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Author : Alessandro Faldi
Publisher :
ISBN 13 :
Total Pages : 560 pages
Book Rating : 4.:/5 (319 download)
Download or read book Thermodynamics and Diffusion in Radical Polymerization written by Alessandro Faldi and published by . This book was released on 1992 with total page 560 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Joe Su-Shien Lin
Publisher :
ISBN 13 :
Total Pages : 338 pages
Book Rating : 4.3/5 (129 download)
Download or read book Thermodynamics and Diffusion in Polymer Solutions Containing Associating Species written by Joe Su-Shien Lin and published by . This book was released on 1980 with total page 338 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Han-Tai Liu
Publisher :
ISBN 13 :
Total Pages : 234 pages
Book Rating : 4.:/5 (943 download)
Download or read book A Study of Thermodynamics and Molecular Diffusion in Polymer-solvent Systems written by Han-Tai Liu and published by . This book was released on 1980 with total page 234 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Graeme Moad
Publisher : Elsevier
ISBN 13 : 0080442889
Total Pages : 667 pages
Book Rating : 4.0/5 (84 download)
Download or read book The Chemistry of Radical Polymerization written by Graeme Moad and published by Elsevier. This book was released on 2006 with total page 667 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book commences with a general introduction outlining the basic concepts of radical polymerization. This is followed by a chapter on radical reactions that is intended to lay the theoretical ground-work for the succeeding chapters on initiation, propagation and termination.
Author : Alastair M. North
Publisher : Pergamon
ISBN 13 :
Total Pages : 144 pages
Book Rating : 4.3/5 (91 download)
Download or read book The Kinetics of Free Radical Polymerization written by Alastair M. North and published by Pergamon. This book was released on 1966 with total page 144 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Nicolay V Tsarevsky
Publisher : Royal Society of Chemistry
ISBN 13 : 1849737428
Total Pages : 379 pages
Book Rating : 4.8/5 (497 download)
Download or read book Fundamentals of Controlled/Living Radical Polymerization written by Nicolay V Tsarevsky and published by Royal Society of Chemistry. This book was released on 2013-04-25 with total page 379 pages. Available in PDF, EPUB and Kindle. Book excerpt: Controlled/living radical polymerization (CRP) has revolutionized and revitalized the field of synthetic polymer chemistry over the last twenty years as it is now possible to prepare a wide variety of previously inaccessible macromolecules under relatively mild conditions. Fundamentals of Controlled/Living Radical Polymerization provides an in-depth coverage of the essential chemical principles that enable and govern each of the CRP methods. The book starts with a brief historical overview of the major findings in polymer science which eventually led to the development of living ionic and living radical systems. It then goes on to introduce the main CRP techniques including their mechanistic understanding. The book also provides the information needed to select the appropriate reagents and conditions to conduct various CRP methods in a practical setting. Therefore, in addition to a newcomer gaining an appreciation for what has already been accomplished, the reader will be armed with the tools needed to begin independent research. Fundamentals of Controlled/Living Radical Polymerization provides essential insight into a rapidly growing field that goes beyond a simple literature review of the area. Written by leading experts in the field, the book is an indispensible resource for all researchers, instructors, and students in polymer chemistry.
Author : James M. Caruthers
Publisher : American Institute of Chemical Engineers
ISBN 13 :
Total Pages : 208 pages
Book Rating : 4.3/5 (91 download)
Download or read book Handbook of Diffusion and Thermal Properties of Polymers and Polymer Solutions written by James M. Caruthers and published by American Institute of Chemical Engineers. This book was released on 1998 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: Accompanying computer disk contains procedures needed in order to navigate the various screens for implementation of the different correlative or predictive methods, and how to access the experimental base
Author : Michio Kurata
Publisher : CRC Press
ISBN 13 : 9783718600236
Total Pages : 328 pages
Book Rating : 4.6/5 (2 download)
Download or read book Thermodynamics of Polymer Solutions written by Michio Kurata and published by CRC Press. This book was released on 1982 with total page 328 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Thomas John Tulig
Publisher :
ISBN 13 :
Total Pages : 520 pages
Book Rating : 4.:/5 (319 download)
Download or read book Molecular Dynamics of High-conversion Free Radical Polymerization written by Thomas John Tulig and published by . This book was released on 1983 with total page 520 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Broja Mohan Mandal
Publisher : World Scientific
ISBN 13 : 9814322466
Total Pages : 468 pages
Book Rating : 4.8/5 (143 download)
Download or read book Fundamentals of Polymerization written by Broja Mohan Mandal and published by World Scientific. This book was released on 2013 with total page 468 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the last twenty years, the field of the chemistry of polymerization witnessed enormous growth through the development of new concepts, catalysts, processes etc. Examples are: non classical living polymerizations (group transfer polymerization, living carbocationic polymerization, living radical polymerization and living ring-opening metathesis polymerization (ROMP)); new catalysts (metallocenes and late transition metal catalysts for stereospecific polymerization, Schrock and Grubbs catalyst for ROMP among others) and new processes such as miniemulsion, microemulsion polymerization and dispersion polymerization (in polar solvents). Apart from the developments in the chemistry of polymerization, methods have been developed for the evaluation of highly reliable rate constants of propagation in radical as well as cationic polymerization. All these have revolutionized the field of synthetic polymer chemistry. In the book, fundamentals of both the new and old polymerization chemistry have been dealt with. The new chemistry has been given nearly equal space along with the old.
Author : Anil Kumar
Publisher : CRC Press
ISBN 13 : 9780203911891
Total Pages : 720 pages
Book Rating : 4.9/5 (118 download)
Download or read book Fundamentals of Polymer Engineering, Revised and Expanded written by Anil Kumar and published by CRC Press. This book was released on 2003-01-21 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: Exploring the characterization, thermodynamics and structural, mechanical, thermal and transport behavior of polymers as melts, solutions and solids, this text covers essential concepts and breakthroughs in reactor design and polymer production and processing. It contains modern theories, end-of-chapter problems and real-world examples for a clear understanding of polymer function and development. Fundamentals of Polymer Engineering, Second Edition provides a thorough grounding in the fundamentals of polymer science for more advanced study in the field of polymers. Topics include reaction engineering of step-growth polymerization, emulsion polymerization, and polymer diffusion.
Author : Wayne F. Reed
Publisher : John Wiley & Sons
ISBN 13 : 0470917385
Total Pages : 493 pages
Book Rating : 4.4/5 (79 download)
Download or read book Monitoring Polymerization Reactions written by Wayne F. Reed and published by John Wiley & Sons. This book was released on 2014-01-21 with total page 493 pages. Available in PDF, EPUB and Kindle. Book excerpt: Offers new strategies to optimize polymer reactions With contributions from leading macromolecular scientists and engineers, this book provides a practical guide to polymerization monitoring. It enables laboratory researchers to optimize polymer reactions by providing them with a better understanding of the underlying reaction kinetics and mechanisms. Moreover, it opens the door to improved industrial-scale reactions, including enhanced product quality and reduced harmful emissions. Monitoring Polymerization Reactions begins with a review of the basic elements of polymer reactions and their kinetics, including an overview of stimuli-responsive polymers. Next, it explains why certain polymer and reaction characteristics need to be monitored. The book then explores a variety of practical topics, including: Principles and applications of important polymer characterization tools, such as light scattering, gel permeation chromatography, calorimetry, rheology, and spectroscopy Automatic continuous online monitoring of polymerization (ACOMP) reactions, a flexible platform that enables characterization tools to be employed simultaneously during reactions in order to obtain a complete record of multiple reaction features Modeling of polymerization reactions and numerical approaches Applications that optimize the manufacture of industrially important polymers Throughout the book, the authors provide step-by-step strategies for implementation. In addition, ample use of case studies helps readers understand the benefits of various monitoring strategies and approaches, enabling them to choose the best one to match their needs. As new stimuli-responsive and "intelligent" polymers continue to be developed, the ability to monitor reactions will become increasingly important. With this book as their guide, polymer scientists and engineers can take full advantage of the latest monitoring strategies to optimize reactions in both the lab and the manufacturing plant.
Author : Sabine Enders
Publisher : Springer
ISBN 13 : 3642176828
Total Pages : 434 pages
Book Rating : 4.6/5 (421 download)
Download or read book Polymer Thermodynamics written by Sabine Enders and published by Springer. This book was released on 2011-01-18 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: Making Flory-Huggins Practical: Thermodynamics of Polymer-Containing Mixtures, by B. A. Wolf * Aqueous Solutions of Polyelectrolytes: Vapor-Liquid Equilibrium and Some Related Properties, by G. Maurer, S. Lammertz, and L. Ninni Schäfer * Gas-Polymer Interactions: Key Thermodynamic Data and Thermophysical Properties, by J.-P. E. Grolier, and S. A.E. Boyer * Interfacial Tension in Binary Polymer Blends and the Effects of Copolymers as Emulsifying Agents, by S. H. Anastasiadis * Theory of Random Copolymer Fractionation in Columns, by Sabine Enders * Computer Simulations and Coarse-Grained Molecular Models Predicting the Equation of State of Polymer Solutions, by K. Binder, B. Mognetti, W. Paul, P. Virnau, and L. Yelash * Modeling of Polymer Phase Equilibria Using Equations of State, by G. Sadowski
Author : Gennadiĭ Efremovich Zaikov
Publisher : Nova Publishers
ISBN 13 : 9781590338544
Total Pages : 212 pages
Book Rating : 4.3/5 (385 download)
Download or read book Chemical Reactions in Liquid and Solid Phase written by Gennadiĭ Efremovich Zaikov and published by Nova Publishers. This book was released on 2003 with total page 212 pages. Available in PDF, EPUB and Kindle. Book excerpt: This collection examines the influence of liquid and solid states during radical, ionic, and molecular reactions, specifically how cage effect, diffusion hindrance, donor-acceptor interaction, electrostatic interaction, dispersion forces and other factors affect the rates, mechanism, and direction of chemical reactions. Topics of the 11 papers include spherical hydrogel particles for endovascular embolisation, the synthesis and thermal degradation of phenolic resins, mono-molecular chain termination in dimethacrylate postpolymerisation, and calculating the effect of chain deformation on macromolecule scission. Most of the researchers work in Russia.
Author : Roger John Zipfel
Publisher :
ISBN 13 :
Total Pages : 166 pages
Book Rating : 4.:/5 (47 download)
Download or read book The Diffusion Controlled Free Radical Polymerization of Styrene written by Roger John Zipfel and published by . This book was released on 1969 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Pascal Hesse
Publisher : Cuvillier Verlag
ISBN 13 : 3736926820
Total Pages : 326 pages
Book Rating : 4.7/5 (369 download)
Download or read book Radical Polymerization Kinetics in Aqueos Solution and in Systems with Secondary and Tertiary Radicals Studied by Novel Pulsed- Laser Techniques written by Pascal Hesse and published by Cuvillier Verlag. This book was released on 2008-08-08 with total page 326 pages. Available in PDF, EPUB and Kindle. Book excerpt: Abstract Rate coefficients of propagation, kp, of termination, kt, and of intramolecular transfer-to-polymer, kbb, have been studied via pulsed-laser polymerization (PLP) methods for systems with strong intermolecular interactions, such as hydrogen bonds, and for polymerizations with two types of distinctly different radicals being present. The propagation kinetics of methacrylic acid (MAA) and N-vinyl pyrrolidone (NVP) in aqueous solution has been investigated by the PLP-SEC technique which combines PLP-initiation with subsequent analysis of the produced polymer by size-exclusion chromatography. The experimental conditions of monomer concentration, temperature, pressure and degree of monomer ionization have been varied in wide ranges. The dependence of kp on monomer-to-polymer conversion has been determined from PLP-SEC experiments with pre-mixed polymer. The variation of kp may be adequately explained by the interaction of solvent and monomer molecules with the transition state structure for propagation. The termination rate coefficients of MAA and NVP have been studied by the SP PLP NIR method in which the change in monomer concentration after single pulse (SP) initiation is monitored via s time-resolved near infrared spectroscopy (NIR). The variations of kt with conversion for different initial monomer concentrations reflect the diffusion-controlled character of the termination step with kt being governed by segmental, translational, and reaction diffusion. In acrylate polymerization backbiting reactions may occur by which chain-end secondary propagating radicals (SPR) are transformed into tertiary midchain radicals (MCR) via 1,5-hydrogen shift. MCRs can react back to SPRs by monomer addition. The basic kinetic scheme has to be extended for additional reactions steps, as SPR and MCR species show widely different kp and kt, respectively. The impact of MCR formation on the applicability of the experimental techniques for kp and kt determination, i.e. PLP-SEC and SP-PLP-NIR, was investigated by PREDICI simulations. A novel experimental method has been developed by which kbb and the rate coefficient for monomer addition to the MCR, kpt, for butyl acrylate (BA) have been determined from PLP-SEC experiments carried out under extended variation of laser pulse repetition rates. Insights into the kinetics, especially of the termination reactivity of secondary and tertiary acrylate radicals, have been obtained by measurements of full electron spin resonance (ESR) spectra under stationary UV and pseudo-stationary PLP initiation, respectively, or by time-resolved monitoring of SPR and MCR concentrations after application of a laser single pulse (SP-PLP-ESR). By the latter technique also chain-length-dependent individual kt values are accessible. For acrylic acid (AA) polymerization in aqueous solution, the complexities associated with strong solvent effects on the rate coefficients and with the pronounced MCR build-up add to each other. Attempts were made to consider the resulting consequences for the kinetic data of AA polymerization in aqueous solution published so far.
Author :
Publisher : Cuvillier Verlag
ISBN 13 : 3736919913
Total Pages : 176 pages
Book Rating : 4.7/5 (369 download)
Download or read book Radical Polymerization: Kinetics and Mechanism written by and published by Cuvillier Verlag. This book was released on 2006-08-22 with total page 176 pages. Available in PDF, EPUB and Kindle. Book excerpt:
