Analysis of Cu Diffusion in ZnTe-Based Contacts for Thin-Film CdS

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ISBN 13 :
Total Pages : 5 pages
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Book Synopsis Analysis of Cu Diffusion in ZnTe-Based Contacts for Thin-Film CdS by :

Download or read book Analysis of Cu Diffusion in ZnTe-Based Contacts for Thin-Film CdS written by and published by . This book was released on 1998 with total page 5 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ohmic contacts to thin-film CdS/CdTe photovoltaic devices have been formed using a two-layer contact interface of undoped ZnTe (ZnTe) and Cu-doped ZnTe (ZnTe:Cu), followed by Ni or Ti as an outer metallization. Secondary ion mass spectroscopy (SIMS) is used to study Cu diffusion within this back-contact structure, and also, to monitor Cu diffusion from the contact into the CdTe. When Ni metallization is used, the ZnTe:Cu layer becomes increasingly depleted of Cu, and Ni diffusion into the ZnTe:Cu increases as the contact deposition temperature increases from 100 C to 300 C. Cu depletion is not observed when Ni is replaced with Ti. Diffusion of Cu from the ZnTe:Cu layer into the ZnTe layer also increases with contact deposition temperature, and produces a buildup of Cu at the ZnTe/CdTe interface. High-mass resolution SIMS indicates that, although Cu levels in the CdTe remain low, Cu diffusion from the contact proceeds into the CdTe layer and toward the CdTe/CdS junction region.

Analysis of Cu Difusion in ZnTe-Based Contacts for Thin-Film CdS/CdTe Solar Cells

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ISBN 13 :
Total Pages : 0 pages
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Book Synopsis Analysis of Cu Difusion in ZnTe-Based Contacts for Thin-Film CdS/CdTe Solar Cells by :

Download or read book Analysis of Cu Difusion in ZnTe-Based Contacts for Thin-Film CdS/CdTe Solar Cells written by and published by . This book was released on 1998 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ohmic contacts to thin-film CdS/CdTe photovoltaic devices have been formed using a two-layer contact interface of undoped ZnTe (ZnTe) and Cu-doped ZnTe (ZnTe:Cu), followed by Ni or Ti as an outer metallization. Secondary ion mass spectroscopy (SIMS) is used to study Cu diffusion within this back-contact structure, and also, to monitor Cu diffusion from the contact into the CdTe. When Nimetallization is used, the ZnTe:Cu layer becomes increasingly depleted of Cu, and Ni diffusion into the ZnTe:Cu increases as the contact deposition temperature increases from 100 deg. C to 300 deg. C. Cu depletion is not observed when Ni is replaced with Ti. Diffusion of Cu from the ZnTe:Cu layer into the ZnTe layer also increases with contact deposition temperature, and produces a buildup of Cuat the ZnTe/CdTe interface. High-mass resolution SIMS indicates that, although Cu levels in the CdTe remain low, Cu diffusion from the contact proceeds into the CdTe layer and toward the CdTe/CdS junction region.

Effects of Cu Diffusion from ZnTe

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ISBN 13 :
Total Pages : 8 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Effects of Cu Diffusion from ZnTe by :

Download or read book Effects of Cu Diffusion from ZnTe written by and published by . This book was released on 2008 with total page 8 pages. Available in PDF, EPUB and Kindle. Book excerpt: We study the performance of CdS/CdTe thin film PV devices processed with a ZnTe:Cu/Ti contact to investigate how carrier lifetime in the CdTe layer is affected by Cu diffusion from the contact.

Effects of Cu Diffusion From ZnTe

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ISBN 13 :
Total Pages : 18 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Effects of Cu Diffusion From ZnTe by :

Download or read book Effects of Cu Diffusion From ZnTe written by and published by . This book was released on 2008 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Formation of ZnTe

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ISBN 13 :
Total Pages : 6 pages
Book Rating : 4.:/5 (727 download)

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Book Synopsis Formation of ZnTe by :

Download or read book Formation of ZnTe written by and published by . This book was released on 2006 with total page 6 pages. Available in PDF, EPUB and Kindle. Book excerpt: We study the performance of CdS/CdTe thin-film devices contacted with ZnTe:Cu/Ti of various thickness at a higher-than-optimum temperature of (almost equal to)360 C. At this temperature, optimum device performance requires the same thickness of ZnTe:Cu as for similar contacts formed at a lower temperature of 320 C. C-V analysis indicates that a ZnTe:Cu layer thickness of (almost equal to)

Evolution of CdS/CdTe Device Performance During Cu Diffusion

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ISBN 13 :
Total Pages : pages
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Book Synopsis Evolution of CdS/CdTe Device Performance During Cu Diffusion by :

Download or read book Evolution of CdS/CdTe Device Performance During Cu Diffusion written by and published by . This book was released on 2005 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

NCPV Photovoltaics Program Review

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Publisher : American Institute of Physics
ISBN 13 :
Total Pages : 860 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis NCPV Photovoltaics Program Review by : National Center for Photovoltaics (U.S.)

Download or read book NCPV Photovoltaics Program Review written by National Center for Photovoltaics (U.S.) and published by American Institute of Physics. This book was released on 1999-03-12 with total page 860 pages. Available in PDF, EPUB and Kindle. Book excerpt: This proceedings volume compiles 123 papers that were presented orally or as posters at the National Center for Photovoltaics (NCPV) Program Review Meeting, held in Denver, Colorado, on September 8-11, 1998. The purpose of this meeting was to highlight the advances made in various areas of photovoltaics by and through the NCPV during the period of December 1997 to September 1998. Topics covered ranged from research in crystalline silicon and thin-film technologies, to manufacturing of photovoltaic modules, to applications of and markets for photovoltaic products.

SIMS Analysis of Cu in ZnTe-based Back Contacts for CdTe/CdS Solar Cells

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ISBN 13 :
Total Pages : 146 pages
Book Rating : 4.:/5 (439 download)

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Book Synopsis SIMS Analysis of Cu in ZnTe-based Back Contacts for CdTe/CdS Solar Cells by : Chitra Narayanswamy

Download or read book SIMS Analysis of Cu in ZnTe-based Back Contacts for CdTe/CdS Solar Cells written by Chitra Narayanswamy and published by . This book was released on 1999 with total page 146 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Synerjy

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ISBN 13 :
Total Pages : 618 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Synerjy by :

Download or read book Synerjy written by and published by . This book was released on 1996 with total page 618 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Analysis of the ZnTe

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ISBN 13 :
Total Pages : 9 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis Analysis of the ZnTe by : M. J. Romero

Download or read book Analysis of the ZnTe written by M. J. Romero and published by . This book was released on 2003 with total page 9 pages. Available in PDF, EPUB and Kindle. Book excerpt: We report on the recent use of cathodoluminescence (CL) to probe the depth-dependent changes in radiative recombination that occur in CdTe devices during ZnTe:Cu contacting procedures. These types of CL measurements may be useful to assist in linking impurity diffusion (e.g., Cu) from the contact with depth-dependent variation in electrical activation within the CdTe layer. Variable-energy CL suggests that diffusion from the ZnTe:Cu contact interface may assist in reducing donors levels in the CdTe bulk, and thereby yield p-type material in the region near the contact. CL analysis near abrupt metal discontinuities provides estimates of diffusion lengths for carriers associated with both excitonic and donor-to-acceptor pair recombination. Finally, CL measurements at increasing excitation levels (i.e., increasing electron-beam current) provides estimates of the defect state density, as well as providing evidence that discrete multiple defect bands may exist in CdTe prior to contacting.

Electrical Characterization of Cu Composition Effects in CdS/CdTe Thin-Film Solar Cells with a ZnTe:Cu Back Contact: Preprint

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ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (14 download)

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Book Synopsis Electrical Characterization of Cu Composition Effects in CdS/CdTe Thin-Film Solar Cells with a ZnTe:Cu Back Contact: Preprint by :

Download or read book Electrical Characterization of Cu Composition Effects in CdS/CdTe Thin-Film Solar Cells with a ZnTe:Cu Back Contact: Preprint written by and published by . This book was released on 2012 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: We study the effects of Cu composition on the CdTe/ZnTe:Cu back contact and the bulk CdTe. For the back contact, its potential barrier decreases with Cu concentration while its saturation current density increases. For the bulk CdTe, the hole density increases with Cu concentration. We identify a Cu-related deep level at0.55 eV whose concentration is significant when the Cu concentration ishigh. The device performance, which initially increases with Cu concentration then decreases, reflects the interplay between the positive influences and negative influences (increasing deep levels in CdTe) of Cu.

Formation of ZnTe

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ISBN 13 :
Total Pages : 18 pages
Book Rating : 4.:/5 (316 download)

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Book Synopsis Formation of ZnTe by : M. R. Young

Download or read book Formation of ZnTe written by M. R. Young and published by . This book was released on 2006 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: The conclusions of this report are that Cu diffusion from a ZnTe:Cu contact causes good and bad things. The good (Cu in CdS low 10{sup 18} cm{sup -3})--increase in CdTe N{sub A}-N{sub D} that leads to V{sub oc} and FF improvement. The bad (Cu in CdS low 10{sup 18} cm{sup -3})--(1) possibly decreased of shunt resistance ; (2) depletion width in CdTe can become too narrow for optimum current collection at J{sub MPP}; (3) donor reduction in CdS (significant FF loss in LIV); and (4) excessive Cu diffusion into CdS readily observed by red-light bias QE.

Advanced Concepts in Photovoltaics

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Publisher : Royal Society of Chemistry
ISBN 13 : 1849739951
Total Pages : 631 pages
Book Rating : 4.8/5 (497 download)

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Book Synopsis Advanced Concepts in Photovoltaics by : Arthur J. Nozik

Download or read book Advanced Concepts in Photovoltaics written by Arthur J. Nozik and published by Royal Society of Chemistry. This book was released on 2014-07-10 with total page 631 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photovoltaic systems enable the sun’s energy to be converted directly into electricity using semiconductor solar cells. The ultimate goal of photovoltaic research and development is to reduce the cost of solar power to reach or even become lower than the cost of electricity generated from fossil and nuclear fuels. The power conversion efficiency and the cost per unit area of the phototvoltaic system are critical factors that determine the cost of photovoltaic electricity. Until recently, the power conversion efficiency of single-junction photovoltaic cells has been limited to approximately 33% - the so-called Shockley-Queisser limit. This book presents the latest developments in photovoltaics which seek to either reach or surpass the Shockley-Queisser limit, and to lower the cell cost per unit area. Progress toward this ultimate goal is presented for the three generations of photovoltaic cells: the 1st generation based on crystalline silicon semiconductors; the 2nd generation based on thin film silicon, compound semiconductors, amorphous silicon, and various mesoscopic structures; and the 3rd generation based on the unique properties of nanoscale materials, new inorganic and organic photoconversion materials, highly efficient multi-junction cells with low cost solar concentration, and novel photovoltaic processes. The extent to which photovoltaic materials and processes can meet the expectations of efficient and cost effective solar energy conversion to electricity is discussed. Written by an international team of expert contributors, and with researchers in academia, national research laboratories, and industry in mind, this book is a comprehensive guide to recent progress in photovoltaics and essential for any library or laboratory in the field.

Formation of ZnTe:Cu/Ti Contacts at High Temperature for CdS/CdTe Devices

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ISBN 13 :
Total Pages : 4 pages
Book Rating : 4.:/5 (173 download)

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Book Synopsis Formation of ZnTe:Cu/Ti Contacts at High Temperature for CdS/CdTe Devices by :

Download or read book Formation of ZnTe:Cu/Ti Contacts at High Temperature for CdS/CdTe Devices written by and published by . This book was released on 2006 with total page 4 pages. Available in PDF, EPUB and Kindle. Book excerpt: We study the performance of CdS/CdTe thin-film devices contacted with ZnTe:Cu/Ti of various thickness at a higher-than-optimum temperature of ~360°C. ... performance is limited for this device by poor fill factor. We suggest poor fill factor is due to Cu-related acceptors compensating donors in CdS.

Critical Interfacial Issues in Thin-Film Optoelectronic and Energy Conversion Devices: Volume 796

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ISBN 13 :
Total Pages : 192 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Critical Interfacial Issues in Thin-Film Optoelectronic and Energy Conversion Devices: Volume 796 by : Materials Research Society. Meeting

Download or read book Critical Interfacial Issues in Thin-Film Optoelectronic and Energy Conversion Devices: Volume 796 written by Materials Research Society. Meeting and published by . This book was released on 2004-04-09 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt: The MRS Symposium Proceeding series is an internationally recognised reference suitable for researchers and practitioners.

Electrical Characterization of Thin Film CdTe Solar Cells

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Publisher :
ISBN 13 : 9781109861761
Total Pages : 320 pages
Book Rating : 4.8/5 (617 download)

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Book Synopsis Electrical Characterization of Thin Film CdTe Solar Cells by : Darshini Desai

Download or read book Electrical Characterization of Thin Film CdTe Solar Cells written by Darshini Desai and published by . This book was released on 2007 with total page 320 pages. Available in PDF, EPUB and Kindle. Book excerpt: Photovoltaic device modeling results obtained using AMPS (Analysis of microelectronic and photonic structures) suggest that the dominant recombination mechanism is the SRH recombination through midgap states.

ZnTe

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ISBN 13 :
Total Pages : 7 pages
Book Rating : 4.:/5 (682 download)

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Book Synopsis ZnTe by :

Download or read book ZnTe written by and published by . This book was released on 2003 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ability to produce high-performance CdS/CdTe photovoltaic (PV) devices that incorporate high-transparency back contacts for multijunction thin-film PV applications will require an even greater level of understanding than has been required for single-junction devices. This study reports some of our initial investigations at NREL to modify the ZnTe:Cu contact process previously developed for single-junction applications for optimal use as a transparent back contact. We have succeeded in producing devices incorporating a transparent ZnTe:Cu/ITO/metal-grid contact that demonstrates nominally identical light I-V (LIV) performance to the ZnTe:Cu/Ti contact used in single-junction devices. However, we have determined that the transparent conducting oxide (TCO), CdS, CdTe, and ZnTe:Cu layers are all factors in the optical absorption within the device. Finally, we have concluded that optimizing the transparent ZnTe:Cu contact for use with NREL-produced device material will require a more detailed understanding of the evolution of the junction region during the contact process.