Carbon Nanotube and Related Field Emitters

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Publisher : John Wiley & Sons
ISBN 13 : 3527632107
Total Pages : 551 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Carbon Nanotube and Related Field Emitters by : Yahachi Saito

Download or read book Carbon Nanotube and Related Field Emitters written by Yahachi Saito and published by John Wiley & Sons. This book was released on 2010-10-01 with total page 551 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotubes (CNTs) have novel properties that make them potentially useful in many applications in nanotechnology, electronics, optics and other fields of materials science. These characteristics include extraordinary strength, unique electrical properties, and the fact that they are efficient heat conductors. Field emission is the emission of electrons from the surface of a condensed phase into another phase due to the presence of high electric fields. CNT field emitters are expected to make a breakthrough in the development of field emission display technology and enable miniature X-ray sources that will find a wide variety of applications in electronic devices, industry, and medical and security examinations. This first monograph on the topic covers all aspects in a concise yet comprehensive manner - from the fundamentals to applications. Divided into four sections, the first part discusses the preparation and characterization of carbon nanotubes, while part two is devoted to the field emission properties of carbon nanotubes, including the electron emission mechanism, characteristics of CNT electron sources, and dynamic behavior of CNTs during operation. Part three highlights field emission from other nanomaterials, such as carbon nanowalls, diamond, and silicon and zinc oxide nanowires, before concluding with frontier R&D applications of CNT emitters, from vacuum electronic devices such as field emission displays, to electron sources in electron microscopes, X-ray sources, and microwave amplifiers. Edited by a pioneer in the field, each chapter is written by recognized experts in the respective fields.

Thermionic Electron Sources

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Publisher :
ISBN 13 :
Total Pages : 38 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis Thermionic Electron Sources by : George A. Haas

Download or read book Thermionic Electron Sources written by George A. Haas and published by . This book was released on 1961 with total page 38 pages. Available in PDF, EPUB and Kindle. Book excerpt: A survey of the emission characteristics of modern thermionic electron sources is presented. In addition to a discussion of recent advances among the more commonly used emitters such as oxide cathodes, thoriated cathodes, and metal c thodes, a tabulation of the thermionic properties of over one hundred various new matrix and refractory-coated cathodes is given. (Author).

Nanotube Superfiber Materials

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Publisher : William Andrew
ISBN 13 : 1455778648
Total Pages : 861 pages
Book Rating : 4.4/5 (557 download)

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Book Synopsis Nanotube Superfiber Materials by : Mark Schulz

Download or read book Nanotube Superfiber Materials written by Mark Schulz and published by William Andrew. This book was released on 2013-09-16 with total page 861 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nanotube Superfiber Materials refers to different forms of macroscale materials with unique properties constructed from carbon nanotubes. These materials include nanotube arrays, ribbons, scrolls, yarn, braid, and sheets. Nanotube materials are in the early stage of development and this is the first dedicated book on the subject. Transitioning from molecules to materials is a breakthrough that will positively impact almost all industries and areas of society. Key properties of superfiber materials are high flexibility and fatigue resistance, high energy absorption, high strength, good electrical conductivity, high maximum current density, reduced skin and proximity effects, high thermal conductivity, lightweight, good field emission, piezoresistive, magnetoresistive, thermoelectric, and other properties. These properties will open up the door to dozens of applications including replacing copper wire for power conduction, EMI shielding, coax cable, carbon biofiber, bullet-proof vests, impact resistant glass, wearable antennas, biomedical microdevices, biosensors, self-sensing composites, supercapacitors, superinductors, hybrid superconductor, reinforced elastomers, nerve scaffolding, energy storage, and many others. The scope of the book covers three main areas: Part I: Processing; Part II: Properties; and Part III: Applications. Processing involves nanotube synthesis and macro scale material formation methods. Properties covers the mechanical, electrical, chemical and other properties of nanotubes and macroscale materials. Different approaches to growing high quality long nanotubes and spinning the nanotubes into yarn are explained in detail. The best ideas are collected from all around the world including commercial approaches. Applications of nanotube superfiber cover a huge field and provides a broad survey of uses. The book gives a broad overview starting from bioelectronics to carbon industrial machines. - First book to explore the production and applications of macro-scale materials made from nano-scale particles - Sets out the processes for producing macro-scale materials from carbon nanotubes, and describes the unique properties of these materials - Potential applications for CNT fiber/yarn include replacing copper wire for power conduction, EMI shielding, coax cable, carbon biofiber, bullet-proof vests, impact resistant glass, wearable antennas, biomedical microdevices, biosensors, self-sensing composites, supercapacitors, superinductors, hybrid superconductor, reinforced elastomers, nerve scaffolding, energy storage, and many others

Nanostructured Carbon Electron Emitters and Their Applications

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Publisher : CRC Press
ISBN 13 : 1000333795
Total Pages : 374 pages
Book Rating : 4.0/5 (3 download)

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Book Synopsis Nanostructured Carbon Electron Emitters and Their Applications by : Yahachi Saito

Download or read book Nanostructured Carbon Electron Emitters and Their Applications written by Yahachi Saito and published by CRC Press. This book was released on 2022-01-27 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon forms a variety of allotropes due to the diverse hybridization of s- and p-electron orbitals, including the time-honored graphite and diamond as well as new forms such as C60 fullerene, nanotubes, graphene, and carbyne. The new family of carbon isotopes—fullerene, nanotubes, graphene, and carbyne—is called “nanostructured carbon” or “nanocarbon.” These isotopes exhibit extreme properties such as ultrahigh mechanical strength, ultrahigh charge–carrier mobility, and high thermal conductivity, attracting considerable attention for their electronic and mechanical applications as well as for exploring new physics and chemistry in the field of basic materials science. Electron sources are important in a wide range of areas, from basic physics and scientific instruments to medical and industrial applications. Carbon nanotubes (CNTs) and graphene behave as excellent electron-field emitters owing to their exceptional properties and offer several benefits compared to traditional cathodes. Field emission (FE) produces very intense electron currents from a small surface area with a narrow energy spread, providing a highly coherent electron beam—a combination that not only provides us with the brightest electron sources but also explores a new field of electron beam–related research. This book presents the enthusiastic research and development of CNT-based FE devices and focuses on the fundamental aspects of FE from nanocarbon materials, including CNTs and graphene, and the latest research findings related to it. It discusses applications of FE to X-ray and UV generation and reviews electron sources in vacuum electronic devices and space thrusters. Finally, it reports on the new forms of carbon produced via FE from CNT.

Perspective of Carbon Nanotubes

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Publisher : BoD – Books on Demand
ISBN 13 : 1789844010
Total Pages : 250 pages
Book Rating : 4.7/5 (898 download)

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Book Synopsis Perspective of Carbon Nanotubes by : Hosam El-Din Saleh

Download or read book Perspective of Carbon Nanotubes written by Hosam El-Din Saleh and published by BoD – Books on Demand. This book was released on 2019-12-11 with total page 250 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotubes belong to new nanomaterials and have been known for almost 20 years, but their history is somewhat lengthier. They have been identified as promising candidates for various applications.High-temperature preparation techniques are conventional techniques for the synthesis of carbon nanotubes using arc discharge or laser ablation, but today these methods are being replaced by low-temperature vapor deposition techniques, since orientation, alignment, nanotube length, diameter, purity, and density of carbon nanotubes can be precisely controlled. The synthesis of carbon nanotubes by chemical vapor deposition on catalyst arrays leads to nanotube models grown from specific sites on surfaces. The controlled synthesis of nanotubes opens up interesting possibilities in nanoscience and nanotechnologies, including electrical, mechanical and electromechanical properties and devices, chemical functionalization, surface chemistry and photochemistry, molecular sensors, and interfacing with moderate biological systems.Carbon nanotubes are used in many applications due to their unique electrical, mechanical, optical, thermal, and other properties. Conductive and high-strength composite materials, energy saving and energy conversion devices, sensors, visualization of field emissions and sources of radiation, means for storing hydrogen, and nanoscale semiconductor devices, probes, and interconnections are some of the many applications of carbon nanotubes.

Multi-Walled Carbon Nanotubes

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Publisher :
ISBN 13 : 9783039212309
Total Pages : 184 pages
Book Rating : 4.2/5 (123 download)

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Book Synopsis Multi-Walled Carbon Nanotubes by : Simone Morais

Download or read book Multi-Walled Carbon Nanotubes written by Simone Morais and published by . This book was released on 2019 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since their discovery, multi-walled carbon nanotubes (MWCNTs) have received tremendous attention due to their unique electrical, optical, physical, chemical, and mechanical properties. Remarkable advances have been made in the synthesis, purification, structural characterization, functionalization, and application of MWCNTs. Their particular characteristics make them well suited for a plethora of applications in a number of fields, namely nanoelectronics, nanofluids, energy management, (electro)catalysis, materials science, construction of (bio)sensors based on different detection schemes, multifunctional nanoprobes for biomedical imaging, and sorbents for sample preparation or removal of contaminants from wastewater. They are also useful as anti-bacterial agents, drug delivery nanocarriers, etc. The current relevant application areas are countless. This Special Issue presents original research and review articles that address advances, trends, challenges, and future perspectives regarding synthetic routes, structural features, properties, behaviors, and industrial or scientific applications of MWCNTs in established and emerging areas.

Field Emission and Field Ionization

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Publisher :
ISBN 13 :
Total Pages : 216 pages
Book Rating : 4.:/5 (45 download)

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Book Synopsis Field Emission and Field Ionization by : Robert Gomer

Download or read book Field Emission and Field Ionization written by Robert Gomer and published by . This book was released on 1961 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Market: Students and researchers in vacuum and surface science, microscopy, and semiconductor physics. This definitive work was based on four lectures presented at Harvard University in 1958. When it was written, field emission was one of the few techniques available for surface studies and the attainment of ultra-high vacuum was a little-known art. Though more sophisticated treatments have since been developed, Gomer's pioneering work remains valid to this day.

Aligned Carbon Nanotubes

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Publisher : Springer Science & Business Media
ISBN 13 : 3642304907
Total Pages : 310 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Aligned Carbon Nanotubes by : Zhifeng Ren

Download or read book Aligned Carbon Nanotubes written by Zhifeng Ren and published by Springer Science & Business Media. This book was released on 2012-09-05 with total page 310 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book gives a survey of the physics and fabrication of carbon nanotubes and their applications in optics, electronics, chemistry and biotechnology. It focuses on the structural characterization of various carbon nanotubes, fabrication of vertically or parallel aligned carbon nanotubes on substrates or in composites, physical properties for their alignment, and applications of aligned carbon nanotubes in field emission, optical antennas, light transmission, solar cells, chemical devices, bio-devices, and many others. Major fabrication methods are illustrated in detail, particularly the most widely used PECVD growth technique on which various device integration schemes are based, followed by applications such as electrical interconnects, nanodiodes, optical antennas, and nanocoax solar cells, whereas current limitations and challenges are also be discussed to lay the foundation for future developments.

Field Emission Electronics

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Publisher : Springer
ISBN 13 : 3319565613
Total Pages : 578 pages
Book Rating : 4.3/5 (195 download)

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Book Synopsis Field Emission Electronics by : Nikolay Egorov

Download or read book Field Emission Electronics written by Nikolay Egorov and published by Springer. This book was released on 2017-06-01 with total page 578 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is dedicated to field emission electronics, a promising field at the interface between “classic” vacuum electronics and nanotechnology. In addition to theoretical models, it includes detailed descriptions of experimental and research techniques and production technologies for different types of field emitters based on various construction principles. It particularly focuses on research into and production of field cathodes and electron guns using recently developed nanomaterials and carbon nanotubes. Further, it discusses the applications of field emission cathodes in new technologies such as light sources, flat screens, microwave and X-ray devices.

Metal Oxide Nanocomposites

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Publisher : John Wiley & Sons
ISBN 13 : 1119363578
Total Pages : 432 pages
Book Rating : 4.1/5 (193 download)

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Book Synopsis Metal Oxide Nanocomposites by : B. Raneesh

Download or read book Metal Oxide Nanocomposites written by B. Raneesh and published by John Wiley & Sons. This book was released on 2021-02-17 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Oxide Nanocomposites: Synthesis and Applications summarizes many of the recent research accomplishments in the area of metal oxide-based nanocomposites. This book focussing on the following topics: Nanocomposites preparation and characterization of metal oxide nanocomposites; synthesis of core/shell metal oxide nanocomposites; multilayer thin films; sequential assembly of nanocomposite materials; semiconducting polymer metal oxide nanocomposites; graphene-based metal and metal oxide nanocomposites; carbon nanotube–metal–oxide nanocomposites; silicon mixed oxide nanocomposites; gas semiconducting sensors based on metal oxide nanocomposites; metal ]organic framework nanocomposite for hydrogen production and nanocomposites application towards photovoltaic and photocatalytic.

Industrial Applications of Carbon Nanotubes

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Publisher : William Andrew
ISBN 13 : 0323415318
Total Pages : 510 pages
Book Rating : 4.3/5 (234 download)

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Book Synopsis Industrial Applications of Carbon Nanotubes by : Huisheng Peng

Download or read book Industrial Applications of Carbon Nanotubes written by Huisheng Peng and published by William Andrew. This book was released on 2016-10-08 with total page 510 pages. Available in PDF, EPUB and Kindle. Book excerpt: Industrial Applications of Carbon Nanotubes covers the current applications of carbon nanotubes in various industry sectors, from the military to visual display products, and energy harvesting and storage. It also assesses the opportunities and challenges for increased commercialization and manufacturing of carbon nanotubes in the years ahead. Real-life case studies illustrate how carbon nanotubes are used in each industry sector covered, providing a valuable resource for scientists and engineers who are involved and/or interested in carbon nanotubes in both academia and industry. The book serves as a comprehensive guide to the varied uses of carbon nanotubes for specialists in many related fields, including chemistry, physics, biology, and textiles. - Explains how carbon nanotubes can be used to improve the efficiency and performance of industrial products - Includes real-life case studies to illustrate how carbon nanotubes have been successfully employed - Explores how carbon nanotubes could be mass-manufactured in the future, and outlines the challenges that need to be overcome

Carbon Nanomaterials

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Publisher : CRC Press
ISBN 13 : 1466502428
Total Pages : 516 pages
Book Rating : 4.4/5 (665 download)

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Book Synopsis Carbon Nanomaterials by : Yury Gogotsi

Download or read book Carbon Nanomaterials written by Yury Gogotsi and published by CRC Press. This book was released on 2013-10-24 with total page 516 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides information on synthesis, properties, and applications of carbon nanomaterials. With novel materials, such as graphene (atomically flat carbon) or carbon onions (carbon nanospheres), the family of carbon nanomaterials is rapidly growing. This book provides a state-of-the-art overview and in-depth analysis of the most important ca

Carbon Nanotubes

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Publisher : CRC Press
ISBN 13 : 1420004212
Total Pages : 339 pages
Book Rating : 4.4/5 (2 download)

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Book Synopsis Carbon Nanotubes by : Michael J. O’Connell

Download or read book Carbon Nanotubes written by Michael J. O’Connell and published by CRC Press. This book was released on 2018-10-03 with total page 339 pages. Available in PDF, EPUB and Kindle. Book excerpt: Since their discovery more than a decade ago, carbon nanotubes (CNTs) have held scientists and engineers in captive fascination, seated on the verge of enormous breakthroughs in areas such as medicine, electronics, and materials science, to name but a few. Taking a broad look at CNTs and the tools used to study them, Carbon Nanotubes: Properties and Applications comprises the efforts of leading nanotube researchers led by Michael O’Connell, protégé of the late father of nanotechnology, Richard Smalley. Each chapter is a self-contained treatise on various aspects of CNT synthesis, characterization, modification, and applications. The book opens with a general introduction to the basic characteristics and the history of CNTs, followed by discussions on synthesis methods and the growth of “peapod” structures. Coverage then moves to electronic properties and band structures of single-wall nanotubes (SWNTs), magnetic properties, Raman spectroscopy of electronic and chemical behavior, and electromechanical properties and applications in NEMS (nanoelectromechanical systems). Turning to applications, the final sections of the book explore mechanical properties of SWNTs spun into fibers, sidewall functionalization in composites, and using SWNTs as tips for scanning probe microscopes. Taking a fresh look at this burgeoning field, Carbon Nanotubes: Properties and Applications points the way toward making CNTs commercially viable.

Handbook of Carbon Nanotubes

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Publisher : Springer Nature
ISBN 13 : 3030913465
Total Pages : 2099 pages
Book Rating : 4.0/5 (39 download)

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Book Synopsis Handbook of Carbon Nanotubes by : Jiji Abraham

Download or read book Handbook of Carbon Nanotubes written by Jiji Abraham and published by Springer Nature. This book was released on 2022-11-16 with total page 2099 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Handbook covers the fundamentals of carbon nanotubes (CNT), their composites with different polymeric materials (both natural and synthetic) and their potential advanced applications. Three different parts dedicated to each of these aspects are provided, with chapters written by worldwide experts in the field. It provides in-depth information about this material serving as a reference book for a broad range of scientists, industrial practitioners, graduate and undergraduate students, and other professionals in the fields of polymer science and engineering, materials science, surface science, bioengineering and chemical engineering. Part 1 comprises 22 chapters covering early stages of the development of CNT, synthesis techniques, growth mechanism, the physics and chemistry of CNT, various innovative characterization techniques, the need of functionalization and different types of functionalization methods as well as the different properties of CNT. A full chapter is devoted to theory and simulation aspects. Moreover, it pursues a significant amount of work on life cycle analysis of CNT and toxicity aspects. Part 2 covers CNT-based polymer nanocomposites in approximately 23 chapters. It starts with a short introduction about polymer nanocomposites with special emphasis on CNT-based polymer nanocomposites, different manufacturing techniques as well as critical issues concerning CNT-based polymer nanocomposites. The text deeply reviews various classes of polymers like thermoset, elastomer, latex, amorphous thermoplastic, crystalline thermoplastic and polymer fibers used to prepare CNT based polymer composites. It provides detailed awareness about the characterization of polymer composites. The morphological, rheological, mechanical, viscoelastic, thermal, electrical, electromagnetic shielding properties are discussed in detail. A chapter dedicated to the simulation and multiscale modelling of polymer nanocomposites is an additional attraction of this part of the Handbook. Part 3 covers various potential applications of CNT in approximately 27 chapters. It focuses on individual applications of CNT including mechanical applications, energy conversion and storage applications, fuel cells and water splitting, solar cells and photovoltaics, sensing applications, nanofluidics, nanoelectronics and microelectronic devices, nano-optics, nanophotonics and nano-optoelectronics, non-linear optical applications, piezo electric applications, agriculture applications, biomedical applications, thermal materials, environmental remediation applications, anti-microbial and antibacterial properties and other miscellaneous applications and multi-functional applications of CNT based polymer nanocomposites. One chapter is fully focussed on carbon nanotube research developments: published papers and patents. Risks associated with carbon nanotubes and competitive analysis of carbon nanotubes with other carbon allotropes are also addressed in this Handbook.

Nanoplatform-Based Molecular Imaging

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Publisher : John Wiley & Sons
ISBN 13 : 1118110021
Total Pages : 848 pages
Book Rating : 4.1/5 (181 download)

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Book Synopsis Nanoplatform-Based Molecular Imaging by : Xiaoyuan Chen

Download or read book Nanoplatform-Based Molecular Imaging written by Xiaoyuan Chen and published by John Wiley & Sons. This book was released on 2011-04-20 with total page 848 pages. Available in PDF, EPUB and Kindle. Book excerpt: The cutting-edge guide on advancing the science of molecular imaging using nanoparticles Nanoplathform-Based Molecular Imaging provides rationale for using nanoparticle-based probes for molecular imaging, then discusses general strategies for this underutilized, yet promising, technology. It addresses general strategies of particle synthesis and surface chemistry, applications in computed tomography optical imaging, magnetic resonance imaging, ultrasound, multimodality imaging, theranostics, and finally, the clinical perspectives of nanoimaging. This comprehensive volume summarizes the opinions of those in the forefront of research and describes the latest developments by emphasizing fundamentals and initiating hands-on application.

Graphdiyne

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Publisher : John Wiley & Sons
ISBN 13 : 3527347879
Total Pages : 404 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Graphdiyne by : Yuliang Li

Download or read book Graphdiyne written by Yuliang Li and published by John Wiley & Sons. This book was released on 2022-01-10 with total page 404 pages. Available in PDF, EPUB and Kindle. Book excerpt: Graphdiyne Discover the most cutting-edge developments in the study of graphdiyne from a pioneer of the field In Graphdiyne: Fundamentals and Applications in Renewable Energy and Electronics, accomplished chemist Dr. Yuliang Li delivers a practical and insightful compilation of theoretical and experimental developments in the study of graphdiyne. Of interest to both academics and industrial researchers in the fields of nanoscience, organic chemistry, carbon science, and renewable energies, the book systematically summarizes recent research into the exciting new material. Discover information about the properties of graphdiyne through theoretical simulations and experimental characterizations, as well as the development of graphdiyne with appropriate preparation technology. Learn to create new graphdiyne-based materials and better understand its intrinsic properties. Find out about synthetic methodologies, the controlled growth of aggregated state structures, and structural characterization. In addition to demonstrating the interdisciplinary potential and relevance of graphdiyne, the book also offers readers: A thorough introduction to basic structure and band gap engineering, including molecular and electronic structure, mechanical properties, and the layers structure of bulk graphdiyne Explorations of Graphdiyne synthesis and characterization, including films, nanotube arrays and nanowires, nanowalls, and nanosheets, as well as characterization methods Discussions of the functionalization of graphdiyne, including heteroatom doping, metal decoration, and absorption of guest molecules Rigorous treatments of Graphdiyne-based materials in catalytic applications, including photo- and electrocatalysts Perfect for organic chemists, electronics engineers, materials scientists, and physicists, Graphdiyne: Fundamentals and Applications in Renewable Energy and Electronics will also find its place on the bookshelves of surface and solid-state chemists, electrochemists, and catalytic chemists seeking a one-stop reference on this rising-star carbon material.

Carbon Nanotubes

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Publisher : John Wiley & Sons
ISBN 13 : 3527618058
Total Pages : 224 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Carbon Nanotubes by : Stephanie Reich

Download or read book Carbon Nanotubes written by Stephanie Reich and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 224 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon nanotubes are exceptionally interesting from a fundamental research point of view. Many concepts of one-dimensional physics have been verified experimentally such as electron and phonon confinement or the one-dimensional singularities in the density of states; other 1D signatures are still under debate, such as Luttinger-liquid behavior. Carbon nanotubes are chemically stable, mechanically very strong, and conduct electricity. For this reason, they open up new perspectives for various applications, such as nano-transistors in circuits, field-emission displays, artificial muscles, or added reinforcements in alloys. This text is an introduction to the physical concepts needed for investigating carbon nanotubes and other one-dimensional solid-state systems. Written for a wide scientific readership, each chapter consists of an instructive approach to the topic and sustainable ideas for solutions. The former is generally comprehensible for physicists and chemists, while the latter enable the reader to work towards the state of the art in that area. The book gives for the first time a combined theoretical and experimental description of topics like luminescence of carbon nanotubes, Raman scattering, or transport measurements. The theoretical concepts discussed range from the tight-binding approximation, which can be followed by pencil and paper, to first-principles simulations. We emphasize a comprehensive theoretical and experimental understanding of carbon nanotubes including - general concepts for one-dimensional systems - an introduction to the symmetry of nanotubes - textbook models of nanotubes as narrow cylinders - a combination of ab-initio calculations and experiments - luminescence excitation spectroscopy linked to Raman spectroscopy - an introduction to the 1D-transport properties of nanotubes - effects of bundling on the electronic and vibrational properties and - resonance Raman scattering in nanotubes.