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Author : Evaldas Veleckis
Publisher :
ISBN 13 :
Total Pages : 24 pages
Book Rating : 4.:/5 (664 download)
Download or read book Carbon Isotope Effect in the Decarboxylation of the Mono-anion of Malonic Acid written by Evaldas Veleckis and published by . This book was released on 1953 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Harold Simon Weber
Publisher :
ISBN 13 :
Total Pages : 24 pages
Book Rating : 4.:/5 (657 download)
Download or read book Temperature Dependence of the Carbon Intramolecular Isotope Effect in the Decarboxylation of the Mono-anion of Malonic Acid in Quinoline Solution written by Harold Simon Weber and published by . This book was released on 1954 with total page 24 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbon Isotope Effects in the Decarboxylation of Malonic Acid Vapor written by and published by . This book was released on 1960 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Richard Masayoshi Ikeda
Publisher :
ISBN 13 :
Total Pages : 220 pages
Book Rating : 4.:/5 (649 download)
Download or read book Carbon Isotope Effects written by Richard Masayoshi Ikeda and published by . This book was released on 1958 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Carbon Isotope Effects in Malonic Acid Decarboxylation. I. Influence of Perdeuteration. Ii. The Ionization Effect written by and published by . This book was released on 1963 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : William George Koch
Publisher :
ISBN 13 :
Total Pages : 380 pages
Book Rating : 4.:/5 (642 download)
Download or read book Carbon Isotope Effects in Malonic Acid Decarboxylation written by William George Koch and published by . This book was released on 1963 with total page 380 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Irwin Theodore David
Publisher :
ISBN 13 :
Total Pages : 36 pages
Book Rating : 4.:/5 (648 download)
Download or read book Temperature Dependence of the Intramolecular Carbon Isotope Effect in the Decarboxylation of Malonic Acid in Water Solution written by Irwin Theodore David and published by . This book was released on 1958 with total page 36 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Graham William Stone
Publisher :
ISBN 13 :
Total Pages : 190 pages
Book Rating : 4.:/5 (374 download)
Download or read book Carbon-13 Isotope Effects in the Decarboxylation of Malonic and Substituted Malonic Acid written by Graham William Stone and published by . This book was released on 1970 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Robert Josephs
Publisher :
ISBN 13 :
Total Pages : 34 pages
Book Rating : 4.:/5 (646 download)
Download or read book Temperature Dependence of the Intramolecular Carbon Isotope Effect in the Decarboxylation of Malonic Acid in Water Solution written by Robert Josephs and published by . This book was released on 1959 with total page 34 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Rue Linn Belford
Publisher :
ISBN 13 :
Total Pages : 56 pages
Book Rating : 4.:/5 (669 download)
Download or read book Temperature Dependence of Some Carbon Isotope Effects in the Decarboxylation of Normal Malonic Acid written by Rue Linn Belford and published by . This book was released on 1953 with total page 56 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Marvin J. Stern
Publisher :
ISBN 13 :
Total Pages : 44 pages
Book Rating : 4.3/5 (91 download)
Download or read book Heavy-atom Kinetic Isotope Effects written by Marvin J. Stern and published by . This book was released on 1972 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 896 pages
Book Rating : 4.3/5 (91 download)
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1967 with total page 896 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :
Publisher :
ISBN 13 :
Total Pages : 44 pages
Book Rating : 4.:/5 (319 download)
Download or read book NBS Special Publication written by and published by . This book was released on 1972 with total page 44 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Richard Lee Rowton
Publisher :
ISBN 13 :
Total Pages : 170 pages
Book Rating : 4.:/5 (32 download)
Download or read book Carbon-14 Isotope Effects in the Decarboxylation of 2- Benzoylpropionic Acid written by Richard Lee Rowton and published by . This book was released on 1959 with total page 170 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Kathryn D. Burke
Publisher :
ISBN 13 : 9781303627545
Total Pages : 241 pages
Book Rating : 4.6/5 (275 download)
Download or read book Insights Into Chemical Reactivity written by Kathryn D. Burke and published by . This book was released on 2013 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Primary versus secondary 18O equilibrium isotope effects on the acidity of a variety of carbon, boron, nitrogen, and phosphorus acids were computated by DFT using the B3LYP/aug-cc-pVTZ basis set. The results show that while both isotope effects are normal for the deprotonation of a Brønsted acid, the magnitude of the secondary equilibrium isotope effect is larger than the magnitude of the corresponding primary equilibrium isotope effect. This does not hold for hydroxide addition to Lewis acids, where the primary equilibrium isotope effects are inverse and larger in magnitude than the secondary equilibrium isotope effects, which are normal. The symmetry of the hydrogen bond of hydrogen cyclohexene-1,2-dicarboxylate monoanion was determined in chloroform using the NMR method of isotopic perturbation. The observed increase in the chemical shift separation as the temperature decreases suggests that this monoanion is a mixture of tautomers in rapid equilibrium, and has an asymmetric hydrogen bond. The mechanism for the base-catalyzed decomposition of malonic anhydride to ketene and carbon dioxide was studied computationally. The DFT methods included the B3LYP/6-31G+(d) basis set with and without the polarized continuum model of chloroform and the MP2/cc-pVDZ basis set. The decomposition proceeds via deprotonation of malonic anhydride by the base catalyst. The malonic anhydride anion undergoes ring-opening to form a ketene carboxylate intermediate. Decarboxylation of this intermediate results in a ketene anion which rapidly deprotonates a molecule of malonic anhydride to form the ketene product and continue the catalytic cycle.
Author : Vernon F. Raaen
Publisher :
ISBN 13 :
Total Pages : 416 pages
Book Rating : 4.3/5 (91 download)
Download or read book Carbon-14 written by Vernon F. Raaen and published by . This book was released on 1968 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : American Chemical Society
Publisher :
ISBN 13 :
Total Pages : 1766 pages
Book Rating : 4.:/5 (31 download)
Download or read book Journal of the American Chemical Society written by American Chemical Society and published by . This book was released on 1960 with total page 1766 pages. Available in PDF, EPUB and Kindle. Book excerpt: Proceedings of the Society are included in v. 1-59, 1879-1937.
