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A Novel Initiating System For Controlled Radical Polymerization Of Methyl Methacrylate
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Book Synopsis A Novel Initiating System for Controlled Radical Polymerization of Methyl Methacrylate by : Mustafa Çıkılmazkaya
Download or read book A Novel Initiating System for Controlled Radical Polymerization of Methyl Methacrylate written by Mustafa Çıkılmazkaya and published by . This book was released on 2003 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook of Vinyl Polymers by : Munmaya Mishra
Download or read book Handbook of Vinyl Polymers written by Munmaya Mishra and published by CRC Press. This book was released on 2008-07-24 with total page 784 pages. Available in PDF, EPUB and Kindle. Book excerpt: Radical polymerization is one of the most widely used means of producing vinyl polymers, supporting a myriad of commercial uses. Maintaining the quality of the critically acclaimed first edition, the Handbook of Vinyl Polymers: Radical Polymerization, Process, and Technology, Second Edition provides a fully updated, single-volume source on the chemistry, technology, and applications of vinyl polymers. Emphasizes radical initiating systems and mechanisms of action... Written by renowned researchers in the field, this handbook is primarily concerned with the physical and organic chemistry of radical vinyl polymerization. The authors survey the most recent advances, processing methods, technologies, and applications of free radical vinyl polymerization. The book features thorough coverage of polymer functionalization, photo initiation, block and graft copolymers, and polymer composites. Analyzes living/controlled radical polymerization, one of the latest developments in the field... Combining fundamental aspects with the latest advances, processing methods, and applications in free radical vinyl polymerization and polymer technology, this invaluable reference provides a unified, in-depth, and innovative perspective of radical vinyl polymerization.
Book Synopsis Controlled Radical Polymerisation Using Novel Chain Transfer Agents and Initiating Systems by :
Download or read book Controlled Radical Polymerisation Using Novel Chain Transfer Agents and Initiating Systems written by and published by . This book was released on 2008 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis New Methods of Polymer Synthesis by : J.R. Ebdon
Download or read book New Methods of Polymer Synthesis written by J.R. Ebdon and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 348 pages. Available in PDF, EPUB and Kindle. Book excerpt: Few polymer chemists have much familiarity with recent developments in the synthesis of speciality polymers. This volume provides up-to-date reviews of areas of current interest and is directed at polymer chemists in the academic world and industry.
Download or read book Nitroxides written by Olivier Ouari and published by Royal Society of Chemistry. This book was released on 2021-05-13 with total page 611 pages. Available in PDF, EPUB and Kindle. Book excerpt: Nitroxides are versatile small organic molecules possessing a stabilised free radical. With their unpaired electron spin they display a unique reactivity towards various environmental factors, enabling a diverse range of applications. They have uses as synthetic tools, such as catalysts or building blocks; imaging agents and probes in biomedicine and materials science; for medicinal antioxidant applications; and in energy storage. Polynitroxides (polymers bearing pendant nitroxide sidechains) have been used in organic radical batteries, oxidation catalysts and in exchange reactions for constructing complex architectures. Chapters in this book cover the synthesis of nitroxides, EPR studies and magnetic resonance applications, physiochemical studies, and applications including in batteries, imaging and organic synthesis. With contributions from leaders in the field, Nitroxides will be of interest to graduate students and researchers across chemistry, physics, biology and materials science.
Book Synopsis Preparation and Evaluation of Novel Initiators for the Thermally Mild Living and Controlled Free Radical Polymerization of Methacrylates by : Omari E Ansong
Download or read book Preparation and Evaluation of Novel Initiators for the Thermally Mild Living and Controlled Free Radical Polymerization of Methacrylates written by Omari E Ansong and published by . This book was released on 2008 with total page 153 pages. Available in PDF, EPUB and Kindle. Book excerpt: A number of nitroxide adducts and N-acyloxytrialkylammonium salts were prepared, isolated, characterized and evaluated as initiators for the controlled and living free radical polymerization of methacrylate and dimethacrylate monomers under mildly thermal and photochemical conditions. The initiators and polymerization methods that were developed could potentially be used for improving resins employed in dental applications. Using very easy synthesis strategies, the following nitroxide initiators were prepared in high purity, isolated and characterized: 1-Benzoylperoxy-2,2,6,6-tetramethyl-piperidine (BPO/TEMPO), 1-(2'-Cyano-2'-propoxy)-2,2,6,6-tetramethylpiperidine (AIBN/TEMPO), 1,1-ditertbutyl-1-(1-methyl-1-cyanoethoxy)-amine (AIBN/DBN), 1,1-ditertbutyl-1-(benzoylperoxy)-amine (BPO/DBN) and 2,2,6,6,-tetramethyl-4-oxo-1-(1-methyl-1-cyanoethoxy)-piperidine (AIBN/4-OXO-TEMPO). Using H2SO4 additive and an improved unimolecular initiation in nitroxide mediated polymerization, living and controlled polymerization of methyl methacrylate (MMA), tri-ethylene glycol dimethacrylate (TEGDMA) and ethoxylated bisphenol A dimethacrylate (EBPADMA) were accomplished, for the first time ever for most of the initiators. Linear polymers (PMMA) were produced in high yield (93 %) under mildly thermal conditions (T = 70 oC) and with excellent attributes: (PDI = 1.04-1.26), Mn (87000), Tg (122-128 oC), Td (290-410 oC). Highly crosslinked polymers, poly(TEGDMA) and poly(EBPADMA), were produced in high yield (100 %) with Td (350-400 oC). The initiators were stable for a year and half at 0 oC. Two routes were investigated for the preparation of N-acyloxytrialkylammonium salts. The more efficient of these routes was used to make several novel analogs of the salts. The salts were evaluated for the free radical polymerization of MMA, TEGDMA and EBPADMA under mildly thermal (T = 60 oC) conditions with and without H2SO4 additive. Polymerization rate, yield and polymer attributes all improved upon application of H2SO4 additive. PMMA was produced with excellent attributes (PDI = 1.01-1.06), Mn (96,000-122000), Td (330-385) and Tg (127-134). Highly crosslinked poly(TEGDMA) and poly(EBPADMA) were produced with Td ranges of 300-374 oC and 375-411 oC respectively.
Book Synopsis The Chemistry of Radical Polymerization by : Graeme Moad
Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Book Synopsis Macromolecular Syntheses by : Charles Gilbert Overberger
Download or read book Macromolecular Syntheses written by Charles Gilbert Overberger and published by . This book was released on 2002 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is an up-to-date collection of presentations and posters given at a tutorial and workshop sponsored by the Polymer Division of the American Chemical Society. The material included encompasses recent research results, overviews of critical areas and short presentations in the form of posters and preprints. The book is targeted at established workers in the field of fluoropolymers as well as those wishing to develop a quick understanding of current knowledge and trends in this important field.
Book Synopsis Controlled/living Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Controlled/living Radical Polymerization written by Krzysztof Matyjaszewski and published by Academic. This book was released on 2009 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Recent progress in the field of controlled/living radical polymerization.
Book Synopsis The Controlled Radical Polymerization of Methyl Methacrylate with Iron (III) \ Triphenylphosphine Compexes by : Berkant Bedri
Download or read book The Controlled Radical Polymerization of Methyl Methacrylate with Iron (III) \ Triphenylphosphine Compexes written by Berkant Bedri and published by . This book was released on 2002 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes by : Fumin Ma
Download or read book The Atom Transfer Radical Polymerization of Methyl Methacrylate in Ionic Liquid Media of 1-Methylimidazolium Alkyltes written by Fumin Ma and published by . This book was released on 2011 with total page 7 pages. Available in PDF, EPUB and Kindle. Book excerpt: Three brønsted acidic ionic liquids, 1-methylimidazolium acetate ([Hmim][CH3COO]), 1-methylimidazolium propionate ([Hmim][CH3CH2COO]) and 1-methylimidazolium butyrate ([Hmim][CH3CH2CH2COO]) were used as reaction medium for atom transfer radical polymerization of methyl methacrylate with ethyl 2-bromoisobutyrate (EBiB)/CuBr as the initiating system. Kinetic studies, chain extension and block copolymerization confirmed the well-controlled manner of these polymerizations in three brønsted acidic ionic liquids. The reactions were fast and the polydispersities of the polymers were quite narrow (1.10
Book Synopsis Self Initiated Polymerization of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method by : Hanim Hafizah Mazlan
Download or read book Self Initiated Polymerization of Methyl Methacrylate Using Atom Teransfer Radical Polymerization Method written by Hanim Hafizah Mazlan and published by . This book was released on 2008 with total page 48 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook of Radical Polymerization by : Krzysztof Matyjaszewski
Download or read book Handbook of Radical Polymerization written by Krzysztof Matyjaszewski and published by John Wiley & Sons. This book was released on 2003-04-14 with total page 934 pages. Available in PDF, EPUB and Kindle. Book excerpt: Klassische und moderne Verfahren der radikalischen Polymerisation: In diesem handlichen Band finden Sie Antworten auf theoretische und praktische Fragen. Neben grundlegenden Ausführungen zur Einteilung radikalischer Polymere sind Angaben über die wichtigsten experimentellen Verfahren zur Synthese, Reinigung und Charakterisierung von Polymeren enthalten. Interessante Zugabe: ein Abriß der Geschichte der Radikalkettenpolymerisation.
Book Synopsis Trichlorocyanuric acid initiated atom transfer radical polymerization of methyl methacrylate by : Deniz Yuluğ
Download or read book Trichlorocyanuric acid initiated atom transfer radical polymerization of methyl methacrylate written by Deniz Yuluğ and published by . This book was released on 2004 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Principles of Polymerization by : George G. Odian
Download or read book Principles of Polymerization written by George G. Odian and published by Wiley-Interscience. This book was released on 1991-11 with total page 808 pages. Available in PDF, EPUB and Kindle. Book excerpt: Describes the physical and organic chemistry of the reactions by which polymer molecules are synthesized. Begins by introducing the characteristics which distinguish polymers from their much smaller sized homologs. Proceeds to a detailed study of three types of polymerization reactions: step, chain and ring-opening. Reactions are characterized as to their kinetic and thermodynamic features, their scope and utility for synthesis of different types of polymer structures, and the process conditions which are used to carry them out. Assumes a background in organic and physical chemistry and can serve as either a self-teaching guide to polymers for the beginner or as a handy reference for the experienced polymer chemist. Each chapter includes a selection of problems to aid learning and a solutions manual is available on request.
Book Synopsis Cu0-catalyzed Surface-initiated Controlled Radical Polymerization of 2-hydroxyethyl Methacrylate by : Joan Jornod
Download or read book Cu0-catalyzed Surface-initiated Controlled Radical Polymerization of 2-hydroxyethyl Methacrylate written by Joan Jornod and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Handbook of Phase Transfer Catalysis by : Y. Sasson
Download or read book Handbook of Phase Transfer Catalysis written by Y. Sasson and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 579 pages. Available in PDF, EPUB and Kindle. Book excerpt: Phase transfer catalysis is a sophisticated chemical technique which can be used to perform a variety of chemical reactions under mild conditions and with improved control. Since the concept was developed, both the theoretical and practical synthetic applications have seen considerable development, to the point where the technique can be applied to many areas of chemistry. Thus, phase transfer methods are now utilized in many applications, from research chemistry to full-scale production, where the benefits of faster, cleaner and more selective reactions are required. In this new book, the editors have brought together a range of contributors, each of whom is working at the forefront of the technology, to provide a clear, concise and ahtoritative review of this important area of chemistry. Industrial and academic chemists working on the synthesis, scale-up, production or analysis of a wide range of chemical products will find this book an essential reference on phase transfer technology.
