Redox-Active Ligands

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Publisher : John Wiley & Sons
ISBN 13 : 352783088X
Total Pages : 373 pages
Book Rating : 4.5/5 (278 download)

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Book Synopsis Redox-Active Ligands by : Marine Desage-El Murr

Download or read book Redox-Active Ligands written by Marine Desage-El Murr and published by John Wiley & Sons. This book was released on 2024-01-31 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Redox-Active Ligands Authoritative resource showcasing a new family of ligands that can lead to better catalysts and promising applications in organic synthesis Redox-Active Ligands gives a comprehensive overview of the unique features of redox-active ligands, describing their structure and synthesis, the characterization of their coordination complexes, and important applications in homogeneous catalysis. The work reflects the diversity of the subject by including ongoing research spanning coordination chemistry, organometallic chemistry, bioinspired catalysis, proton and electron transfer, and the ability of such ligands to interact with early and late transition metals, lanthanides, and actinides. The book is divided into three parts, devoted to introduction and concepts, applications, and case studies. After the introduction on key concepts related to the field, and the different types of ligands and complexes in which ligand-centered redox activity is commonly observed, mechanistic and computational studies are described. The second part focuses on catalytic applications of redox-active complexes, including examples from radical transformations, coordination chemistry and organic synthesis. Finally, case studies of redox-active guanidine ligands, and of lanthanides and actinides are presented. Other specific sample topics covered include: An overview of the electronic features of redox-active ligands, covering their historical perspective and biological background The versatility and mode of action of redox-active ligands, which sets them apart from more classic and tunable ligands such as phosphines or N-heterocyclic carbenes Preparation and catalytic applications of complexes of stable N-aryl radicals Metal complexes with redox-active ligands in H+/e- transfer transformations By providing up-to-date information on important concepts and applications, Redox-Active Ligands is an essential reading for researchers working in organometallic and coordination chemistry, catalysis, organic synthesis, and (bio)inorganic chemistry, as well as newcomers to the field.

Organometallic Reactions

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Publisher : John Wiley & Sons
ISBN 13 : 9780471061304
Total Pages : 470 pages
Book Rating : 4.0/5 (613 download)

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Book Synopsis Organometallic Reactions by : Ernest I. Becker

Download or read book Organometallic Reactions written by Ernest I. Becker and published by John Wiley & Sons. This book was released on 1971 with total page 470 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Handbook of Transition Metal Polymerization Catalysts

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Publisher : John Wiley & Sons
ISBN 13 : 1119242215
Total Pages : 895 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Handbook of Transition Metal Polymerization Catalysts by : Ray Hoff

Download or read book Handbook of Transition Metal Polymerization Catalysts written by Ray Hoff and published by John Wiley & Sons. This book was released on 2018-04-20 with total page 895 pages. Available in PDF, EPUB and Kindle. Book excerpt: Including recent advances and historically important catalysts, this book overviews methods for developing and applying polymerization catalysts – dealing with polymerization catalysts that afford commercially acceptable high yields of polymer with respect to catalyst mass or productivity. • Contains the valuable data needed to reproduce syntheses or use the catalyst for new applications • Offers a guide to the design and synthesis of catalysts, and their applications in synthesis of polymers • Includes the information essential for choosing the appropriate reactions to maximize yield of polymer synthesized • Presents new chapters on vanadium catalysts, Ziegler catalysts, laboratory homopolymerization, and copolymerization

Main Group Strategies towards Functional Hybrid Materials

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Publisher : John Wiley & Sons
ISBN 13 : 1119235979
Total Pages : 557 pages
Book Rating : 4.1/5 (192 download)

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Book Synopsis Main Group Strategies towards Functional Hybrid Materials by : Thomas Baumgartner

Download or read book Main Group Strategies towards Functional Hybrid Materials written by Thomas Baumgartner and published by John Wiley & Sons. This book was released on 2018-03-12 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: Showcases the highly beneficial features arising from the presence of main group elements in organic materials, for the development of more sophisticated, yet simple advanced functional materials Functional organic materials are already a huge area of academic and industrial interest for a host of electronic applications such as Organic Light-Emitting Diodes (OLEDs), Organic Photovoltaics (OPVs), Organic Field-Effect Transistors (OFETs), and more recently Organic Batteries. They are also relevant to a plethora of functional sensory applications. This book provides an in-depth overview of the expanding field of functional hybrid materials, highlighting the incredibly positive aspects of main group centers and strategies that are furthering the creation of better functional materials. Main Group Strategies towards Functional Hybrid Materials features contributions from top specialists in the field, discussing the molecular, supramolecular and polymeric materials and applications of boron, silicon, phosphorus, sulfur, and their higher homologues. Hypervalent materials based on the heavier main group elements are also covered. The structure of the book allows the reader to compare differences and similarities between related strategies for several groups of elements, and to draw crosslinks between different sections. The incorporation of main group elements into functional organic materials has emerged as an efficient strategy for tuning materials properties for a wide range of practical applications Covers molecular, supramolecular and polymeric materials featuring boron, silicon, phosphorus, sulfur, and their higher homologues Edited by internationally leading researchers in the field, with contributions from top specialists Main Group Strategies towards Functional Hybrid Materials is an essential reference for organo-main group chemists pursuing new advanced functional materials, and for researchers and graduate students working in the fields of organic materials, hybrid materials, main group chemistry, and polymer chemistry.

Ruthenium Complexes

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Publisher : John Wiley & Sons
ISBN 13 : 3527339574
Total Pages : 344 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Ruthenium Complexes by : Alvin A. Holder

Download or read book Ruthenium Complexes written by Alvin A. Holder and published by John Wiley & Sons. This book was released on 2018-02-27 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by a team of highly respected researchers combining their expertise in chemistry, physics, and medicine, this book focuses on the use of rutheniumcontaining complexes in artificial photosynthesis and medicine. Following a brief introduction to the basic coordination chemistry of ruthenium complexes and their synthesis in section one, as well as their photophysical and photochemical properties, the authors discuss in detail the major concepts of artificial photosynthesis and mechanisms of hydrogen production and water oxidation with ruthenium in section two. The third section of the text covers biological properties and important medical applications of ruthenium complexes as therapeutic agents or in diagnostic imaging. Aimed at stimulating research in this active field, this is an invaluable information source for researchers in academia, health research institutes and governmental departments working in the field of organometallic chemistry, green and sustainable chemistry as well as medicine/drug discovery, while equally serving as a useful reference also for scientists in industry.

Spin States in Biochemistry and Inorganic Chemistry

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Publisher : John Wiley & Sons
ISBN 13 : 1118898281
Total Pages : 500 pages
Book Rating : 4.1/5 (188 download)

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Book Synopsis Spin States in Biochemistry and Inorganic Chemistry by : Marcel Swart

Download or read book Spin States in Biochemistry and Inorganic Chemistry written by Marcel Swart and published by John Wiley & Sons. This book was released on 2015-09-22 with total page 500 pages. Available in PDF, EPUB and Kindle. Book excerpt: It has long been recognized that metal spin states play a central role in the reactivity of important biomolecules, in industrial catalysis and in spin crossover compounds. As the fields of inorganic chemistry and catalysis move towards the use of cheap, non-toxic first row transition metals, it is essential to understand the important role of spin states in influencing molecular structure, bonding and reactivity. Spin States in Biochemistry and Inorganic Chemistry provides a complete picture on the importance of spin states for reactivity in biochemistry and inorganic chemistry, presenting both theoretical and experimental perspectives. The successes and pitfalls of theoretical methods such as DFT, ligand-field theory and coupled cluster theory are discussed, and these methods are applied in studies throughout the book. Important spectroscopic techniques to determine spin states in transition metal complexes and proteins are explained, and the use of NMR for the analysis of spin densities is described. Topics covered include: DFT and ab initio wavefunction approaches to spin states Experimental techniques for determining spin states Molecular discovery in spin crossover Multiple spin state scenarios in organometallic reactivity and gas phase reactions Transition-metal complexes involving redox non-innocent ligands Polynuclear iron sulfur clusters Molecular magnetism NMR analysis of spin densities This book is a valuable reference for researchers working in bioinorganic and inorganic chemistry, computational chemistry, organometallic chemistry, catalysis, spin-crossover materials, materials science, biophysics and pharmaceutical chemistry.

Annual Review of Physical Chemistry

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Publisher :
ISBN 13 : 9780824310240
Total Pages : 560 pages
Book Rating : 4.3/5 (12 download)

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Book Synopsis Annual Review of Physical Chemistry by : Henry Eyring

Download or read book Annual Review of Physical Chemistry written by Henry Eyring and published by . This book was released on 1973 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Mechanistic Processes in Organometallic Chemistry

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Author :
Publisher : Faraday Discussions
ISBN 13 : 9781788016773
Total Pages : 502 pages
Book Rating : 4.0/5 (167 download)

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Book Synopsis Mechanistic Processes in Organometallic Chemistry by :

Download or read book Mechanistic Processes in Organometallic Chemistry written by and published by Faraday Discussions. This book was released on 2020-01-02 with total page 502 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry underpins the majority of homogeneous catalysis, which is used in a range of areas from the multi-tonne-scale synthesis of polymers to the discovery and preparation of high-value molecules, such as pharmaceuticals and agrochemicals. The development and/or optimisation of many of these catalytic applications crucially depends on the discovery and understanding of mechanistic processes in organometallic chemistry. As such, mechanistic investigations have played a key role in the field of organometallic chemistry since its early days, but the recent and rapid growth in transition-metal catalysed organic reactions, where fundamental mechanistic insight is frequently lagging behind synthetic developments, emphasises their contemporary importance. In addition, there have been many significant developments recently in the physical methods that can be used to gain mechanistic understanding in organometallic chemistry (e.g. NMR spectroscopic developments, such as new hyperpolarisation techniques, in-situ IR for reaction monitoring, novel methodologies for kinetic analysis, and novel computational approaches). This volume focusses on mechanistic studies coupled with novel experimental and computational methods and brings together experts with a wide range of interests and backgrounds, including those developing new physical methods for mechanistic investigations and the potential end users of these methods. In this volume, the topics covered include: Physical methods for mechanistic understanding Understanding unusual element-element bond formation and activation Computational and theoretical approaches for mechanistic understanding Mechanistic insight into organic and industrial transformations

Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands

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Author :
Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 458 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands by : Charles Andrew McAuliffe

Download or read book Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands written by Charles Andrew McAuliffe and published by John Wiley & Sons. This book was released on 1973 with total page 458 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Transition Metal Complexes of Neutral Eta1-Carbon Ligands

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Author :
Publisher : Springer Science & Business Media
ISBN 13 : 3642047211
Total Pages : 260 pages
Book Rating : 4.6/5 (42 download)

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Book Synopsis Transition Metal Complexes of Neutral Eta1-Carbon Ligands by : Remi Chauvin

Download or read book Transition Metal Complexes of Neutral Eta1-Carbon Ligands written by Remi Chauvin and published by Springer Science & Business Media. This book was released on 2010-01-12 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is part of a series that gives the broad scientific readership a comprehensive summary and critical overview of specific topics in the field of organometallic chemistry. This text focuses on transition metal complexes of neutral eta1-carbon ligands.

Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands

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Author :
Publisher :
ISBN 13 : 9781349815609
Total Pages : 0 pages
Book Rating : 4.8/5 (156 download)

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Book Synopsis Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands by : Charles Andrew McAuliffe

Download or read book Transition Metal Complexes of Phosphorus, Arsenic and Antimony Ligands written by Charles Andrew McAuliffe and published by . This book was released on 1973 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:

On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes

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Author :
Publisher : World Scientific
ISBN 13 : 9814488003
Total Pages : 654 pages
Book Rating : 4.8/5 (144 download)

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Book Synopsis On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes by : John L Burmeister

Download or read book On Being Well-coordinated: A Half-century Of Research On Transition Metal Complexes written by John L Burmeister and published by World Scientific. This book was released on 2003-10-14 with total page 654 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book distils the research accomplishments of Professor Fred Basolo during the five decades when he served as a world leader in the modern renaissance of inorganic chemistry. Its primary focus is on the very important area of chemistry known as coordination chemistry.Most of the elements in the periodic table are metals, and most of the chemistry of metals involves coordination chemistry. This is the case in the currently significant areas of research, including organometallic homogenous catalysis, biological reactions of metalloproteins, and even the solid state extended structures of new materials. In these systems, the metals are of primary importance because they are the sites of ligand substitution or redox reactions. In the solid materials, the coordination number of the metal and its stereochemistry are of major importance.Some fifty years of research on transition metal complexes carried out in the laboratory of Professor Basolo at Northwestern University is recorded here as selected scientific publications. The book is divided into three different major research areas, each dealing with some aspect of coordination chemistry. In each case, introductory remarks are presented which indicate what prompted the research projects and what the major accomplishments were. Although the research was of the academic, curiosity-driven type, some aspects have proven to be useful to others involved in projects that were much more applied in nature.

Transition Metal Complexes as Drugs and Chemotherapeutic Agents

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Publisher : Springer Science & Business Media
ISBN 13 : 9401175683
Total Pages : 304 pages
Book Rating : 4.4/5 (11 download)

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Book Synopsis Transition Metal Complexes as Drugs and Chemotherapeutic Agents by : N. Farrell

Download or read book Transition Metal Complexes as Drugs and Chemotherapeutic Agents written by N. Farrell and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 304 pages. Available in PDF, EPUB and Kindle. Book excerpt: When this book was first conceived as a project the expanding interest in the clinical use of platinum and gold complexes made a survey of the relevant biological properties of metal complexes timely and appropriate. This timeliness has not diminished during the gestation and final publica tion of the manuscript. The introduction contains an explanation of the layout and approach to the book, which I wrote as an overall survey of the wide variety of biological properties of metal complexes. Hopefully, the reader will see the parallels in mechanisms and behavior, even in different organisms. The writing was considerably helped by the enthusiasm and confidence (totally unearned on my part) in the project of Professor Brian James and lowe him my special thanks. I also owe a great debt of gratitude to my colleagues, and especially to Eucler Paniago, of the Universidade Federal de Minas Gerais, for their comprehension and for the initial leave of absence which allowed me to begin the project. To those who read some or all of the manuscript and made suggestions, Bernhard Lippert, Kirsten Skov, and Tom Tritton, as well as the editor's reviewer I am also grateful. As usual, the final responsibility for errors or otherwise rests with the author.

Ligand Platforms in Homogenous Catalytic Reactions with Metals

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Publisher : John Wiley & Sons
ISBN 13 : 1118203518
Total Pages : 358 pages
Book Rating : 4.1/5 (182 download)

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Book Synopsis Ligand Platforms in Homogenous Catalytic Reactions with Metals by : Ryohei Yamaguchi

Download or read book Ligand Platforms in Homogenous Catalytic Reactions with Metals written by Ryohei Yamaguchi and published by John Wiley & Sons. This book was released on 2014-11-17 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Serving as a user's manual for synthetic organic and catalytic chemists, this book guides chemists in the design and choice of ligands to catalyze organic reactions and apply the results for more efficient, green, and practical synthesis. • Focuses on the role of ligands in metal complexes that catalyze green organic transformations: a hot topic in the area of organic synthesis and green chemistry • Offers a comprehensive resource to help readers design and choose ligands and understand selectivity/reactivity characteristics • Addresses a gap by taking novel ligand approaches and including up-to-date discussion on hydrogen transfers and reactions • Presents important industrial perspective and provides rational explanations of ligand effects, impacts, and novelty

Variety in Coordination Modes of Ligands in Metal Complexes

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Publisher : Springer Science & Business Media
ISBN 13 : 3642501486
Total Pages : 129 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis Variety in Coordination Modes of Ligands in Metal Complexes by : Shinichi Kawaguchi

Download or read book Variety in Coordination Modes of Ligands in Metal Complexes written by Shinichi Kawaguchi and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 129 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal complexes play important roles as catalysts or other participants in synthetic and biological reactions. Substrates and sometimes attacking reagents also are activated through coordination with metal atoms or ions. In these events the natures not only of the central metals but also of ancillary ligands exert important influences on the stability and reactivity of the coordinated substrates. A ligand in general can adopt various coordination modes depending on its chemical environment, thus functioning as a probe. The number of coordination modes increases with increasing complexity of the ligand. In this book it is shown that even the simplest mono- and diatomic ligands such as H, CO, and N2 exhibit a variety of coordination modes, which are related to their reactions. The thiocyanate anion is taken up as a representative of the triatomic ambidentate ligands, and factors influencing the preferences for N- und S-bonding are summarized. Coordination chemistry of ß-dicarbonyl compounds is a highlight of this book. Acetylacetone, one of the most familiar Werner ligands, is shown to favor -carbon and n-allylic bonding in many instances. Its versatile behaviour in changing coordination modes is revealed.

Fundamental World of Quantum (3 volume set)

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Publisher : Springer
ISBN 13 : 9781402025846
Total Pages : 2159 pages
Book Rating : 4.0/5 (258 download)

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Book Synopsis Fundamental World of Quantum (3 volume set) by : Erkki J. Brändas

Download or read book Fundamental World of Quantum (3 volume set) written by Erkki J. Brändas and published by Springer. This book was released on 2005-08-01 with total page 2159 pages. Available in PDF, EPUB and Kindle. Book excerpt:

An Introduction to Transition-metal Chemistry: Ligand-field Theory

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Publisher :
ISBN 13 :
Total Pages : 184 pages
Book Rating : 4.:/5 (319 download)

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Book Synopsis An Introduction to Transition-metal Chemistry: Ligand-field Theory by : Leslie E. Orgel

Download or read book An Introduction to Transition-metal Chemistry: Ligand-field Theory written by Leslie E. Orgel and published by . This book was released on 1966 with total page 184 pages. Available in PDF, EPUB and Kindle. Book excerpt: