The Stabilization Of Polyvnyl Chloride

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Degradation and Stabilisation of PVC

Author : J. Owen
Publisher : Springer Science & Business Media
ISBN 13 : 9400956185
Total Pages : 325 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Degradation and Stabilisation of PVC by : J. Owen

Download or read book Degradation and Stabilisation of PVC written by J. Owen and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 325 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polyvinyl chloride has played a key role in the development of the plastics industry over the past 40 years and continues to be a polymer of major importance. The reasons for its enormous versatility and range of application derive from a combination of the basic structure which gives rise to a relatively tough and rigid material and its ability to accept a range of plasticisers and other additives which can modify its physical characteristics to produce a range of flexible products. Two major problems, however, have tested the skill and ingenuity of PVC technologists since earliest times. One is the thermal instability of the material at the temperatures required for melt processing and fabrication, and the second is the photochemical instability which until recently has limited the potentially large range of outdoor applications. Both problems have been handled in a commercially satisfactory way by the gradual development of a range of stabilisers, lubricants and other processing aids and the high quality material which has resulted has led to massive utilisation of PVC by industry. Totally adequate stabilisation requires a detailed understanding of the mechanisms by which degradation processes are initiated and propagated. Although great advances have been made in this respect in recent years the problem remains incompletely understood. This book presents an account of the present position and the problems which remain to be solved.

The Stabilization of Polyvinyl Chloride

Author : Fernand Chevassus
Publisher :
ISBN 13 :
Total Pages : 410 pages
Book Rating : 4.0/5 ( download)

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Book Synopsis The Stabilization of Polyvinyl Chloride by : Fernand Chevassus

Download or read book The Stabilization of Polyvinyl Chloride written by Fernand Chevassus and published by . This book was released on 1963 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Photostabilization of Polymers

Author : J.F. Rabek
Publisher : Springer Science & Business Media
ISBN 13 : 9400907478
Total Pages : 607 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Photostabilization of Polymers by : J.F. Rabek

Download or read book Photostabilization of Polymers written by J.F. Rabek and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 607 pages. Available in PDF, EPUB and Kindle. Book excerpt: During the last two decades, the production of polymers and plastics has been increasing rapidly. In spite of developing new polymers and polymeric materials, only 40-60 are used commercially on a large scale. It has been estimated that half of the annual production of polymers is employed outdoors. Increasing the stability of polymers and plastics towards heat, light, atmospheric oxygen and other environmental agents and weathering conditions has always been a very important problem. The photochemical instability of most of polymers limits them to outdoor application, where they are photo degraded fast over periods ranging from months to a few years. To the despair of technologists and consumers alike, photodegrada tion and environmental ageing of polymers occur much faster than can be expected from knowledge collected in laboratories. In many cases, improved methods of preparation and purification of both monomers and polymers yield products of better quality and higher resistance to heat and light. However, without stabilization of polymers by applica tion of antioxidants (to decrease thermal oxidative degradation) and photostabilizers (to decrease photo-oxidative degradation) it would be impossible to employ polymers and plastics in everyday use.

Polyvinyl Chloride Degradation

Author : George Wypych
Publisher : Elsevier Publishing Company
ISBN 13 :
Total Pages : 284 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Polyvinyl Chloride Degradation by : George Wypych

Download or read book Polyvinyl Chloride Degradation written by George Wypych and published by Elsevier Publishing Company. This book was released on 1985 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Good,No Highlights,No Markup,all pages are intact, Slight Shelfwear,may have the corners slightly dented, may have slight color changes/slightly damaged spine.

Polymer Additives

Author : Jiri E. Kresta
Publisher : Springer Science & Business Media
ISBN 13 : 1461327970
Total Pages : 403 pages
Book Rating : 4.4/5 (613 download)

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Book Synopsis Polymer Additives by : Jiri E. Kresta

Download or read book Polymer Additives written by Jiri E. Kresta and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 403 pages. Available in PDF, EPUB and Kindle. Book excerpt: Ever since the beginning of the plastics and rubber industry, it was realized that useful products could be produced only if cer tain additives were incorporated into polymers. With the help of these additives, when physically dispersed in a polymer matrix, it has been possible to improve stability against thermal, oxidative, UV, hydrolytic and biological degradation, mechanical properties, flammability, cost, and processibility of plastics. The enormous growth of the volume of plastics consumed by modern society, and new application areas for plastics, have created a demand for new, better additives and better understanding of their functions in polymer systems. As a result of these trends there is a need for sharing of information on progress achieved in the area of polymer additives among engineers and scientists of the plastics industry and academia. This book is based on expanded and updated papers originally presented at the International Symposium on Polymer Additives, which was held in Las Vegas, Nevada, and was sponsored by the American Chemical Society, Division of Polymeric Materials Science and Engi neering. The book is divided into five parts which cover advances in various areas of polymer additives. The first part is devoted to the progress in understanding of UV degradation and stabilization of various polymers. Oxidation degradation and stabilization of plastic materials is covered in the second part. New developments in the stabilization of PVC are presented in the third part.

PVC Handbook

Author : Charles E. Wilkes
Publisher : Hanser Gardner Publications
ISBN 13 : 9781569903797
Total Pages : 723 pages
Book Rating : 4.9/5 (37 download)

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Book Synopsis PVC Handbook by : Charles E. Wilkes

Download or read book PVC Handbook written by Charles E. Wilkes and published by Hanser Gardner Publications. This book was released on 2005 with total page 723 pages. Available in PDF, EPUB and Kindle. Book excerpt: In this single handbook, the editors aim to give a diverse audience of readers a complete account of all aspects of PVC--from monomer manufacture to polymerization; the gamut of such additives as stabilizers, lubricants, plasticizers, impact modifiers, fillers and reinforcing agents; blends and alloys; compounding and processing; characterization; combustion resistance and weatherability; product engineering design; applications; environmental and safety; and finally the PVC industry dynamics. This handbook contains both practical formulation information as well as a mechanistic view of why PVC behaves as it does.

Aging and Stabilization of Polymers

Author : M. B. Neiman
Publisher : Springer Science & Business Media
ISBN 13 : 146158549X
Total Pages : 374 pages
Book Rating : 4.4/5 (615 download)

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Book Synopsis Aging and Stabilization of Polymers by : M. B. Neiman

Download or read book Aging and Stabilization of Polymers written by M. B. Neiman and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt: The need for a broad development of the production of polymer ma terials has become evident. All these materials are subject to various types of aging (destruction); hence, stabilizers which permit the stor age, reprocessing, and use of polymer materials without any appreci able change in their properties must be introduced into them. In recent years, this problem of stabilizing polymers has attracted the attention of many scientists and technologists, both in the USSR and abroad. The scientific basis of the foreign studies will be found in a number of theo retical premises, but chiefly the theory of chain reactions with un branched chains. In the Soviet Union, the concepts of Academician N. N. Semenov on chain reactions with degenerate branches have become the starting point of theoretical studies of the stabilization and destruction of polymers. Soviet scientists have developed a theory of critical concentrations of antioxidants and have shown that the processes of stabilization have a very complex chemical character. The nature of the polymers them selves greatly affects these processes and consequently, different stabil izers are required for polymers of different structures. In addition, it has been shown that the antioxidants used thus far can not only cause chain termination, but can also initiate oxidation and give rise to de generate branches.

Organic Polymer Chemistry

Author : K. J. Saunders
Publisher : Springer Science & Business Media
ISBN 13 : 9401725047
Total Pages : 480 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Organic Polymer Chemistry by : K. J. Saunders

Download or read book Organic Polymer Chemistry written by K. J. Saunders and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 480 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book deals with the organic chemistry of polymers which find technological use as adhesives, fibres, paints, plastics and rubbers. For the most part, only polymers which are of commercial significance are considered and the primary aim of the book is to relate theoretical aspects to industrial practice. The book is mainly intended for use by students in technical institutions and universities who are specializing in polymer science and by graduates who require an introduction to this field. Several excellent books have recently appeared dealing with the physical chemistry of polymers but the organic chemistry of polymers has not received so much attention. In recognition of this situation and because the two aspects of polymer chemistry are often taught separately, this book deals specifically with organic chemistry and topics of physical chemistry have been omitted. Also, in this way the book has been kept to a reasonable size. This is not to say that integration of the two areas of polymer science is undesirable; on the contrary, it is of the utmost importance that the inter-relationship should b~ appreciated. I wish to record my thanks to my colleagues with whom I have had many helpful discussions, particularly Mrs S. L. Radchenko. I also thank Miss E. Friesen for obtaining many books and articles on my behalf and Mr H. Harms for encouragement and assistance. I am also grateful to Mrs M. Stevens who skilfully prepared the manuscript. Department of Chemical and Metallurgical Technology, Ryerson Polytechnical Institute, K. J. S.

Encyclopedia of PVC

Author : Leonard I. Nass
Publisher :
ISBN 13 :
Total Pages : 626 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Encyclopedia of PVC by : Leonard I. Nass

Download or read book Encyclopedia of PVC written by Leonard I. Nass and published by . This book was released on 1976 with total page 626 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Volume 1 of this outstanding resource concentrates on safety and environmental concerns in the manufacture and use of resins, and thoroughly discusses theories of degradation, plasticization, solvation, and stabilization. "

Synthetic Rubbers: Their Chemistry and Technology

Author : D.C. Blackley
Publisher : Springer Science & Business Media
ISBN 13 : 9400966199
Total Pages : 381 pages
Book Rating : 4.4/5 (9 download)

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Book Synopsis Synthetic Rubbers: Their Chemistry and Technology by : D.C. Blackley

Download or read book Synthetic Rubbers: Their Chemistry and Technology written by D.C. Blackley and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 381 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book has its origin in a proposal made a few years ago that I should collaborate with Dr H. J. Stern in the production of a third edition of his well-known text-book entitled Rubber: Natural and Synthetic. The sugges tion was that I should contribute a series of chapters on synthetic rubbers. Although, in the event, it has not proved possible to publish the full book in the form originally planned, it was apparent that, with some restructuring, the material which I had collected would be valuable as an independent summary of the chemistry and technology of synthetic rubbers. It is in this form that the material is now offered. The primary purpose of this book is to provide a brief up-to-date survey of the principal types of synthetic rubber which have been and are currently available. Two classes of material are included which are regarded by some as being thermoplastics rather than rubbers, namely, plasticised polyvinyl chloride and the thermoplastic synthetic rubbers. The topics which are covered for each main family of synthetic rubbers are (i) the sources of the monomers, (ii) polymerisation procedures and the effects of important polymerisation variables upon the rubber produced, (iii) the types of rubber currently available commercially, (iv) interesting aspects of the compounding of the rubbers, with special reference to such matters as vulcanisation, reinforcement, protection against degradation, and (where appropriate) plasticisation, and (v) an indication of applications.

Advances in Polymer Sciences and Technology

Author : Bhuvanesh Gupta
Publisher : Springer
ISBN 13 : 9811325685
Total Pages : 247 pages
Book Rating : 4.8/5 (113 download)

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Book Synopsis Advances in Polymer Sciences and Technology by : Bhuvanesh Gupta

Download or read book Advances in Polymer Sciences and Technology written by Bhuvanesh Gupta and published by Springer. This book was released on 2018-11-01 with total page 247 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book presents select papers presented at the annual meeting of the Asian Polymer Association. The chapters in this volume document and report on a wide range of significant recent results for various applications, as well as scientific developments in the areas of polymer science and engineering. The chapters include original research from all areas of polymer science and technology with a focus on the manufacture, processing, analysis and application of long chain polymer molecules. This book will be of interest to researchers in academia and industry alike.

PVC Degradation and Stabilization

Author : George Wypych
Publisher : Elsevier
ISBN 13 : 1927885620
Total Pages : 521 pages
Book Rating : 4.9/5 (278 download)

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Book Synopsis PVC Degradation and Stabilization by : George Wypych

Download or read book PVC Degradation and Stabilization written by George Wypych and published by Elsevier. This book was released on 2020-03-11 with total page 521 pages. Available in PDF, EPUB and Kindle. Book excerpt: PVC Degradation and Stabilization, Fourth Edition, includes new developments in PVC production, new stabilization methods and mechanisms, new approaches to plasticization, methods of waste reprocessing, accelerated degradation due to electric breakdown, and much more. The book contains all the information necessary for the successful design of stabilization formulas in any PVC-based product. Other topics covered include degradation by thermal energy, UV, gamma and other forms of radiation, chemical degradation, and more. Analytical methods for studying degradative and stabilization processes aid readers in establishing a system for verifying results of stabilization with different stabilizing systems. Many new topics included in this edition are of particular interest today. These comprise new developments in PVC production yielding range of new grades, new stabilization methods and mechanisms (e.g. synergistic mixtures containing hydrotalcites and their synthetic equivalents, beta-diketones, functionalized fillers, Shiff bases), new approaches to plasticization, methods of waste reprocessing (life cycle assessment, reformulation, biodegradable materials, and energy recovery), accelerated degradation due to electric breakdown, and many more - Revised to include cutting-edge research, patent updates and other information required to design successful stabilization in PVC-based products - Covers chemical structure, PVC manufacturing technology, morphology, degradation by thermal energy, mechanodegradation, and more - Includes a chapter on the analytical methods used in studying degradative and stabilization processes - Discusses information on the effects of PVC and its additives on health, safety and the environment

PVC

Author : J. Leadbitter
Publisher : iSmithers Rapra Publishing
ISBN 13 : 9781859570296
Total Pages : 164 pages
Book Rating : 4.5/5 (72 download)

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Book Synopsis PVC by : J. Leadbitter

Download or read book PVC written by J. Leadbitter and published by iSmithers Rapra Publishing. This book was released on 1994 with total page 164 pages. Available in PDF, EPUB and Kindle. Book excerpt: This report reviews the composition and synthesis of PVC, composition and formulation technology, compounding and manufacturing technology, and the additional range of materials made possible by blending with other polymers. It is completed by around 500 abstracts selected from the Rapra Polymer Library database.

Polyvinyl Chloride Stabilization

Author : George Wypych
Publisher : Elsevier Publishing Company
ISBN 13 :
Total Pages : 436 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Polyvinyl Chloride Stabilization by : George Wypych

Download or read book Polyvinyl Chloride Stabilization written by George Wypych and published by Elsevier Publishing Company. This book was released on 1986 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt:

PVC Additives

Author : Michael Schiller
Publisher : Carl Hanser Verlag GmbH Co KG
ISBN 13 : 1569908729
Total Pages : 499 pages
Book Rating : 4.5/5 (699 download)

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Book Synopsis PVC Additives by : Michael Schiller

Download or read book PVC Additives written by Michael Schiller and published by Carl Hanser Verlag GmbH Co KG. This book was released on 2022-04-11 with total page 499 pages. Available in PDF, EPUB and Kindle. Book excerpt: PVC differs in its stabilization compared to other commodity plastics. Various metal compounds are suitable for the stabilization of PVC: lead, tin, calcium, magnesium, zinc, rare earths, and also almost-metal-free systems. These differences are described in the introductory part of this book, with their advantages, possibilities, and problems, from the perspective of the chemist but made understandable for salespeople and technicians. Numerous tables and figures are included, providing structures and physico-chemical data. A special section for beginners is dedicated to guiding formulations and test methods. A relatively short section deals with development trends in Europe. Sustainability is a major theme, and it is demonstrated that PVC has a strong potential to develop into a fully sustainable material. Another section deals with the everyday problems in the processing of PVC, such as the formation of specks, photo-effects, and plate-out. Plate-out is a common problem in the processing of PVC but only relatively few publications cover it. The causes, influencing factors, and mechanisms are still poorly understood. This section, unique in the literature, provides assistance in the selection and dosage of raw materials to PVC processor, based on the influencing factors during processing.

Polyvinylchloride-based Blends

Author : Visakh P. M.
Publisher : Springer Nature
ISBN 13 : 303078455X
Total Pages : 240 pages
Book Rating : 4.0/5 (37 download)

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Book Synopsis Polyvinylchloride-based Blends by : Visakh P. M.

Download or read book Polyvinylchloride-based Blends written by Visakh P. M. and published by Springer Nature. This book was released on 2021-09-23 with total page 240 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book summarizes many of the recent research accomplishments in the area of polyvinylchloride (PVC)-based blends and their preparation, characterization and applications. Various sub-topics are addressed, such as the state-of-the-art of PVC based blends, new challenges and opportunities, emphasis being given to the types and sizes of components/fillers and optimum compositions of PVC blends, their processing and structure-properties relationships, modification/compatibilization methods, and possible applications. PVC/thermoplastic based nano, micro and macro blends, PVC membranes, bio-based plasticizers and PVC blends with components from renewable resources are reported. The various chapters in this book are contributed by prominent researchers from industry, academia and government/private research laboratories across the globe. It covers an up-to-date record on the major findings and observations in the field of PVC-based blends.

Handbook of Plasticizers

Author : George Wypych
Publisher : Elsevier
ISBN 13 : 1774670232
Total Pages : 917 pages
Book Rating : 4.7/5 (746 download)

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Book Synopsis Handbook of Plasticizers by : George Wypych

Download or read book Handbook of Plasticizers written by George Wypych and published by Elsevier. This book was released on 2023-02-08 with total page 917 pages. Available in PDF, EPUB and Kindle. Book excerpt: Handbook of Plasticizers, Fourth Edition provides a comprehensive review of the current literature as well as cutting-edge details on plasticizers obtained from renewable resources. The book specifies the typical properties of plasticizers belonging to one of thirty-one groups, including expected properties in a given group. The mechanisms of plasticizers, plasticization production steps, and their material behavior in plasticized systems are outlined, along with theoretical background to help readers understand practical observations and methods of material improvement. Other chapters cover the effects on the physical and mechanical properties of plasticized materials, their use in polymers, processing defects formation, and more. This is an essential professional reference, providing R&D scientists, production chemists, and engineers the information they need to avoid certain plasticizers in applications where they may cause health or material durability problems. In addition, the book shows readers how and where to use plasticizers more effectively. - Provides detailed coverage of thirty-one groups of plasticizers, covering their properties, production, processing, applications, health and environmental aspects - Contains new material on odors in plastic materials and their removal - Includes expanded coverage of plasticizers from renewable resources