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Acetylene And Its Polymers
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Book Synopsis Acetylene and Its Polymers by : Seth C. Rasmussen
Download or read book Acetylene and Its Polymers written by Seth C. Rasmussen and published by Springer. This book was released on 2018-07-21 with total page 136 pages. Available in PDF, EPUB and Kindle. Book excerpt: This Brief presents for the first time a detailed historical overview of the development of acetylene polymers, beginning with the initial discovery of acetylene in 1836 and continuing up through the 2000 Nobel Prize in Chemistry. The polymerization of acetylene is most commonly associated with polyacetylene, which was found to be conductive when treated with oxidizing agents such as Br2 or I2 in the mid‐to‐late 1970s. In fact, under the right conditions, oxidized polyacetylenes can exhibit conductivities into the metallic regime, thus providing the first example of an organic polymer exhibiting metallic conductivity. As a consequence, the 2000 Nobel Prize in Chemistry was awarded to Hideki Shirakawa, Alan MacDiarmid, and Alan Heeger for this pioneering research, the award citation reading “for the discovery and development of electrically conductive polymers.” Because of this, most incorrectly view polyacetylene, as well as conducting polymers in general, to originate in the 1970s. In this work, the author examines the polymerization of acetylene from early thermal polymerization studies to the ultimate production of the fully conjugated polyacetylene. Although true polyacetylene was not successfully produced until the 1950s by Giulio Natta, the polymerization of acetylene dates back to 1866 with the work of Marcellin Berthelot. These initial efforts were continued by a range of scientists to produce a polymeric material collectively given the name cuprene in 1900 by Paul Sabatier. Between the initial cuprene studies and the production of true polyacetylene, two related materials were also studied, usually referred to as polyenes and polyvinylenes. Although both of these materials could be thought of as forms of polyacetylene, neither was actually generated from the direct polymerization of acetylene. Readers will gain insight into the fact that polyacetylene and conducting organic polymers have a much longer history than commonly believed and involved the work of a significant number of Nobel Laureates.
Download or read book Polyacetylene written by James C.W. Chien and published by Elsevier. This book was released on 2012-12-02 with total page 649 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyacetylene: Chemistry, Physics, and Material Science reviews the chemistry, physics, and material science of polyacetylene. Topics covered include polymerization and crystal structure of polyacetylene, isomerization, neutral defects, and solitons. Globular morphology and the effect of heat of polymerization on polyacetylene are also discussed, along with doping and chemical reactions of polyacetylene. This book is comprised of 12 chapters and begins with an introduction to a few basic principles of polymer chemistry and solid-state physics, followed by an overview of charge-transfer salts and conducting polymers other than polyacetylene and a historical background on polyacetylene and a general description of its properties. The next chapter gives a detailed treatment of polymerization, with particular reference to the mechanisms and kinetics of acetylene polymerization and direct determination of polyacetylene molecular weight by radioquenching. The remaining chapters focus on the crystal structures and morphology of undoped polyacetylenes; methods of isomerization; spectroscopic, physical, and mechanical properties of undoped polyacetylene; and various chemical reactions of polyacetylene and polymethylacetylene. The probable mechanisms of doping are proposed and theoretical models for polyacetylene are presented. The final chapter considers a few technical applications of polyacetylene. This monograph will be of interest to chemists, physicists, and polymer scientists and engineers.
Book Synopsis Handbook of Conducting Polymers, Fourth Edition - 2 Volume Set by : John R. Reynolds
Download or read book Handbook of Conducting Polymers, Fourth Edition - 2 Volume Set written by John R. Reynolds and published by CRC Press. This book was released on 2019-11-14 with total page 1488 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last 10 years there have been major advances in fundamental understanding and applications and a vast portfolio of new polymer structures with unique and tailored properties was developed. Work moved from a chemical repeat unit structure to one more based on structural control, new polymerization methodologies, properties, processing, and applications. The 4th Edition takes this into account and will be completely rewritten and reorganized, focusing on spin coating, spray coating, blade/slot die coating, layer-by-layer assembly, and fiber spinning methods; property characterizations of redox, interfacial, electrical, and optical phenomena; and commercial applications.
Book Synopsis The Chemistry of Polymers by : John W Nicholson
Download or read book The Chemistry of Polymers written by John W Nicholson and published by Royal Society of Chemistry. This book was released on 2007-10-31 with total page 204 pages. Available in PDF, EPUB and Kindle. Book excerpt: "The Chemistry of Polymers is a concise, easy-to-read, inexpensive introduction to the subject and fulfils the need for a polymer text written from an applied angle. It covers the basics of polymer chemistry while emphasising the practical applications and is essential for those who wish to acquire a rapid overview of the field. This book covers the basics of polymer synthesis, characterisation, reaction kinetics and materials science, as well as important specialised topics such as polymer degradation, polymers and pollution, and a variety of technological developments. Now in its second edition, the book has been revised and expanded to reflect recent developments in the subject. There are, for example, extensive updates to the ""Special topics in polymer chemistry"" section, with an additional section on optically active polymers, expanded sections on ionic and co-ordination polymerisations, and copolymerisation, and additional examples of new environmental legislation are outlined wherever appropriate."
Download or read book Click Polymerization written by Anjun Qin and published by Royal Society of Chemistry. This book was released on 2018-08-28 with total page 248 pages. Available in PDF, EPUB and Kindle. Book excerpt: Click chemistry describes organic reactions which are highly efficient, regioselective and allow for mild reaction conditions. The archetypal click reaction of Cu(I)-catalyzed azide-alkyne cycloaddition (CuAAC) is used in many diverse areas and has been extensively developed for polymer synthesis, leading to the term of click polymerization. This technique enables the preparation of functional polymers with linear and topological structures that have the potential to be used in optoelectronics and biological fields. Edited by world renowned experts, Click Polymerization is the first book to comprehensively summarize this approach to polymer synthesis consolidating all the different reaction types in one resource. From the basic knowledge through to the latest developments in synthesis, chapters include transition-metal catalysed and metal-free azide-alkyne click polymerizations as well as thiol-ene, thiol-yne and thiol-epoxy click polymerizations. The book provides an authoritative guide to click polymerization techniques for graduate students and researchers interested in polymer chemistry and materials science.
Book Synopsis Conductive Polymers by : Raymond B. Seymour
Download or read book Conductive Polymers written by Raymond B. Seymour and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 236 pages. Available in PDF, EPUB and Kindle. Book excerpt: Those who recognize that our modern life style is dependent, to a large extent, on the use of organic polymers as thermal and elec trical insulators, may be surprised to learn that specific plastics may also be used as conductors of electricity. In addition to demon strating the versatility of polymers, this use as conductors will lead to developments which were not possible with other available materials of construction. This is a new field which is growing rapidly because of intensive research and developmental efforts by many different industrial, governmental and university investigators. Many of these researchers reported advances in this art at a symposium on conductive polymers sponsored by the American Chemical Society's Division of Organic Coatings and Plastics Chemistry held at the Second Chemical Congress of the North American Continent at Las Vegas, in August 1980. The proceedings of this timely symposium are presented in this book. The editor wishes to take this opportunity to express his grati tude to the authors who contributed to this book and to the ACS Organic Coatings and Plastics Division for sponsoring this effort. Raymond B. Seymour Department of Polymer Science University of Southern Mississippi Hattiesburg, MS 39401 v CONTENTS 1 New Horizons in Conductive Polymers Raymond B. Seymour Synthesis and Characterization of Conductive 7 Palladium Containing Polyimide Films • T.L. Wohlford. J. Schaff. L.T. Taylor.
Book Synopsis Modern Acetylene Chemistry by : Peter J. Stang
Download or read book Modern Acetylene Chemistry written by Peter J. Stang and published by John Wiley & Sons. This book was released on 2008-09-26 with total page 527 pages. Available in PDF, EPUB and Kindle. Book excerpt: This comprehensive handbook presents the full potential of modern acetylene chemistry, from organic synthesis through materials science to bioorganic chemistry. K. Houk, H. Hopf, P. Stang, K. M. Nicholas, N. Schore, M. Regitz, K. C. Nicolaou, R. Gleiter, L. Scott, R. Grubbs, H. Iwamura, J. Moore, and F. Diederich - internationally renowned authors introduce the reader, in a didactically skilful manner, to the state-of-the-art in alkyne chemistry. Emphasis is placed on presenting carefully selected and instructive examples as well as essential references to the original literature. Special benefits: Each chapter is rounded off by useful experimental procedures.
Book Synopsis Manufacture of Fine Chemicals from Acetylene by : Sifang Li
Download or read book Manufacture of Fine Chemicals from Acetylene written by Sifang Li and published by Walter de Gruyter GmbH & Co KG. This book was released on 2021-07-19 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt: The book gives a complete overview on today’s research, development and industrialization of fine chemicals from acetylene. The author provides a comprehensive methodology by covering derivatives from acetylene reacting with formaldehyde, alcohol, ketone, halogen and acetic acid. The book offers extensive and practical reference work for chemists and chemical engineers as well as university teachers and students.
Book Synopsis The Chemistry of Acetylene by : Julius Arthur Nieuwland
Download or read book The Chemistry of Acetylene written by Julius Arthur Nieuwland and published by . This book was released on 1945 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Stereoselective Polymerization with Single-Site Catalysts by : Lisa S. Baugh
Download or read book Stereoselective Polymerization with Single-Site Catalysts written by Lisa S. Baugh and published by CRC Press. This book was released on 2007-11-29 with total page 698 pages. Available in PDF, EPUB and Kindle. Book excerpt: New synthetic techniques allow chemists to modify polymer microstructures more precisely than ever, making it possible to design materials that meet increasingly demanding performance requirements. Written and edited by experts in the field, Stereoselective Polymerization with Single-Site Catalysts reviews how the relative stereochemistry of
Download or read book Technical Translations written by and published by . This book was released on 1959 with total page 802 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Acetylene Chemistry by : François Diederich
Download or read book Acetylene Chemistry written by François Diederich and published by John Wiley & Sons. This book was released on 2006-03-06 with total page 528 pages. Available in PDF, EPUB and Kindle. Book excerpt: Acetylenes are an important and valuable class of compounds in organic synthesis. This book expands on this historically well-established concept, while incorporating the many new developments that have widened the number of applications in this field. It remains the only handbook available that embodies all the important facets of acetylene chemistry. Following the first section on synthesis, the leading authors deal with advanced materials before turning to the properties and theory of acetylenes, while a final section looks at the biological aspects. With its range of experimental procedures, this book is a practical aid for both organic and organometallic chemists, as well as for materials scientists, biochemists, and industrial chemists.
Download or read book Nuclear Science Abstracts written by and published by . This book was released on 1964 with total page 1522 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Functional Monomers and Polymers, Second Edition by : Kiichi Takemoto
Download or read book Functional Monomers and Polymers, Second Edition written by Kiichi Takemoto and published by CRC Press. This book was released on 1997-07-17 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt: Highlighting solutions to more recently identified problems, this work focuses on the chemistry and technology involved in the functionalization of monomers, and the preparation and processing of polymers to serve specific material needs. It reflects the advances that have occurred in the field since the publication of the first edition.
Book Synopsis Handbook of Advanced Electronic and Photonic Materials and Devices, Ten-Volume Set by : Hari Singh Nalwa
Download or read book Handbook of Advanced Electronic and Photonic Materials and Devices, Ten-Volume Set written by Hari Singh Nalwa and published by Academic Press. This book was released on 2000-10-09 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Vol. 1: Semiconductors;Vol. 2: Semiconductors Devices;Vol. 3: High-Tc Superconductors and Organic Conductors; Vol. 4: Ferroelectrics and Dielectrics; Vol. 5: Chalcogenide Glasses and Sol-Gel Materials; Vol. 6 Nanostructured Materials; Vol. 7: Liquid Crystals, Display and Laser Materials; Vol. 8: Conducting Polymers; Vol. 9: Nonlinear Optical Materials; Volume 10: Light-Emitting Diodes, Lithium Batteries and Polymer Devices
Book Synopsis The Chemistry of Acetylene by : Julius Arthur Nieuwland
Download or read book The Chemistry of Acetylene written by Julius Arthur Nieuwland and published by . This book was released on 1945 with total page 242 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook of Polymer Synthesis, Characterization, and Processing by : Enrique Saldivar-Guerra
Download or read book Handbook of Polymer Synthesis, Characterization, and Processing written by Enrique Saldivar-Guerra and published by John Wiley & Sons. This book was released on 2013-03-04 with total page 660 pages. Available in PDF, EPUB and Kindle. Book excerpt: Covering a broad range of polymer science topics, Handbook of Polymer Synthesis, Characterization, and Processing provides polymer industry professionals and researchers in polymer science and technology with a single, comprehensive handbook summarizing all aspects involved in the polymer production chain. The handbook focuses on industrially important polymers, analytical techniques, and formulation methods, with chapters covering step-growth, radical, and co-polymerization, crosslinking and grafting, reaction engineering, advanced technology applications, including conjugated, dendritic, and nanomaterial polymers and emulsions, and characterization methods, including spectroscopy, light scattering, and microscopy.
