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Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis And Hydrogenation Of N N Dimethylformamide
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Book Synopsis Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis and Hydrogenation of N, N-Dimethylformamide by : Serge Schreiner
Download or read book Carbon Dioxide Reduction Via Homogeneous Catalytic Synthesis and Hydrogenation of N, N-Dimethylformamide written by Serge Schreiner and published by . This book was released on 1988 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: The previously reported catalytic reaction between CO2, H2, and (CH3)2NH to yield N, N-dimethylformamide (DMF) has been found to produce also trimethylamine (TMA) in the presence of several Ru, Os, Rh, Ir and Pt complexes. In separate experiments, the hydrogenation of DMF, catalyzed by the same or other complexes, also gave TMA. Thus, evidence is presented for the overall catalytic reduction of CO2 the the methyl group ( -CH3, incorporated in TMA). Keywords: Carbon dioxide, Hydrogenation, Homogeneous catalysis, N, N Dimethylformamide, Ethyl radicals.
Book Synopsis Transformation of Carbon Dioxide to Formic Acid and Methanol by : Wan-Hui Wang
Download or read book Transformation of Carbon Dioxide to Formic Acid and Methanol written by Wan-Hui Wang and published by Springer. This book was released on 2017-10-26 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt: This brief explains the principles and fundamentals of carbon dioxide utilization and highlights the transformation to fuels and value-added chemicals such as formic acid and methanol. It is divided into six chapters, including an introduction to the basics of CO2 utilization and transformation of CO2 to formic acid and methanol with homogeneous and heterogeneous catalysts, respectively. The brief will appeal to a wide readership of academic and industrial researchers focusing on homogeneous and heterogeneous catalysis, organometallic chemistry, green chemistry, energy conversion and storage.
Book Synopsis Chemical Transformations of Carbon Dioxide by : Xiao-Feng Wu
Download or read book Chemical Transformations of Carbon Dioxide written by Xiao-Feng Wu and published by Springer. This book was released on 2018-07-10 with total page 261 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry Collections presents critical reviews from the journal Topics in Current Chemistry organized in topical volumes. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field.
Book Synopsis The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide by : G. Henrici-Olive
Download or read book The Chemistry of the Catalyzed Hydrogenation of Carbon Monoxide written by G. Henrici-Olive and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 239 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the oil embargo, in the winter 1973174, parts of Western Europe present ed an almost war-like aspect on Saturdays and Sundays: no traffic on the high ways, no crowds at ski resorts and other weekend entertainment places, no gaso line at the pumps. Living and teaching then in that part of the world, and discussing the situa tion with our students, we came to the conclusion that it would be timely to col lect the fine chemistry already known at the time in the field of conversion of coal to gasoline and other chemicals, and by this way help to draw the attention to this important alternative to crude oil. The idea of this book was born. The energy shock of the early seventies has been healthy and of great conse quences in chemistry. Large amounts of research money have been put to work since, and our knowledge of the possibilities and limitations of coal-based chemistry has increased enormously. During several years it appeared inap propriate to write a monograph about a topic which was in the midst of such an impetuous development. Nevertheless, we collected, and critically selected, the upcoming work as it appeared in the literature, and also tried to provide some modest input ourselves. Now, ten years later, the situation seems to be settled to a certain degree.
Book Synopsis Reversible Homogeneous Catalysis of Carbon Dioxide Hydrogenation/Reduction at Room Temperature and Low Pressures Mediated by Platinum(O)-Diphosphine Cluster Complex in Solution by : Serge Schreiner
Download or read book Reversible Homogeneous Catalysis of Carbon Dioxide Hydrogenation/Reduction at Room Temperature and Low Pressures Mediated by Platinum(O)-Diphosphine Cluster Complex in Solution written by Serge Schreiner and published by . This book was released on 1987 with total page 10 pages. Available in PDF, EPUB and Kindle. Book excerpt: A platinum complex,?Pt2(u-PCP)3 (PCP = (C6H5)2PCH2P(C6H6)2, catalyzes the synthesis of N, N-dimehtylformamide (DMF) from CO2, H2 and (CH3)2NH in toluene solution at 25-100C and total pressures of 0.96-114 atm of the three reactant gases. The turnover numbers, DMF/complex/day, range from 9 at 25C and 0.96 atm to 1375 at 100 C and 114 atm. The homogeneous synthesis of DMF is readily reversible by either increasing the temperature, lowering the pressure of the reactants, or both, during the catalytic reaction. The formation of DMF appears to be dependent on the partial pressures of the individual reactants. Separate reactions of the three reactants with (Pt2(u-PCP)3) at ambient conditions (25C, 700 torr) give adducts with (CH3)2NH, but not with CO2 or H2. Keywords: Carbon Dioxide, Hydrogenation, Homogeneous Catalysis, N, N dimethylformamide, Platinum, Phosphine Complex.
Book Synopsis Carbon Dioxide to Chemicals and Fuels by : M. Aulice Scibioh
Download or read book Carbon Dioxide to Chemicals and Fuels written by M. Aulice Scibioh and published by Elsevier. This book was released on 2018-01-02 with total page 511 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon Dioxide to Chemicals and Fuels provides a snapshot of the present status of this rapidly growing field, examining ongoing breakthroughs in research and development, motivations, innovations and their respective impacts and perspectives. It also covers in detail the existing technical barriers to achieving key goals in this area. This book details the various methods, both currently available and potential, for conversion of CO2 into fuels and chemicals. With explanation of concepts and their applications, Carbon Dioxide to Chemicals and Fuels offers an interdisciplinary approach that draws on and clarifies the most recent research trends. Explains the fundamental aspects of CO2 utilization Provides recent developments in CO2 utilization for the production of chemicals Answers the questions surrounding why some processes have not commercialized Discusses and analyses in detail many available catalytic conversion methods
Book Synopsis Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology by : Inamuddin
Download or read book Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology written by Inamuddin and published by Springer Nature. This book was released on 2019-11-13 with total page 202 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents chemical and biological methods to convert carbon dioxide into various products such as methanol, ethanol, formic acid, formaldehyde, volatile organic compounds, syngas and polymers.
Book Synopsis Conversion of Carbon Dioxide into Hydrocarbons Vol. 1 Catalysis by : Inamuddin
Download or read book Conversion of Carbon Dioxide into Hydrocarbons Vol. 1 Catalysis written by Inamuddin and published by Springer Nature. This book was released on 2020-01-01 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents the catalytic conversion of carbon dioxide into various hydrocarbons and other products using photochemical, electrochemical and thermo-chemical processes. Products include formate, formic acid, alcohols, lower and higher hydrocarbons, gases such as hydrogen, carbon monoxide and syngas.
Book Synopsis Green Biphasic Homogeneous Catalysis and Synthesis Using Carbon Dioxide by : David Jacob Heldebrant
Download or read book Green Biphasic Homogeneous Catalysis and Synthesis Using Carbon Dioxide written by David Jacob Heldebrant and published by . This book was released on 2005 with total page 334 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Catalytic Reduction of Carbon Dioxide to Methane and Other Species Via Formamide Intermediation: Synthesis and Hydrogenation of HC(O)NH2 in the Presence of (Ir(Cl)CO)(Ph3P)2). by : L. Vaska
Download or read book Catalytic Reduction of Carbon Dioxide to Methane and Other Species Via Formamide Intermediation: Synthesis and Hydrogenation of HC(O)NH2 in the Presence of (Ir(Cl)CO)(Ph3P)2). written by L. Vaska and published by . This book was released on 1988 with total page 13 pages. Available in PDF, EPUB and Kindle. Book excerpt: Formamide, HC(O)NH2, is catalytically synthesized from Carbon dioxide, Hydrogen and Ammonia in homogeneous toluene or alcohol solutions mediated by Ir(Cl)(CO)(Ph3P)2. The same iridium compound is used in the catalytic hydrogenation of neat formamide which leads to methane and N-methylformamides. The latter overall reaction is complicated due to the concurrent thermal decomposition of formamide yielding carbon black, NH3, Carbon monoxide, CO2, and water. The various possible steps in this complex catalytic system are briefly examined. Keywords: Trans-chlorocarbonylbis(triphenylphosphine)iridium. (aw).
Book Synopsis Technical Reports Awareness Circular : TRAC. by :
Download or read book Technical Reports Awareness Circular : TRAC. written by and published by . This book was released on 1988-07 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Greenhouse Gas Carbon Dioxide Mitigation by : Martin M. Halmann
Download or read book Greenhouse Gas Carbon Dioxide Mitigation written by Martin M. Halmann and published by CRC Press. This book was released on 1998-11-23 with total page 592 pages. Available in PDF, EPUB and Kindle. Book excerpt: Any mention of the "greenhouse effect" tends to ignite controversy. While the rising atmospheric concentrations of greenhouse gases-especially carbon dioxide- are certainly among the most pressing issues today, theoretical and perceived consequences have been subject to conjecture and misinformation. That raging debate has obscured an important fact: scientists and engineers are hard at work on methods to reduce CO2 emissions, and devise practical methods for their remediation. Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology sheds light on the most recent advancements, documented by two of the world's leading researchers on CO2. Aware of the complexity and still-unknown factors behind climatic change, the authors consider the need to make CO2 mitigation viable for both environmental and economic gain. To that end, Professor Halmann offers new insights into interesting chemical pathways for the conversion of CO2 to useful products. Steinberg adds real-life engineering solutions, applicable to heavy CO2-producing industrial processes, and improving efficiency of energy conversion. Exciting theories and pilot projects are also testing the potential for CO2 utilization, conversion, reduction, and disposal. Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology reports on the use of biomass, such as ocean fertilization and "energy farms," to put CO2 to practical and safe use. Professional and academic readers involved with CO2 research will find Greenhouse Gas Carbon Dioxide Mitigation: Science and Technology an invaluable roadmap for information and inspiration-a way to move beyond argument, and into action.
Book Synopsis CO2 Hydrogenation Catalysis by : Yuichiro Himeda
Download or read book CO2 Hydrogenation Catalysis written by Yuichiro Himeda and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.
Book Synopsis Carbon Dioxide Recovery and Utilization by : M. Aresta
Download or read book Carbon Dioxide Recovery and Utilization written by M. Aresta and published by Springer Science & Business Media. This book was released on 2013-06-29 with total page 422 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon Dioxide Recovery and Utilization is a complete and informative resource on the carbon dioxide sources and market at the European Union level, with reference to the world situation. The book covers the following themes: - Sources of carbon dioxide and their purity, - Market of carbon dioxide and its uses, - Separation techniques of carbon dioxide from flue gases, - Analysis of the potential of each technique and application, - Basic science and technology of supercritical CO2, - Reactions in supercritical CO2 and its use as reactive solvent, - Utilization of CO2 in the synthesis of chemicals with low energy input, - Conversion of CO2 into fuels: existing techniques, - Dry reforming of methane, - Assessment of the use of carbon dioxide for the synthesis of methanol. This book is unique in providing integrated information and a perspective on innovative technologies for the use of carbon dioxide. The book is suitable for use as a textbook for courses in chemical engineering and chemistry. It is also of great interest as a general reference for those involved with technologies for avoiding carbon dioxide production and for economists. This is an invaluable reference for specialists on synthetic chemistry, gas separation, supercritical fluids, carbon dioxide marketing, renewable energy and sustainable development. In addition, it will be useful for those working in the chemical industry and for policy makers for carbon dioxide mitigation, innovative technologies, carbon recycling, and power generation.
Book Synopsis New and Future Developments in Catalysis by : Yuichiro Himeda
Download or read book New and Future Developments in Catalysis written by Yuichiro Himeda and published by Elsevier Inc. Chapters. This book was released on 2013-07-11 with total page 33 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis CO2 as a Building Block in Organic Synthesis by : Shoubhik Das
Download or read book CO2 as a Building Block in Organic Synthesis written by Shoubhik Das and published by John Wiley & Sons. This book was released on 2020-09-16 with total page 623 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the fascinating application of CO2 as a building block in organic synthesis This important book explores modern organic synthesis’ use of the cheap, non-toxic and abundant chemical CO2as an attractive C1 building block. With contributions from an international panel of experts, CO2 as a Building Block in Organic Synthesis offers a review of the most important reactions which use CO2 as a building block in organic synthesis. The contributors examine a wide-range of CO2 reactions including methylation reactions, CH bond functionalization, carboxylation, cyclic carbonate synthesis, multicomponent reactions, and many more. The book reviews the most recent developments in the field and also: Presents the most important reactions like CH-bond functionalization, carboxylation, carbonate synthesis and many more Contains contributions from an international panel of experts Offers a comprehensive resource for academics and professionals in the field Written for organic chemists, chemists working with or on organometallics, catalytic chemists, pharmaceutical chemists, and chemists in industry, CO2 as Building Block in Organic Synthesis contains an analysis of the most important reactions which use CO2 as an effective building block in organic synthesis.
Book Synopsis Homogeneous Hydrogenation by : P.A. Chaloner
Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
