Bioconversion of Biodiesel-derived Crude Glycerol Waste to 1,3 Propanediol and Gellan Using Adapted Bacterial Isolates

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ISBN 13 :
Total Pages : 244 pages
Book Rating : 4.:/5 (858 download)

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Book Synopsis Bioconversion of Biodiesel-derived Crude Glycerol Waste to 1,3 Propanediol and Gellan Using Adapted Bacterial Isolates by : Kerisha Raghunandan

Download or read book Bioconversion of Biodiesel-derived Crude Glycerol Waste to 1,3 Propanediol and Gellan Using Adapted Bacterial Isolates written by Kerisha Raghunandan and published by . This book was released on 2013 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Bioconversion of Crude Glycerol to Biofuels and Value-added Bioproducts

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ISBN 13 :
Total Pages : pages
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Book Synopsis Bioconversion of Crude Glycerol to Biofuels and Value-added Bioproducts by : Md. Shafiqur Rahman

Download or read book Bioconversion of Crude Glycerol to Biofuels and Value-added Bioproducts written by Md. Shafiqur Rahman and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Increasing demand and the rising cost of fossil fuels, as well as a concern for global climate change have shifted global efforts to utilize renewable resources for the production of a 'greener' energy replacement. Biodiesel, a renewable fuel produced by transesterification of animal fats and vegetable oils, generates about 10% (v/v) of crude glycerol as a core by-product. Consequently, the recent booming of biodiesel industry all over the world has generated a large amount of crude glycerol, creating an oversupply problem. The economic feasibility of the biodiesel industry has been crucially affected due to a high volume (by worldwide surplus) of crude glycerol generated from the biodiesel production process. Consequently, with the increasing number of biodiesel production plants, a large number of glycerol production plants can be expected to be shut down within a few years due to the price drop that will result from the oversupply of glycerol. Therefore, this abundance of glycerol provides an opportunity for the development of new commercial uses. Glycerol, a core by-product of biodiesel production has become an inexpensive and easily obtainable product for which new applications have to be discovered. At present, there is a lack of microorganisms which can efficiently convert crude glycerol to value-added bio-products. The new isolate of bacteria that would permit screening, isolation and over-expression of enzyme would help overcome these challenges. Thus, this research is to identify novel bacterial strains which are capable of efficiently converting glycerol aerobically, and improve the strains for large scale production of value-added products. In Chapter 2 and 3, this study shows a number of bacterial strains isolated from environmental consortia were screened for their capability of converting low or negative-value biodiesel-derived crude glycerol to value-added products. Primarily, an aerobic batch biotransformation process was carried out to observe the kinetics of glycerol dehydrogenase (GDH) activity, bio-product formation and glycerol utilization. Therefore, the major bio-product obtained from this biotransformation of glycerol was 2,3-butanediol (2,3-BD) with minor co-products including acetoin, 1,3-propanediol (1,3-PDO) and acetate. In this study, three bacterial species Klebsiella pneumoniae, K. variicola and Serratia liquefaciens newly isolated from soil and paper mill waste were the highest producers of 2,3-BD. The novel strains K. pneumoniae SRP2 and, K. variicola SRP3 were used to construct a co-culture, capable of simultaneously converting crude glycerol to concurrently produce up to 27.87 g/L of 2,3-BD, yielding 0.73g 2,3-BD per gram glycerol (0.73g/g) using 37.0 g/L glycerol under aerobic conditions in batch culture, showing great potential for biotransformation bioprocess. Therefore, an attempt has been made to produce a major product 2,3-butanediol (2,3-BD) from glycerol as a sole carbon source using newly isolated novel bacterial strains Klebsiella variicola SRP3 and K. pneumoniae SRP2 in a series of batch and fed-batch processes under aerobic process. These studies also compare the bacterial cell biomass, bio-products and a key enzyme glycerol dehydrogenase (GDH) production of K. variicola SRP3 and K. pneumoniae SRP2 isolated from paper mill waste when grown in aerobic condition. The incubation temperature, pH, glycerol concentration and nitrogen sources were the most important factors ruling the GDH. This study also revealed that an increased GDH activity led to a substantially enhanced production of 2,3-BD as a principal product with 1,3-propanediol (1,3-PDO), acetoin and acetate as minor. In Chapter 4-6, the studies of high production of 2,3-butanediol (2,3-BD) from pure and biodiesel derived crude glycerol using an ethyl methanesulfonate (EMS) mutant K. pneumoniae SRM2, and two adapted mutants K. variicola SRM3 and K. variicola SW3 developed from the newly isolated wild type strains K. pneumoniae SRP2 and K. variicola SRM2 respectively are reported. However, as stated in Chapter 4, an adapted mutant strain K. variicola SRM3 withstanding 200 g/L glycerol could efficiently convert glycerol to 29.87 g/L 2,3-BD and 7.08 g/L acetoin from 50.0 g/L glycerol in a batch culture, and an acidic initial pH (pH 5.0) led to enhanced 1.3-fold increased GDH activity of 721.5 units/mg protein from 558.2 units/mg protein.

Energy from Toxic Organic Waste for Heat and Power Generation

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Publisher : Woodhead Publishing
ISBN 13 : 0081025297
Total Pages : 225 pages
Book Rating : 4.0/5 (81 download)

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Book Synopsis Energy from Toxic Organic Waste for Heat and Power Generation by : Debabrata Barik

Download or read book Energy from Toxic Organic Waste for Heat and Power Generation written by Debabrata Barik and published by Woodhead Publishing. This book was released on 2018-11-07 with total page 225 pages. Available in PDF, EPUB and Kindle. Book excerpt: Energy from Toxic Organic Waste for Heat and Power Generation presents a detailed analysis on using scientific methods to recover and reuse energy from Toxic waste. Dr. Barik and his team of expert authors recognize that there has been a growing rise in the quantum and diversity of toxic waste materials produced by human activity, and as such there is an increasing need to adopt new methods for the safe regeneration and minimization of waste produce around the world. It is predominately broken down into 5 sections: The first section provides and overview on the Toxic waste generation addressing the main components for the imbalance in ecosystem derived from human activity The second section sets out ways in which toxic waste can be managed through various methods such as chemical treatment, cracking and Electro-beam treatment The final 3 sections deliver an insight in to how energy can be extracted and recycled into power from waste energy and the challenges that these may offer This book is essential reference for engineering industry workers and students seeking to adopt new techniques for reducing toxic waste and in turn extracting energy from it whilst complying with pollution control standards from across the world. Presents techniques which can be adopted to reduce toxic organic waste while complying with regulations and extract useable energy it Includes case studies of various global industries such as nuclear, medical and research laboratories to further enhance the readers understanding of efficient planning, toxic organic waste reduction methods and energy conversion techniques Analyses methods of extracting and recycling energy from toxic organic waste products

Microbial Production of Propanediol from Biodiesel Glycerol

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.2/5 (241 download)

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Book Synopsis Microbial Production of Propanediol from Biodiesel Glycerol by : Narisetty Vivek

Download or read book Microbial Production of Propanediol from Biodiesel Glycerol written by Narisetty Vivek and published by . This book was released on 2024-02-07 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Microbial Production of Propanediol from Biodiesel Glycerol" by Narisetty Vivek is a comprehensive guidebook for researchers, students, and professionals in the field of biotechnology and bioprocessing. This book delves into the emerging field of using microbial bioprocessing for the production of propanediol from biodiesel-derived crude glycerol. The author covers a broad range of topics, including the selection of microbial strains, optimization of bioprocess parameters, and scale-up strategies for the efficient and cost-effective production of propanediol. The book is structured to provide a thorough understanding of the underlying concepts and principles of microbial bioprocessing. It starts with an introduction to the basics of bioprocessing, followed by a detailed discussion of the bioprocess development for propanediol production. The author highlights the significance of biodiesel-derived crude glycerol as a feedstock for propanediol production and describes the various challenges associated with the use of this feedstock. The book also covers the latest advancements in microbial bioprocessing techniques and technologies, including the use of genetically modified microorganisms, metabolic engineering, and synthetic biology. The author provides a critical analysis of the current state of the art and future prospects for microbial propanediol production from biodiesel-derived crude glycerol. Overall, "Microbial Production of Propanediol from Biodiesel Glycerol" is an excellent reference book for researchers, students, and professionals interested in the use of microbial bioprocessing for sustainable and eco-friendly production of propanediol.

Isolation and Characterization of Bioconversion Microbes and Aerobic Conversion of Crude Glycerol to Value-added Bioproducts

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Isolation and Characterization of Bioconversion Microbes and Aerobic Conversion of Crude Glycerol to Value-added Bioproducts by : Iman Almuharef

Download or read book Isolation and Characterization of Bioconversion Microbes and Aerobic Conversion of Crude Glycerol to Value-added Bioproducts written by Iman Almuharef and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Renewable forms of energy are of significant interest in today's economies. Biofuel is a renewable fuel produced by biological means. Biofuel is very useful because it does not have a finite supply, and it produces fewer pollutants than fossil fuels. Recently, there is a serious concern about future of fossil-based fuels due to increasing price of crude oil around the world, depletion of its sources, several important environmental issues (greenhouse effect and global warming) and increasing energy demands. Thus, this situation has imposed researchers for further exploring the renewable energy sources to produce environmentally friendly fuel that not cause any pollution to the atmosphere. Additionally, nowadays, supplies like plants, organic wastes, and agricultural products are often used to produce biofuel. Until now, bioethanol and biodiesel are the most widely produced and used as biofuel. Biodiesel-derived crude glycerol and lignocellulosic (from cell walls of woody plants) biomass are two attractive low-cost renewable resources for biofuel production. Efficient and cost-effective production of biofuel from these sources through biotechnological methods depends on the development of a suitable bioconversion process. The main aims of this study were to i) isolate and characterize the novel as well as highly efficient cellulase or glycerol dehydrogenase (GDH) producing bacterial strains, and ii) optimize the enzyme production parameters during fermentation. These strains could be considered for the biorefinery industry for hydrolysis of lignocellulosic biomass or bioconversion of glycerol so as to accelerate biofuel commercialization. In this research project, three potential glycerol metabolizing strains of Serratia sp. were isolated from paper mill waste of Resolute Forest Products, Thunder Bay, Ontario, Canada. The glycerol bioconversion abilities of the promising strain S. proteamaculans SRWQ1 were analyzed ii using crude glycerol (byproduct from biodiesel production) as the sole carbon source. During shake flask fermentation under aerobic conditions at an optimal incubation temperature of 25°C, the strain SRWQ1 used 98% of the crude glycerol and produced 18.43 ± 1.55 g/L 2,3-butanediol (BDO) and 8.38 ± 0.76 g/L acetoin, with yields of 0.4 and 0.06 g/g, respectively. When the culture medium (minimal salt medium) was supplemented with 50 g/L of glycerol as the sole carbon source, and 5 g/L yeast extract and 5 g/L peptone as the nitrogen sources, the maximum glycerol dehydrogenase (DGH) activity was 408.69 ± 0.069 U/mg protein. The incubation temperature, pH, glycerol concentration and nitrogen sources are the most important factors ruling the GDH activity. Slightly acidic initial pH (pH 6.0) led to enhanced GDH activity and biomass production. This is the first report that S. proteamaculans species can efficiently convert glycerol to produce green products 2,3-BDO and acetoin. Twenty cellulase-producing bacterial strains were isolated from Kingfisher Lake, Ontario, Canada, and screened for cellulase activity using the carboxymethyl cellulose (CMC) agar plate assay. Isolates showing large halos of depolymerization were further assayed to quantify enzyme production ability and identified by using 16S rDNA sequence analysis. The molecular weight of crude cellulase samples was determined ∼50 kDa with sodium dodecyl sulfate-polyacrylamide gel electrophoresis (SDS-PAGE). The Bacillus strain IM7 showed the highest carboxymethyl cellulase (CMCase) activity (17.7 ± 0.17 IU/mL) after 48 h of incubation at a yeast extract concentration of 15 g/L. A temperature of at 30°C and pH 5.0 were the optimal conditions for cellulase production. The highest activity (24.59 ± 0.09 IU/mL) was recorded when the culture medium was supplemented with 2% mannose as a co-substrate. The increased glucose content by using mannose in the hydrolysate process resulted in the dramatic increase in enzyme activity.

Glycerol

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Publisher : Springer
ISBN 13 : 3319593757
Total Pages : 116 pages
Book Rating : 4.3/5 (195 download)

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Book Synopsis Glycerol by : Claudio J. A. Mota

Download or read book Glycerol written by Claudio J. A. Mota and published by Springer. This book was released on 2017-06-15 with total page 116 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is aimed at providing a concise discussion on the use of glycerol as a renewable raw material for the chemical industry. With the increasing use of biodiesel produced from oils and fats, there is a surplus of glycerol in the world. This abundant and rather cheap raw material can be transformed in commodities and specialty chemicals, as well as in fuels. The book describes the main processes of chemical transformation of glycerol, highlighting those that are currently in commercial use and pointing out potential processes to be used in the future. The first chapter introduces the concept of biofuel and briefly describes the production of biodiesel. It also highlights glycerol as the main byproduct of biodiesel synthesis and presents some numbers regarding the world production of glycerol. The second chapter shows the common uses of glycerol and addresses the point whether or not they can drain the large amounts of glycerol produced from biodiesel. The chapter addresses pros and cons of each use. The third chapter covers the main biotechnological processes of glycerol transformation. The fourth chapter thoroughly describes the main thermochemical processes to transform glycerol into commodities, products that will be further used in the chemical industry to produce polymers, for instance. The fifth chapter covers the production of glycerol derivatives of high added-value. The sixth chapter addresses the use of glycerol in the context of a biorefinery. The main idea is to show that many of the processes described in the previous chapters could be entirely green, using exclusively renewable raw materials.

Microbial Conversions of Raw Glycerol

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Publisher : Nova Science Publishers
ISBN 13 : 9781606923924
Total Pages : 0 pages
Book Rating : 4.9/5 (239 download)

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Book Synopsis Microbial Conversions of Raw Glycerol by : George Aggelis

Download or read book Microbial Conversions of Raw Glycerol written by George Aggelis and published by Nova Science Publishers. This book was released on 2009 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Glycerol is a simple carbon source than can be easy assimilated by numerous eukaryotic and prokaryotic microorganisms. However, this compound had been neglected as substrate for microbial fermentations for many years due mainly to its high cost. Nevertheless, recent developments in the fuel market, led to the production in large scale of biodiesel derived from vegetable oil, reversed this situation. Currently glycerol is available in large quantities in the biodiesel production units. This industry produces enormous quantities of glycerol as a by-product, during transesterification process of the oil with methanol or ethanol. Therefore, glycerol turns into an attractive feedstock. Biotechnology provides a broad range of methods for the valorisation of raw glycerol. Important commodities and high-added value products of industrial interest, such as organic acids, bioplastics, polyunsaturated fatty acids, carotenoids etc could be produced from raw glycerol. Glycerol can also be recycled after its conversion into microbial triacylglycerols and then to biodiesel. In this book, the biochemical pathways of glycerol metabolism in prokaryotic and eukaryotic cells cultivated under various conditions are discussed. The various methods, proposed so far in the international literature for the valorisation of glycerol by biotechnological means, are shown and discussed by using scientific and technological criteria. Evaluation of the economic viability of the 1,3-propanediol production processes is also presented. All chapters (research articles and reviews) were reviewed by experts. Although the examples presented are, doubtless, the more important, there are also a lot of other applications based on raw glycerol.

Conversion of Crude Glycerol from the Biodiesel Industry to Value Added Products

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (128 download)

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Book Synopsis Conversion of Crude Glycerol from the Biodiesel Industry to Value Added Products by : Bijaya Kumar Uprety

Download or read book Conversion of Crude Glycerol from the Biodiesel Industry to Value Added Products written by Bijaya Kumar Uprety and published by . This book was released on 2017 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Crude glycerol is a major by-product of the biodiesel industries. For every 100 kg of biodiesel produced, approximately 10 kg of the byproduct glycerol is generated. With the large increase in biodiesel production, there is a glut in the glycerol produced. Presently crude glycerol is purified to its purer marketable form, burnt as a fuel or mixed with animal feed. However, none of these options contribute considerable revenues to the concerned biodiesel industry. Additionally, some of these routes are not environmentally friendly. It has thus become imperative to find ways to convert crude glycerol to some value-added products. Bioconversion of crude glycerol to microbial lipids is one possible way to valorize it. However, impurities like methanol, salts and soap present in crude glycerol inhibit the growth of microbes used for such conversions. The research work carried out in this thesis addressed these issues and developed tangible alternatives to overcome these problems. Initially the possible use of a heterogeneous catalyst Calcium oxide (CaO) attached to support alumina (Al2O3) for the production of biodiesel was studied. We found that the use of such a catalyst improves the purity of biodiesel and the glycerol produced. Crude glycerol obtained using such insoluble catalysts contained lower levels of impurities and can be converted relatively easily to other useful products. With CaO anchored on Al2O3 as catalyst, the purity of biodiesel and glycerol were found to be 97.66% and 96.36% respectively. The unanchored heterogeneous catalyst CaO resulted in purities of 96.75% and 92.73% respectively. As the byproduct glycerol containing smaller amount of impurities, the use of anchored heterogeneous catalyst is recommended. The potential use of ash from various sources as a cheap alternative heterogeneous catalyst was also studied. With the use of ash from birch bark and fly ash from wood pellets as catalysts, biodiesel and glycerol with purity in the ranges of 88.06%-99.92% and 78.18%-88.23% respectively were obtained. Since such catalysts are cheap and reusable, their application can reduce expenses and the use of environmentally unsafe compounds. The crude glycerol used in all experiments was obtained from a biodiesel producer in Ontario (Canada). It was found to contain 44.56 wt.% glycerol and many impurities including 13.86 wt.% methanol, 32.97 wt.% soap and 4.38 wt.%. After the characterization of the sample it was converted to microbial lipids using an oleaginous yeast Rhodosporidium toruloides ATCC 10788. When this strain was grown on crude glycerol, double the biomass (21.16 g/L) and triple the lipid concentration (11.27 g/L) was obtained compared to growth on pure glycerol media. The capacity of this strain to grow on crude glycerol with high levels of impurities and produce large amounts of lipids proves its robustness. Investigation of the effect of individual components on the lipid production ability of this strain showed it to be capable of using soap as a sole carbon source. This was also the reason for enhanced lipid production even in the presence of other impurities present in crude glycerol. The lipids obtained were rich in oleic acid (47.16%), a mono-unsaturated fatty acid (MUFA). Feedstock rich in MUFA are considered suitable for biodiesel production. Thus, the process of conversion of crude glycerol to microbial lipids can be integrated to existing biodiesel plants. This will help in the management of crude glycerol produced during biodiesel production, save transportation and disposal costs and contribute to the revenues of such industries.

Utilization of Biodiesel-Derived Crude Glycerol by Fungi for Biomass and Lipid Production

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ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Utilization of Biodiesel-Derived Crude Glycerol by Fungi for Biomass and Lipid Production by : Kimberly Marchand

Download or read book Utilization of Biodiesel-Derived Crude Glycerol by Fungi for Biomass and Lipid Production written by Kimberly Marchand and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

The Future of Glycerol

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Publisher : Royal Society of Chemistry
ISBN 13 : 0854041249
Total Pages : 145 pages
Book Rating : 4.8/5 (54 download)

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Book Synopsis The Future of Glycerol by : Mario Pagliaro

Download or read book The Future of Glycerol written by Mario Pagliaro and published by Royal Society of Chemistry. This book was released on 2008 with total page 145 pages. Available in PDF, EPUB and Kindle. Book excerpt: By-products of global biodiesel manufacturing are a modern day global fact responsible for igniting a number of year's worldwide intense research activity into human chemical ingenuity. This highly anticipated 2nd Edition depicts how practical limitations posed by glycerol chemistry are solved based on the understanding of the fundamental chemistry of glycerol and by application of catalysis science and technology. The authors report and comment on employable, practical avenues applicable to convert glycerol into value added products of mass consumption. The best-selling reference book in the.

Electrochemical Synthesis of 1,3-propanediol from Crude Glycerol from Biodiesel Production

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Publisher :
ISBN 13 :
Total Pages : 300 pages
Book Rating : 4.:/5 (921 download)

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Book Synopsis Electrochemical Synthesis of 1,3-propanediol from Crude Glycerol from Biodiesel Production by :

Download or read book Electrochemical Synthesis of 1,3-propanediol from Crude Glycerol from Biodiesel Production written by and published by . This book was released on 2009 with total page 300 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work was carried out to evaluate the optimum conditions for synthesis of 1,3-propanediol from crude glycerol by an electrochemical technique. The experiment of glycerol reforming was separated into three parts. The first part was studied the glycerol reforming from synthetic and purified crude glycerol to 1,3- propanediol by the electrochemical technique. It was found that the optimum conditions; applied current intensity of 4.5 A, an initial pH of 1 set by H2SO4, 2.93 g/l NaCl, electrical charge of 100 Ah/l with Pt electrode; provided the yield of 1,3- propanediol by using synthetic and crude glycerol of 40.81% and 4.76%, respectively. For the second part, the purification of crude glycerol from biodiesel plant under strong acid conditions by using the chemical process was observed. The pH of crude glycerol was adjusted to 2.2 by 1.19 M H3PO4 and extracted glycerolrich layer solution with n-C6H14. After that, glycerol-rich layer neutralized with 12.50 M KOH and extracted with excess C2H5OH could provide the purity of glycerol around 97.92 % with low contaminant levels ash, matter organic non glycerol and water around 0.01, 0.79 and 1.28% w/w, respectively. As studied in the final part of the purified crude glycerol reforming to 1,3-propanediol, the optimum conditions of applied current intensity of 6 A, an initial pH of 1, and an electrical charge of 184.61 Ah/l with Pt electrode could provide the yield of 1,3-propanediol about 26.31%.

Bioconversion of Biodiesel By-products to Value-added Chemicals

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ISBN 13 :
Total Pages : 217 pages
Book Rating : 4.:/5 (972 download)

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Book Synopsis Bioconversion of Biodiesel By-products to Value-added Chemicals by : Apilak Salakkam

Download or read book Bioconversion of Biodiesel By-products to Value-added Chemicals written by Apilak Salakkam and published by . This book was released on 2012 with total page 217 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Microbial Conversion of Raw Glycerol in to Value Added Products

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Publisher : LAP Lambert Academic Publishing
ISBN 13 : 9783659179051
Total Pages : 100 pages
Book Rating : 4.1/5 (79 download)

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Book Synopsis Microbial Conversion of Raw Glycerol in to Value Added Products by : Hiren K. Patel

Download or read book Microbial Conversion of Raw Glycerol in to Value Added Products written by Hiren K. Patel and published by LAP Lambert Academic Publishing. This book was released on 2014-04-01 with total page 100 pages. Available in PDF, EPUB and Kindle. Book excerpt: Renewable energy sources and biofuel, including biodiesel, have been gaining increasing attention recently as a replacement for fossil fuels. However, their implementation in the general market depends on making these fuels more competitive. A convenient way to lower the cost of biofuel is to use the by-products as a potential source of energy, rather than treating them as waste. The industrial conversion of renewable resources into useful compounds, namely bio-based materials, has been receiving much attention from the environmental point of view. The crude glycerol from biodiesel production represents an abundant and inexpensive carbon source. Glycerol is yielded at about 10% as a by-product during the process of biodiesel production. The global biodiesel market is estimated to reach 39 billion gallons by 2020, growing at an average annual growth of 42%. Therefore, microbial conversion of raw glycerol into value added fermented products were investigated aiming to facilitate the utilization of waste glycerol.

From Glycerol to Value-Added Products

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (136 download)

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Book Synopsis From Glycerol to Value-Added Products by : Patrick Cognet

Download or read book From Glycerol to Value-Added Products written by Patrick Cognet and published by . This book was released on 2020 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: In a context where the role of biofuels will continue to grow, it is necessary to take into account the current state of their various manufacturing processes and to anticipate the expansion of the market. Thus, current biodiesel production processes generate a significant amount of glycerol as a by-product (about 100 kg per ton of processed vegetable oil). An explosion of the biodiesel market must integrate the valorization of glycerol whose current market of distribution (cosmetics, drugs, polymers, etc.) is not guaranteed such an expansion. This valuation will contribute effectively to the profitability and sustainability of the processes from which it derives. Glycerol physicochemical and toxicological properties give it the potential to be used as solvent, biolubricant, dispersant, and surfactant, among others. It is also widely used in the food industry as a preservative and sweetener. Beyond these applications, glycerol can also be used as a raw material for a wide range of chemicals. Glycerol is a highly functionalized molecule with specific physico-chemical properties, which can be used in different reactions as a reactant or a building block. For example, glycerol can be used as a starting material for antibiotic production, biosurfactants, organic acid production (lactic, propionic, succinic, citric acid, glyoxylic acid, glyoxalic acid, amino acids, etc.), alcohols (propanediols), glycerol esters, acrolein production, etc. These products can be obtained either through chemical reactions such as acetalization, dehydration, glycerolysis, esterification, etherification, aqueous phase reforming, oxidation, carboxylation, electrochemical routes, or through enzymatic reactions. However, it must be kept in mind that the development of industrial processes relies on the use of crude glycerol from biodiesel production. For that purpose, robust processes involving impurities-insensitive catalysts or pre-purification have to be developed. Finally, the separation of the chemical products obtained after glycerol conversion is also a key step toward the development of viable glycerol-based processes.

A Study of Anaerobic Fermentation of Biodiesel Derived Crude Glycerol Into Butanol Using Clostridium Pasteurianum ATCC 6013

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ISBN 13 :
Total Pages : 394 pages
Book Rating : 4.:/5 (81 download)

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Book Synopsis A Study of Anaerobic Fermentation of Biodiesel Derived Crude Glycerol Into Butanol Using Clostridium Pasteurianum ATCC 6013 by : Keerthi Prasad Venkataramanan

Download or read book A Study of Anaerobic Fermentation of Biodiesel Derived Crude Glycerol Into Butanol Using Clostridium Pasteurianum ATCC 6013 written by Keerthi Prasad Venkataramanan and published by . This book was released on 2012 with total page 394 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Glycerol

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Publisher : Elsevier
ISBN 13 : 0128123338
Total Pages : 156 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Glycerol by : Mario Pagliaro

Download or read book Glycerol written by Mario Pagliaro and published by Elsevier. This book was released on 2017-02-28 with total page 156 pages. Available in PDF, EPUB and Kindle. Book excerpt: Glycerol: The Renewable Platform Chemical provides a valuable overview of the glycerol market, including industrial applications and sustainable production of glycerol. Replacing previous works on the subject, this useful resource describes glycerol, also known as glycerine, and its chemical derivatives, especially the new bioglycerol-derived products. The monograph also discusses how the industrial use of glycerol as raw material for producing commodity chemicals depends on broader scope and lower cost of the catalytic process used to convert glycerol of varying purity grades into valued monomers. New chapters on glycerol polymers, the use of glycerol as antifreeze, and its sustainable production offer relevant information for researchers and professionals from academics and industry alike. The book features new processes, such as low cost and biocompatible glycerol polymers as a major alternative to the conventional polymers, with the first practical applications now emerging in the biomedical and patient care markets. The book offers both a source of inspiration for new projects and a reliable source of information on how glycerol is replacing petrochemicals in many real world applications. Features completely unique information and insight from leading expert Mario Pagliaro, including recent developments in the field, gathered from over a decade of intense R&D activities Includes new chapters on the glycerol market, glycerol polymers, the use of glycerol in the cement and construction industries, its use an antifreeze, and its sustainable production Contains reliable, accessible information appropriate for research chemists and chemical engineers in the chemical, oleochemicals, biodiesel, biotechnology and cement industries as well as in academia

Production of Value Added Products from Biodiesel-derived Crude Glycerine

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Publisher :
ISBN 13 :
Total Pages : 106 pages
Book Rating : 4.:/5 (111 download)

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Book Synopsis Production of Value Added Products from Biodiesel-derived Crude Glycerine by :

Download or read book Production of Value Added Products from Biodiesel-derived Crude Glycerine written by and published by . This book was released on 2015 with total page 106 pages. Available in PDF, EPUB and Kindle. Book excerpt: Glycerine -- Clostridium diolis -- 1,3-propanediol -- Butyric acid -- Lactic acid -- Acetic acid -- Ultrasound -- Glycerol -- Gliserien -- 1,3-propaandiol -- Bottersuur -- Melksuur -- Asynsuur -- Ultraklank -- Gliserol.