The role of rare earths in catalysis

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Publisher :
ISBN 13 :
Total Pages : 419 pages
Book Rating : 4.4/5 (445 download)

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Book Synopsis The role of rare earths in catalysis by : Karl A. Gschneidner

Download or read book The role of rare earths in catalysis written by Karl A. Gschneidner and published by . This book was released on 2000 with total page 419 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the numerous applications of the rare-earth elements, the field of catalysis accounts for a large number. Catalysis represents approximately 20% of the total market sales of rare earths worldwide. As a matter of fact two main applications have been prominent in the last decades: zeolite stabilization for fluid cracking catalysts, and automotive post-combustion catalytic treatment. The oldest use of rare earths in catalysis deals with the structural and chemical stabilization of the zeolites for petroleum cracking applications. For a long time this has been an area of application for non-separated rare earths. The addition of several percent of rare earths in the pores of the zeolite results in a strong surface acidity, which is essential for an efficient conversion of high-weight molecules into lighter species, like low-octane fuel, even in the very aggressive conditions of the petroleum industry. The popular demand for high-quality air in spite of the traffic congestion in large cities resulted in larger and larger constraints in the emission exhaust from cars. Thus highly efficient catalysts have had to be designed, and due to the combination of its redox properties and very good thermal stability, cerium oxide has been since the beginning, early in the 1980s, a major component of the three-way catalysts (TWC) now used in all modern gasoline cars. The future of rare earths in catalysis is probably bright. The fact that approximately 400 patents are applied for yearly in the area since 1992 is an illustration of a very active area. Usage of rare earths in catalysis is expected to grow due to their highly specific properties. Instead of the physical properties used in electronic applications, one deals now with redox properties, water and thermal stability, coordination numbers and so forth. The rare earths are so specific in these properties that their use can hardly be avoided, not only for the beauty of academic studies but also for the development of industrial applications with immediate influence on everyday life. Careful control of the synthesis conditions and the definition of optimum composition in each case are the keys to the preparation of highly performing compounds for catalytic applications. They must actually be considered as high performance products with functional properties, and not just chemical species. Chapters devoted primarily to catalysis have been published in earlier volumes of the Handbook. In this volume several more are added. The first is an extension of the earlier chapter 43, on interactions at surfaces of metals and alloys, to reactions such as hydrogenation, methanation, ammonia synthesis, saturated hydrocarbon reactions, dehydrogenation of hydrogenated materials, hydrodesulfurization, and carbon monoxide oxidation. The second chapter reports on the wide variety of catalyzed reactions involving metals and alloys in the innovated form of metal overlayers or bimetallic compounds with some transition metals produced from ammonia solutions. This is followed by a chapter on catalysis with mixed oxides usually having perovskite or perovskite-related structures. Then follows a comprehensive discussion on the background and current role of cerium oxide and associated materials for post-treatment of exhaust gases for pollution control. These three-way catalysts (TWC) are designed to render harmless the CO, NOx, and unburned hydrocarbons from internal combustion engines. The next chapter considers the wide field of zeolite catalysts containing rare earths from their historic use in petroleum refining in the 1960s to other petrochemical and fine chemical applications today. The final chapter documents the use of the triflates (the trifluoro-methane-sulfonyl group which is a hard Lewis acid in both aqueous and organic solutions) as versatile catalysts in carbon-carbon bond-forming reactions. Their stability in the presence of water, in spite of their being hard Lewis acids, enhances their growing usefulness.

The Role of Rare Earths in Catalysis

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Author :
Publisher : North-Holland
ISBN 13 : 9780444504722
Total Pages : 436 pages
Book Rating : 4.5/5 (47 download)

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Book Synopsis The Role of Rare Earths in Catalysis by : Karl A. Gschneidner

Download or read book The Role of Rare Earths in Catalysis written by Karl A. Gschneidner and published by North-Holland. This book was released on 2000 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: Among the numerous applications of the rare-earth elements, the field of catalysis accounts for a large number. Catalysis represents approximately 20% of the total market sales of rare earths worldwide. As a matter of fact two main applications have been prominent in the last decades: zeolite stabilization for fluid cracking catalysts, and automotive post-combustion catalytic treatment. The oldest use of rare earths in catalysis deals with the structural and chemical stabilization of the zeolites for petroleum cracking applications. For a long time this has been an area of application for non-separated rare earths. The addition of several percent of rare earths in the pores of the zeolite results in a strong surface acidity, which is essential for an efficient conversion of high-weight molecules into lighter species, like low-octane fuel, even in the very aggressive conditions of the petroleum industry. The popular demand for high-quality air in spite of the traffic congestion in large cities resulted in larger and larger constraints in the emission exhaust from cars. Thus highly efficient catalysts have had to be designed, and due to the combination of its redox properties and very good thermal stability, cerium oxide has been since the beginning, early in the 1980s, a major component of the three-way catalysts (TWC) now used in all modern gasoline cars. The future of rare earths in catalysis is probably bright. The fact that approximately 400 patents are applied for yearly in the area since 1992 is an illustration of a very active area. Usage of rare earths in catalysis is expected to grow due to their highly specific properties. Instead of the physical properties used in electronic applications, one deals now with redox properties, water and thermal stability, coordination numbers and so forth. The rare earths are so specific in these properties that their use can hardly be avoided, not only for the beauty of academic studies but also for the development of industrial applications with immediate influence on everyday life. Careful control of the synthesis conditions and the definition of optimum composition in each case are the keys to the preparation of highly performing compounds for catalytic applications. They must actually be considered as high performance products with functional properties, and not just chemical species. Chapters devoted primarily to catalysis have been published in earlier volumes of the Handbook. In this volume several more are added. The first is an extension of the earlier chapter 43, on interactions at surfaces of metals and alloys, to reactions such as hydrogenation, methanation, ammonia synthesis, saturated hydrocarbon reactions, dehydrogenation of hydrogenated materials, hydrodesulfurization, and carbon monoxide oxidation. The second chapter reports on the wide variety of catalyzed reactions involving metals and alloys in the innovated form of metal overlayers or bimetallic compounds with some transition metals produced from ammonia solutions. This is followed by a chapter on catalysis with mixed oxides usually having perovskite or perovskite-related structures. Then follows a comprehensive discussion on the background and current role of cerium oxide and associated materials for post-treatment of exhaust gases for pollution control. These three-way catalysts (TWC) are designed to render harmless the CO, NOx, and unburned hydrocarbons from internal combustion engines. The next chapter considers the wide field of zeolite catalysts containing rare earths from their historic use in petroleum refining in the 1960s to other petrochemical and fine chemical applications today. The final chapter documents the use of the triflates (the trifluoro-methane-sulfonyl group which is a hard Lewis acid in both aqueous and organic solutions) as versatile catalysts in carbon-carbon bond-forming reactions. Their stability in the presence of water, in spite of their being hard Lewis acids, enhances their growing usefulness.

Rare Earth Elements

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 311078825X
Total Pages : 432 pages
Book Rating : 4.1/5 (17 download)

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Book Synopsis Rare Earth Elements by : Basudeb Basu

Download or read book Rare Earth Elements written by Basudeb Basu and published by Walter de Gruyter GmbH & Co KG. This book was released on 2023-05-22 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the years, the uses and applications of rare earth elements (REEs) diversified in various fields such as catalysis, production of magnets, glasses, alloys, and electronics. This book consists of fifteen chapters, which present recent advances and outlook on REEs and their oxides/salts in catalytic organic transformations, biomedical applications, bioremediation and environmental impacts.

Molecular Catalysis of Rare-Earth Elements

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Publisher : Springer
ISBN 13 : 3642128114
Total Pages : 241 pages
Book Rating : 4.6/5 (421 download)

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Book Synopsis Molecular Catalysis of Rare-Earth Elements by : Peter W. Roesky

Download or read book Molecular Catalysis of Rare-Earth Elements written by Peter W. Roesky and published by Springer. This book was released on 2010-07-30 with total page 241 pages. Available in PDF, EPUB and Kindle. Book excerpt: Alexander L. Reznichenko and Kai C. Hultzsch: Catalytic -Bond Metathesis Zhichao Zhang, Dongmei Cui, Baoli Wang, Bo Liu, Yi Yang: Polymerization of 1,3-Conjugated Dienes with Lanthanide Precursors Frank T. Edelmann: Homogeneous Catalysis using Lanthanide Amidinates and Guanidinates Tianshu Li, Jelena Jenter, Peter W. Roesky: Rare Earth Metal Post-metallocene Catalysts with Chelating Amido Ligands

Handbook on the Physics and Chemistry of Rare Earths

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Publisher :
ISBN 13 :
Total Pages : 544 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Handbook on the Physics and Chemistry of Rare Earths by :

Download or read book Handbook on the Physics and Chemistry of Rare Earths written by and published by . This book was released on 2005 with total page 544 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Science and Technology of Rare Earth Materials

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Author :
Publisher : Elsevier
ISBN 13 : 0323138977
Total Pages : 454 pages
Book Rating : 4.3/5 (231 download)

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Book Synopsis Science and Technology of Rare Earth Materials by : E C Subbarao

Download or read book Science and Technology of Rare Earth Materials written by E C Subbarao and published by Elsevier. This book was released on 2012-12-02 with total page 454 pages. Available in PDF, EPUB and Kindle. Book excerpt: Science and Technology of Rare Earth Materials reviews the important aspects of the science and technology of rare earth materials, covering the entire spectrum from occurrence to extraction and purification, phase relationships, electronic structure, and applications. This book is organized into five sections encompassing 19 chapters. The occurrence, extraction, and production of rare earths are discussed in the first section, followed by purification methods employed for rare earths, together with the role of impurities on their behavior. The phase relations among the rare earth alloys, including a particular reference to the technologically important rare earth-cobalt alloys, and phase relations among the rare earth oxides are considered in the second section. The succeeding two sections focus on studies of the electronic structure of rare earth materials, with emphasis on the use of nuclear magnetic resonance and Mössbauer spectroscopy. Theoretical conceptions are set forth as well as the effect of crystal fields and valence fluctuations on the properties of rare earth systems. The final section describes some of the extensive current uses of rare earth materials such as in the steel industry and in permanent magnets, as well as emerging applications in catalysis, hydrogen storage, ferroelectrics, and fast ion conductors. This book is a valuable resource for researchers and students interested in rare earths.

Rare Earth Chemistry

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Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110653729
Total Pages : 746 pages
Book Rating : 4.1/5 (16 download)

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Book Synopsis Rare Earth Chemistry by : Rainer Pöttgen

Download or read book Rare Earth Chemistry written by Rainer Pöttgen and published by Walter de Gruyter GmbH & Co KG. This book was released on 2020-10-26 with total page 746 pages. Available in PDF, EPUB and Kindle. Book excerpt: This work introduces into the chemistry, materials science and technology of Rare Earth Elements. The chapters by experienced lecturers describe comprehensively the recent studies of their characteristics, properties and applications in functional materials. Due to the broad range of covered topics as hydrogen storage materials, LEDs or permanent magnets this work gives an up-to-date presentation of this fascinating research.

Fluid Cracking Catalysts

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Publisher : CRC Press
ISBN 13 : 9780824700799
Total Pages : 368 pages
Book Rating : 4.7/5 (7 download)

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Book Synopsis Fluid Cracking Catalysts by : Mario L. Occelli

Download or read book Fluid Cracking Catalysts written by Mario L. Occelli and published by CRC Press. This book was released on 1998-01-05 with total page 368 pages. Available in PDF, EPUB and Kindle. Book excerpt: Reviews recent accomplishments in the field of fluid cracking catalysts (FCC). Discusses the development of more specialized and effective catalysts and processes as well as the modification of current technology to meet future challenges in fuel refining. Written by nearly 50 internationally recognized experts from academia and industry.

Rare Earth Elements

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Publisher : DIANE Publishing
ISBN 13 : 1437937985
Total Pages : 18 pages
Book Rating : 4.4/5 (379 download)

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Book Synopsis Rare Earth Elements by : Marc Humphries

Download or read book Rare Earth Elements written by Marc Humphries and published by DIANE Publishing. This book was released on 2010-11 with total page 18 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contents: (1) Intro.; (2) What are Rare Earth Elements (REE)?; (3) Major End Uses and Applications: Demand for REE; The Application of REE in National Defense; (4) Rare Earth Resources and Production Potential; Supply Chain Issues; Role of China; (5) Rare Earth Legislation in the 111th Congress: H.R. 4866, and S. 3521, the Rare Earths Supply-Chain Technology and Resources Transformation Act of 2010; H.R. 5136, the FY 2011 Nat. Defense Authorization Act; P.L. 111-84, the FY 2010 Nat. Defense Authorization Act; (6) Possible Policy Options: Authorize and Appropriate Funding for a USGS Assessment; Support and Encourage Greater Exploration for REE; Challenge China on Its Export Policy; Establish a Stockpile. Illustrations.

A Bibliography of Research in Catalysis with the Rare Earth Elements

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (197 download)

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Book Synopsis A Bibliography of Research in Catalysis with the Rare Earth Elements by : Molycorp, Inc. Chemicals and Rare Earths Division

Download or read book A Bibliography of Research in Catalysis with the Rare Earth Elements written by Molycorp, Inc. Chemicals and Rare Earths Division and published by . This book was released on 1971* with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Catalysis by Ceria and Related Materials

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Publisher : World Scientific
ISBN 13 : 1848169647
Total Pages : 909 pages
Book Rating : 4.8/5 (481 download)

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Book Synopsis Catalysis by Ceria and Related Materials by : Alessandro Trovarelli

Download or read book Catalysis by Ceria and Related Materials written by Alessandro Trovarelli and published by World Scientific. This book was released on 2013 with total page 909 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book follows the 2002 edition of Catalysis by Ceria and Related Materials, which was the first book entirely devoted to ceria and its catalytic properties. In the ten years since the first edition a massive amount of work has been carried out in the field, and ceria has gained a prominent position in catalysis as one of the most valuable material for several applications. This second edition covers fundamental and applied aspects of the latest advances in ceria-based materials with a special focus on structural, redox and catalytic features. Special emphasis is given to nano-engineered and nano-shaped systems which are a key factor in the predictive and rational design of ceria with novel properties.In addition, the book presents recent advances in emerging and traditional large-scale applications of ceria in catalysis, such as the treatment of emissions from mobile sources (including diesel and gasoline engines). The primary readership includes catalysis and material science researchers from academy and industry and postdoctorate and graduate students in chemistry, chemical engineering and physics.

Handbook on Rare Earth Metals and Alloys (Properties, Extraction, Preparation and Applications)

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Publisher : ASIA PACIFIC BUSINESS PRESS Inc.
ISBN 13 : 8178331209
Total Pages : 557 pages
Book Rating : 4.1/5 (783 download)

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Book Synopsis Handbook on Rare Earth Metals and Alloys (Properties, Extraction, Preparation and Applications) by : NPCS Board of Consultants & Engineers

Download or read book Handbook on Rare Earth Metals and Alloys (Properties, Extraction, Preparation and Applications) written by NPCS Board of Consultants & Engineers and published by ASIA PACIFIC BUSINESS PRESS Inc.. This book was released on 2009-04-01 with total page 557 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare earths are essential constituents of more than 100 mineral species and present in many more through substitution. They have a marked geochemical affinity for calcium, titanium, niobium, zirconium, fluoride, phosphate and carbonate ions. Industrially important minerals, which are utilized at present for rare earths production, are essentially three, namely monazite, bastnasite and xenotime. In modern time techniques for exploration of rare earths and yttrium minerals include geologic identification of environments of deposition and surface as well as airborne reconnaissance with magnetometric and radiometric equipment. There are numerous applications of rare earths such as in glass making industry, cracking catalysts, electronic and optoelectronic devices, medical technology, nuclear technology, agriculture, plastic industry etc. Lot of metals and alloys called rare earth are lying in the earth which required to be processed. Some of the important elements extracted from rare earths are uranium, lithium, beryllium, selenium, platinum metals, tantalum, silicon, molybdenum, manganese, chromium, cadmium, titanium, tungsten, zirconium etc. There are different methods involved in production of metals and non metals from rare earths for example; separation, primary crushing, secondary crushing, wet grinding, dry grinding etc. The rare earths are silver, silverymwhite, or gray metals; they have a high luster, but tarnish readily in air, have high electrical conductivity. The rare earths share many common properties this makes them difficult to separate or even distinguish from each other. There are very small differences in solubility and complex formation between the rare earths. The rare earth metals naturally occur together in minerals. Rare earths are found with non metals, usually in the 3+ oxidation state. At present all the rare earth resources in India are in the form of placer monazite deposits, which also carry other industrially important minerals like ilmenite, rutile, zircon, sillimanite and garnet. Some of the fundamentals of the book are commercially important rare earth minerals, exploration for rare earth resources, rare earth resources of the world, some rare earth minerals and their approximate compositions, rare earths in cracking catalysts, rare earth based phosphors, interdependence of applications and production of rare earths, uranium alloys, conversion of ores to lithium chemicals, characterization and analysis of very pure silicon, derivation of molybdenum metal, electoplating and chromizing, electrolytic production of titanium, heat treatment of titanium alloys, tensile properties of alloys etc. The book covers occurrence of rare earth, resources of the world, production of lithium metals, compounds derived from the metals, chemical properties of beryllium, uses of selenium, derivation of molybdenum metals, ore concentration and treatment and many more. This is a unique book of its kind, which will be a great asset for scientists, researchers, technocrats and entrepreneurs. 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Progress in the Science and Technology of the Rare Earths

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Author :
Publisher : Elsevier
ISBN 13 : 1483185877
Total Pages : 373 pages
Book Rating : 4.4/5 (831 download)

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Book Synopsis Progress in the Science and Technology of the Rare Earths by : Leroy Eyring

Download or read book Progress in the Science and Technology of the Rare Earths written by Leroy Eyring and published by Elsevier. This book was released on 2013-09-17 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: Progress in the Science and Technology of the Rare Earths, Volume 2 is a collection of papers that details the advancement in various areas of rare earth technology. The coverage of the text includes the practical applications and methods of preparation of rare earth materials. The selection also covers topics about the various properties of rare earths, such as the molecular field model of exchange coupling in rare earth materials; thermodynamic and magnetic properties of the rare earth chalcogenides and pnictides; and structural and solid state chemistry of pure rare earth oxides. The book will be of great use to individuals involved in the research and development of technologies that utilize rare earth materials.

Extractive Metallurgy of Niobium

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Publisher : Routledge
ISBN 13 : 1351448978
Total Pages : 272 pages
Book Rating : 4.3/5 (514 download)

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Book Synopsis Extractive Metallurgy of Niobium by : A.K. Suri

Download or read book Extractive Metallurgy of Niobium written by A.K. Suri and published by Routledge. This book was released on 2017-11-13 with total page 272 pages. Available in PDF, EPUB and Kindle. Book excerpt: The growth and development witnessed today in modern science, engineering, and technology owes a heavy debt to the rare, refractory, and reactive metals group, of which niobium is a member. Extractive Metallurgy of Niobium presents a vivid account of the metal through its comprehensive discussions of properties and applications, resources and resource processing, chemical processing and compound preparation, metal extraction, and refining and consolidation. Typical flow sheets adopted in some leading niobium-producing countries for the beneficiation of various niobium sources are presented, and various chemical processes for producing pure forms of niobium intermediates such as chloride, fluoride, and oxide are discussed. The book also explains how to liberate the metal from its intermediates and describes the physico-chemical principles involved. It is an excellent reference for chemical metallurgists, hydrometallurgists, extraction and process metallurgists, and minerals processors. It is also valuable to a wide variety of scientists, engineers, technologists, and students interested in the topic.

ACS Monograph

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Publisher :
ISBN 13 :
Total Pages : 408 pages
Book Rating : 4.X/5 (4 download)

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Book Synopsis ACS Monograph by :

Download or read book ACS Monograph written by and published by . This book was released on 1921 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Homogeneous Catalysis

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Publisher : John Wiley & Sons
ISBN 13 :
Total Pages : 262 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis Homogeneous Catalysis by : George William Parshall

Download or read book Homogeneous Catalysis written by George William Parshall and published by John Wiley & Sons. This book was released on 1980 with total page 262 pages. Available in PDF, EPUB and Kindle. Book excerpt: Contains a balanced discussion of homogeneous catalytic reactions that are used in industry, featuring every documented example employed in a current commercial process, or that have a broad application in the organic synthesis laboratory. Incorporates synthesis with chiral catalysts in chapters on hydrogenation, CO chemistry and olefin oxidation. New additions include Tennessee Eastman's coal-based acetic anhydride plant and IFP's Dimersol process for dimerizing propylene as well as major changes in the areas on pharmaceuticals, flavors, fragrances, agricultural and electronic chemicals.

Lanthanides, Tantalum and Niobium

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Publisher : Springer Science & Business Media
ISBN 13 : 364287262X
Total Pages : 383 pages
Book Rating : 4.6/5 (428 download)

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Book Synopsis Lanthanides, Tantalum and Niobium by : Peter Möller

Download or read book Lanthanides, Tantalum and Niobium written by Peter Möller and published by Springer Science & Business Media. This book was released on 2013-11-09 with total page 383 pages. Available in PDF, EPUB and Kindle. Book excerpt: Rare Earth Elements (REE) as well as tantalum and niobium are of tremendous importance because of their specific high-technology applications. The contributions gathered in this volume give an up-to-date survey on the mineralogy, primary ore deposits, prospecting, processing and applications of REE, Ta, and Nd, making this volume a useful handbook for practitioners and students. Finally, the comprehensive coverage of the fundamental aspects, especially as regards REE as tracers of geological phenomena, will prove extremely helpful.