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The Effect Of Rhodium Precursor On Carbon Monoxide Hydrogenation Catalysts
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Author :Piet W.N.M. van Leeuwen Publisher :Springer Science & Business Media ISBN 13 :0306469472 Total Pages :291 pages Book Rating :4.3/5 (64 download)
Book Synopsis Rhodium Catalyzed Hydroformylation by : Piet W.N.M. van Leeuwen
Download or read book Rhodium Catalyzed Hydroformylation written by Piet W.N.M. van Leeuwen and published by Springer Science & Business Media. This book was released on 2006-04-11 with total page 291 pages. Available in PDF, EPUB and Kindle. Book excerpt: In the last decade there have been numerous advances in the area of rhodium-catalyzed hydroformylation, such as highly selective catalysts of industrial importance, new insights into mechanisms of the reaction, very selective asymmetric catalysts, in situ characterization and application to organic synthesis. The views on hydroformylation which still prevail in the current textbooks have become obsolete in several respects. Therefore, it was felt timely to collect these advances in a book. The book contains a series of chapters discussing several rhodium systems arranged according to ligand type, including asymmetric ligands, a chapter on applications in organic chemistry, a chapter on modern processes and separations, and a chapter on catalyst preparation and laboratory techniques. This book concentrates on highlights, rather than a concise review mentioning all articles in just one line. The book aims at an audience of advanced students, experts in the field, and scientists from related fields. The didactic approach also makes it useful as a guide for an advanced course.
Book Synopsis Journal of the Chemical Society by :
Download or read book Journal of the Chemical Society written by and published by . This book was released on 1988 with total page 1006 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Advances in Chemical Conversions for Mitigating Carbon Dioxide by : T. Inui
Download or read book Advances in Chemical Conversions for Mitigating Carbon Dioxide written by T. Inui and published by Elsevier. This book was released on 1998-03-12 with total page 720 pages. Available in PDF, EPUB and Kindle. Book excerpt: Global environmental problems, especially global warming caused by the accelerative accumulation of carbon dioxide in the atmosphere, are of great importance for humans. The world's population is now approaching 6 billion, and is still increasing. Developments in communication systems and transportation tools have made the circulation of information, technologies and materials easier, which results in rapid economic growth, particularly in the East and Southeastern Asian countries. Increased affluence leads to an increased consumption of fossil fuels. Inevitably, this leads to an increase in carbon dioxide emission and environmentally hazardous materials which in turn precipitates climatic changes on a global scale. Recent studies showed that the increase in carbon dioxide emission for last year was the highest in the past seven years, and the total amount of carbon dioxide emission from all over the world reached 6.5 billion tons. Furthermore, one cannot overlook the report which appeared recently in Nature, that the floor-area of the iceberg in the South Pole has already decreased by 25% in the past five decades.Over 260 scientists and engineers from 21 countries who had a strong interest and wished to contribute to solve the carbon dioxide problem attended this conference. The papers presented in this volume cover most of the possibilities of the chemical conversion of carbon dioxide.
Book Synopsis Solid State Chemistry in Catalysis by : Robert K. Grasselli
Download or read book Solid State Chemistry in Catalysis written by Robert K. Grasselli and published by . This book was released on 1985 with total page 386 pages. Available in PDF, EPUB and Kindle. Book excerpt: Good,No Highlights,No Markup,all pages are intact, Slight Shelfwear,may have the corners slightly dented, may have slight color changes/slightly damaged spine.
Book Synopsis Catalysis: An Integrated Approach by : R.A. van Santen
Download or read book Catalysis: An Integrated Approach written by R.A. van Santen and published by Elsevier. This book was released on 2000-09-26 with total page 646 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book concentrates on industrially relevant reactions which are catalyzed by heterogeneous and homogeneous catalysts. Homogeneous catalysis by metal complexes is treated jointly with heterogeneous catalysis using metallic and non-metallic solids. In both areas the high degree of sophistication of spectroscopic techniques and theoretical modelling has led to an enormous increase in our understanding at the molecular level. This holds for the kinetics of the reactions and the reactivities of the catalysts, as well as for the syntheses of the catalytic materials. The development of catalysis science since the first edition of this book has necessitated a thorough revision, including special chapters on biocatalysis, catalyst characterization and adsorption methods. The multidisciplinary nature of catalysis is reflected in the choice of a novel combination of basic disciplines which will be refreshing and inspiring to readers.
Book Synopsis Homogeneous Hydrogenation by : P.A. Chaloner
Download or read book Homogeneous Hydrogenation written by P.A. Chaloner and published by Springer Science & Business Media. This book was released on 2013-11-11 with total page 293 pages. Available in PDF, EPUB and Kindle. Book excerpt: Homogeneous hydrogenation is one of the most thoroughly studied fields of homogeneous catalysis. The results of these studies have proved to be most important for an understanding of the underlying principles of the activation of small molecules by transition metal complexes. During the past three decades homogeneous hydrogenation has found widespread application in organic chemistry, including the production of important pharmaceuticals, especially where a sophisticated degree of selectivity is required. This volume presents a general account of the main principles and applications of homogeneous hydrogenation by transition metal complexes. Special attention is devoted to the mechanisms by which these processes occur, and the role of the recently discovered complexes of molecular hydrogen is described. Sources of hydrogen, other than H2, are also considered (transfer hydrogenation). The latest achievements in highly stereoselective hydrogenations have made possible many new applications in organic synthesis. These applications are documented by giving details of the reduction of important unsaturated substrates (alkenes, alkynes, aldehydes and ketones, nitrocompounds, etc.). Hydrogenation in biphasic and phase transfer catalyzed systems is also described. Finally, a discussion of the biochemical routes of H2 activation highlights the similarities and differences in performing hydrogenation in both natural and synthetic systems. For researchers working in the fields of homogeneous catalysis, especially in areas such as pharmaceuticals, plastics and fine chemicals.
Book Synopsis Natural Gas Conversion VI by : T.H. Fleisch
Download or read book Natural Gas Conversion VI written by T.H. Fleisch and published by Elsevier. This book was released on 2001-06-01 with total page 577 pages. Available in PDF, EPUB and Kindle. Book excerpt: This volume contains peer-reviewed manuscripts describing the scientific and technological advances presented at the 6th Natural Gas Conversion Sumposium held in Alaska in June 2001. This symposium continues the tradition of excellence and the status as the premier technical meeting in this area established by previous meetings.The 6th Natural Gas Conversion Symposium is conducted under the overall direction of the Organizing Committee. The Program Committee was responsible for the review, selection, editing of most of the manuscripts included in this volum. A standing International Advisory Board has ensured the effective long-term planning and the continuity and technical excellence of these meetings.
Book Synopsis CO2 Hydrogenation Catalysis by : Yuichiro Himeda
Download or read book CO2 Hydrogenation Catalysis written by Yuichiro Himeda and published by John Wiley & Sons. This book was released on 2021-06-28 with total page 322 pages. Available in PDF, EPUB and Kindle. Book excerpt: A guide to the effective catalysts and latest advances in CO2 conversion in chemicals and fuels Carbon dioxide hydrogenation is one of the most promising and economic techniques to utilize CO2 emissions to produce value-added chemicals. With contributions from an international team of experts on the topic, CO2 Hydrogenation Catalysis offers a comprehensive review of the most recent developments in the catalytic hydrogenation of carbon dioxide to formic acid/formate, methanol, methane, and C2+ products. The book explores the electroreduction of carbon dioxide and contains an overview on hydrogen production from formic acid and methanol. With a practical review of the advances and challenges in future CO2 hydrogenation research, the book provides an important guide for researchers in academia and industry working in the field of catalysis, organometallic chemistry, green and sustainable chemistry, as well as energy conversion and storage. This important book: Offers a unique review of effective catalysts and the latest advances in CO2 conversion Explores how to utilize CO2 emissions to produce value-added chemicals and fuels such as methanol, olefins, gasoline, aromatics Includes the latest research in homogeneous and heterogeneous catalysis as well as electrocatalysis Highlights advances and challenges for future investigation Written for chemists, catalytic chemists, electrochemists, chemists in industry, and chemical engineers, CO2 Hydrogenation Catalysis offers a comprehensive resource to understanding how CO2 emissions can create value-added chemicals.
Book Synopsis Carbon Monoxide in Organic Synthesis by : Bartolo Gabriele
Download or read book Carbon Monoxide in Organic Synthesis written by Bartolo Gabriele and published by John Wiley & Sons. This book was released on 2022-01-10 with total page 434 pages. Available in PDF, EPUB and Kindle. Book excerpt: Carbon Monoxide in Organic Synthesis A thoroughly up-to-date overview of carbonylation reactions in the presence of carbon monoxide In Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry, expert researcher and chemist Bartolo Gabriele delivers a robust summary of the most central advances in the field of carbonylation reactions in the presence of carbon monoxide. Beginning with a brief introduction on the importance of carbon monoxide as a building block in modern organic synthesis, the author goes on to describe metal-catalyzed carbonylations utilizing iron, cobalt, nickel, copper, and manganese. Descriptions of palladium, ruthenium, and rhodium-catalyzed reactions follow, as do discussions of metal-free carbonylation processes. The book is organized by metal to make the book useful as a guide for researchers from both academia and industry whose work touches on the direct synthesis of carbonyl compounds, carboxylic acid derivatives, and heterocycles. It aims to stimulate further discoveries in this rapidly developing field. Readers will also enjoy: A thorough introduction to carbonylations promoted by first row transition metal catalysts, including cobalt-catalyzed and nickel-catalyzed carbonylations An exploration of carbonylations promoted by second row transition metal catalysts, including ruthenium-, rhodium-, palladium(0)-, and palladium (II)-catalyzed carbonylations Practical discussions of miscellaneous carbonylation reactions, including carbonylations promoted by third row transition metal catalysts and metal-free carbonylation processes Perfect for catalytic and organic chemists, Carbon Monoxide in Organic Synthesis: Carbonylation Chemistry is also an indispensable resource for chemists working with organometallics and industrial chemists seeking a summary of important processes used to synthesize value-added products.
Book Synopsis Applied Homogeneous Catalysis by : Arno Behr
Download or read book Applied Homogeneous Catalysis written by Arno Behr and published by John Wiley & Sons. This book was released on 2012-04-16 with total page 717 pages. Available in PDF, EPUB and Kindle. Book excerpt: Auf fortgeschrittenem Niveau und mit didaktischem Anspruch bietet Ihnen dieser Band zahlreiche Fragen mit Antworten und eine breite Palette von Fallstudien aus der Industrie, ergänzt durch weiterführende Literaturhinweise und Referenzen der Originalliteratur. Insbesondere geht es um die modernsten katalytischen Prozesse mit ihren Anwendungen in der Pharmazie und der Feinchemikalien-Industrie, wobei auch kommerzielle Aspekte besprochen werden. Der Autor, ein erfahrener Dozent mit Industriepraxis, legt Chemikern und Chemieingenieuren damit ein praxistaugliches Hilfsmittel vor.
Book Synopsis Homogeneous Transition-metal Catalysis by : Christopher Masters
Download or read book Homogeneous Transition-metal Catalysis written by Christopher Masters and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 284 pages. Available in PDF, EPUB and Kindle. Book excerpt: Soluble catalysts are used extensively in many branches of chemistry and are indeed a vital constituent of many natural processes. They find wide application throughout the chemical industry where they assist in the production of several million tonnes of chemicals each year. Since homogeneous systems, especially those incorporating transition metals, often function effectively under milder conditions than their heterogeneous counterparts, they are becoming increasingly important at a time when the chemical industry in particular, and society in general, is seeking ways of conserving energy and of making the best possible use of available resources. My principal objective in- writing this book is to engender sufficient enthusiasm for, and knowledge of, the subject in the reader that he or she will be encouraged to begin, or continue, to make their own contribution to advancing our knowledge of homogeneous catalysis. After attempting to acquaint the reader with some of the ground rules I have tried to describe the present scope, and the future potential, of this fascinating field of chemistry by drawing both on academic and on industrial data sources. This approach stems from a personal conviction that future progress could be considerably hastened by a more meaningful dialogue between chemists working both in industrial and in academic research institutions. Wherever possible, examples of the commercial application of homogeneous catalyst systems have been included and no attempt has been made in any way to disguise the many unresolved questions and exciting challenges which still pervade this rapidly developing area.
Book Synopsis Engineering Solutions for CO2 Conversion by : Tomas Ramirez Reina
Download or read book Engineering Solutions for CO2 Conversion written by Tomas Ramirez Reina and published by John Wiley & Sons. This book was released on 2021-07-19 with total page 498 pages. Available in PDF, EPUB and Kindle. Book excerpt: A comprehensive guide that offers a review of the current technologies that tackle CO2 emissions The race to reduce CO2 emissions continues to be an urgent global challenge. "Engineering Solutions for CO2 Conversion" offers a thorough guide to the most current technologies designed to mitigate CO2 emissions ranging from CO2 capture to CO2 utilization approaches. With contributions from an international panel representing a wide range of expertise, this book contains a multidisciplinary toolkit that covers the myriad aspects of CO2 conversion strategies. Comprehensive in scope, it explores the chemical, physical, engineering and economical facets of CO2 conversion. "Engineering Solutions for CO2 Conversion" explores a broad range of topics including linking CFD and process simulations, membranes technologies for efficient CO2 capture-conversion, biogas sweetening technologies, plasma-assisted conversion of CO2, and much more. This important resource: * Addresses a pressing concern of global environmental damage, caused by the greenhouse gases emissions from fossil fuels * Contains a review of the most current developments on the various aspects of CO2 capture and utilization strategies * Incldues information on chemical, physical, engineering and economical facets of CO2 capture and utilization * Offers in-depth insight into materials design, processing characterization, and computer modeling with respect to CO2 capture and conversion Written for catalytic chemists, electrochemists, process engineers, chemical engineers, chemists in industry, photochemists, environmental chemists, theoretical chemists, environmental officers, "Engineering Solutions for CO2 Conversion" provides the most current and expert information on the many aspects and challenges of CO2 conversion.
Book Synopsis Oxygenates by Homologation or CO Hydrogenation with Metal Complexes by : A. Braca
Download or read book Oxygenates by Homologation or CO Hydrogenation with Metal Complexes written by A. Braca and published by Springer Science & Business Media. This book was released on 1993-12-31 with total page 254 pages. Available in PDF, EPUB and Kindle. Book excerpt: Born and initially developed in various industrial laboratories, mainly in U.S.A. and Gennany, homogeneous phase catalytic carbon monoxide hydrogenation and alcohols and their derivatives carbonylation and homologation, have generally been considered and reviewed separately in the course of their 40 years history without concern for common aspects in the chemical transfonnations and in catalysis. Thanks to researchers of Japanese companies participating in the National C 1 Chemistry Project (1980-1987) the scientific and technical approaches in this field have been unified and applied in parallel, in the light of some common aspects of the chemical reactions and mechanisms. Now, at a moment when research seems becahned, a general presentation and discussion of the most recent topics might be an useful basis for further development of this chemistry. To delimit and simplify the discussion of the chemical aspects and the nature of the catalysts involved, the present review is limited to reactions employing homogeneous metal complexes for the direct conversion of syngas to oxygenates and to the hydrocarbonylation of these last to homologous derivatives. Since the previous practically contemporary reviews by Dombek [in Adv. Organomet. Chern. (1983)] on CO hydrogenation and by the present authors [in Asp.Homog.Catal.(Reidel Pu.l984)] on alcohol homologation fully cover the literature up to 1982, here we mainly refer to work done after 1982, and consider the cited reviews as covering the historical development of research in the 1940- 1980 period.
Book Synopsis Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis by : Jean-Marie Basset
Download or read book Surface Organometallic Chemistry: Molecular Approaches to Surface Catalysis written by Jean-Marie Basset and published by Springer Science & Business Media. This book was released on 2012-12-06 with total page 340 pages. Available in PDF, EPUB and Kindle. Book excerpt: Surface organometallic chemistry is a new field bringing together researchers from organometallic, inorganic, and surface chemistry and catalysis. Topics ranging from reaction mechanisms to catalyst preparation are considered from a molecular basis, according to which the "active site" on a catalyst surface has a supra-molecular character. This. the first book on the subject, is the outcome of a NATO Workshop held in Le Rouret. France, in May. 1986. It is our hope that the following chapters and the concluding summary of recommendations for research may help to provide a definition of surface organometallic chemistry. Besides catalysis. the central theme of the Workshop, four main topics are considered: 1) Reactions of organometallics with surfaces of metal oxides, metals. and zeolites; 2) Molecular models of surfaces, metal oxides, and metals; 3) Molecular approaches to the mechanisms of surface reactions; 4) Synthesis and modification of zeolites and related microporous solids. Most surface organometallic chemistry has been carried out on amorphous high-surf ace-area metal oxides such as silica. alumina. magnesia, and titania. The first chapter. contributed by KNOZINGER. gives a short summary of the structure and reactivity of metal oxide surfaces. Most of our understanding of these surfaces is based on acid base and redox chemistry; this chemistry has developed from X-ray and spectroscopic data, and much has been inferred from the structures and reactivities of adsorbed organic probe molecules. There are major opportunities for extending this understanding by use of well-defined (single crystal) oxide surfaces and organometallic probe molecules.
Book Synopsis Chemistry of the Platinum Group Metals by : F.R. Hartley
Download or read book Chemistry of the Platinum Group Metals written by F.R. Hartley and published by Elsevier. This book was released on 2013-10-22 with total page 645 pages. Available in PDF, EPUB and Kindle. Book excerpt: The chemistry of platinum group metals is a rapidly expanding commercially important field. It is dominated by the catalytic properties of the metals. They are useful in petrochemical and general chemical plants and are becoming increasingly important as autocatalysts for pollution control. The book covers recent developments in the chemistry of the six platinum group metals, namely, platinum, palladium, rhodium, iridium, ruthenium and osmium. The material falls into three broad areas. Firstly, the occurrence, extraction and use of the metals, especially in catalysis, electrochemistry, energy and electronics. Secondly, organometallic and homogeneous catalytic chemistry and last but not least coordination chemistry including biochemistry and cancer therapy. The work is aimed at scientists in universities and in industry using any of the six platinum group metals in research. It will be useful for those studying the compounds of the metals themselves, and those considering to use either the metals or their complexes and catalysts in their experimental work.
Download or read book Fossil Energy Update written by and published by . This book was released on 1981 with total page 886 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author :David J. Cole-Hamilton Publisher :Springer Science & Business Media ISBN 13 :9781402040863 Total Pages :270 pages Book Rating :4.0/5 (48 download)
Book Synopsis Catalyst Separation, Recovery and Recycling by : David J. Cole-Hamilton
Download or read book Catalyst Separation, Recovery and Recycling written by David J. Cole-Hamilton and published by Springer Science & Business Media. This book was released on 2006-01-13 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book looks at new ways of tackling the problem of separating reaction products from homogeneous catalytic solutions. The new processes involve low leaching supported catalysts, soluble supports such as polymers and dendrimers and unusual solvents such as water, fluorinated organics, ionic liquids and supercritical fluids. The advantages of the different possibilities are discussed alongside suggestions for further research that will be required for commercialisation. Unlike other books, in addition to the chemistry involved, the book looks at the process design that would be required to bring the new approaches to fruition. Comparisons are given with existing processes that have already been successfully applied and examples are given where these approaches are not suitable. The book includes: - New processes for the separation of products from solutions containing homogeneous catalysts - Catalysts on insoluble or soluble supports – fixed bed catalysts - continuous flow or ultrafiltration - Biphasic systems: water - organic, fluorous - organic, ionic liquid – organic, supercritical fluids (monophasic or biphasic with water, organic or ionic liquid) - Comparisons with current processes involving atmospheric or low temperature distillation - Consideration of Chemistry and Process Design - Advantages and disadvantages of each process exposed - Consideration of what else is need for commercialisation