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A Transient Kinetic And Infrared Study Of Carbon Monoxide Hydrogenation On Supported Platinum Catalysts
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Book Synopsis A Transient Kinetic and Infrared Study of Carbon Monoxide Hydrogenation on Supported Platinum Catalysts by : Thomas K. Leong
Download or read book A Transient Kinetic and Infrared Study of Carbon Monoxide Hydrogenation on Supported Platinum Catalysts written by Thomas K. Leong and published by . This book was released on 1986 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Simultaneous Kinetic and Infrared Studies of Carbon Monoxide Oxidation on Supported Platinum Catalyst by : Kwang-Ho Park
Download or read book Simultaneous Kinetic and Infrared Studies of Carbon Monoxide Oxidation on Supported Platinum Catalyst written by Kwang-Ho Park and published by . This book was released on 1987 with total page 522 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Transient Infrared Studies of Carbon Monoxide Oxidation on a Supported Platinum Catalyst by : Stephen Mark Dwyer
Download or read book Transient Infrared Studies of Carbon Monoxide Oxidation on a Supported Platinum Catalyst written by Stephen Mark Dwyer and published by . This book was released on 1980 with total page 278 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reduction of Nitric Oxide by Carbon Monoxide Over a Silica Supported Platinum Catalyst by : D'Arcy Harold Lorimer
Download or read book Reduction of Nitric Oxide by Carbon Monoxide Over a Silica Supported Platinum Catalyst written by D'Arcy Harold Lorimer and published by . This book was released on 1978 with total page 330 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis An in Situ Infrared Study of Carbon Monoxide Oxidation on a Supported Platinum Catalyst by : Irene Beatrice Ang
Download or read book An in Situ Infrared Study of Carbon Monoxide Oxidation on a Supported Platinum Catalyst written by Irene Beatrice Ang and published by . This book was released on 1980 with total page 118 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Kinetic and Infrared Study of Carbon Monoxide Adsorption and Hydrogenation on Palladium Catalysts by : Shi-yann Wang
Download or read book A Kinetic and Infrared Study of Carbon Monoxide Adsorption and Hydrogenation on Palladium Catalysts written by Shi-yann Wang and published by . This book was released on 1980 with total page 402 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis An Infrared Study of the Oxidation of Carbon Monoxide on a Platinum Catalyst by : Henry Douglas Cochran
Download or read book An Infrared Study of the Oxidation of Carbon Monoxide on a Platinum Catalyst written by Henry Douglas Cochran and published by . This book was released on 1973 with total page 396 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Direct Observation of the Kinetically Relevant Site of CO Hydrogenation on Supported Ru Catalyst at 700 K by Time-Resolved FT-IR Spectroscopy by :
Download or read book Direct Observation of the Kinetically Relevant Site of CO Hydrogenation on Supported Ru Catalyst at 700 K by Time-Resolved FT-IR Spectroscopy written by and published by . This book was released on 2008 with total page 29 pages. Available in PDF, EPUB and Kindle. Book excerpt: Time-resolved FT-IR spectra of carbon monoxide hydrogenation over alumina-supported ruthenium particles were recorded on themillisecond time scale at 700 K using pulsed release of CO and a continuous flow of H2/N2 (ratio 0.067 or 0.15, 1 atm total pressure). Adsorbed carbon monoxide was detected along with gas phase products methane (3016 and 1306 cm-1), water (1900 +- 1300 cm-1), and carbon dioxide (2348 cm-1). Aside from adsorbed CO, no other surface species were observed. The rate of formation of methane is 2.5 +- 0.4 s-1 and coincides with the rate of carbon dioxide growth (3.4 +- 0.6 s-1), thus indicating that CH4 and CO2 originate from a common intermediate. The broad band of adsorbed carbon monoxide has a maximum at 2010 cm-1 at early times (36 ms) that shifts gradually to 1960 cm-1 over a period of 3 s as a result of the decreasing surface concentration of CO. Kinetic analysis of the adsorbed carbon monoxide reveals that surface sites absorbing at the high frequency end of the infrared band are temporally linked to gas phase product growth. Specifically, a (linear) CO site at 2026 cm-1 decays with a rate constant of 2.9 +- 0.1 s-1, which coincides with the rise constant of CH4. This demonstrates that the linear CO site at 2026 cm-1 is the kinetically most relevant one for the rate-determining CO dissociation step under reaction conditions at 700 K.
Book Synopsis An Infrared and Kinetic Study of NO Reduction by CO Over a Pt Catalyst by : Charles Nicholas Ludvik
Download or read book An Infrared and Kinetic Study of NO Reduction by CO Over a Pt Catalyst written by Charles Nicholas Ludvik and published by . This book was released on 1975 with total page 220 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Kinetic Study of the Reactions and Interactions of Carbon Monoxide, Oxygen and Hydrogen Over a Platinum-alumina Catalyst by : Thomas Charles Fitzgerald
Download or read book A Kinetic Study of the Reactions and Interactions of Carbon Monoxide, Oxygen and Hydrogen Over a Platinum-alumina Catalyst written by Thomas Charles Fitzgerald and published by . This book was released on 1979 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Masters Theses in the Pure and Applied Sciences by : Wade H. Shafer
Download or read book Masters Theses in the Pure and Applied Sciences written by Wade H. Shafer and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Masters Theses in the Pure and Applied Sciences was first conceived, published, and disseminated by the Center for Information and Numerical Data Analysis and Synthesis (CINDAS) * at Purdue University in 1957, starting its coverage of theses with the academic year 1955. Beginning with Volume 13, the printing and dissemination phases of the activity were transferred to University Microfilms/Xerox of Ann Arbor, Michigan, with the thougtit that such an arrangement would be more beneficial to the academic and general scientific and technical community. After five years of this joint undertaking we had concluded that it was in the interest of all con cerned if the printing and distribution of the volumes were handled by an interna tional publishing house to assure improved service and broader dissemination. Hence, starting with Volume 18, Masters Theses in the Pure and Applied Sciences has been disseminated on a worldwide basis by Plenum Publishing Cor poration of New York, and in the same year the coverage was broadened to include Canadian universities. All back issues can also be ordered from Plenum. We have reported in Volume 31 (thesis year 1986) a total of 11 ,480 theses titles trom 24 Canadian and 182 United States universities. We are sure that this broader base tor these titles reported will greatly enhance the value ot this important annual reterence work. While Volume 31 reports theses submitted in 1986, on occasion, certain univer sities do re port theses submitted in previousyears but not reported at the time.
Book Synopsis Time-Resolved FT-IR Spectroscopy of CO Hydrogenation OverSupported Ru Catalyst at 700K. by :
Download or read book Time-Resolved FT-IR Spectroscopy of CO Hydrogenation OverSupported Ru Catalyst at 700K. written by and published by . This book was released on 2006 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Time-resolved FT-IR spectra of carbon monoxide hydrogenation over alumina-supported ruthenium were recorded on the millisecond timescale at 703 K using various H2 concentrations (1 atm total pressure). Adsorbed carbon monoxide was detected along with gas phase products methane (3016 and 1306 cm−1), water (sharp bands from 1900 - 1300 cm−1), and carbon dioxide (2348 cm−1). No other surface species were detected other than adsorbed carbon monoxide. The rate of formation of methane (2.5 ± 0.4 s−1) coincides with the rate of formation of carbon dioxide (3.4 ± 0.6 s−1), and bands due to water are observed to grow in over time. These results establish that methane and carbon dioxide originate from the same intermediate. The adsorbed carbon monoxide band is broad and unsymmetrical with a maximum at 2010 cm−1 in spectra observed at 36 ms that shifts over 3000 ms to 1960 cm−1 due to decreasing amounts of adsorbed carbon monoxide. Kinetic analysis of the adsorbed carbon monoxide band reveals that only a portion of the band can be temporally linked to gas phase products that we observe over the first 1000 ms of catalysis. This result suggests that we are observing dispersive kinetics, which is most likely due to heterogeneity of the surface environment.
Book Synopsis An Infrared Study of the Hydrogenation of Carbon Dioxide Over Supported Rhodium Catalysts by : Michael Allen Henderson
Download or read book An Infrared Study of the Hydrogenation of Carbon Dioxide Over Supported Rhodium Catalysts written by Michael Allen Henderson and published by . This book was released on 1984 with total page 218 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Gravimetric Adsorption Study of Hydrogen and Carbon Monoxide on a Supported Ruthenium Catalyst by : Wayne Allen Bollinger
Download or read book Gravimetric Adsorption Study of Hydrogen and Carbon Monoxide on a Supported Ruthenium Catalyst written by Wayne Allen Bollinger and published by . This book was released on 1976 with total page 188 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Kinetic Study of the Reduction of Nitric Oxide by Carbon Monoxide Over an Alumina Supported Platinum Catalyst by : S. Tariq Hussain
Download or read book A Kinetic Study of the Reduction of Nitric Oxide by Carbon Monoxide Over an Alumina Supported Platinum Catalyst written by S. Tariq Hussain and published by . This book was released on 1988 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Elementary-step Modeling and Transient FTIR Studies of Carbon Monoxide and Ethylene Oxidation on Silicia-supported Platinum and Rhodium Catalysts by : Ravindra Sant
Download or read book Elementary-step Modeling and Transient FTIR Studies of Carbon Monoxide and Ethylene Oxidation on Silicia-supported Platinum and Rhodium Catalysts written by Ravindra Sant and published by . This book was released on 1988 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Kinetic Study on the Adsorption and Reaction of Hydrogen Over Silica-supported Ruthenium and Silver-ruthenium Catalysts During the Hydrogenation of Carbon Monoxide by : David Paul VanderWiel
Download or read book A Kinetic Study on the Adsorption and Reaction of Hydrogen Over Silica-supported Ruthenium and Silver-ruthenium Catalysts During the Hydrogenation of Carbon Monoxide written by David Paul VanderWiel and published by . This book was released on 1998 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt: The apparent activation energy for methanation decreased from about 23 kcal/mol for Ru/SiO2 to about 18 kcal/mol for the Ag-Ru/SiO2 series. These results show good correlation with previous hydrogen microcalorimetry measurements on the same catalysts by our group. The mechanism of the synergistic effect of Ag on Ru is presented in terms of "portal site mediated adsorption", whereby hydrogen is supplied to the catalyst surface by rapid dissociative adsorption occurring at low coordination sites which are preferentially blocked by Ag in bimetallic systems.
