The Mesoscopic Theory of Polymer Dynamics

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Publisher : Springer Science & Business Media
ISBN 13 : 9048122317
Total Pages : 256 pages
Book Rating : 4.0/5 (481 download)

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Book Synopsis The Mesoscopic Theory of Polymer Dynamics by : Vladimir N. Pokrovskii

Download or read book The Mesoscopic Theory of Polymer Dynamics written by Vladimir N. Pokrovskii and published by Springer Science & Business Media. This book was released on 2009-12-16 with total page 256 pages. Available in PDF, EPUB and Kindle. Book excerpt: The theory presented in this book explains in a consistent manner all dynamics effects observed in very concentrated solutions and melts of linear polymers from a macromolecular point of view. The presentation is compact and self-contained.

The Mesoscopic Theory of Polymer Dynamics

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Publisher : Springer Science & Business Media
ISBN 13 : 0792366824
Total Pages : 243 pages
Book Rating : 4.7/5 (923 download)

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Book Synopsis The Mesoscopic Theory of Polymer Dynamics by : Vladimir Nikolaevich Pokrovskiĭ

Download or read book The Mesoscopic Theory of Polymer Dynamics written by Vladimir Nikolaevich Pokrovskiĭ and published by Springer Science & Business Media. This book was released on 2000 with total page 243 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our brutal century of atom bombs and spaceships can also be called the century ofpolymers. In any case, the broad spreading ofsynthetic polymer materials is one of thesigns of our time. A look at the various aspects of our life is enough to convince us that polymeric materials (textiles, pl- tics, rubbers) are as widely spread and important in our life as are other materials (metals and non-metals) derived from small molecules. Polymers have entered the life of the twentieth century as irreplaceable construction materials. Polymers differ from other substances by the size of their molecules which, appropriately enough, are referred to as macromolecules, since they consist of thousands or tens of thousands of atoms (molecular weight up to -4 6 10 ormore) andhave a macroscopic rectilinear length (upto 10 cm). The atoms ofa macromolecule are firmly held together by valence bonds, fo- ing a single entity. In polymeric substances, the weaker van der Waals forces have an effect on the components of the macromolecules which form the system. The structure of polymeric systems is more complicated than that oflow-molecular solids or liquids, but there are some common features: the atoms within a given macromolecule are ordered, but the centres ofmass of the individual macromolecules and parts of them are distributed randomly. Remarkably, the mechanical response of polymeric systems combines the elasticity of a solid with the fluidity of a liquid.

The Theory of Polymer Dynamics

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Author :
Publisher : Oxford University Press
ISBN 13 : 9780198520337
Total Pages : 420 pages
Book Rating : 4.5/5 (23 download)

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Book Synopsis The Theory of Polymer Dynamics by : Masao Doi

Download or read book The Theory of Polymer Dynamics written by Masao Doi and published by Oxford University Press. This book was released on 1988 with total page 420 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book provides a comprehensive account of the modern theory for the dynamical properties of polymer solutions. The theory has undergone dramatic evolution over the last two decades due to the introduction of new methods and concepts that have extended the frontier of theory from dilute solutions in which polymers move independently to concentrated solutions where many polymers converge. Among the properties examined are viscoelasticity, diffusion, dynamic light scattering, and electric birefringence. Nonlinear viscoelasticity is discussed in detail on the basis of molecular dynamical models. The book bridges the gap between classical theory and new developments, creating a consistent picture of polymer solution dynamics over the entire concentration range.

Statistical Physics of Polymers

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Publisher : Springer Science & Business Media
ISBN 13 : 366210024X
Total Pages : 223 pages
Book Rating : 4.6/5 (621 download)

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Book Synopsis Statistical Physics of Polymers by : Toshihiro Kawakatsu

Download or read book Statistical Physics of Polymers written by Toshihiro Kawakatsu and published by Springer Science & Business Media. This book was released on 2013-03-09 with total page 223 pages. Available in PDF, EPUB and Kindle. Book excerpt: From the reviews: "...This book is a very useful addition to polymer literature, and it is a pleasure to recommend it to the polymer community." (J.E. Mark, University of Cincinnati, POLYMER NEWS)

Introduction to Polymer Dynamics

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Publisher : CUP Archive
ISBN 13 : 9780521388498
Total Pages : 72 pages
Book Rating : 4.3/5 (884 download)

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Book Synopsis Introduction to Polymer Dynamics by : Pierre-Gilles de Gennes

Download or read book Introduction to Polymer Dynamics written by Pierre-Gilles de Gennes and published by CUP Archive. This book was released on 1990-09-20 with total page 72 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book, based on lectures given at the Polytechnic of Milan, gives a broad overview of the field of polymer dynamics. In these lectures the aim is to stress the fundamental concepts of the behaviour of polymers without drawing on the more advanced mathematical formalism which often obscures the natural elegance of the subject matter. Professor De Gennes is one of the most distinguished workers in the field of material science. Therefore this book will be welcomed by both the experienced researcher in the area and the interested layman. It will be of particular value to graduate students.

Tube Theory of Entangled Polymer Dynamics

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Publisher :
ISBN 13 :
Total Pages : 149 pages
Book Rating : 4.:/5 (526 download)

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Book Synopsis Tube Theory of Entangled Polymer Dynamics by : Tom McLeish

Download or read book Tube Theory of Entangled Polymer Dynamics written by Tom McLeish and published by . This book was released on 2002 with total page 149 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Mesoscopic Physics of Complex Materials

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Publisher : Springer Science & Business Media
ISBN 13 : 1461221080
Total Pages : 206 pages
Book Rating : 4.4/5 (612 download)

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Book Synopsis Mesoscopic Physics of Complex Materials by : T.S. Chow

Download or read book Mesoscopic Physics of Complex Materials written by T.S. Chow and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: A cross-disciplinary study of the physical properties of complex fluids, solids, and interfaces as a function of their mesoscopic structures, with empasis on nonequilibrium phenomena. The book introduces readers to the methods of non-equilibrium statistical mechanics as applied to complex materials, but always connects theories with experiments. It shows the underlying connections between topics as diverse as critical phenomena in colloidal dynamics, glassy state relaxation and deformation, reinforced polymer composites, molecular level mixing in nanocomposites, and rough surfaces and interfaces. At the same time, each chapter is designed to be independent from the others so that the book can serve as a reference work as well as a text. It is not designed to review all the recent work in mesoscopic physics, which spans many disciplines, but rather attempts to establish a general framework for understanding and developing new materials that can not be designed by the trial and error methods. A familiarity with the basics of statistical mechanics and condensed matter physics is assumed.

Polymer Dynamics and Relaxation

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Publisher : Cambridge University Press
ISBN 13 : 1107320259
Total Pages : 369 pages
Book Rating : 4.1/5 (73 download)

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Book Synopsis Polymer Dynamics and Relaxation by : Richard Boyd

Download or read book Polymer Dynamics and Relaxation written by Richard Boyd and published by Cambridge University Press. This book was released on 2007-09-13 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers exhibit a range of physical characteristics, from rubber-like elasticity to the glassy state. These particular properties are controlled at the molecular level by the mobility of the structural constituents. Remarkable changes in mobility can be witnessed with temperature, over narrow, well defined regions, termed relaxation processes. This is an important, unique phenomenon controlling polymer transition behaviour and is described here at an introductory level. The important types of relaxation processes from amorphous to crystalline polymers and polymeric miscible blends are covered, in conjunction with the broad spectrum of experimental methods used to study them. In-depth discussion of molecular level interpretation, including atomistic level computer simulations and applications to molecular mechanism elucidation, are discussed. The result is a self-contained approach to polymeric interpretation suitable for researchers in materials science, physics and chemistry interested in the relaxation processes of polymeric systems.

Polymers and Neutron Scattering

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Publisher : Oxford University Press on Demand
ISBN 13 : 9780198500636
Total Pages : 436 pages
Book Rating : 4.5/5 (6 download)

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Book Synopsis Polymers and Neutron Scattering by : Julia S. Higgins

Download or read book Polymers and Neutron Scattering written by Julia S. Higgins and published by Oxford University Press on Demand. This book was released on 1996 with total page 436 pages. Available in PDF, EPUB and Kindle. Book excerpt: The application of neutron scattering to polymers has been extremely successful during the last two decades. This book presents, for the first time, both the theories and experimental examples which are needed to understand how these techniques can be applied. Now available in paperback forthe first time this book is specifically written to introduce the newcomer and non-expert to the experimental techniques and the basic theory necessary to understand the results.

Scattering and Dynamics of Polymers

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Publisher : John Wiley & Sons
ISBN 13 : 0470828250
Total Pages : 269 pages
Book Rating : 4.4/5 (78 download)

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Book Synopsis Scattering and Dynamics of Polymers by : Charles C. Han

Download or read book Scattering and Dynamics of Polymers written by Charles C. Han and published by John Wiley & Sons. This book was released on 2011-07-05 with total page 269 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scattering is a very powerful tool to study the structure of polymers. Written by highly regarded and respected scientists in the field, this book presents the latest developments in the field of scattering in a uniform, systematic manner. This volume arms readers with both theoretical and experimental aspects of the intended area, offering much simplified theoretical explanations on the physics of scattering. The authors provide discussion on applications of experimental techniques. Han and Akcasu begin with a traditional treatment of light scattering from plane waves, followed by consistent application of density (in both real and Fourier space) correlation functions in both space and time. The authors do not distinguish among light, X-ray, and neutron, excepting their scattering length, q-range, coherence and detection differences. Readers can therefore concentrate on exactly the scattering tools they need to use, while theoretical explanation on the physics of scattering can be made much more simplified and uniform. Presents the latest development in the field of scattering in a uniform, systematic manner Arms readers with both theoretical and experimental aspects Gives a much simpler theoretical explanation on the physics of scattering Demonstrates application of experimental techniques

Polymer Dynamics in Dilute Media

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Publisher : Stanford University
ISBN 13 :
Total Pages : 135 pages
Book Rating : 4.F/5 ( download)

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Book Synopsis Polymer Dynamics in Dilute Media by : Shikha Somani

Download or read book Polymer Dynamics in Dilute Media written by Shikha Somani and published by Stanford University. This book was released on 2011 with total page 135 pages. Available in PDF, EPUB and Kindle. Book excerpt: Polymers undergo a sharp coil to stretch conformational transition in extension dominated flows when the strain rate exceeds a critical value. Dramatic change in flow behavior is known to occur at the coil-stretch transition, making it useful for several commercial applications. Despite decades of study, this phenomenon remains surrounded with controversy as the effect of solvent properties and fluid flow elements on this transition is not fully understood. In this work, we present a study of the coil-stretch transition and related hysteresis phenomenon using stochastic computer simulations. We first investigate the effect of solvent quality on the coil-stretch transition using Brownian dynamics simulations. Unlike experiments, which are plagued with problems related to polydispersity of polymers and inaccurate control over flow profiles, simulations offer a powerful platform to systematically study the effect of solvent quality while keeping all other parameters in the system constant. The system consists of a polymer subjected to planar elongational flow in both theta solvents and good solvents. The polymer is represented by a bead-spring chain model undergoing elongational flow. Solvent-mediated effects such as fluctuating hydrodynamic interactions (HI) and excluded volume (EV) are included rigorously. Conformational hysteresis is understood in terms of a 1-D energy landscape theory with an activation energy barrier for transition. At steady state, depending upon the flow rate, the energy landscape can either have one or two energy wells. An energy landscape with one well corresponds to the coiled state at low flow rate and stretched state at high flowrate. The double welled landscape corresponds to the hysteretic regime where both coiled and stretched conformational states coexist across the ensemble population. A key factor in determining the effect of solvent quality is the use of a proper measure of solvent quality. In almost all earlier studies, the effect of molecular weight on solvent quality has been neglected, producing inconsistent results. Here, the solvent quality is quantified carefully such that the effect of molecular weight and temperature is taken into account. Contrary to earlier findings, it is observed that with improvement in solvent quality, the chains unravel faster and the critical strain rate at which the coil to stretch transition takes place decreases. Furthermore, the solvent quality has a profound effect on the scaling of the critical strain rate with molecular weight and on both the transient and steady state properties of the system. Universal functions are shown to exist for the observed dynamic and static properties, which will prove useful in determining the operating parameters for experiments. In particular, the ratio of the two different relaxation times (longest relaxation time and zero shear rate viscosity) is found to be a universal function of solvent quality independent of molecular weight. The relaxation times (both the longest relaxation time and the zero shear rate viscosity) increase while the critical strain rate is found to decrease with solvent quality. Next, the study of conformational hysteresis is extended to more complicated 3-D flows to understand the effect of flow vorticity on this phenomenon. Heretofore, there has been no systematic methodology for studying the dynamical interactions between polymer molecules and elementary flow patterns in three-dimensional flows. Such a framework is essential not just for gaining valuable insights into the physics of complex fluids at a fundamental level, but it is also crucial for various important applications like turbulent drag reduction where the underlying physical mechanisms involve dynamical interactions between polymers and turbulence fine scale flow features. Such a study is presented here to provide a framework to interpret complex fluid phenomenon in terms of elementary flow patterns. We investigate the conformational hysteresis using rigorous Brownian dynamics simulations and specifically explore the effect of flow vorticity on the lifetime and width of the hysteresis window in 3-D flows. A systematic procedure is developed with careful eigenvalue analysis to explore the sole effect of vorticity on polymer dynamics keeping the principal strain rate fixed. It is observed that the hysteresis width shrinks due to increase in flow vorticity irrespective of the flow type (bi-extensional, bi-compressional, spiral-inwards, spiral-outwards etc). This is further traced to the alignment of eigenvectors with the principal eigenvector direction leading to enhanced fluctuations. Vorticity is found to have a significant effect on both the transient and the steady state properties. Understanding the effect of vorticity on polymer conformational hysteresis can further help in understanding the fundamental processes in complex flows.

Polymer Physics and Engineering

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Publisher : Springer
ISBN 13 : 354044484X
Total Pages : 244 pages
Book Rating : 4.5/5 (44 download)

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Book Synopsis Polymer Physics and Engineering by :

Download or read book Polymer Physics and Engineering written by and published by Springer. This book was released on 2003-07-01 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Polymer Dynamics

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Publisher :
ISBN 13 :
Total Pages : pages
Book Rating : 4.:/5 (13 download)

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Book Synopsis Polymer Dynamics by : Doug Grzetic

Download or read book Polymer Dynamics written by Doug Grzetic and published by . This book was released on 2011 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:

Fundamentals of Polymer Physics and Molecular Biophysics

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Publisher : Cambridge University Press
ISBN 13 : 1107058708
Total Pages : 345 pages
Book Rating : 4.1/5 (7 download)

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Book Synopsis Fundamentals of Polymer Physics and Molecular Biophysics by : Himadri B. Bohidar

Download or read book Fundamentals of Polymer Physics and Molecular Biophysics written by Himadri B. Bohidar and published by Cambridge University Press. This book was released on 2015-01-05 with total page 345 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Provides a physical interpretation of the data obtained in macromolecular transport phenomena in a given system and also addresses some important issues and concepts related to biopolymers such as proteins and nucleic acids"--

On the Simulation and Theory of Polymer Dynamics in Sieving Media

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Publisher :
ISBN 13 :
Total Pages : 372 pages
Book Rating : 4.:/5 (647 download)

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Book Synopsis On the Simulation and Theory of Polymer Dynamics in Sieving Media by : Martin Kenward

Download or read book On the Simulation and Theory of Polymer Dynamics in Sieving Media written by Martin Kenward and published by . This book was released on 2007 with total page 372 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Hyperbolic Problems: Theory, Numerics, Applications. Volume I

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Publisher : Springer Nature
ISBN 13 : 3031552601
Total Pages : 376 pages
Book Rating : 4.0/5 (315 download)

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Book Synopsis Hyperbolic Problems: Theory, Numerics, Applications. Volume I by : Carlos Parés

Download or read book Hyperbolic Problems: Theory, Numerics, Applications. Volume I written by Carlos Parés and published by Springer Nature. This book was released on with total page 376 pages. Available in PDF, EPUB and Kindle. Book excerpt:

Viscoelasticity of Polymers

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Publisher : Springer
ISBN 13 : 9401775648
Total Pages : 615 pages
Book Rating : 4.4/5 (17 download)

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Book Synopsis Viscoelasticity of Polymers by : Kwang Soo Cho

Download or read book Viscoelasticity of Polymers written by Kwang Soo Cho and published by Springer. This book was released on 2016-05-30 with total page 615 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book offers a comprehensive introduction to polymer rheology with a focus on the viscoelastic characterization of polymeric materials. It contains various numerical algorithms for the processing of viscoelastic data, from basic principles to advanced examples which are hard to find in the existing literature. The book takes a multidisciplinary approach to the study of the viscoelasticity of polymers, and is self-contained, including the essential mathematics, continuum mechanics, polymer science and statistical mechanics needed to understand the theories of polymer viscoelasticity. It covers recent achievements in polymer rheology, such as theoretical and experimental aspects of large amplitude oscillatory shear (LAOS), and numerical methods for linear viscoelasticity, as well as new insights into the interpretation of experimental data. Although the book is balanced between the theoretical and experimental aspects of polymer rheology, the author’s particular interest in the theoretical side will not remain hidden. Aimed at readers familiar with the mathematics and physics of engineering at an undergraduate level, the multidisciplinary approach employed enables researchers with various scientific backgrounds to expand their knowledge of polymer rheology in a systematic way.