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Author : Trond Rogne
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (858 download)
Download or read book Aqueous Corrosion of Steel in H2S and H2S/CO2 Containing Solutions written by Trond Rogne and published by . This book was released on 1983 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Trond Rogne
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (245 download)
Download or read book Internal Corrosion Offshore Pipelines written by Trond Rogne and published by . This book was released on 1982 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Fazlollah Madani Sani
Publisher :
ISBN 13 :
Total Pages : 670 pages
Book Rating : 4.:/5 (13 download)
Download or read book The Effect of Salt Concentration on Aqueous Strong Acid, Carbon Dioxide, and Hydrogen Sulfide Corrosion of Carbon Steel written by Fazlollah Madani Sani and published by . This book was released on 2021 with total page 670 pages. Available in PDF, EPUB and Kindle. Book excerpt: Aqueous brines are often produced during hydrocarbon recovery from geological reservoirs as an unwanted by-product. Degree of salinity is always an issue in produced water. In the USA, salt concentration in waters produced from conventional oil and gas wells falls in the range of 1 g/l (~ 0.1 wt.%) to 400 g/l (~ 28 wt.%). Besides salts, CO2 and H2S are ubiquitous in the production stream. Dissolution of these gases in produced waters results in evolution of corrosive species, such as CO2(aq), H2S(aq), H2CO3(aq), H+(aq), HCO-3(aq), and HS-(aq) that cause severe corrosion problems for carbon steel; primary material used in the construction of oil and gas pipelines. Combination of aqueous salts with dissolved CO2(aq) and H2S(aq) and their related species, has always been a great concern for pipeline operators in terms of corrosion problems. A large body of research exists on CO2 and H2S corrosion of oil and gas facilities, mostly at low salt concentrations; up to 3 wt.%. However, only a limited number of studies has investigated CO2 corrosion at high salt concentrations and to the best of this author’s knowledge, this number is zero for H2S corrosion. In the present study, the effect of salt (NaCl) concentration on aqueous uniform strong acid, CO2, and H2S corrosion of carbon steel is investigated. The key parameters in the corrosion process that are influenced by salt concentration are identified: transport phenomena (solution density, solution viscosity and diffusion coefficients of dissolved species), solution chemistry, and electrochemistry of the underlying reactions. Models have been reproduced and developed to account for the effect of salinity (up to ~ 5 m NaCl) on transport phenomena and solution chemistry. The Smolyakov and the square root (Kohlrausch law) equations were chosen for correcting the diffusion coefficients for the effect of temperature, and salt concentration, respectively, using new coefficients obtained in this study. The mixed solvent electrolyte (MSE) model, which is the only comprehensive solution chemistry model available in the literature for the H2O-NaCl-CO2-H2S systems is reproduced. The MSE model is used to calculate the equilibrium activity and activity coefficients of dissolved species important in aqueous strong acids, CO2, and H2S corrosion of carbon steel. pH measurements at 1 bar total pressure and temperatures below 80oC showed that the autogenous pH of aqueous CO2- and H2S-saturated solutions decreased with increasing NaCl concentration. The reason for the decrease in the solution pH was attributed to the increase in the activity coefficient of the H+ ion. The effect of salt concentration on electrochemistry and rate of strong acid, CO2, and H2S corrosion was studied by performing eight sets of experiments in aqueous N2-, CO2-, and H2S-satuared solutions at temperatures below 80oC, 1 bar total pressure, solution pH values between 3 to 5, and different NaCl concentrations, ranging from 0.1 wt.% (0.017 m) to 20 wt.% (4.27 m). The weight loss and linear polarization resistance corrosion rate measurements showed that the corrosion rate for all three types of corrosion generally decreased with increasing NaCl concentration. The analysis of potentiodynamic polarization sweeps indicated that increasing NaCl concentration decreased the rate of the cathodic H+ ion reduction reaction continually, while the rate of the cathodic water reduction reaction was mostly increased. The rate of anodic dissolution of iron in the active region increased at lower NaCl concentrations and then switched trend and decreased at higher NaCl concentrations. In strong acid corrosion, salt concentration seemed to have no effect on the mechanism of active dissolution of iron.
Author : Aria Kahyarian
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (18 download)
Download or read book Mechanism and Prediction of Mild Steel Corrosion in Aqueous Solutions Containing Carboxylic Acids, Carbon Dioxide, and Hydrogen Sulfide written by Aria Kahyarian and published by . This book was released on 2018 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Pipeline corrosion in upstream oil and gas production and transmission facilities is a major design and maintenance concern. Corrosion in such environments is, to the most part, the results of the presence of an aqueous phase containing weak acids such as carboxylic acids, carbonic acid, and hydrogen sulfide. The proper understanding of encountered corrosion processes and reliable predicted corrosion rates are essential for major design decisions relating to material selection, pipe wall thickness allowance and adoption of appropriate maintenance procedures, such as use of corrosion inhibitors and frequency of in-line inspections.
Author :
Publisher :
ISBN 13 :
Total Pages : 760 pages
Book Rating : 4.:/5 (3 download)
Download or read book Energy Research Abstracts written by and published by . This book was released on 1983 with total page 760 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Liwei Zhang
Publisher : Springer Nature
ISBN 13 : 9819923921
Total Pages : 136 pages
Book Rating : 4.8/5 (199 download)
Download or read book Corrosion in CO2 Capture, Transportation, Geological Utilization and Storage written by Liwei Zhang and published by Springer Nature. This book was released on 2023-07-21 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book systematically discusses the operational stages with high risk of CO2-induced corrosion in CCUS projects, and related measures for corrosion control. CO2 capture, utilization, and storage (CCUS) is a key technology to mitigate climate change and substantially reduce greenhouse gas emissions from fossil fuels. CCUS deals with high concentration CO2, which is very corrosive in a humid environment. Therefore, it is very important to characterize, monitor, and mitigate CO2-induced corrosion in all processes of the CCUS operation chain. Some corrosion control techniques included in this book (e.g., CO2-resisting wellbore cement additives) are beneficial for corrosion control research and engineering practices. This book belongs to the field of corrosion science and engineering, and the expected readership is researchers and engineers working on CCUS.
Author : A. M. El-Sherik
Publisher : Woodhead Publishing
ISBN 13 : 0081012195
Total Pages : 928 pages
Book Rating : 4.0/5 (81 download)
Download or read book Trends in Oil and Gas Corrosion Research and Technologies written by A. M. El-Sherik and published by Woodhead Publishing. This book was released on 2017-06-09 with total page 928 pages. Available in PDF, EPUB and Kindle. Book excerpt: Trends in Oil and Gas Corrosion Research and Technologies: Production and Transmission delivers the most up-to-date and highly multidisciplinary reference available to identify emerging developments, fundamental mechanisms and the technologies necessary in one unified source. Starting with a brief explanation on corrosion management that also addresses today’s most challenging issues for oil and gas production and transmission operations, the book dives into the latest advances in microbiology-influenced corrosion and other corrosion threats, such as stress corrosion cracking and hydrogen damage just to name a few. In addition, it covers testing and monitoring techniques, such as molecular microbiology and online monitoring for surface and subsurface facilities, mitigation tools, including coatings, nano-packaged biocides, modeling and prediction, cathodic protection and new steels and non-metallics. Rounding out with an extensive glossary and list of abbreviations, the book equips upstream and midstream corrosion professionals in the oil and gas industry with the most advanced collection of topics and solutions to responsibly help solve today’s oil and gas corrosion challenges. Covers the latest in corrosion mitigation techniques, such as corrosion inhibitors, biocides, non-metallics, coatings, and modeling and prediction Solves knowledge gaps with the most current technology and discoveries on specific corrosion mechanisms, highlighting where future research and industry efforts should be concentrated Achieves practical and balanced understanding with a full spectrum of subjects presented from multiple academic and world-renowned contributors in the industry
Author : Chaudhery Mustansar Hussain
Publisher : Elsevier
ISBN 13 : 0323951864
Total Pages : 477 pages
Book Rating : 4.3/5 (239 download)
Download or read book Handbook of Corrosion Engineering written by Chaudhery Mustansar Hussain and published by Elsevier. This book was released on 2023-08-09 with total page 477 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Corrosion Engineering: Modern Theory, Fundamentals and Practical Applications explores recent progress in metals corrosion and associated protection processes, spanning all corrosion-related characteristics utilized in natural and industrial environments, including monitoring and testing. The book combines the science and engineering of corrosion to assist readers in conducting exact corrosion evaluations in the design and plant management phases, including optimal protection methods. The book examines the basics of corrosion science, including the electrochemical mechanism, thermodynamic and kinetic aspects, different corrosion forms—such as uniform, localized, and stress corrosion phenomena—and protection systems adopted to combat corrosion, including inhibitors, coatings, and cathodic protection. Focuses on industrial requirements, including codes, standards, regulations, and specifications Recommends materials for control and prevention of corrosion damage Offers industry-tested best practices, rationales, and case studies Covers materials, corrosion, corrosion inhibition, coating, heat treatment, test and inspection, and mechanical design and integrity Includes websites of interest and information about latest research Comprises exercises and practical examples to understand, predict, estimate and mitigate corrosion problems Features numerous pictures, figures, graphs, and schematic models to ensure a clear understanding of the science and engineering of corrosion
Author : Angeire S. Huggins Gonzalez
Publisher :
ISBN 13 :
Total Pages : 231 pages
Book Rating : 4.:/5 (118 download)
Download or read book Galvanic Interactions in Sweet and Sour Environments written by Angeire S. Huggins Gonzalez and published by . This book was released on 2019 with total page 231 pages. Available in PDF, EPUB and Kindle. Book excerpt: Corrosion of carbon steel exposed to aqueous environments containing dissolved carbon dioxide (CO2) and hydrogen sulfide (H2S) is responsible for many failures of equipment and pipelines in the oil and gas industry. Corrosion product films, e.g., iron carbonate (FeCO3) and iron sulfide (FexSy), play a major role in enhancing localized corrosion after breakdown of these films by either mechanical or chemical means. This has been attributed to galvanic effects driven by the difference in open circuit potential (OCP) between steel covered by FeCO3 or FexSy and bare uncovered areas. Upon localized breakdown of the films, a galvanic current flows between the bare metal areas (anodes) and the areas covered with FeCO3 or FexSy (cathodes). Although many studies have evaluated these galvanic effects, there are still some questions remaining related to the cathodic nature of corrosion product films and their role in enhancing localized corrosion. The present study focused on the evaluation of galvanic interactions of iron (Fe) in CO2 and CO2/H2S environments. The corrosion rate and OCP were measured over time for samples under various conditions, corrosion products on those samples were characterized, and galvanic currents were measured between samples exposed to different conditions. The test conditions were selected to favor the formation of protective films. Fe and steel samples were immersed in 1% NaCl saturated with 100% CO2 or 0.1, 1, 10% H2S/balance CO2. The pH of the bulk solution was adjusted to values between 6 and 8, while the temperature was controlled between 20°C and 80°C. Corrosion product layers were characterized using scanning electron microscopy, energy-dispersive X-ray spectroscopy and X-ray photoelectron spectroscopy. The galvanic interactions were measured using a modified split cell that allowed customization of different environments in each of the half cells, along with simultaneous monitoring of the galvanic current and driving force as indicated by the difference in OCPs. The results indicated that the pH of the bulk solutions plays a major role in the formation of protective FeCO3 scales. Fe exhibited a passive-like behavior when immersed in a solution at 80°C with pH adjusted to 8. The split cell experiments showed that after reaching a passive-like behavior, Fe was cathodic when coupled to samples immersed in a solution with lower pH, and the galvanic current was approximately 2.4 μA/cm2. The galvanic current decreased with increasing temperature and pH gradient between the half cells. The study of artificial couples between Fe electrodes in 1% NaCl solutions saturated with 0.1, 1 or 10% H2S/balance CO2 and with CO2 showed that the galvanic current increased with temperature and %H2S in the gas mixture. At 20°C and 0.1-1%H2S/balance CO2, the FexSy-covered electrodes were cathodic compared to Fe in CO2-saturated solution. At higher temperature and H2S/CO2 ratio, the FexSy covered samples were anodic. The reversal in polarity in the evaluation of temperature, pH and H2S/CO2 ratio suggested that the cathodic or anodic nature of FexSy films may be influenced by the local chemistry in the film/metal interface.
Author : Tahir R. Hamad
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (643 download)
Download or read book Effect of Corrosion Inhibitors on Corrosion Rate and Hydrogen Up-take by Steel in CO2 Containing Solutions written by Tahir R. Hamad and published by . This book was released on 1994 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ruishu Feng
Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (951 download)
Download or read book Electrochemical Corrosion of Carbon Steels in H2S-containing Brines written by Ruishu Feng and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The electrochemical corrosion behaviors of high strength low alloy carbon steel, Grade S-135, and ultra-high strength low alloy carbon steel, Grade UD-165, were investigated in alkaline brines at pH of 7.9, 10.7, and 12.4 and four H2S partial pressures (PH2S) from 0 to 69 kPa at 85 oC using in situ electrochemical measurements, ex situ surface analyses, and software modeling. HS-(aq) was calculated to be the dominant sulfide species from pH 7.9 to 12.4. After 60 hours, polarization resistance (Rpol) of S-135 and UD-165 generally increased as pH increased at lower PH2S (0 and 0.83 kPa), whereas Rpol decreased and then increased as pH increased at higher PH2S (8.3 and 69 kPa). At each pH, the lower PH2S increased Rpol or did not significantly change Rpol, whereas the higher PH2S decreased Rpol. Two opposite effects from H2S were proposed, an accelerating effect due to H2S(aq) and HS-(aq) facilitating the Faradaic reactions and the localized corrosion, and an inhibiting effect due to the protectiveness of the corrosion products. The inhibiting effect was often observed at relatively low H2S concentrations at pH 7.9 and 12.4. The electrochemical impedance did not change significantly at different stir rates for both S-135 and UD-165, indicating that mass transport in the bulk solution was not the rate determining step. The corrosion products generally changed from iron carbonate and sulfides to iron oxide as pH increased, which agreed with the Pourbaix diagrams. Solution pH in the three solutions were calculated to be 8.1, 9.8, and 10.8 at 200 oC, respectively. Polarization resistance values of UD-165 at 200 °C were consistently one to two orders of magnitude lower than at 85 °C, which corresponded to a drastic increase in corrosion rate at elevated temperature. At 200 °C, Rpol at 9.8 was the smallest after 60 hours among the three solutions. The modeled results were in reasonable agreement with the experimental CR values within a factor of 4. A new method derived from the generalized Butler-Volmer equation allowed to obtain anodic Tafel slopes from LSV even with the effect of limiting current. At 200 oC, the ba values indicated that the anodic reactions followed the Bockris mechanism at pH 8.1 and a two-electron mechanism at pH 9.8 and 10.8. As pH increased, the major corrosion products changed from pyrrhotite/siderite to magnetite although the corrosion products were a mixture of iron carbonate, sulfide and oxide. At 4 °C and 10 MPa total pressure, experimental results for two drill steels, Grade S-135 and Grade UD-165, showed a distinct drop in corrosion rate when transitioning from sweet (CO2) corrosion to sour (H2S) corrosion in 5% wt. NaCl brine. It was found that a CO2:H2S ratio as high as 1000 was still enough for sour corrosion to dominate the conditions tested. The CO2+H2S condition and H2S condition had the similar anodic and cathodic Tafel slopes, which were smaller than the CO2 condition. The presence of H2S could have caused the formation of FeS(s) at the steel surface where the pH and Fe2+(aq) concentration might be higher than in the bulk solution.
Author : J. H. Field
Publisher :
ISBN 13 :
Total Pages : 28 pages
Book Rating : 4.3/5 (91 download)
Download or read book Removing Hydrogen Sulfide by Hot Potassium Carbonate Absorption written by J. H. Field and published by . This book was released on 1960 with total page 28 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Payman Sharifi Abdar
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)
Download or read book Mechanism and Modeling of Galvanic Corrosion Between Mild Steel and Iron Aulfides in Acidic Solutions written by Payman Sharifi Abdar and published by . This book was released on 2023 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Sour hydrocarbon reservoirs, containing H2S gas, are receiving increasing attention due to the growing demand for energy. Although uniform corrosion is not a significant obstacle for oil and gas companies in sour environments, the major challenge in this field is prevention of localized corrosion that can cause failures in production infrastructure. Formation of different types of iron sulfides as corrosion products has been postulated to be a main culprit for localized attack, due to their wide-ranging physicochemical properties, such as their electrical conductivities. The galvanic coupling between iron sulfides layers and mild steel was shown to be the mechanism associated with the localized attacks in sour environments. However, the mechanism of galvanic coupling between mild steel and iron sulfides has not been understood due to the lack of systematic and parametric studies. The research described herein addresses the galvanic coupling between mild steel and iron sulfide polymorphs to investigate the involved mechanisms. For the first step, the uniform corrosion of mild steel in aqueous H2S solutions was critically reviewed, and the mechanism associated with this system including the involved chemical electrochemical reactions was fully described. Furthermore, the mathematical modeling of uniform corrosion rate of mild steel in H2S environments was also comprehensively reviewed. In addition, some new approaches for the modeling of electrochemical reactions as well as corrosion rate were proposed, and the validity of the proposed models were verified through comparing with experimental data. Next step of the current research focused on the galvanic corrosion between mild steel and iron sulfides using both experimental and modeling investigations. In the experimental section, a systematic study was performed in order to determine the contribution of the influential parameters on the galvanic corrosion between mild steel and iron sulfides. On that account, the effect of several important parameters including iron sulfide type, cathode to anode surface area ratio, and solution’s conductivity was examined. Although the conductivity of solution did not show significant impact on the galvanic corrosion rate in the studied experimental conditions, the type of iron sulfide as well as the cathode to anode surface area ratio notably affected the galvanic coupling process. Specifically, the two types of iron sulfides used here, pyrite and pyrrhotite, were shown to produce different galvanic corrosion due to their different electrochemical behaviors. To further elucidate the mechanism of the impact of iron sulfide type, the cathodic behavior of pyrite and pyrrhotite was systematically studied using rotating disk electrode system. The results revealed that pyrrhotite has significantly higher cathodic current than pyrite. This difference originates from different cathodic reactions occurring at the surface of these iron sulfides. Therefore, the associated cathodic reactions were also proposed in this study. The modeling section started with the proposed model for the cathodic current density of mild steel, pyrite, and pyrrhotite. The mathematical model was based on the proposed cathodic reactions as well as the constants found from experimental investigation. The proposed model was then verified by comparing it to the experimental data obtained in this study. In the final part of the current study, a mathematical model based on the polarization measurements was proposed for the prediction of galvanic corrosion rate between mild steel and iron sulfides. The model was compared with the experimental results at various experimental conditions, and very good agreement was found between experimental and modeling results. To summarize, the current research was ale to reveal some mechanistic aspects of the galvanic coupling between mild steel and iron sulfides. The impact of the influential parameters and the electrochemical characteristic of iron sulfides were revealed. Also, the current research, for the first time, developed a mathematical model for the prediction of cathodic current on iron sulfides and the galvanic corrosion rate between mild steel and iron sulfides.
Author :
Publisher :
ISBN 13 :
Total Pages : 1416 pages
Book Rating : 4.F/5 ( download)
Download or read book Petroleum Abstracts. Literature and Patents written by and published by . This book was released on 1990 with total page 1416 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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Publisher : Elsevier
ISBN 13 : 0444527877
Total Pages : 3652 pages
Book Rating : 4.4/5 (445 download)
Download or read book Shreir's Corrosion written by and published by Elsevier. This book was released on 2009-02-27 with total page 3652 pages. Available in PDF, EPUB and Kindle. Book excerpt: This four-volume reference work builds upon the success of past editions of Elsevier’s Corrosion title (by Shreir, Jarman, and Burstein), covering the range of innovations and applications that have emerged in the years since its publication. Developed in partnership with experts from the Corrosion and Protection Centre at the University of Manchester, Shreir’s Corrosion meets the research and productivity needs of engineers, consultants, and researchers alike. Incorporates coverage of all aspects of the corrosion phenomenon, from the science behind corrosion of metallic and non-metallic materials in liquids and gases to the management of corrosion in specific industries and applications Features cutting-edge topics such as medical applications, metal matrix composites, and corrosion modeling Covers the benefits and limitations of techniques from scanning probes to electrochemical noise and impedance spectroscopy
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Publisher :
ISBN 13 :
Total Pages : 866 pages
Book Rating : 4.3/5 (91 download)
Download or read book Air Pollution Abstracts written by and published by . This book was released on 1971 with total page 866 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Abdullah Hussein
Publisher : Gulf Professional Publishing
ISBN 13 : 0323995918
Total Pages : 1124 pages
Book Rating : 4.3/5 (239 download)
Download or read book Essentials of Flow Assurance Solids in Oil and Gas Operations written by Abdullah Hussein and published by Gulf Professional Publishing. This book was released on 2022-10-19 with total page 1124 pages. Available in PDF, EPUB and Kindle. Book excerpt: Flow assurance solids deposition is one of the main challenges in oil and gas production operations with millions of dollars spent annually on their mitigation. Essentials of Flow Assurance Solids in Oil and Gas Operations works as an all-inclusive reference for engineers and researchers, covering all the different types of solids that are commonly encountered in oil and gas fields. Structured to flow through real-world operations, the reference branches through each solid deposit problem where the root causes are as well as modeling, monitoring, characterization, and management strategies, all comprehensively reviewed in the light of contemporary research breakthroughs. Backed by several field case studies, Essentials of Flow Assurance Solids in Oil and Gas Operations gives petroleum and reservoir engineers a resource to correlate between the theoretical fundamentals and field practical applications allowing for sustainable and optimal operations. Provides the main operations of oil and gas fields, the characteristics of produced fluids, and the main flow assurance challenges Furnishes the basic principles of deposits formation and mitigation, starting with a full investigation of the problems, then mechanisms, causes, predictions, modelling, and sample analysis, followed by management Distinctively discusses the operational and environmental implications of flow assurance solids and their management using chemical and nonchemical methods Teaches engineers through impactful visuals and data sets included in every chapter
