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Synthesis Structures And Characterization Of Metal Organocarboxylate Compounds
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Book Synopsis The Chemistry of Metal-Organic Frameworks, 2 Volume Set by : Stefan Kaskel
Download or read book The Chemistry of Metal-Organic Frameworks, 2 Volume Set written by Stefan Kaskel and published by John Wiley & Sons. This book was released on 2016-09-13 with total page 899 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
Book Synopsis Metal-Organic Framework Materials by : Leonard R. MacGillivray
Download or read book Metal-Organic Framework Materials written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2014-09-19 with total page 1210 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-Organic Frameworks (MOFs) are crystalline compounds consisting of rigid organic molecules held together and organized by metal ions or clusters. Special interests in these materials arise from the fact that many are highly porous and can be used for storage of small molecules, for example H2 or CO2. Consequently, the materials are ideal candidates for a wide range of applications including gas storage, separation technologies and catalysis. Potential applications include the storage of hydrogen for fuel-cell cars, and the removal and storage of carbon dioxide in sustainable technical processes. MOFs offer the inorganic chemist and materials scientist a wide range of new synthetic possibilities and open the doors to new and exciting basic research. Metal-Organic Frameworks Materials provides a solid basis for the understanding of MOFs and insights into new inorganic materials structures and properties. The volume also reflects progress that has been made in recent years, presenting a wide range of new applications including state-of-the art developments in the promising technology for alternative fuels. The comprehensive volume investigates structures, symmetry, supramolecular chemistry, surface engineering, recognition, properties, and reactions. The content from this book will be added online to the Encyclopedia of Inorganic and Bioinorganic Chemistry: http://www.wileyonlinelibrary.com/ref/eibc
Book Synopsis Synthesis, Structures, and Characterization of Metal-organocarboxylate Compounds by : Marlon T. Conato
Download or read book Synthesis, Structures, and Characterization of Metal-organocarboxylate Compounds written by Marlon T. Conato and published by . This book was released on 2012 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Studies on the Synthesis and Structural Characterization of Magnesium Carboxylates with Flexible and Rigid Organic Acid Linkers by : Tausif Siddiqui
Download or read book Studies on the Synthesis and Structural Characterization of Magnesium Carboxylates with Flexible and Rigid Organic Acid Linkers written by Tausif Siddiqui and published by . This book was released on 2013 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal organic framework structures are an important research area in materials chemistry due to their many potential applications in the areas of gas-adsorption, ion-exchange, selective gas separation, potential drug delivery application and catalysis. The inorganic compounds that possess open channels and cavities in their structures are classified as framework materials. This thesis presents various studies conducted on the synthesis and structural characterization of magnesium carboxylates with flexible and rigid organic acid linkers. These syntheses were conducted in order to synthesize magnesium based novel framework compounds with desired porosities and structural attributes.
Book Synopsis Introduction to Reticular Chemistry by : Omar M. Yaghi
Download or read book Introduction to Reticular Chemistry written by Omar M. Yaghi and published by John Wiley & Sons. This book was released on 2019-03-22 with total page 684 pages. Available in PDF, EPUB and Kindle. Book excerpt: A concise introduction to the chemistry and design principles behind important metal-organic frameworks and related porous materials Reticular chemistry has been applied to synthesize new classes of porous materials that are successfully used for myraid applications in areas such as gas separation, catalysis, energy, and electronics. Introduction to Reticular Chemistry gives an unique overview of the principles of the chemistry behind metal-organic frameworks (MOFs), covalent organic frameworks (COFs), and zeolitic imidazolate frameworks (ZIFs). Written by one of the pioneers in the field, this book covers all important aspects of reticular chemistry, including design and synthesis, properties and characterization, as well as current and future applications Designed to be an accessible resource, the book is written in an easy-to-understand style. It includes an extensive bibliography, and offers figures and videos of crystal structures that are available as an electronic supplement. Introduction to Reticular Chemistry: -Describes the underlying principles and design elements for the synthesis of important metal-organic frameworks (MOFs) and related materials -Discusses both real-life and future applications in various fields, such as clean energy and water adsorption -Offers all graphic material on a companion website -Provides first-hand knowledge by Omar Yaghi, one of the pioneers in the field, and his team. Aimed at graduate students in chemistry, structural chemists, inorganic chemists, organic chemists, catalytic chemists, and others, Introduction to Reticular Chemistry is a groundbreaking book that explores the chemistry principles and applications of MOFs, COFs, and ZIFs.
Book Synopsis Metal-Organic Frameworks by : Leonard R. MacGillivray
Download or read book Metal-Organic Frameworks written by Leonard R. MacGillivray and published by John Wiley & Sons. This book was released on 2010-12-17 with total page 440 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks represent a new class of materials that may solve the hydrogen storage problem associated with hydrogen-fueled vehicles. In this first definitive guide to metal-organic framework chemistry, author L. MacGillivray addresses state-of-art developments in this promising technology for alternative fuels. Providing professors, graduate and undergraduate students, structural chemists, physical chemists, and chemical engineers with a historical perspective, as well as the most up-to-date developments by leading experts, Metal-Organic Frameworks examines structure, symmetry, supramolecular chemistry, surface engineering, metal-organometallic frameworks, properties, and reactions.
Book Synopsis Diversification and Functionalization of Organic Components in Metal-Organic Frameworks by : Noelle Ruiz Catarineu
Download or read book Diversification and Functionalization of Organic Components in Metal-Organic Frameworks written by Noelle Ruiz Catarineu and published by . This book was released on 2017 with total page 119 pages. Available in PDF, EPUB and Kindle. Book excerpt: Described in this dissertation are a range of methods for expanding the complexity of materials in the class of metal-organic frameworks (MOFs). From their discovery in the mid-1990's until today, metal-organic frameworks have largely been built from a narrow set of building blocks: symmetric, aromatic, carboxylates and first row transition or rare earth metals. While much work has been devoted to investigating the scope of their possible applications, more fundamental understanding of their chemistry is needed for the full potential of this class of materials to be realized. In addition to their crystallinity and porosity, the primary reason for the success of metal-organic frameworks in fields ranging from gas storage to catalysis stems from their inherent tunability. Metal-organic frameworks, in contrast to other porous materials such as zeolites, are modular in that they are built from discrete organic and inorganic components and can therefore be tailored to specific purposes. Increasing the attainable complexity of these materials allows for greater optimization toward existing applications and for exploring previously undiscovered areas. Complexity in solid-state materials is introduced through heterogeneity of composition or distribution. For metal-organic frameworks, this heterogeneity is manifested either in the backbone composing the underlying network or in the functionalities exposed to the pore space. Both approaches are investigated in this dissertation. Heterogeneity of the backbone rests in the diversity of the organic and inorganic building units. Heterogeneity of the pore space is provided by functionalization of organic and inorganic structural building units without altering their structural properties. Chapter One presents an introduction to rational design of metal-organic frameworks encompassing the context and background for this work. The building block approach provides control of metal-organic framework structure, stability, and functionality. Both inorganic and organic building units are available for modification. Variations in linker length, geometry, and connectivity correlate with changes in the extended structure. Choice of coordinating group is another element of control. Much remains to be investigated in terms of linkage type in metal-organic frameworks by exploring new coordinating groups. Concerning the metal components, the multifarious clusters and chains serving as secondary building units (SBUs) have implications for the structure, stability, and function of these materials. The identity of the metal ions comprising these secondary building units impacts these aspects as well. Heterogeneity of metal-organic framework backbones has been achieved in mixed linker and mixed metal systems. Strategies to achieve pure phases of materials with mixed components include synthesis from a mixture of starting materials as well as post-synthetic modification. Inside heterogeneous pore spaces, desired functionalities coordinate to the metals of the frameworks or are sidechains of the organic linkers. An analysis of the structure and property implications of constructing metal-organic frameworks from heterotopic linkers, meaning those linkers with non-identical coordinating groups, had not been reported. The lack of investigation in this area was the impetus for the research presented in Chapters Two and Three. Chapter Two describes the design, synthesis, and characterization of a heterotritopic linker for metal-organic frameworks. This compound bears a carboxylic acid, catechol, and pyridone and was not known in the literature. The original and optimized synthetic routes are given. The linker is synthesized reproducibly on gram scale in three steps with a single column chromatography purification. The analytical data for this linker are given, including the mass spectrometry, one-dimensional and two-dimensional nuclear magnetic resonance, and infrared spectra. The reasoning behind the choice of metrics and coordinating groups is described. Chapter Three details the synthesis, structure elucidation and refinement, and properties of a metal-organic framework constructed from a heterotritopic linker and zinc(II), termed MOF-910. Despite the asymmetry of the linker, MOF-910 is both highly crystalline and symmetric. Synthetic conditions for crystallization of the heterotritopic linker with zinc(II) required an added base, such as triethylamine. The material is highly porous with a Brunauer-Emmett-Teller surface area of 2,120 m2 g-1and hexagonal channels 21 Å in diameter. The material is remarkably thermally and chemically stable for a zinc-based metal-organic framework. Integrity of the framework is maintained up to 320 °C and under acidic and basic aqueous conditions. The catechol moiety undergoes oxidation to the corresponding semiquinone during the metal-organic framework synthesis. The electron paramagnetic resonance spectrum indicates a ligand-centered radical. Chapter Four concerns the applications and reticular chemistry insights uncovered by MOF-910. One focus is the prediction and control of structure of metal-organic frameworks through lower symmetry and heterotopic linkers. The process for reducing MOF-910 to its underlying topological network is explained. The tto (ttriangles. tetrahedra, octahedra) net, of which MOF-910 is the first representation, is described. The tendency of heterotopic linkers to form helical secondary building units is investigated. The dependence of helical pitch on the distance between the most proximal coordinating groups in asymmetric polytopic linkers is discussed. The contributions of these discoveries to the field of reticular chemistry are stated. The electrochromic and gas adsorption behavior of MOF-910 are described as well. Treatment with a mild oxidant converts colorless crystals to bright red with no change in structure discernible by single-crystal X-ray diffraction and no change in surface area. Exposure to a mild reductant causes red crystals to lose color. Chapter Five focuses on functionalization of metal-organic frameworks constructed from tetrakis(4-carboxyphenyl)porphyrin and zirconium(IV) clusters. The introduction of functionality through the organic ligand is described in MOF-525 and MOF-545. Since the porphyrin core is not involved in structure formation of these metal-organic frameworks, additional reactive sites were installed in these frameworks by coordination to the porphyrin pyrroles. The synthetic conditions for constructing zirconium(IV) metal-organic frameworks with porphyrin linkers bound to aluminum(III), chromium(III), manganese(III), iron(III), cobalt(III), nickel(II), copper(II), and zinc(II) are reported. The synthesis of the aluminum(III) and chromium(III) linkers is given. The activation conditions for these generally difficult to evacuate mesoporous materials are listed. The ability of these metalated porphyrin materials to capture toxic gases is reported.
Book Synopsis Metal-Organic Frameworks by : Lars Öhrström
Download or read book Metal-Organic Frameworks written by Lars Öhrström and published by American Chemical Society. This book was released on 2021-03-25 with total page 244 pages. Available in PDF, EPUB and Kindle. Book excerpt: Some 80,000 metal-organic frameworks (MOFs) have been reported as of 2020. With intriguing structures and fascinating properties, MOFs are poised to be a defining material of the 21st century with a great deal of commercial potential from methane fuel automobile tanks to carbon capturing. Metal-Organic Frameworks provides an introduction to the complex world of MOFs. Researchers new to MOFs can use this work as a jumping-off point for theoretical study or applied research. The work is broad and expansive in scope, but inclusive and comprehensive in detail. The authors provide a personal perspective of MOF research that provides a strong foundation in the basic methods and themes as well as directs the reader in how to think about MOFs. Sixteen MOF structures are animated, providing more clarity into the dimensionality of MOFs. Accompanying links take the reader to additional 3-D structures provided by The Cambridge Crystallographic Data Centre (CCDC).
Book Synopsis Synthesis, structures and characterization of coordination compounds with the transition metals, Ni(II), Mn(II), Cr(III), Fe(III), using ligands based on iminodiacetic acid and N-heterocycles by :
Download or read book Synthesis, structures and characterization of coordination compounds with the transition metals, Ni(II), Mn(II), Cr(III), Fe(III), using ligands based on iminodiacetic acid and N-heterocycles written by and published by Cuvillier Verlag. This book was released on 2004-03-29 with total page 150 pages. Available in PDF, EPUB and Kindle. Book excerpt: The research into supramolecular chemistry presented in tis work has resulted in the synthtesis and characterization of twenty coordination compounds. These can be considered to fall into three categories:
Book Synopsis Synthesis, Structures and Characterization of Coordination Compounds with the Transition Metals, Ni(II), Cu(II), Mn(II), Cr(III), Fe(III), Using Ligands Based on Iminodiacetic Acid and N-heterocycles by : Maria Paula Juanico
Download or read book Synthesis, Structures and Characterization of Coordination Compounds with the Transition Metals, Ni(II), Cu(II), Mn(II), Cr(III), Fe(III), Using Ligands Based on Iminodiacetic Acid and N-heterocycles written by Maria Paula Juanico and published by Cuvillier Verlag. This book was released on 2003 with total page 151 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Cobalt-based Coordination Complexes with Various Organic Linkers by : Md Faruque Hasan
Download or read book Synthesis and Characterization of Cobalt-based Coordination Complexes with Various Organic Linkers written by Md Faruque Hasan and published by . This book was released on 2018 with total page 166 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal-organic frameworks (MOFs) are being explored and investigated for a wide range of potential industrial applications due to the massive diversity of its structures and so many properties. Metal-organic framework compounds offer extremely large surface area, higher empty space volume, flexible networks, perfect mechanical and thermal stability, MOF can provide size or shape selectivity, and all of these are necessary for many industrial applications. In this research, different types of cobalt MOFs and coordination complexes have been synthesized with solvothermal process by fabricating cobalt (II) ion (normally metal salt) coordinated with organic ligand (normally organic carboxylate acid or basic organic compound or sometimes both and Nitrogen based third party linkers) and required solvent with subsequent heating condition. Various characterization techniques have been employed such as: single crystal X-ray diffraction (SXRD), powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), thermogravimetric analysis (TGA), nuclear magnetic resonance (NMR), and BET surface area.
Book Synopsis Synthesis and Characterization of Metal-organic and Supramolecular Compounds Based on Chiral Ligands by : Barbara Wisser
Download or read book Synthesis and Characterization of Metal-organic and Supramolecular Compounds Based on Chiral Ligands written by Barbara Wisser and published by . This book was released on 2007 with total page 196 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A by : Kazuo Nakamoto
Download or read book Infrared and Raman Spectra of Inorganic and Coordination Compounds, Part A written by Kazuo Nakamoto and published by John Wiley & Sons. This book was released on 2008-12-22 with total page 350 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Sixth Edition of this classic work comprises the most comprehensive and current guide to infrared and Raman spectra of inorganic, organometallic, bioinorganic, and coordination compounds. From fundamental theories of vibrational spectroscopy to applications in a variety of compound types, this has been extensively updated. New topics include the theoretical calculations of vibrational frequencies (DFT method), chemical synthesis by matrix co-condensation reactions, time-resolved Raman spectroscopy, and more. This volume is a core reference for chemists and medical professionals working with infrared or Raman spectroscopies and an excellent textbook for graduate courses.
Book Synopsis Creating Special Chemicals from Metals. by : Champaka G
Download or read book Creating Special Chemicals from Metals. written by Champaka G and published by . This book was released on 2023-09-10 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: Metal Carboxylates: Structural Synthesis" is an insightful and comprehensive guide that immerses readers in the intriguing world of metal carboxylates, shedding light on their structural synthesis and diverse applications. This meticulously crafted book delves into the fundamental principles and methodologies of synthesizing metal carboxylates, providing a deep understanding of their unique properties and versatility. The book begins by unraveling the theoretical foundations, elucidating how metal carboxylates are synthesized and how their structures are determined. It explores a wide array of metals and carboxylic acids, showcasing the vast landscape of possibilities in the field. Readers will gain valuable insights into the role of metal carboxylates in various industries, including chemistry, materials science, catalysis, and more. "Metal Carboxylates: Structural Synthesis" also highlights the importance of analytical techniques such as X-ray crystallography, spectroscopy, and thermal analysis in characterizing these compounds. It not only equips readers with the knowledge to synthesize metal carboxylates but also empowers them to analyze and understand their properties in depth. Whether you are a seasoned chemist, a materials scientist, or a student eager to explore this fascinating domain, this book serves as an indispensable resource. It opens doors to the world of metal carboxylates, offering a profound appreciation of their synthesis and structural intricacies. With practical insights and theoretical foundations, this book is your gateway to mastering the synthesis of metal carboxylates and unlocking their potential across various scientific and industrial realms. "Metal Carboxylates: Structural Synthesis" is a must-read for those seeking to embark on a journey of discovery and innovation in the field of coordination chemistry and materials science.
Book Synopsis Advances in Energy Materials by : Iuliana Stoica
Download or read book Advances in Energy Materials written by Iuliana Stoica and published by CRC Press. This book was released on 2023-10-27 with total page 365 pages. Available in PDF, EPUB and Kindle. Book excerpt: This new volume focuses on materials used for energy generation and includes a wide spectrum of applications to solve alternative energy issues. The book reviews the state-of-the-art issues in global energy problems and reports on advanced methods of preparation of nanoscale energy materials with explanations of the structure and properties. It highlights current developments in the energy sector from the materials angle along with new techniques. Topics include polymer nanocomposites with smart behavior and their applicability of in energy applications; magnetorheological and electrorheological properties of smart polymer systems and their energy-related applications; metal-organic frameworks-emerging porous materials for energy applications; applications of carbon nanotubes in energy harvesting and storage; new developments in piezoelectric materials; and much more.
Download or read book Modular Chemistry written by Josef Michl and published by Springer. This book was released on 2012-11-06 with total page 677 pages. Available in PDF, EPUB and Kindle. Book excerpt: Modular Chemistry: the First Steps In recent years, there has been increasing interest among chemists, physicists, materials scientists, biologists, engineers, and others in the assembly of well defmed, relatively large functional structures from repetitive units that themselves are molecules of some complexity. Using the dictionary defmition of a module (a detachable section, compartment, or unit with a specific purpose or function, and in electronics, a compact assembly functioning as a component of a larger unit) [1], we feel that this newly emerging field of endeavor could be called "modular chemistry" [2]. The NATO Advanced Research Workshop on Modular Chemistry that was held on September 9 to 12, 1995, at Aspen Lodge near Estes Park, Colorado, was meant to bring together prominent contributors to modular chemistry as it is being born, and to examine the associated birth pangs. It was concluded that although real, these are not nearly as bad as giving birth to a hedgehog tail first, and that the ultimate rewards were likely to be far more satisfying in terms of new ideas and enabling methodology. The level of excitement about the possibilities that are opening up for modular chemists, and also the challenge involved, are perhaps best documented by noting that the planned discussion periods at the workshop were as long as the oral presentation periods, and yet, each discussion ran over the allocated time.
Book Synopsis The Chemistry of Metal-Organic Frameworks, 2 Volume Set by : Stefan Kaskel
Download or read book The Chemistry of Metal-Organic Frameworks, 2 Volume Set written by Stefan Kaskel and published by Wiley-VCH. This book was released on 2016-09-13 with total page 904 pages. Available in PDF, EPUB and Kindle. Book excerpt: Providing vital knowledge on the design and synthesis of specific metal-organic framework (MOF) classes as well as their properties, this ready reference summarizes the state of the art in chemistry. Divided into four parts, the first begins with a basic introduction to typical cluster units or coordination geometries and provides examples of recent and advanced MOF structures and applications typical for the respective class. Part II covers recent progress in linker chemistries, while special MOF classes and morphology design are described in Part III. The fourth part deals with advanced characterization techniques, such as NMR, in situ studies, and modelling. A final unique feature is the inclusion of data sheets of commercially available MOFs in the appendix, enabling experts and newcomers to the field to select the appropriate MOF for a desired application. A must-have reference for chemists, materials scientists, and engineers in academia and industry working in the field of catalysis, gas and water purification, energy storage, separation, and sensors.
