 with total page 460 pages. Available in PDF, EPUB and Kindle. Book excerpt: Piperidine, one of the simplest heterocyclic systems, is found in nature as part of several alkaloid compounds. Both natural and especially unnatural piperidine derivatives present interesting pharmacological properties. From a structural viewpoint, the conformation of piperidine has been the subject of one of the fiercest controversies in structural organic chemistry in the last few years. As a result of the combined use of several spectroscopic techniques, the conformational behavior of most types of piperidine-related compounds has been clarified. Some piperidine derivatives, namely, N-acylpiperidine, &agr;-cyanopiperidines and piperidones are extremely useful and versatile intermediates in organic synthesis. The present book offers an updated and integrated view of all these topics. The aim of the book is twofold. Firstly, to reveal to the reader the combined use of different spectroscopic data, to facilitate an insight into the structure and conformational properties of any new piperidine derivative. Secondly, to establish a consistent link between conformation and reactivity for a variety of piperidine derivatives. Such a bridge is a key step for stereocontrol when dealing with the application of piperidine derivatives as synthetic intermediates. The book is conceived so that most of the information comes from visual inspection of the very abundant graphic material. An exhaustive subject index of more than 450 entries is also included.

Organic Reactions in Water

Author : U. Marcus Lindstrom
Publisher : John Wiley & Sons
ISBN 13 : 047099424X
Total Pages : 424 pages
Book Rating : 4.4/5 (79 download)

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Book Synopsis Organic Reactions in Water by : U. Marcus Lindstrom

Download or read book Organic Reactions in Water written by U. Marcus Lindstrom and published by John Wiley & Sons. This book was released on 2008-04-15 with total page 424 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volatile organic solvents are the normal media used in both research scale and industrial scale synthesis of organic chemicals. Their environmental impact is significant, however, and so the development of alternative reaction media has become of great interest. Developments in the use of water as a solvent for organic synthesis have reached the point where it could now be considered a viable solvent for many organic reactions. Organic Reactions in Water demonstrates the underlying principles of using water as a reaction solvent and, by reference to a range of reaction types and systems, it’s effective use in synthetic organic chemistry. Written by an internationally respected team of contributors, and with a strong focus on the practical use of water as a reaction medium, this book illustrates the enormous potential of water for the development of new and unique chemistries and synthetic strategies, while at the same time offering a much reduced environmental impact.

Reactions and synthesis

Author : Francis A. Carey
Publisher : Springer Science & Business Media
ISBN 13 :
Total Pages : 844 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Reactions and synthesis by : Francis A. Carey

Download or read book Reactions and synthesis written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 1990 with total page 844 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part B of the new edition (previous was 1983) of this text/reference expands on the material contained in Part A Structure and mechanisms by providing an up-to-date treatment of synthetically useful reactions and an illustration of their application. Includes a new section on synthetic applications

The Chemistry of Organolithium Compounds

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 0470023228
Total Pages : 768 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis The Chemistry of Organolithium Compounds by : Zvi Rappoport

Download or read book The Chemistry of Organolithium Compounds written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2006-06-14 with total page 768 pages. Available in PDF, EPUB and Kindle. Book excerpt: Patai Series: The Chemistry of Functional Groups A series of advanced treatises founded by Professor Saul Patai and under the general editorship of Professor Zvi Rappoport The Patai Series publishes comprehensive reviews on all aspects of specific functional groups. Each volume contains outstanding surveys on theoretical and computational aspects, NMR, MS, other spectroscopical methods and analytical chemistry, structural aspects, thermochemistry, photochemistry, synthetic approaches and strategies, synthetic uses and applications in chemical and pharmaceutical industries, biological, biochemical and environmental aspects. To date, over 100 volumes have been published in the series. Recently Published Titles * The chemistry of the Cyclopropyl Group (Volume 2) * The chemistry of the Hydrazo Azo and Azozy Groups (Volume 2, 2 parts) * The chemistry of Double-Bonded Functional Groups (Volume 3, 2 parts) * The chemistry of Organophosphorus Compounds (Volume 4) * The chemistry of Halides, Pseudo-Halides and Azides (Volume 2, 2 parts) * The chemistry of the Amino, Nitro and Nitroso Groups (2 volumes, 2 parts) * The chemistry of Dienes and Polyenes (2 volumes) * The chemistry of Organic Derivatives of Gold and Silver * The chemistry of Organic Silicon Compounds (2 volumes, 4 parts) * The chemistry of Organic Germanium, Tin and Lead Compounds (Volume 2, 2 parts) * The chemistry of Phenols (2 parts) * The chemistry of Organolithium Compounds (2 parts) * The chemistry of Cyclobutanes (2 parts) * Forthcoming Titles * The chemistry of Peroxides (Volume 2, 2 parts) * The chemistry of Organozinc Compounds * The chemistry of Anilines The Patai Series Online The Patai Series is available in electronic format on Wiley InterScience. All new titles will be published online and a growing list of older titles is added every year. It is the ultimate goal that all titles published in the Patai Series will be available in electronic format.

Tin in Organic Synthesis

Author : Michel Pereyre
Publisher : Butterworth-Heinemann
ISBN 13 : 1483161072
Total Pages : 353 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Tin in Organic Synthesis by : Michel Pereyre

Download or read book Tin in Organic Synthesis written by Michel Pereyre and published by Butterworth-Heinemann. This book was released on 2013-10-22 with total page 353 pages. Available in PDF, EPUB and Kindle. Book excerpt: Tin in Organic Synthesis is a systematic presentation of the organic chemistry of tin. This book discusses the significant advances that have been made with regard to the applications of organotin compounds as reagents or intermediates in organic synthesis and points out directions for future developments. This monograph is comprised of 17 chapters divided into four sections. Following a brief introduction to organotin chemistry, the production of the organotin reagents, which are most usually employed in organic synthesis, is described. Special emphasis is placed on the creation of a fresh tin-carbon bond, a preliminary step in numerous fruitful applications. The following chapters are devoted to synthetic applications involving tin-hydrogen, tin-carbon, and tin-heteroatom bonds. The reduction of organic halides, carbonyl compounds, thio, nitrogen compounds, unsaturated carbon-carbon bonds, and seleno and telluro compounds is considered. The discussion then turns to electrophilic cleavages of tin-carbon bonds, which are of possible interest in organic synthesis, along with transmetallation and metallation of organotin compounds. The creation of new carbon-carbon bonds through substitution, addition, or elimination reactions is also examined. The remaining chapters focus on organotin alkoxides, organotin enolates, organotin oxides and peroxides, and organotin esters. This book will be of interest to students and researchers in the field of organic chemistry.

Modern Carbonyl Olefination

Author : Takeshi Takeda
Publisher : John Wiley & Sons
ISBN 13 : 352760538X
Total Pages : 365 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Modern Carbonyl Olefination by : Takeshi Takeda

Download or read book Modern Carbonyl Olefination written by Takeshi Takeda and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: While this important reaction class is among the most important and most widely used in organic chemistry, this is the first book to summarize the many different olefination methods, including: * Wittig reaction * Peterson reaction * Julia olefination * Utilizing the Tebbe and related reagents * Low-valent chromium, zinc or titanium mediated olefination * McMurry coupling plus the related reactions in each case and the application to asymmetric synthesis. It thus collates in one ready reference the current level of knowledge as well as new developments in this constantly evolving field -- information which until now has been dispersed throughout the literature.

The Chemistry of Organomagnesium Compounds, 2 Volume Set

Author : Zvi Rappoport
Publisher : John Wiley & Sons
ISBN 13 : 047075186X
Total Pages : 920 pages
Book Rating : 4.4/5 (77 download)

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Book Synopsis The Chemistry of Organomagnesium Compounds, 2 Volume Set by : Zvi Rappoport

Download or read book The Chemistry of Organomagnesium Compounds, 2 Volume Set written by Zvi Rappoport and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 920 pages. Available in PDF, EPUB and Kindle. Book excerpt: Magnesium remains almost unique among the metals in its ability to react directly with a wide variety of compounds. This organic chemistry field has seen steady progress, and a volume on this topic is long overdue. In the tradition of the Patai Series this title treats all aspects of functional groups, containing chapters on the theoretical and computational foundations; on analytical and spectroscopic aspects with dedicated chapters on Mass Spectrometry, NMR, IR/UV, etc.; on reaction mechanisms; on applications in syntheses. Depending on the functional group there are also chapters on industrial use, on effects in biological and/or environmental systems. Since the area of Organomagnesium Chemistry continues to grow far beyond the classical Grignard Reagents, this is an essential resource to help the reader keep abreast of the latest developments.

Basic Principles of Organic Chemistry

Author : John D. Roberts
Publisher :
ISBN 13 : 9780805383218
Total Pages : 1596 pages
Book Rating : 4.3/5 (832 download)

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Book Synopsis Basic Principles of Organic Chemistry by : John D. Roberts

Download or read book Basic Principles of Organic Chemistry written by John D. Roberts and published by . This book was released on 1977 with total page 1596 pages. Available in PDF, EPUB and Kindle. Book excerpt: Introduction what is organic chemistry all about?; Structural organic chemistry the shapes of molecules functional groups; Organic nomenclature; Alkanes; Stereoisomerism of organic molecules; Bonding in organic molecules atomic-orbital models; More on nomenclature compounds other than hydrocarbons; Nucleophilic substitution and elimination reactions; Separation and purification identification of organic compounds by spectroscopic techniques; Alkenes and alkynes. Ionic and radical addition reactions; Alkenes and alkynes; Oxidation and reduction reactions; Acidity or alkynes.