Advances In Metal Carbene Chemistry

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Advances in Metal Carbene Chemistry

Author : U. Schubert
Publisher : Springer Science & Business Media
ISBN 13 : 9400923171
Total Pages : 405 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Advances in Metal Carbene Chemistry by : U. Schubert

Download or read book Advances in Metal Carbene Chemistry written by U. Schubert and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 405 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are only few topics in organometallic chemistry, which have stimulated research activities in as many areas, as transition-metal carbene (alkylidene) complexes. About 25 years after the first planned synthesis of a carbene complex in E.O. Fischer's laboratory in Munich the NATO Advanced Research Workshop on Transition-Metal Carbene Complexes was the first meeting which,brought together scientists from different disciplines to discuss inorganic, organic, theoretical structural catalysis-related aspects of metal carbene chemistry. The 70th birthday of Professor E.O. Fischer was a good occasion for this enterprise. The organizers of the meeting (K.D. Dotz, Marburg; F.R. KreiBl, Munchen; U. Schubert, Wurzburg) were encouraged by the fact that most of the leading scientists in this area were able to participate in the workshop. The very high standard of the contributions is reflected in this book, which contains papers from the majority of the participants. The Proceedings show the state of the art in metal carbene chemistry and will hopefully be a landmark in the development of this area of chemistry. Generous financial support for the workshop and for the preparation of this book was provided by the Scientific Affairs Division of NATO and some companies. The organizers also acknowledge the efforts of the staff of the Bildungs zentrum der Hans-Seidel-Stiftung in Wild bad Kreuth for creating a pleasant and stimulating atmosphere during the conference.

Advances in Metal Carbene Chemistry

Author : U. Schubert
Publisher :
ISBN 13 : 9789400923188
Total Pages : 438 pages
Book Rating : 4.9/5 (231 download)

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Book Synopsis Advances in Metal Carbene Chemistry by : U. Schubert

Download or read book Advances in Metal Carbene Chemistry written by U. Schubert and published by . This book was released on 1989-04-30 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal-Catalyzed Carbene Transformations

Author : Jianbo Wang
Publisher : John Wiley & Sons
ISBN 13 : 3527347992
Total Pages : 450 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Transition Metal-Catalyzed Carbene Transformations by : Jianbo Wang

Download or read book Transition Metal-Catalyzed Carbene Transformations written by Jianbo Wang and published by John Wiley & Sons. This book was released on 2022-05-16 with total page 450 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents an up-to-date overview of the rapidly growing field of carbene transformations Carbene transformations have had an enormous impact on catalysis and organometallic chemistry. With the growth of transition metal-catalyzed carbene transformations in recent decades, carbene transformations are today an important compound class in organic synthesis as well as in the pharmaceutical and agrochemical industries. Edited by leading experts in the field, Transition Metal-Catalyzed Carbene Transformations is a thorough summary of the most recent advances in the rapidly expanding research area. This authoritative volume covers different reaction types such as ring forming reactions and rearrangement reactions, details their conditions and properties, and provides readers with accurate information on a wide range of carbene reactions. Twelve in-depth chapters address topics including carbene C-H bond insertion in alkane functionalization, the application of engineered enzymes in asymmetric carbene transfer, progress in transition-metal-catalyzed cross-coupling using carbene precursors, and more. Throughout the text, the authors highlight novel catalytic systems, transformations, and applications of transition-metal-catalyzed carbene transfer. Highlights the dynamic nature of the field of transition-metal-catalyzed carbene transformations Summarizes the catalytic radical approach for selective carbene cyclopropanation, high enantioselectivity in X-H insertions, and bio-inspired carbene transformations Introduces chiral N,N'-dioxide and chiral guanidine-based catalysts and different transformations with gold catalysis Discusses approaches in cycloaddition reactions with metal carbenes and polymerization with carbene transformations Outlines multicomponent reactions through gem-difunctionalization and transition-metal-catalyzed cross-coupling using carbene precursors Transition Metal-Catalyzed Carbene Transformations is essential reading for all chemists involved in organometallics, including organic and inorganic chemists, catalytic chemists, and chemists working in industry.

Metal Carbenes in Organic Synthesis

Author : K H Dtz
Publisher : Springer Science & Business Media
ISBN 13 : 9783540218333
Total Pages : 396 pages
Book Rating : 4.2/5 (183 download)

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Book Synopsis Metal Carbenes in Organic Synthesis by : K H Dtz

Download or read book Metal Carbenes in Organic Synthesis written by K H Dtz and published by Springer Science & Business Media. This book was released on 2004-09-21 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt: With contributions by numerous experts

Metal Carbenes in Organic Synthesis

Author : Florencio Zaragoza Dörwald
Publisher : John Wiley & Sons
ISBN 13 : 3527614079
Total Pages : 290 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Metal Carbenes in Organic Synthesis by : Florencio Zaragoza Dörwald

Download or read book Metal Carbenes in Organic Synthesis written by Florencio Zaragoza Dörwald and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt: There are hardly more versatile compounds in organic synthesis than carbene complexes. The rapid development of new synthetic methods involving carbene complexes - stereoselective cyclopropanation, carbonyl olefination, olefin metathesis, etc. - reveals the value and high potential of these compounds. Their application ranges from the synthesis of fine chemicals to polymer production. This comprehensive, well structured handbook presents the fundamental principles and the recent advances in carbene complex chemistry. Arranged according to structure and reactivity, all relevant classes of carbene complexes, their generation, and application in organic synthesis are discussed in detail. Critically selected, up-to-date references and valuable experimental procedures await the reader. Every chemist searching for a concise introduction and reference work for carbene complex chemistry will welcome this practical guide. "...this concise presentation of all the aspects of the use of carbene complexes in synthesis will help provide the impetus for even more rapid developments in this field of research." R. H. Grubbs (Caltech)

Advances in Metal-Organic Chemistry

Author : Lanny S. Liebeskind
Publisher : Elsevier
ISBN 13 : 1483284417
Total Pages : 305 pages
Book Rating : 4.4/5 (832 download)

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Book Synopsis Advances in Metal-Organic Chemistry by : Lanny S. Liebeskind

Download or read book Advances in Metal-Organic Chemistry written by Lanny S. Liebeskind and published by Elsevier. This book was released on 2013-10-22 with total page 305 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Metal-Organic Chemistry: A Research Annual, Volume 2 presents the virtues of metal-oriented organic chemistry utilizing stoichiometric and catalytic reagents. This book discusses of value for the synthesis of generally useful organic structures. Organized into seven chapters, this volume begins with an overview of the synthetic applications of chromium tricarbonyl stabilized benzylic carbanions. This text then examines the application of organometallic complexes to stereoselective organic synthesis. Other chapters consider the carbine addition reaction that has been shown to be useful in many cases, but complications arise because of the inherently high reactivity of these species. This book discusses as well the most common substituted-arene complexes, particularly those of benzaldehyde and benzoic acid that are stable when prepared by indirect routes via acetals or esters. The final chapter deals with the efficient ring homologation methodology for cyclic alkenes. This book is a valuable resource for synthetic organic chemists and organometallic chemists.

Advances in Organometallic Chemistry

Author :
Publisher : Elsevier
ISBN 13 : 0443294232
Total Pages : 298 pages
Book Rating : 4.4/5 (432 download)

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Book Synopsis Advances in Organometallic Chemistry by :

Download or read book Advances in Organometallic Chemistry written by and published by Elsevier. This book was released on 2024-07-25 with total page 298 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Organometallic Chemistry, Volume 82, the latest release in this longstanding serial, is known for its comprehensive coverage of topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more. Chapters in this new release include Pd-catalysis: a useful tool in the field of polymer synthesis. Recent advances and applications, Modern Mechanistic Approaches for the Depolymerization of Commodity Plastics via Homogeneous Metal Catalysis, Functionalization of fullerenes by transition metal catalyzed cyclization reactions, and Synergistic Metal-Ligand Reactivity in Half-Sandwich Complexes of Fe, Co, and Ni for Bond Activation and Catalysis. Contains contributions from leading authorities in the field of organometallic chemistry Covers topics in organometallic synthesis, reactions, mechanisms, homogeneous catalysis, and more Informs and updates readers on the latest developments in the field Carefully edited to provide easy-to-read material

The Organometallic Chemistry of N-heterocyclic Carbenes

Author : Han Vinh Huynh
Publisher : John Wiley & Sons
ISBN 13 : 1118698797
Total Pages : 352 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis The Organometallic Chemistry of N-heterocyclic Carbenes by : Han Vinh Huynh

Download or read book The Organometallic Chemistry of N-heterocyclic Carbenes written by Han Vinh Huynh and published by John Wiley & Sons. This book was released on 2017-02-03 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

Contemporary Carbene Chemistry

Author : Robert A. Moss
Publisher : John Wiley & Sons
ISBN 13 : 1118730267
Total Pages : 506 pages
Book Rating : 4.1/5 (187 download)

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Book Synopsis Contemporary Carbene Chemistry by : Robert A. Moss

Download or read book Contemporary Carbene Chemistry written by Robert A. Moss and published by John Wiley & Sons. This book was released on 2013-10-17 with total page 506 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presents the most innovative results in carbene chemistry, setting the foundation for new discoveries and applications The discovery of stable carbenes has reinvigorated carbene chemistry research, with investigators seeking to develop carbenes into new useful catalysts and ligands. Presenting the most innovative and promising areas of carbene research over the past decade, this book explores newly discovered structural, catalytic, and organometallic aspects of carbene chemistry, with an emphasis on new and emerging synthetic applications. Contemporary Carbene Chemistry features contributions from an international team of pioneering carbene chemistry researchers. Collectively, these authors have highlighted the most interesting and promising areas of investigation in the field. The book is divided into two parts: Part 1, Properties and Reactions of Carbenes, explores new findings on carbene stability, acid-base behavior, and catalysis. Carbenic structure and reactivity are examined in chapters dedicated to stable carbenes, carbodicarbenes, carbenes as guests in supramolecular hosts, tunneling in carbene and oxacarbene reactions, and ultrafast kinetics of carbenes and their excited state precursors. Theoretical concerns are addressed in chapters on computational methods and dynamics applied to carbene reactions. Part 2, Metal Carbenes, is dedicated to the synthetic dimensions of carbenes, particularly the reactions and catalytic properties of metal carbenes. The authors discuss lithium, rhodium, ruthenium, chromium, molybdenum, tungsten, cobalt, and gold. All the chapters conclude with a summary of the current situation, new challenges on the horizon, and promising new research directions. A list of key reviews and suggestions for further reading also accompanies every chapter. Each volume of the Wiley Series on Reactive Intermediates in Chemistry and Biology focuses on a specific reactive intermediate, offering a broad range of perspectives from leading experts that sets the stage for new applications and further discoveries.

Iron Catalysis: Design And Applications

Author : Jose M Palomo
Publisher : World Scientific
ISBN 13 : 1786349639
Total Pages : 350 pages
Book Rating : 4.7/5 (863 download)

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Book Synopsis Iron Catalysis: Design And Applications by : Jose M Palomo

Download or read book Iron Catalysis: Design And Applications written by Jose M Palomo and published by World Scientific. This book was released on 2021-03-15 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: Iron Catalysis: Design and Applications is an exciting new book that takes readers inside the world of iron catalysis guided by international catalysis expert, Dr Jose M Palomo. Iron is the most abundant metal in the planet, cost-effective, environmentally friendly, with an easily manipulated remediation process. In the last few years the use of this nonprecious metal has gained extraordinary attention particularly for its potential as a catalyst in different areas. This book compiles a series of chapters describing the most significant advances in the last few years since the design of different iron catalysts and nanocatalysts and iron-containing artificial and natural enzymes. The chapters also cover its application in different areas of interest such as organic synthesis, environmental remediation, enzyme-like activities or the creation of novel types of electrodes for battery design.

N-Heterocyclic Carbenes in Transition Metal Catalysis

Author : Frank Glorius
Publisher : Springer
ISBN 13 : 3540369309
Total Pages : 240 pages
Book Rating : 4.5/5 (43 download)

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Book Synopsis N-Heterocyclic Carbenes in Transition Metal Catalysis by : Frank Glorius

Download or read book N-Heterocyclic Carbenes in Transition Metal Catalysis written by Frank Glorius and published by Springer. This book was released on 2007-02-05 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this book leading experts have surveyed major areas of application of NHC metal complexes in catalysis. The authors have placed a special focus on nickel- and palladium-catalyzed reactions, on applications in metathesis reactions, on oxidation reactions and on the use of chiral NHC-based catalysts. This compilation is rounded out by an introductory chapter and a chapter dealing with synthetic routes to NHC metal complexes.

The Organometallic Chemistry of N-heterocyclic Carbenes

Author : Han Vinh Huynh
Publisher : John Wiley & Sons
ISBN 13 : 1118698800
Total Pages : 352 pages
Book Rating : 4.1/5 (186 download)

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Book Synopsis The Organometallic Chemistry of N-heterocyclic Carbenes by : Han Vinh Huynh

Download or read book The Organometallic Chemistry of N-heterocyclic Carbenes written by Han Vinh Huynh and published by John Wiley & Sons. This book was released on 2017-01-23 with total page 352 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Organometallic Chemistry of N-heterocyclic Carbenes describes various aspects of N-heterocyclic Carbenes (NHCs) and their transition metal complexes at an entry level suitable for advanced undergraduate students and above. The book starts with a historical overview on the quest for carbenes and their complexes. Subsequently, unique properties, reactivities and nomenclature of the four classical NHCs derived from imidazoline, imidazole, benzimidazole and 1,2,4-triazole are elaborated. General and historically relevant synthetic aspects for NHCs, their precursors and complexes are then explained. The book continues with coverage on the preparation and characteristics of selected NHC complexes containing the most common metals in this area, i.e. Ni, Pd, Pt, Ag, Cu, Au, Ru, Rh and Ir. The book concludes with an overview and outlook on the development of various non-classical NHCs beyond the four classical types. Topics covered include: Stabilization, dimerization and decomposition of NHCs Stereoelectronic properties of NHCs and their evaluation Diversity of NHCs Isomers of NHC complexes and their identification NMR spectroscopic signatures of NHC complexes normal, abnormal and mesoionic NHCs The Organometallic Chemistry of N-heterocyclic Carbenes is an essential resource for all students and researchers interested in this increasingly important and popular field of research.

New Aspects of Zirconium Containing Organic Compounds

Author : Ilan Marek
Publisher : Springer Science & Business Media
ISBN 13 : 9783540222217
Total Pages : 200 pages
Book Rating : 4.2/5 (222 download)

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Book Synopsis New Aspects of Zirconium Containing Organic Compounds by : Ilan Marek

Download or read book New Aspects of Zirconium Containing Organic Compounds written by Ilan Marek and published by Springer Science & Business Media. This book was released on 2005-02-18 with total page 200 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal carbene complexes have made their way from organometallic curiosities to valuable reagents and catalysts. They offer novel synthetic opportunities in carbon-carbon bond formation based on either carbene-centered reactions or on metal-templated processes which makes them indispensable in modern synthetic methodology. The most prominent metal carbenes are now either commercially available or easy to synthesize and handle with modern laboratory techniques. This volume organized in eight chapters written by the leading scientists in the field illustrates the theoretical background, non-classical nucleophilic and cycloaddition patterns, chromium-templated benzannulation and photo-induced reactions, rhodium-catalyzed carbene transfer as well as the principles and applications of olefin metathesis which has coined the progress in synthetic methodology over the past decade. Designed for researchers in academia and industry as well as graduate students it presents the state-of-the-art potential of carbene complexes in modern organic synthesis.

Organometallic Chemistry and Catalysis

Author : Didier Astruc
Publisher : Springer Science & Business Media
ISBN 13 : 3540461299
Total Pages : 598 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Organometallic Chemistry and Catalysis by : Didier Astruc

Download or read book Organometallic Chemistry and Catalysis written by Didier Astruc and published by Springer Science & Business Media. This book was released on 2007-08-14 with total page 598 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume covers both basic and advanced aspects of organometallic chemistry of all metals and catalysis. In order to present a comprehensive view of the subject, it provides broad coverage of organometallic chemistry itself. The catalysis section includes the challenging activation and fictionalization of the main classes of hydrocarbons and the industrially crucial heterogeneous catalysis. Summaries and exercises are provides at the end of each chapter, and the answers to these exercises can be found at the back of the book. Beginners in inorganic, organic and organometallic chemistry, as well as advanced scholars and chemists from academia and industry will find much value in this title.

Advances in the Chemistry of Group 10 Transition Metal Carbenes

Author : Cody Robert Work
Publisher :
ISBN 13 :
Total Pages : 290 pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Advances in the Chemistry of Group 10 Transition Metal Carbenes by : Cody Robert Work

Download or read book Advances in the Chemistry of Group 10 Transition Metal Carbenes written by Cody Robert Work and published by . This book was released on 2022 with total page 290 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Metal-organic Chemistry

Author : Lanny S. Liebeskind
Publisher : JAI Press(NY)
ISBN 13 : 9780892328635
Total Pages : 416 pages
Book Rating : 4.3/5 (286 download)

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Book Synopsis Advances in Metal-organic Chemistry by : Lanny S. Liebeskind

Download or read book Advances in Metal-organic Chemistry written by Lanny S. Liebeskind and published by JAI Press(NY). This book was released on 1989 with total page 416 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Advances in Transition-Metal Mediated Heterocyclic Synthesis

Author : Daniel Sole
Publisher : Academic Press
ISBN 13 : 0128116528
Total Pages : 366 pages
Book Rating : 4.1/5 (281 download)

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Book Synopsis Advances in Transition-Metal Mediated Heterocyclic Synthesis by : Daniel Sole

Download or read book Advances in Transition-Metal Mediated Heterocyclic Synthesis written by Daniel Sole and published by Academic Press. This book was released on 2018-05-17 with total page 366 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Transition-Metal Mediated Heterocyclic Synthesis provides an overview of recent catalytic reactions involving transition metals to produce heterocyclic compounds. The book is organized according to the type of transformation used to achieve the synthesis of the heterocyclic systems (mainly aza- and oxa-heterocycles). As such, it covers recent applications on the synthesis of heterocycles, also describing the details of the novel transformations in a didactic manner to motivate readers in search of new catalytic processes. The editors have included state-of-the-art strategies, including transition-metal reactions involving unsaturated systems (reactions of allenes, new gold(I)-catalyzed reactions, and Prins reaction). Chapters highlight the versatility of organopalladium chemistry dealing with carbonylative transformations, C-H activation reactions, coupling processes, and the control of the ambiphilic character of organopalladium species. Finally, the book discusses new reactions leading to heterocycles based on C-H activation processes catalyzed by other metals (Rh, Ru, Co). Written by an outstanding team of authors who are leading experts in organometallic chemistry and organic synthesis, this book is a valuable resource not only for chemists mainly focused on synthesis, but also for those interested in reaction mechanisms involving transition metals. Helpfully organized by transformation type to stimulate the search for new synthetic processes Completely illustrated and written by global experts Includes thoughtfully selected strategies chosen by the editors to exemplify the state-of-the-art of the subject, including transition-metal reactions involving unsaturated systems, organopalladium chemistry, and metal-catalyzed C-H activation