Advances in Friedel-Crafts Acylation Reactions

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Author :
Publisher : CRC Press
ISBN 13 : 9781420067934
Total Pages : 216 pages
Book Rating : 4.0/5 (679 download)

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Book Synopsis Advances in Friedel-Crafts Acylation Reactions by : Giovanni Sartori

Download or read book Advances in Friedel-Crafts Acylation Reactions written by Giovanni Sartori and published by CRC Press. This book was released on 2009-12-04 with total page 216 pages. Available in PDF, EPUB and Kindle. Book excerpt: Used in the production of a wide number of fine chemicals and pharmaceuticals, the Friedel-Crafts acylation reaction represents a synthetic process of great interest to organic chemists of academia and industry. Nearly 40 years since the last major treatise on the topic and reflecting the growing emphasis on green technology, Advances in Friedel-Crafts Acylation Reactions: Catalytic and Green Processes focuses on how to make this reaction more economically and environmentally friendly by using green acylating conditions, thus minimizing the formation of waste and decreasing production costs. Divided into four parts, the book explores stoichiometric acylations, catalytic homogeneous acylations, catalytic heterogeneous acylations, and phenol acylations. It is structured according to the role played by the catalyst in the activation of reagents as well as in the different modes of regioselectivity encountered in the acylation of arenes, aromatic ethers, and phenols. Incorporating examples of all acid-catalyzed Friedel-Crafts acylation reactions, the text considers classic Lewis and Brönsted acid types along with more innovative and advanced multicomponent superacid catalysts. These range from rare earth triflates or triflimides and their combination with ionic liquids to metal-promoted zeolites and zeotypes, clays, polymetal oxides, sulfated zirconia, heteropoly acids, and Nafion. The book emphasizes the major industrial applications, providing a critical assessment of the differences, advantages, and disadvantages of homogeneous and heterogeneous catalysis. Helping readers to better understand the mechanism of the Friedel-Crafts acylation, the examples in the book substantiate the development of more effective catalysts and more selective processes achieved during the last few decades, enabling industry to embark on a safer and more efficient synthesis of aromatic ketones for the manufacture of a wide array of products.

Advanced Free Radical Reactions for Organic Synthesis

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Publisher : Elsevier
ISBN 13 : 9780080524252
Total Pages : 270 pages
Book Rating : 4.5/5 (242 download)

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Book Synopsis Advanced Free Radical Reactions for Organic Synthesis by : Hideo Togo

Download or read book Advanced Free Radical Reactions for Organic Synthesis written by Hideo Togo and published by Elsevier. This book was released on 2004-01-14 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: Free radical reactions have become increasingly important and a very attractive tool in organic synthesis in the last two decades, due to their powerful, selective, specific, and mild reaction abilities. Advanced Free Radical Reactions for Organic Synthesis reviews information on all types of practical radical reactions, e.g. cyclizations, additions, hydrogen-atom abstractions, decarboxylation reactions. The book usefully provides experimental details for the most important reactions as well as numerous references to the original literature. By covering both the fundamentals and synthetic applications it is therefore suitable for both new and experienced researchers, chemists, biochemists, natural product chemists and graduate students. This title is the definitive guide to radical chemistry for all scientists. Introduces and reviews the use of radicals to perform synthetic transformations Practical details are provided for the most important methods Numerous references to the original literature

Asymmetric catalysis

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Author :
Publisher : JAI Press(NY)
ISBN 13 : 9780762300686
Total Pages : 0 pages
Book Rating : 4.3/5 (6 download)

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Book Synopsis Asymmetric catalysis by : Michael P. Doyle

Download or read book Asymmetric catalysis written by Michael P. Doyle and published by JAI Press(NY). This book was released on 1997 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second volume in a series covering research advances in the field of catalytic processes.

Superelectrophiles and Their Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 0470185112
Total Pages : 312 pages
Book Rating : 4.4/5 (71 download)

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Book Synopsis Superelectrophiles and Their Chemistry by : George A. Olah

Download or read book Superelectrophiles and Their Chemistry written by George A. Olah and published by John Wiley & Sons. This book was released on 2008-01-03 with total page 312 pages. Available in PDF, EPUB and Kindle. Book excerpt: Superelectrophiles and Their Chemistry contains, for the first-time, a discussion of the basics of this emerging field of organic chemistry, alongside tools to help the reader apply the chemistry. Specific tools include an evaluation of the ways to increase the strength of electrophiles, the classification of superelectrophiles, the solvation issues, a review of methods for studying superelectrophilicity, with details of the superelectrophiles that have been identified and studied. Additional information includes substituent effects in activation of superelectrophiles, and solvation in chemical reactions, as well as an insightful look into future applications.

Mechanochemical Organic Synthesis

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Publisher : Elsevier
ISBN 13 : 0128025255
Total Pages : 386 pages
Book Rating : 4.1/5 (28 download)

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Book Synopsis Mechanochemical Organic Synthesis by : Davor Margetic

Download or read book Mechanochemical Organic Synthesis written by Davor Margetic and published by Elsevier. This book was released on 2016-04-23 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mechanochemical Organic Synthesis is a comprehensive reference that not only synthesizes the current literature but also offers practical protocols that industrial and academic scientists can immediately put to use in their daily work. Increasing interest in green chemistry has led to the development of numerous environmentally-friendly methodologies for the synthesis of organic molecules of interest. Amongst the green methodologies drawing attention, mechanochemistry is emerging as a promising method to circumvent the use of toxic solvents and reagents as well as to increase energy efficiency. The development of synthetic strategies that require less, or the minimal, amount of energy to carry out a specific reaction with optimum productivity is of vital importance for large-scale industrial production. Experimental procedures at room temperature are the mildest reaction conditions (essentially required for many temperature-sensitive organic substrates as a key step in multi-step sequence reactions) and are the core of mechanochemical organic synthesis. This green synthetic method is now emerging in a very progressive manner and until now, there is no book that reviews the recent developments in this area. Features cutting-edge research in the field of mechanochemical organic synthesis for more sustainable reactions Integrates advances in green chemistry research into industrial applications and process development Focuses on designing techniques in organic synthesis directed toward mild reaction conditions Includes global coverage of mechanochemical synthetic protocols for the generation of organic compounds

Fine Chemicals through Heterogeneous Catalysis

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Publisher : John Wiley & Sons
ISBN 13 : 3527612971
Total Pages : 636 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Fine Chemicals through Heterogeneous Catalysis by : R. A. Sheldon

Download or read book Fine Chemicals through Heterogeneous Catalysis written by R. A. Sheldon and published by John Wiley & Sons. This book was released on 2008-07-11 with total page 636 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nowadays, the chemical industry is under increased pressure to develop cleaner production processes and technologies. Much effort is devoted to the development of heterogeneous catalysts and their application in industrial-scale organic synthesis. This handbook concentrates on current attempts, focusing on fine chemical production. With contributions from an impressive array of international experts, this is essential reading for everyone interested in the advances in this field.

Catalytic Asymmetric Friedel-Crafts Alkylations

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 3527626980
Total Pages : 317 pages
Book Rating : 4.5/5 (276 download)

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Book Synopsis Catalytic Asymmetric Friedel-Crafts Alkylations by : Marco Bandini

Download or read book Catalytic Asymmetric Friedel-Crafts Alkylations written by Marco Bandini and published by John Wiley & Sons. This book was released on 2009-06-10 with total page 317 pages. Available in PDF, EPUB and Kindle. Book excerpt: This first comprehensive overview of this important synthetic reaction covers the whole spectrum of this modern and rapidly developing field. Clearly structured, the book presents all the known synthetic approaches for the construction of aromatic compounds bearing benzylic stereocenters with a defined configuration. With its representative synthetic procedures, organocatalysis and industrial applications it combines a theoretical basis with practical examples, resulting in valuable advice for beginners and experts alike. The ultimate source for every synthetic chemist in academia and industry.

Advanced Organic Chemistry

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Publisher : Springer Science & Business Media
ISBN 13 : 0387448993
Total Pages : 1199 pages
Book Rating : 4.3/5 (874 download)

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Book Synopsis Advanced Organic Chemistry by : Francis A. Carey

Download or read book Advanced Organic Chemistry written by Francis A. Carey and published by Springer Science & Business Media. This book was released on 2007-06-27 with total page 1199 pages. Available in PDF, EPUB and Kindle. Book excerpt: The two-part, fifth edition of Advanced Organic Chemistry has been substantially revised and reorganized for greater clarity. The material has been updated to reflect advances in the field since the previous edition, especially in computational chemistry. Part A covers fundamental structural topics and basic mechanistic types. It can stand-alone; together, with Part B: Reaction and Synthesis, the two volumes provide a comprehensive foundation for the study in organic chemistry. Companion websites provide digital models for study of structure, reaction and selectivity for students and exercise solutions for instructors.

Strategic Applications of Named Reactions in Organic Synthesis

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Author :
Publisher : Elsevier
ISBN 13 : 0080575412
Total Pages : 864 pages
Book Rating : 4.0/5 (85 download)

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Book Synopsis Strategic Applications of Named Reactions in Organic Synthesis by : Laszlo Kurti

Download or read book Strategic Applications of Named Reactions in Organic Synthesis written by Laszlo Kurti and published by Elsevier. This book was released on 2005-04-29 with total page 864 pages. Available in PDF, EPUB and Kindle. Book excerpt: Kurti and Czako have produced an indispensable tool for specialists and non-specialists in organic chemistry. This innovative reference work includes 250 organic reactions and their strategic use in the synthesis of complex natural and unnatural products. Reactions are thoroughly discussed in a convenient, two-page layout--using full color. Its comprehensive coverage, superb organization, quality of presentation, and wealth of references, make this a necessity for every organic chemist. * The first reference work on named reactions to present colored schemes for easier understanding * 250 frequently used named reactions are presented in a convenient two-page layout with numerous examples * An opening list of abbreviations includes both structures and chemical names * Contains more than 10,000 references grouped by seminal papers, reviews, modifications, and theoretical works * Appendices list reactions in order of discovery, group by contemporary usage, and provide additional study tools * Extensive index quickly locates information using words found in text and drawings

Advanced Organic Chemistry

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Publisher : Academic Press
ISBN 13 : 9780121381103
Total Pages : 308 pages
Book Rating : 4.3/5 (811 download)

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Book Synopsis Advanced Organic Chemistry by : Reinhard Bruckner

Download or read book Advanced Organic Chemistry written by Reinhard Bruckner and published by Academic Press. This book was released on 2002 with total page 308 pages. Available in PDF, EPUB and Kindle. Book excerpt: A best-selling mechanistic organic chemistry text in Germany, this text's translation into English fills a long-existing need for a modern, thorough and accessible treatment of reaction mechanisms for students of organic chemistry at the advanced undergraduate and graduate level. Knowledge of reaction mechanisms is essential to all applied areas of organic chemistry; this text fulfills that need by presenting the right material at the right level.

Part B: Reactions and Synthesis

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Publisher : Springer
ISBN 13 : 366239510X
Total Pages : 972 pages
Book Rating : 4.6/5 (623 download)

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Book Synopsis Part B: Reactions and Synthesis by : Francis A. Carey

Download or read book Part B: Reactions and Synthesis written by Francis A. Carey and published by Springer. This book was released on 2013-11-27 with total page 972 pages. Available in PDF, EPUB and Kindle. Book excerpt:

March's Advanced Organic Chemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 0470084944
Total Pages : 2379 pages
Book Rating : 4.4/5 (7 download)

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Book Synopsis March's Advanced Organic Chemistry by : Michael B. Smith

Download or read book March's Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2007-01-29 with total page 2379 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of a classic in organic chemistry continues its tradition of excellence Now in its sixth edition, March's Advanced Organic Chemistry remains the gold standard in organic chemistry. Throughout its six editions, students and chemists from around the world have relied on it as an essential resource for planning and executing synthetic reactions. The Sixth Edition brings the text completely current with the most recent organic reactions. In addition, the references have been updated to enable readers to find the latest primary and review literature with ease. New features include: More than 25,000 references to the literature to facilitate further research Revised mechanisms, where required, that explain concepts in clear modern terms Revisions and updates to each chapter to bring them all fully up to date with the latest reactions and discoveries A revised Appendix B to facilitate correlating chapter sections with synthetic transformations

Friedel-Crafts Alkylation Chemistry

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Publisher :
ISBN 13 :
Total Pages : 808 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Friedel-Crafts Alkylation Chemistry by : Royston M. Roberts

Download or read book Friedel-Crafts Alkylation Chemistry written by Royston M. Roberts and published by . This book was released on 1984 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal Catalyzed Carbonylation Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 3642390161
Total Pages : 228 pages
Book Rating : 4.6/5 (423 download)

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Book Synopsis Transition Metal Catalyzed Carbonylation Reactions by : Matthias Beller

Download or read book Transition Metal Catalyzed Carbonylation Reactions written by Matthias Beller and published by Springer Science & Business Media. This book was released on 2013-08-13 with total page 228 pages. Available in PDF, EPUB and Kindle. Book excerpt: Transition Metal Catalyzed Carbonylation Reactions is a comprehensive monograph focusing on carbon monoxide usage. This book provides students and researchers in organic synthesis with a detailed discussion of carbonylation from the basics through to applications. The authors have structured the book around the types of reactions, based on the different nucleophiles involved. Scientists working in carbonylation or with carbon monoxide, as well as teachers of organic synthesis can use this book to become familiar with this important area of organic chemistry.

Selectivities in Lewis Acid Promoted Reactions

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Publisher : Springer Science & Business Media
ISBN 13 : 940092464X
Total Pages : 326 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Selectivities in Lewis Acid Promoted Reactions by : Dieter Schinzer

Download or read book Selectivities in Lewis Acid Promoted Reactions written by Dieter Schinzer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: The ASI workshop on "Selectivities in Lewis Acid Promoted Reactions" held in the Emmantina-Hotel in Athens-Glyfada, Greece, October 2-7, 1988 was held to bring some light into the darkness of Lewis acid induced processes. As such the workshop reflects some current trends in organic synthesis, where Lewis acids are becoming a powerful tool in many different modern reactions, e.g. Diels-Alder reactions, Ene reactions, Sakurai reactions, and in general silicon and tin chemistry. The objective of this meeting was to bring together most of the world experts in the field to discuss the major reactions promoted by Lewis acids. Organic synthesis will play a major role in this book connected with some fundamental mechanistic work on allylsilane and -tin chemistry. Both natural product synthesis and unnatural molecules are presented in the chapters. The book presents all the 15 invited lectures and the contributions of 15 posters. I am confident that the material presented in this book will stimulate the chemistry, which has been discussed on our meeting, around the world. The meeting and the book were only possible through a grant of the NATO Scientific Affairs Devision and financial support by the following companies: Kali Chemie (Hannover, W-Germany), E. Merck (Darmstadt, W-Germany), Sandoz (Basel, Switzerland), Schering (Berlin, W-Germany).

March's Advanced Organic Chemistry

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 1119371805
Total Pages : 2146 pages
Book Rating : 4.1/5 (193 download)

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Book Synopsis March's Advanced Organic Chemistry by : Michael B. Smith

Download or read book March's Advanced Organic Chemistry written by Michael B. Smith and published by John Wiley & Sons. This book was released on 2020-02-19 with total page 2146 pages. Available in PDF, EPUB and Kindle. Book excerpt: The completely revised and updated, definitive resource for students and professionals in organic chemistry The revised and updated 8th edition of March's Advanced Organic Chemistry: Reactions, Mechanisms, and Structure explains the theories of organic chemistry with examples and reactions. This book is the most comprehensive resource about organic chemistry available. Readers are guided on the planning and execution of multi-step synthetic reactions, with detailed descriptions of all the reactions The opening chapters of March's Advanced Organic Chemistry, 8th Edition deal with the structure of organic compounds and discuss important organic chemistry bonds, fundamental principles of conformation, and stereochemistry of organic molecules, and reactive intermediates in organic chemistry. Further coverage concerns general principles of mechanism in organic chemistry, including acids and bases, photochemistry, sonochemistry and microwave irradiation. The relationship between structure and reactivity is also covered. The final chapters cover the nature and scope of organic reactions and their mechanisms. This edition: Provides revised examples and citations that reflect advances in areas of organic chemistry published between 2011 and 2017 Includes appendices on the literature of organic chemistry and the classification of reactions according to the compounds prepared Instructs the reader on preparing and conducting multi-step synthetic reactions, and provides complete descriptions of each reaction The 8th edition of March's Advanced Organic Chemistry proves once again that it is a must-have desktop reference and textbook for every student and professional working in organic chemistry or related fields. Winner of the Textbook & Acadmic Authors Association 2021 McGuffey Longevity Award.

Across Conventional Lines

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Publisher : World Scientific
ISBN 13 : 9814498548
Total Pages : 1504 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis Across Conventional Lines by : George A Olah

Download or read book Across Conventional Lines written by George A Olah and published by World Scientific. This book was released on 2003-01-29 with total page 1504 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the course of his distinguished career spanning about half a century, George A Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance. Contents: Volume 1: Early StudiesElectrophilic Aromatic SubstitutionFriedel-Crafts ChemistryStable (Persistent), Long Lived Carbocations: General AspectsTrivalent Alkyl (Cycloalkyl) Cations (Carbenium Ions)π- and πσ-Delocalized CarbocationsHeteroatom and Metal Substituted CarbocationsCarbodicationsAromatic and Homoaromatic Cations and DicationsFive and Higher Coordinate (Nonclassical) Carbonium Ions: Controversy and SignificanceMagic Acid and Superacid ChemistrySolid Superacid CatalysisFrom Kekulé's Four-Valent Carbon to Higher Coordinate HypercarbonElectrophilic Chemistry of Saturated HydrocarbonsOnium Ions: General Aspects Volume 2: Oxonium, Sulfonium, Selenonium and Telluronium IonsAzonium IonsHalonium IonsMiscellaneous Onium IonsGitonic Onium Di(Poly)cations and Superelectrophilic ActivationSynthetic Reagents, Methods and ReactionsOxygenation and SulfurationNitration and Nitrosation ChemistryOrganofluorine ChemistryOrganometallic ChemistryPolymer ChemistryNew Approaches to Future of Hydrocarbon NeedsMiscellaneous Studies keywords: