The Chemistry of the Metal Carbon Bond, Volume 2

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Author :
Publisher : Wiley
ISBN 13 : 9780471902829
Total Pages : 936 pages
Book Rating : 4.9/5 (28 download)

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Book Synopsis The Chemistry of the Metal Carbon Bond, Volume 2 by : Frank R. Hartley

Download or read book The Chemistry of the Metal Carbon Bond, Volume 2 written by Frank R. Hartley and published by Wiley. This book was released on 1985 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt: This is the second volume in the series edited by Frank Hartley on The Chemistry of the Metal Carbon Bond. The series is concerned with organometallic compounds from the point of view of the carbon end of the bond and is, therefore, relevant to Organic Chemists. This particular volume is concerned with Carbon-Carbon bonds and their formation using organometallic compounds.

The Nature and Cleavage of Metal-carbon Bonds

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Publisher :
ISBN 13 :
Total Pages : 936 pages
Book Rating : 4.X/5 (1 download)

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Book Synopsis The Nature and Cleavage of Metal-carbon Bonds by : F. R. Hartley

Download or read book The Nature and Cleavage of Metal-carbon Bonds written by F. R. Hartley and published by . This book was released on 1985 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Cleavage of Carbon-Carbon Single Bonds by Transition Metals

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Author :
Publisher : John Wiley & Sons
ISBN 13 : 352733632X
Total Pages : 292 pages
Book Rating : 4.5/5 (273 download)

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Book Synopsis Cleavage of Carbon-Carbon Single Bonds by Transition Metals by : Masahiro Murakami

Download or read book Cleavage of Carbon-Carbon Single Bonds by Transition Metals written by Masahiro Murakami and published by John Wiley & Sons. This book was released on 2015-12-21 with total page 292 pages. Available in PDF, EPUB and Kindle. Book excerpt: Edited by leading experts and pioneers in the field, this is the first up-to-date book on this hot topic. The authors provide synthetic chemists with different methods to activate carbon-carbon sigma bonds in organic molecules promoted by transition metal complexes. They explain the basic principles and strategies for carbon-carbon bond cleavage and highlight recently developed synthetic protocols based on this methodology. In so doing, they cover cleavage of C-C bonds in strained molecules, reactions involving elimination of carbon dioxide and ketones, reactions via retroallylation, and cleavage of C-C bonds of ketones and nitriles. The result is an excellent information source for researchers in academia and industry working in the field of synthetic organic chemistry, while equally serving as supplementary reading for advanced courses in organometallic chemistry and catalysis.

C-C Bond Activation

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Author :
Publisher : Springer
ISBN 13 : 364255055X
Total Pages : 265 pages
Book Rating : 4.6/5 (425 download)

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Book Synopsis C-C Bond Activation by : Guangbin Dong

Download or read book C-C Bond Activation written by Guangbin Dong and published by Springer. This book was released on 2014-09-18 with total page 265 pages. Available in PDF, EPUB and Kindle. Book excerpt: The series Topics in Current Chemistry presents critical reviews of the present and future trends in modern chemical research. The scope of coverage is all areas of chemical science including the interfaces with related disciplines such as biology, medicine and materials science. The goal of each thematic volume is to give the non-specialist reader, whether in academia or industry, a comprehensive insight into an area where new research is emerging which is of interest to a larger scientific audience. Each review within the volume critically surveys one aspect of that topic and places it within the context of the volume as a whole. The most significant developments of the last 5 to 10 years are presented using selected examples to illustrate the principles discussed. The coverage is not intended to be an exhaustive summary of the field or include large quantities of data, but should rather be conceptual, concentrating on the methodological thinking that will allow the non-specialist reader to understand the information presented. Contributions also offer an outlook on potential future developments in the field. Review articles for the individual volumes are invited by the volume editors. Readership: research chemists at universities or in industry, graduate students

Activation of Unreactive Bonds and Organic Synthesis

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Publisher : Springer
ISBN 13 : 3540685251
Total Pages : 275 pages
Book Rating : 4.5/5 (46 download)

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Book Synopsis Activation of Unreactive Bonds and Organic Synthesis by : Shinji Murai

Download or read book Activation of Unreactive Bonds and Organic Synthesis written by Shinji Murai and published by Springer. This book was released on 2003-07-01 with total page 275 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last few years a large repetoire of methods for the activation of unreactive organic functionalities and for their use in organic synthesis has been developed. In this volume, areas ranging from the activation of C-H bonds to the chemical transformation of dinitrogen are authoritatively discussed by leading experts in the field. To activate means to be able to cleave otherwise inert chemical bonds. The cleavage and formation of chemical bonds is fundamental to organic synthesis; these new activation methodologies make hitherto infeasible reactions extremely easy and create new opportunities for innovative organic transformations, for both industry and academia. This is the first book that provides a thorough and timely coverage of both inorganic and organic synthetic aspects of bond activation, thus giving a broad overview of the field and allowing both inorganic and organic chemists ready access to the methodologies involved.

Metal-Carbon Bonds in Enzymes and Cofactors

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Author :
Publisher : Walter de Gruyter GmbH & Co KG
ISBN 13 : 3110436582
Total Pages : 532 pages
Book Rating : 4.1/5 (14 download)

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Book Synopsis Metal-Carbon Bonds in Enzymes and Cofactors by : Astrid Sigel

Download or read book Metal-Carbon Bonds in Enzymes and Cofactors written by Astrid Sigel and published by Walter de Gruyter GmbH & Co KG. This book was released on 2015-07-24 with total page 532 pages. Available in PDF, EPUB and Kindle. Book excerpt: The occurrence of a wide variety of metal-carbon bonds in living organisms, ranging from bacteria to humans, is only recently recognized. Of course, the historical examples are the B12 coenzymes containing cobalt-carbon bonds, but now such bonds are also known for nickel, iron, copper, and other transition metal ions. There is no other comparable book; MILS-6, written by 17 experts, summarizes the most recent insights into this fascinating topic.

Cleavage of Carbon-metal Bonds by Acids

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Publisher :
ISBN 13 :
Total Pages : 360 pages
Book Rating : 4.:/5 (181 download)

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Book Synopsis Cleavage of Carbon-metal Bonds by Acids by : Jin-Young Kim

Download or read book Cleavage of Carbon-metal Bonds by Acids written by Jin-Young Kim and published by . This book was released on 1960 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Comprehensive Organometallic Chemistry III, Volume 3

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Publisher :
ISBN 13 :
Total Pages : 976 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Comprehensive Organometallic Chemistry III, Volume 3 by : D. M. P. Mingos

Download or read book Comprehensive Organometallic Chemistry III, Volume 3 written by D. M. P. Mingos and published by . This book was released on 2007 with total page 976 pages. Available in PDF, EPUB and Kindle. Book excerpt: Provides essential information for any chemist or technologist who needs to use or apply organometallic compounds. Provides a comprehensive overview of recent developments in the field and attempts to predict trends in the field over the next ten years.

Oxidative Carbon-carbon Bond Cleavage Reactions of Metal Flavonolato and Chlorodiketonate Complexes

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (983 download)

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Book Synopsis Oxidative Carbon-carbon Bond Cleavage Reactions of Metal Flavonolato and Chlorodiketonate Complexes by : Sushma L. Saraf

Download or read book Oxidative Carbon-carbon Bond Cleavage Reactions of Metal Flavonolato and Chlorodiketonate Complexes written by Sushma L. Saraf and published by . This book was released on 2016 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: The research presented in this dissertation has focused on studies of metal complexes which undergo oxidative aliphatic carbon-carbon bond cleavage using dioxygen as the oxidant. The goal of this research was to assess the reactivity and elucidate mechanistic details of the carbon-carbon bond cleavage reactions. The first part of this dissertation explores the light-induced dioxygenase reactivity of ruthenium flavonolato compounds. These compounds are of particular interest as they are currently being explored for their anti-cancer activity. The RuII(n6-p-cymene) flavonolato compounds studied were found to undergo photoinduced carbon-carbon bond cleavage albeit with low quantum efficiency. The cleaved products were found to be significantly less toxic than the starting material. The reactivity and loss of toxicity offers the possibility of light-induced deactivation of such compounds to limit overall toxicity. The remainder of the research presented in this dissertation is directed at understanding mechanistic features that govern the aliphatic carbon-carbon bond cleavage reactivity of mononuclear copper(II) chlorodiketonate complexes. Synthetic organic chemists have utilized molecular oxygen and copper catalysts for many organic transformations. However, few reports have appeared demonstrating aliphatic carbon-carbon bond cleavage mediated by copper and O2 and mechanistic details of these processes are limited. The previously reported complex [(6-Ph2TPA)Cu(PhC(O)CClC(O)Ph)]ClO4 was found to undergo aliphatic carbon-carbon bond cleavage under ambient conditions in the presence of O2. Notably, a catalytic amount of chloride anion increases the rate of this reaction. In order to understand this enhanced reactivity, we have performed mechanistic experiments to probe this system. These include: (1) spectroscopic studies to probe anion binding to the copper center; (2) variable temperature kinetic studies to benchmark computational studies; and (3) evaluation of the impact of electron density within the chlorodiketonate substrate on the rate of the reaction. The nature of the anion in the [(6-Ph2TPA)Cu(PhC(O)CClC(O)Ph)]ClO4 system was found to play a significant role in terms of the energy barriers associated with O2 activation and O-O bond cleavage. The electronic nature of the chlorodiketonate was found to affect the kinetics for the C-C bond cleavage reaction suggesting a change in mechanism for O2 activation depending on the substituent present.

Organometallic Chemistry

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Author :
Publisher : Royal Society of Chemistry
ISBN 13 : 085186631X
Total Pages : 534 pages
Book Rating : 4.8/5 (518 download)

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Book Synopsis Organometallic Chemistry by : E. W. Abel

Download or read book Organometallic Chemistry written by E. W. Abel and published by Royal Society of Chemistry. This book was released on 1987 with total page 534 pages. Available in PDF, EPUB and Kindle. Book excerpt: Organometallic chemistry is an interdisciplinary science which continues to grow at a rapid pace. Although there is continued interest in synthetic and structural studies the last decade has seen a growing interest in the potential of organometallic chemistry to provide answers to problems in catalysis synthetic organic chemistry and also in the development of new materials. This Specialist Periodical Report aims to reflect these current interests reviewing progress in theoretical organometallic chemistry, main group chemistry, the lanthanides and all aspects of transition metal chemistry. Specialist Periodical Reports provide systematic and detailed review coverage of progress in the major areas of chemical research. Written by experts in their specialist fields the series creates a unique service for the active research chemist, supplying regular critical in-depth accounts of progress in particular areas of chemistry. For over 80 years the Royal Society of Chemistry and its predecessor, the Chemical Society, have been publishing reports charting developments in chemistry, which originally took the form of Annual Reports. However, by 1967 the whole spectrum of chemistry could no longer be contained within one volume and the series Specialist Periodical Reports was born. The Annual Reports themselves still existed but were divided into two, and subsequently three, volumes covering Inorganic, Organic and Physical Chemistry. For more general coverage of the highlights in chemistry they remain a 'must'. Since that time the SPR series has altered according to the fluctuating degree of activity in various fields of chemistry. Some titles have remained unchanged, while others have altered their emphasis along with their titles; some have been combined under a new name whereas others have had to be discontinued. The current list of Specialist Periodical Reports can be seen on the inside flap of this volume.

Nobel Lectures In Chemistry (2006-2010)

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Author :
Publisher : World Scientific
ISBN 13 : 9814635677
Total Pages : 444 pages
Book Rating : 4.8/5 (146 download)

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Book Synopsis Nobel Lectures In Chemistry (2006-2010) by : Bengt Norden

Download or read book Nobel Lectures In Chemistry (2006-2010) written by Bengt Norden and published by World Scientific. This book was released on 2014-12-26 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt: Mentioned as the second prize area in his will, Chemistry was the most important science for Alfred Nobel's own work. The development of Nobel's inventions as well as the industrial processes he employed were based upon chemical knowledge. This volume is a collection of the Nobel lectures delivered by the prizewinners, together with their biographies and the presentation speeches for the period 2006-2010. Each Nobel lecture is based on the work for which the laureate was awarded the prize.List of prizewinners and their award citations:(2006) Roger D Kornberg — for his studies of the molecular basis of eukaryotic transcription;(2007) Gerhard Ertl — for his studies of chemical processes on solid surfaces;(2008) Osamu Shimomura, Martin Chalfie and Roger Y Tsien — for the discovery and development of the green fluorescent protein, GFP;(2009) Venkatraman Ramakrishnan, Thomas A Steitz and Ada E Yonath — for studies of the structure and function of the ribosome;(2010) Richard F Heck, Ei-ichi Negishi and Akira Suzuki — for palladium-catalyzed cross couplings in organic synthesis.

The Chemistry of the Metal-carbon Bond

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Publisher :
ISBN 13 :
Total Pages : 936 pages
Book Rating : 4.3/5 (91 download)

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Book Synopsis The Chemistry of the Metal-carbon Bond by : F. R. Hartley

Download or read book The Chemistry of the Metal-carbon Bond written by F. R. Hartley and published by . This book was released on 1982 with total page 936 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Chemistry for Degree Students (B.Sc. Elective Semester-V/VI - Elective-I) (As per CBCS)

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Author :
Publisher : S. Chand Publishing
ISBN 13 : 9352535855
Total Pages : 336 pages
Book Rating : 4.3/5 (525 download)

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Book Synopsis Chemistry for Degree Students (B.Sc. Elective Semester-V/VI - Elective-I) (As per CBCS) by : Madan R.L.

Download or read book Chemistry for Degree Students (B.Sc. Elective Semester-V/VI - Elective-I) (As per CBCS) written by Madan R.L. and published by S. Chand Publishing. This book was released on with total page 336 pages. Available in PDF, EPUB and Kindle. Book excerpt: • The subject matter has been divided into twelve chapters written in lucid language. Great care has been taken to explain the topics in such a simple way that it should be possible for the students to understand the various topics easily.

The Chemistry of the Metal Carbon Bond, Volume 5

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Author :
Publisher : Wiley
ISBN 13 : 9780471915560
Total Pages : 616 pages
Book Rating : 4.9/5 (155 download)

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Book Synopsis The Chemistry of the Metal Carbon Bond, Volume 5 by : Frank R. Hartley

Download or read book The Chemistry of the Metal Carbon Bond, Volume 5 written by Frank R. Hartley and published by Wiley. This book was released on 1990-02-09 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Part of a multi-volume work within the series "The Chemistry of Functional Groups", this volume covers the chemistry of the metal-carbon bond as a whole, but lays emphasis on the carbon end. It is also concerned with the use of organometallic compounds in organic and biological synthesis. It includes chapters on synthetic techniques such as sonochemistry, photochemistry and phase-transfer catalysis, on synthetic reactions such as asymmetric synthesis, oxidation and metathesis, on synthetic reagents such as metal clusters, organolanthanide, organoantimony and organobismuth reagents and chapters on biological alkylation and bio-organotin compounds.

Chemistry for Degree Students B.Sc. Third Year

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Publisher : S. Chand Publishing
ISBN 13 : 819477179X
Total Pages : 939 pages
Book Rating : 4.1/5 (947 download)

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Book Synopsis Chemistry for Degree Students B.Sc. Third Year by : Madan R.L.

Download or read book Chemistry for Degree Students B.Sc. Third Year written by Madan R.L. and published by S. Chand Publishing. This book was released on 2022 with total page 939 pages. Available in PDF, EPUB and Kindle. Book excerpt: For B.Sc 3rd year students of all Indian Universities. The book has been prepared keeping view the syllabi prepared by different universities on the basis of Model UGC Curriculum. A large number of illustrations, pictures and interesting examples have been provided to make the reading interesting and understandable. The question that have been provided in the Exercise are in tune with the latest pattern of examination.

Mechanistic Insights Into Carbon-Carbon Bond Oxidative Reconstruction and Construction

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Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (144 download)

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Book Synopsis Mechanistic Insights Into Carbon-Carbon Bond Oxidative Reconstruction and Construction by : Zhong Han Richmond Lee

Download or read book Mechanistic Insights Into Carbon-Carbon Bond Oxidative Reconstruction and Construction written by Zhong Han Richmond Lee and published by . This book was released on 2016 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Chemical manipulation of carbon-carbon bond is an expansive subject and overarching theme in chemistry. By all accounts, it takes a broad and concerted experimental and theoretical effort in order to fully comprehend the nature of this chemical bond that is virtually omnipresent in most important molecules. Developing a more intimate understanding and appreciation of the stability and reactivity of carbon-carbon bonds through quantum chemical calculations is therefore the main theme and driver of this thesis. In this thesis, computational quantum chemistry was employed as the tool to assist in the mechanistic investigation of C=C and C-C bond oxidation by environmental oxidants (O3 and O2) and the associated peroxyl ROO self-reaction chemistry, copper catalysed aerobic photo-oxidation of double, triple and single carbon-carbon bonds, the stereoselective and chemo-divergent construction of C-C bonds, and rhodium catalysed C-C(O) bond formation in Metal Organic Frameworks. It was also used to examine why C-C bonds were not formed during the termination process of radical polymerisation of polyacrylates and decomposition of RAFT-based polymers. The scope of this work is wide but is just the tip of the iceberg on carbon-carbon bond chemistry. This thesis consists of 11 written manuscripts, and is categorised into two parts. The first part focuses on carbon-carbon bond cleavage and oxidative transformation to C(O), so termed 'oxidative reconstruction', and the second part on carbon-carbon bond generation or construction in a stereo and chemo-specific manner. To achieve these research goals, extensive and appropiately benchmarked quantum chemical calculations were used to paint an insightful mechanistic picture of the reactions mentioned, which went beyond simply capturing knowledge of the reactivities and properties of carbon-carbon bonds, but also provided clarifications to experiments, and allowed one to make perceptive chemical predictions. This thesis highlights the important role of theory in allowing new scientific ideas to prosper, for instance updating reaction mechanisms that conform to new experimental observations, enabling better catalysts to be designed and strategies to preserve the durability of polymers. In hindsight, each work and chapter strives to take further steps toward bridging gaps in our knowledge of carbon-carbon bond chemistry.

The Chemistry of the Metal Carbon Bond, Volume 5

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Publisher :
ISBN 13 :
Total Pages : 616 pages
Book Rating : 4.X/5 (1 download)

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Book Synopsis The Chemistry of the Metal Carbon Bond, Volume 5 by : F. R. Hartley

Download or read book The Chemistry of the Metal Carbon Bond, Volume 5 written by F. R. Hartley and published by . This book was released on 1989 with total page 616 pages. Available in PDF, EPUB and Kindle. Book excerpt: Volume 5.