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The Physical Chemistry Of Electrolyte Solutions
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Book Synopsis Physical Chemistry of Electrolyte Solutions by : Josef Barthel
Download or read book Physical Chemistry of Electrolyte Solutions written by Josef Barthel and published by Springer Science & Business Media. This book was released on 1998-04 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: The aim and purpose of this book is a survey of our actual basic knowledge of electrolyte solutions. It is meant for chemical engineers looking for an introduction to this field of increasing interest for various technologies, and for scientists wishing to have access to the broad field of modern electrolyte chemistry.
Book Synopsis Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) by : Lloyd L Lee
Download or read book Molecular Thermodynamics Of Electrolyte Solutions (Second Edition) written by Lloyd L Lee and published by World Scientific. This book was released on 2021-01-07 with total page 295 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrolytes and salt solutions are ubiquitous in chemical industry, biology and nature. This unique compendium introduces the elements of the solution properties of ionic mixtures. In addition, it also serves as a bridge to the modern researches into the molecular aspects of uniform and non-uniform charged systems. Notable subjects include the Debye-Hückel limit, Pitzer's formulation, Setchenov salting-out, and McMillan-Mayer scale. Two new chapters on industrial applications — natural gas treating, and absorption refrigeration, are added to make the book current and relevant.This textbook is eminently suitable for undergraduate and graduate students. For practicing engineers without a background in salt solutions, this introductory volume can also be used as a self-study.
Book Synopsis An Introduction to Aqueous Electrolyte Solutions by : Margaret Robson Wright
Download or read book An Introduction to Aqueous Electrolyte Solutions written by Margaret Robson Wright and published by John Wiley & Sons. This book was released on 2007-06-05 with total page 603 pages. Available in PDF, EPUB and Kindle. Book excerpt: An Introduction to Aqueous Electrolyte Solutions is a comprehensive coverage of the subject including the development of key concepts and theory that focus on the physical rather than the mathematical aspects. Important links are made between the study of electrolyte solutions and other branches of chemistry, biology, and biochemistry, making it a useful cross-reference tool for students studying this important area of electrochemistry. Carefully developed throughout, each chapter includes intended learning outcomes and worked problems and examples to encourage student understanding of this multidisciplinary subject. * a comprehensive introduction to aqueous electrolyte solutions including the development of key concepts and theories * emphasises the connection between observable macroscopic experimental properties and interpretations made at the molecular level * key developments in concepts and theory explained in a descriptive manner to encourage student understanding * includes worked problems and examples throughout An invaluable text for students taking courses in chemistry and chemical engineering, this book will also be useful for biology, biochemistry and biophysics students required to study electrochemistry.
Book Synopsis Physical Chemistry for the Biosciences by : Raymond Chang
Download or read book Physical Chemistry for the Biosciences written by Raymond Chang and published by University Science Books. This book was released on 2005-02-11 with total page 706 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is ideal for use in a one-semester introductory course in physical chemistry for students of life sciences. The author's aim is to emphasize the understanding of physical concepts rather than focus on precise mathematical development or on actual experimental details. Subsequently, only basic skills of differential and integral calculus are required for understanding the equations. The end-of-chapter problems have both physiochemical and biological applications.
Book Synopsis Properties of Aqueous Solutions of Electrolytes by : Ivan D. Zaytsev
Download or read book Properties of Aqueous Solutions of Electrolytes written by Ivan D. Zaytsev and published by CRC Press. This book was released on 1992-08-24 with total page 1782 pages. Available in PDF, EPUB and Kindle. Book excerpt: Properties of Aqueous Solutions of Electrolytes is a handbook that systematizes the information on physico-chemical parameters of multicomponent aqueous electrolyte solutions. This important data collection will be invaluable for developing new methods for more efficient chemical technologies, choosing optimal solutions for more effective methods of using raw materials and energy resources, and other such activities. This edition, the first available in English, has been substantially revised and augmented. Many new tables have been added because of a significantly larger list of electrolytes and their properties (electrical conductivity, boiling and freezing points, pressure of saturated vapors, activity and diffusion coefficients). The book is divided into two sections. The first section provides tables that list the properties of binary aqueous solutions of electrolytes, while the second section deals with the methods for calculating their properties in multicomponent systems. All values are given in PSI units or fractional and multiple units. Metrological characteristics of the experimental methods used for the determination of physico-chemical parameters are indicated as a relative error and those of the computational methods as a relative error or a root-mean square deviation.
Book Synopsis Electrochemistry for Materials Science by : Walfried Plieth
Download or read book Electrochemistry for Materials Science written by Walfried Plieth and published by Elsevier. This book was released on 2008-01-08 with total page 433 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book introduces the principles of electrochemistry with a special emphasis on materials science. This book is clearly organized around the main topic areas comprising electrolytes, electrodes, development of the potential differences in combining electrolytes with electrodes, the electrochemical double layer, mass transport, and charge transfer, making the subject matter more accessible.In the second part, several important areas for materials science are described in more detail. These chapters bridge the gap between the introductory textbooks and the more specialized literature. They feature the electrodeposition of metals and alloys, electrochemistry of oxides and semiconductors, intrinsically conducting polymers, and aspects of nanotechnology with an emphasis on the codeposition of nanoparticles.This book provides a good introduction into electrochemistry for the graduate student. For the research student as well as for the advanced reader there is sufficient information on the basic problems in special chapters. The book is suitable for students and researchers in chemistry, physics, engineering, as well as materials science.- Introduction into electrochemistry- Metal and alloy electrodeposition- Oxides and semiconductors, corrosion- Intrinsically conducting polymers- Codeposition of nanoparticles, multilayers
Book Synopsis Handbook of Aqueous Electrolyte Thermodynamics by : Joseph F. Zemaitis, Jr.
Download or read book Handbook of Aqueous Electrolyte Thermodynamics written by Joseph F. Zemaitis, Jr. and published by John Wiley & Sons. This book was released on 2010-09-16 with total page 876 pages. Available in PDF, EPUB and Kindle. Book excerpt: Expertise in electrolyte systems has become increasingly important in traditional CPI operations, as well as in oil/gas exploration and production. This book is the source for predicting electrolyte systems behavior, an indispensable "do-it-yourself" guide, with a blueprint for formulating predictive mathematical electrolyte models, recommended tabular values to use in these models, and annotated bibliographies. The final chapter is a general recipe for formulating complete predictive models for electrolytes, along with a series of worked illustrative examples. It can serve as a useful research and application tool for the practicing process engineer, and as a textbook for the chemical engineering student.
Book Synopsis Liquids, Solutions, and Interfaces by : W. Ronald Fawcett
Download or read book Liquids, Solutions, and Interfaces written by W. Ronald Fawcett and published by Oxford University Press. This book was released on 2004-07-01 with total page 638 pages. Available in PDF, EPUB and Kindle. Book excerpt: Fifty years ago solution chemistry occupied a major fraction of physical chemistry textbooks, and dealt mainly with classical thermodynamics, phase equilibria, and non-equilibrium phenomena, especially those related to electrochemistry. Much has happened in the intervening period, with tremendous advances in theory and the development of important new experimental techniques. This book brings the reader through the developments from classical macroscopic descriptions to more modern microscopic details.
Book Synopsis Self-diffusion in Electrolyte Solutions by : R. Mills
Download or read book Self-diffusion in Electrolyte Solutions written by R. Mills and published by Elsevier. This book was released on 2013-10-22 with total page 355 pages. Available in PDF, EPUB and Kindle. Book excerpt: This compilation - the first of its kind - fills a real gap in the field of electrolyte data. Virtually all self-diffusion data in electrolyte solutions as reported in the literature have been examined and the book contains over 400 tables covering diffusion in binary and ternary aqueous solutions, in mixed solvents, and of non-electrolytes in various solvents. An important feature of the compilation is that all data have been critically examined and their accuracy assessed. Other features are an introductory chapter in which the methods of measurement are reviewed; appendices containing tables of the limiting self-diffusion coefficients of ions; and a list of references to data which have been omitted but where information about the diffusing system is given. This is the only complete compilation of self-diffusion data in electrolyte solutions. It will appeal to electrochemists in general, particularly now that recent developments in the theory of transport processes require these data. It will also have a special appeal to electroanalytical chemists in that the ionic self-diffusion coefficient is an important quantity for the interpretation of electrode reactions. In addition, the book will interest geochemists and environmental chemists because the migration of radioactive ions from nuclear waste in certain aqueous media will be governed by the tracer-diffusion coefficient.
Book Synopsis Physical Chemistry of Organic Solvent Systems by : A Covington
Download or read book Physical Chemistry of Organic Solvent Systems written by A Covington and published by . This book was released on 1973-11-01 with total page 836 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis A Textbook of Physical Chemistry – Volume 1 by : Mandeep Dalal
Download or read book A Textbook of Physical Chemistry – Volume 1 written by Mandeep Dalal and published by Dalal Institute. This book was released on 2018-01-01 with total page 432 pages. Available in PDF, EPUB and Kindle. Book excerpt: An advanced-level textbook of physical chemistry for the graduate (B.Sc) and postgraduate (M.Sc) students of Indian and foreign universities. This book is a part of four volume series, entitled "A Textbook of Physical Chemistry – Volume I, II, III, IV". CONTENTS: Chapter 1. Quantum Mechanics – I: Postulates of quantum mechanics; Derivation of Schrodinger wave equation; Max-Born interpretation of wave functions; The Heisenberg’s uncertainty principle; Quantum mechanical operators and their commutation relations; Hermitian operators (elementary ideas, quantum mechanical operator for linear momentum, angular momentum and energy as Hermition operator); The average value of the square of Hermitian operators; Commuting operators and uncertainty principle(x & p; E & t); Schrodinger wave equation for a particle in one dimensional box; Evaluation of average position, average momentum and determination of uncertainty in position and momentum and hence Heisenberg’s uncertainty principle; Pictorial representation of the wave equation of a particle in one dimensional box and its influence on the kinetic energy of the particle in each successive quantum level; Lowest energy of the particle. Chapter 2. Thermodynamics – I: Brief resume of first and second Law of thermodynamics; Entropy changes in reversible and irreversible processes; Variation of entropy with temperature, pressure and volume; Entropy concept as a measure of unavailable energy and criteria for the spontaneity of reaction; Free energy, enthalpy functions and their significance, criteria for spontaneity of a process; Partial molar quantities (free energy, volume, heat concept); Gibb’s-Duhem equation. Chapter 3. Chemical Dynamics – I: Effect of temperature on reaction rates; Rate law for opposing reactions of Ist order and IInd order; Rate law for consecutive & parallel reactions of Ist order reactions; Collision theory of reaction rates and its limitations; Steric factor; Activated complex theory; Ionic reactions: single and double sphere models; Influence of solvent and ionic strength; The comparison of collision and activated complex theory. Chapter 4. Electrochemistry – I: Ion-Ion Interactions: The Debye-Huckel theory of ion- ion interactions; Potential and excess charge density as a function of distance from the central ion; Debye Huckel reciprocal length; Ionic cloud and its contribution to the total potential; Debye - Huckel limiting law of activity coefficients and its limitations; Ion-size effect on potential; Ion-size parameter and the theoretical mean-activity coefficient in the case of ionic clouds with finite-sized ions; Debye - Huckel-Onsager treatment for aqueous solutions and its limitations; Debye-Huckel-Onsager theory for non-aqueous solutions; The solvent effect on the mobality at infinite dilution; Equivalent conductivity (Λ) vs. concentration c 1/2 as a function of the solvent; Effect of ion association upon conductivity (Debye- Huckel - Bjerrum equation). Chapter 5. Quantum Mechanics – II: Schrodinger wave equation for a particle in a three dimensional box; The concept of degeneracy among energy levels for a particle in three dimensional box; Schrodinger wave equation for a linear harmonic oscillator & its solution by polynomial method; Zero point energy of a particle possessing harmonic motion and its consequence; Schrodinger wave equation for three dimensional Rigid rotator; Energy of rigid rotator; Space quantization; Schrodinger wave equation for hydrogen atom, separation of variable in polar spherical coordinates and its solution; Principle, azimuthal and magnetic quantum numbers and the magnitude of their values; Probability distribution function; Radial distribution function; Shape of atomic orbitals (s,p & d). Chapter 6. Thermodynamics – II: Classius-Clayperon equation; Law of mass action and its thermodynamic derivation; Third law of thermodynamics (Nernest heat theorem, determination of absolute entropy, unattainability of absolute zero) and its limitation; Phase diagram for two completely miscible components systems; Eutectic systems, Calculation of eutectic point; Systems forming solid compounds Ax By with congruent and incongruent melting points; Phase diagram and thermodynamic treatment of solid solutions. Chapter 7. Chemical Dynamics – II: Chain reactions: hydrogen-bromine reaction, pyrolysis of acetaldehyde, decomposition of ethane; Photochemical reactions (hydrogen - bromine & hydrogen -chlorine reactions); General treatment of chain reactions (ortho-para hydrogen conversion and hydrogen - bromine reactions); Apparent activation energy of chain reactions, Chain length; Rice-Herzfeld mechanism of organic molecules decomposition(acetaldehyde); Branching chain reactions and explosions ( H2-O2 reaction); Kinetics of (one intermediate) enzymatic reaction : Michaelis-Menton treatment; Evaluation of Michaelis 's constant for enzyme-substrate binding by Lineweaver-Burk plot and Eadie-Hofstae methods; Competitive and non-competitive inhibition. Chapter 8. Electrochemistry – II: Ion Transport in Solutions: Ionic movement under the influence of an electric field; Mobility of ions; Ionic drift velocity and its relation with current density; Einstein relation between the absolute mobility and diffusion coefficient; The Stokes- Einstein relation; The Nernst -Einstein equation; Walden’s rule; The Rate-process approach to ionic migration; The Rate process equation for equivalent conductivity; Total driving force for ionic transport, Nernst - Planck Flux equation; Ionic drift and diffusion potential; the Onsager phenomenological equations; The basic equation for the diffusion; Planck-Henderson equation for the diffusion potential.
Book Synopsis Handbook of Electrochemistry by : Cynthia G. Zoski
Download or read book Handbook of Electrochemistry written by Cynthia G. Zoski and published by Elsevier. This book was released on 2007-02-07 with total page 935 pages. Available in PDF, EPUB and Kindle. Book excerpt: Electrochemistry plays a key role in a broad range of research and applied areas including the exploration of new inorganic and organic compounds, biochemical and biological systems, corrosion, energy applications involving fuel cells and solar cells, and nanoscale investigations. The Handbook of Electrochemistry serves as a source of electrochemical information, providing details of experimental considerations, representative calculations, and illustrations of the possibilities available in electrochemical experimentation. The book is divided into five parts: Fundamentals, Laboratory Practical, Techniques, Applications, and Data. The first section covers the fundamentals of electrochemistry which are essential for everyone working in the field, presenting an overview of electrochemical conventions, terminology, fundamental equations, and electrochemical cells, experiments, literature, textbooks, and specialized books. Part 2 focuses on the different laboratory aspects of electrochemistry which is followed by a review of the various electrochemical techniques ranging from classical experiments to scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry. Applications of electrochemistry include electrode kinetic determinations, unique aspects of metal deposition, and electrochemistry in small places and at novel interfaces and these are detailed in Part 4. The remaining three chapters provide useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials. * serves as a source of electrochemical information * includes useful electrochemical data and information involving electrode potentials, diffusion coefficients, and methods used in measuring liquid junction potentials * reviews electrochemical techniques (incl. scanning electrochemical microscopy, electrogenerated chemiluminesence and spectroelectrochemistry)
Book Synopsis Activity Coefficients in Electrolyte Solutions by : Kenneth S. Pitzer
Download or read book Activity Coefficients in Electrolyte Solutions written by Kenneth S. Pitzer and published by CRC Press. This book was released on 2018-05-04 with total page 552 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book was first published in 1991. It considers the concepts and theories relating to mostly aqueous systems of activity coefficients.
Book Synopsis Aqueous Systems at Elevated Temperatures and Pressures by : Roberto Fernandez-Prini
Download or read book Aqueous Systems at Elevated Temperatures and Pressures written by Roberto Fernandez-Prini and published by Elsevier. This book was released on 2004-07-06 with total page 767 pages. Available in PDF, EPUB and Kindle. Book excerpt: The International Association for the Properties of Water and Steam (IAPWS) has produced this book in order to provide an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures. These systems are central to many areas of scientific study and industrial application, including electric power generation, industrial steam systems, hydrothermal processing of materials, geochemistry, and environmental applications. The authors' goal is to present the material at a level that serves both the graduate student seeking to learn the state of the art, and also the industrial engineer or chemist seeking to develop additional expertise or to find the data needed to solve a specific problem. The wide range of people for whom this topic is important provides a challenge. Advanced work in this area is distributed among physical chemists, chemical engineers, geochemists, and other specialists, who may not be aware of parallel work by those outside their own specialty. The particular aspects of high-temperature aqueous physical chemistry of interest to one industry may be irrelevant to another; yet another industry might need the same basic information but in a very different form. To serve all these constituencies, the book includes several chapters that cover the foundational thermophysical properties (such as gas solubility, phase behavior, thermodynamic properties of solutes, and transport properties) that are of interest across numerous applications. The presentation of these topics is intended to be accessible to readers from a variety of backgrounds. Other chapters address fundamental areas of more specialized interest, such as critical phenomena and molecular-level solution structure. Several chapters are more application-oriented, addressing areas such as power-cycle chemistry and hydrothermal synthesis. As befits the variety of interests addressed, some chapters provide more theoretical guidance while others, such as those on acid/base equilibria and the solubilities of metal oxides and hydroxides, emphasize experimental techniques and data analysis.- Covers both the theory and applications of all Hydrothermal solutions - Provides an accessible, up-to-date overview of important aspects of the physical chemistry of aqueous systems at high temperatures and pressures- The presentation of the book is understandable to readers from a variety of backgrounds
Book Synopsis Encyclopedia of Geochemistry by : C.P. Marshall
Download or read book Encyclopedia of Geochemistry written by C.P. Marshall and published by Springer Science & Business Media. This book was released on 1999-07-31 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is a complete and authoritative reference text on an evolving field. Over 200 international scientists have written over 340 separate topics on different aspects of geochemistry including organics, trace elements, isotopes, high and low temperature geochemistry, and ore deposits, to name just a few.
Book Synopsis The Interpretation of Ionic Conductivity in Liquids by : Stuart I. Smedley
Download or read book The Interpretation of Ionic Conductivity in Liquids written by Stuart I. Smedley and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 208 pages. Available in PDF, EPUB and Kindle. Book excerpt: The phenomenon of electrical conductance in liquids is of great impor tance to the technologist, as well as to the theoretical scientist. A glance at Chemical Abstracts will reveal that electrical conductivity can be used as an analytical tool for such diverse substances as concrete and suntan lotion as well as a tool for elucidating the dynamics of molecules in simple liquids. It is a phenomenon that is relatively easily measured, which explains the great diversity of conductance studies that span a range of experimental conditions unequalled in the study of nonequilibrium phenomena. It is clearly impossible for one book, notwithstanding the ability of one author, to cope with so much information or to cover even a significant fraction of the literature on this subject. However, I believe it is possible to bring together in one monograph the mainstream ideas on the interpretation of the phenomenon in relatively simple systems. It is hoped that this book will achieve this result and will provide a concise and coherent account of the interpretation of ionic conductivity in dilute electrolyte solutions, concentrated solutions, low-temperature or glass-forming molten salts, ionic melts, molecular fluids, and fluids of geological and industrial inter est. Most of these topics have been discussed in other books and review articles, but to the best of my knowledge they have not been gathered together in a single monograph.
Book Synopsis Ionic Solution Theory by : Harold L. Friedman
Download or read book Ionic Solution Theory written by Harold L. Friedman and published by . This book was released on 2013-03 with total page 274 pages. Available in PDF, EPUB and Kindle. Book excerpt: Monographs In Statistical Physics And Thermodynamics, Volume 3.
