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Synthesis Structure And Coordination Chemistry Of Mixed Donor Schiff Base Ligands
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Book Synopsis Synthesis, Structure, and Coordination Chemistry of Mixed-donor Schiff Base Ligands by : Dominic P. Halbach
Download or read book Synthesis, Structure, and Coordination Chemistry of Mixed-donor Schiff Base Ligands written by Dominic P. Halbach and published by . This book was released on 2005 with total page 390 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Schiff Base Metal Complexes by : Pranjit Barman
Download or read book Schiff Base Metal Complexes written by Pranjit Barman and published by John Wiley & Sons. This book was released on 2023-05-15 with total page 229 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff Base Metal Complexes Schiff bases are compounds created from a condensed amino compounds, which frequently form complexes with metal ions. They have diverse applications in biology, catalysis, material science and industry. Understanding these compounds, their properties, and the available methods for synthesizing them is a key to unlocking industrial innovation. Schiff Base Metal Complexes provides a comprehensive overview of these compounds. It introduces the compounds and their properties before discussing their various synthesizing methods. A survey of existing and potential applications gives a complete picture and makes this a crucial guide for researchers and industry professionals looking to work with Schiff base complexes. Schiff Base Metal Complexes readers will also find: A systematic and organized structure designed to make information instantly accessible Detailed coverage of thermal synthesis, photochemical synthesis, and more Challenges with different methods described in order to help readers make the correct choice for their own work Schiff Base Metal Complexes is a useful reference for organic chemists, materials scientists, and researchers or industry professionals working with organometallics.
Book Synopsis Structural and Biological Applications of Schiff Base Metal Complexes by : Pallavi Jain
Download or read book Structural and Biological Applications of Schiff Base Metal Complexes written by Pallavi Jain and published by CRC Press. This book was released on 2023-05-31 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: Coordination compounds have been well-known for their wide variety of applications for over a century, as well as enhancing the researcher’s interest and concern in evaluating their action mechanism. It is certainly one of the most intensely discussed research topics. Coordination compounds involve different metal-ion-ligand phenomenon. The involved metal ions play a significant role in structural association and functioning of several processes in the genetic and metabolism system. In recent years, Schiff base ligands have gained significant interest and received a keen interest of many researchers. Schiff’s base ligands have been recognized to hold a wide variety of biological and medicinal activities due to the presence of donor atoms. They have proved exceptional pharmalogical actions such as antimicrobial, anti-tuberclosis, antiplatelet, antidiabetic, antiarthritis, antioxidant, anti-inflammatory, anticancer, antiviral, antimalarial, and analgesic. These biologically active Schiff base ligands have also been shown to inhibit enzyme mobilization and, when bound to a metal ion, exhibit enhanced biological activity, making them useful in a number of fields. As a result, metal complexes of Schiff base ligands are gaining popularity due to their unique properties and functionalities. Schiff base complex-based research for educational and industrial purposes is booming, and the number of publications is gradually increasing. Despite these interests, there is currently no detailed book on Schiff base metal complexes that covers the structures, biological activities, and other non-biological perspectives. This book delves into the structures of Schiff base metal complexes, which are critical in assessing the biological viability of any complex. It also highlights their biological significance in pharma and drug discovery like antibacterial, antifungal, anticancer, anti-inflammatory, anti-arthritis, anti-diabetic, antioxidants, anti-proliferative, antitumor, anticancer, antiviral. The fundamentals of metal complexes are described, as well as an up-to-date outline of developments in synthesis, characterization methods, properties- chemical, thermal, optical, structural, and applications. This book also discusses the other applications of Schiff base metal complexes: as sensor (luminescent, electrochemical, and biosensor), as pigments in dying and paint industries, as photocatalyst to improve the degradation rate. Features : This book would be useful for academia, researchers and engineers working in the area of Schiff base and their metal complexes. This book will give an in-depth account of the properties of Schiff base and their metal complexes. This book will discuss the details of synthesis methods for Schiff base and their metal complexes. This book will cover emerging trends in the use of Schiff base metal complexes in the industry. This book will provide an overview of the wider biological applications of Schiff base metal complexes
Book Synopsis Synthesis and Characterization of New Schiff Bases Ligands with Their Transition and Actinide Metals by : Sali Nabeel Hanna Jabrou
Download or read book Synthesis and Characterization of New Schiff Bases Ligands with Their Transition and Actinide Metals written by Sali Nabeel Hanna Jabrou and published by . This book was released on 2019 with total page 191 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over recent years a great deal of interest has developed in new transition metal complexes of Schiff base ligand. The preparation of new ligand is the most important step in the development of metal complexes that exhibit unique properties and novel reactivity. The electron donor and electron acceptor properties of the ligand, the structural function groups and the position of the ligand in the coordination sphere, together with the reactivity of coordination compounds may be the factor for different studies. The synthesis and structural investigations of Schiff bases and their metal complexes are a considerable center of attention because of their potentially beneficial pharmacological properties and a wide variation in their mode of bonding. Metal coordination complexes have a wide variety of technological and industrial application, ranging from catalysis to anticancer drugs. In these compounds the metal atom itself may have a number of roles, based on its coordination geometry, oxidation state, and magnetic electronic and photochemical behaviors. This study presents the synthesis, characterization, and structural studies of different series of Copper and Uranium complexes of salicylaldehyde Schiff base derivatives with various organic amine compounds. The Schiff bases act as neutral and bidentate ligands, which can attach the metal through the azomethine nitrogen and furfural oxygens. These Schiff bases are prepared by iii reacting salicylaldehyde with various organic amines. In the case of most complexation reactions, highly colored precipitates were formed immediately. The complexes were found to have composition ML2 and M2L2, where M is the metal and L the organic ligand. This implies "mononuclear" structures with one metal + 2 ligands, and "binuclear" where the ligands hold two metal atoms in close proximity. The interesting molecular and crystal structural features of the Schiff base ligand called E-2-((benzo[d]thiazol-2-ylimino)methyl)phenol and its Cu(II) complex are presented in Chapter 2. Further investigations on the coordination chemistry of the Schiff base ligands are made by reacting these ligands with copper and uranium, described in Chapter 3. Another series of dicopper(II) complexes and diuranium complex of the Schiff base ligands, containing azomethine nitrogen and furfural oxygen donor group are investigated to evaluate the role of alkoxo bridge on the structures. Making the compounds with two uranium atoms leads to very high molecular weight, as a path to the highest molecular weight liquid crystal. This lays the pathway to future work for making those crystals. These dinuclear complexes are presented in chapter 4. The objective of the present study is to investigate the coordination chemistry of these ligands with Copper and Uranium. For the ligands this was done by a combination of nuclear magnetic resonance spectroscopy, infrared spectroscopy, ultraviolet-visible spectroscopy and single X-ray crystallography. The metal complexes were analyzed by the same techniques, except that in the case of uranium, all efforts to obtain single crystal for X-ray crystallography proved unsuccessful, so the molecular structure had to be ascertained from the other techniques.
Book Synopsis Vanillin- Aminoquinoline Schiff Bases and their Co(II), Ni(II) and Cu(II) Complexes by : Dr. S. N. Battin
Download or read book Vanillin- Aminoquinoline Schiff Bases and their Co(II), Ni(II) and Cu(II) Complexes written by Dr. S. N. Battin and published by Lulu.com. This book was released on with total page 282 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Schiff Base in Organic, Inorganic and Physical Chemistry by : Takashiro Akitsu
Download or read book Schiff Base in Organic, Inorganic and Physical Chemistry written by Takashiro Akitsu and published by BoD – Books on Demand. This book was released on 2023-03-08 with total page 210 pages. Available in PDF, EPUB and Kindle. Book excerpt: A Schiff base (imine -N=CH-) is a part of a popular group of organic compounds prepared form primary amines and aldehyde. Many studies have been carried out on Schiff bases not only as organic compounds but also as ligands for metal complexes. In this context, this book provides a comprehensive, interdisciplinary review of Schiff base compounds, with an emphasis on the latest advances. It compiles research results, commentary, reviews, and more dealing with preparation, spectroscopy, crystallography, (asymmetric) synthetic roles, physical properties (magnets, optics, etc.), computational chemistry, and theoretical chemistry. The book focuses on Schiff base and its strong connection to organic chemistry, biochemistry, and polymer materials chemistry. It covers three topics: Schiff base of organic chemistry, Schiff base of inorganic chemistry, and Schiff base of functional or biological materials.
Book Synopsis Beauty in Chemistry by : Luigi Fabbrizzi
Download or read book Beauty in Chemistry written by Luigi Fabbrizzi and published by Springer Science & Business Media. This book was released on 2012-02-22 with total page 180 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Beauty of Chemistry in the Words of Writers and in the Hands of Scientists, by Margherita Venturi, Enrico Marchi und Vincenzo Balzani Living in a Cage Is a Restricted Privilege, by Luigi Fabbrizzi Inner and Outer Beauty, by Kenneth N. Raymond und Casey J. Brown The Mechanical Bond: A Work of Art, by Carson J. Bruns und J. Fraser Stoddart The Beauty of Knots at the Molecular Level, by Jean-Pierre Sauvage und David B. Amabilino
Book Synopsis Metal Mediated Template Synthesis of Ligands by : Otilia Costisor
Download or read book Metal Mediated Template Synthesis of Ligands written by Otilia Costisor and published by World Scientific. This book was released on 2004 with total page 316 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book surveys the relatively new area of the synthesis of organic ligands when metal ions act as a template. In the last fifty years this field has undergone an explosive development, marked by a great amount of literature. The material in the book has been arranged according to the type of chemical reaction involved. In this frame, the basic principles of metal template reactions and the shape of the molecules are considered. Designed to satisfy the demands of students, young researchers doing their PhDs, and those working in the field of coordination chemistry, the book details the role of the metal ions and the specific properties of the formed complexes. Metal Mediated Template Synthesis of Ligands offers a comprehensive analysis with wide-ranging references and provides an extensive overview of research on metal-directed organic ligands over the past five decades. Contents: The Template Effect; Alkylation Reactions; Schiff Condensation; Mannich Condensation; Self Condensation of Nitriles; Self-Assembled Systems. Readership: Upper level undergraduates, graduate students, academics, researchers industrialists in inorganic, solid-state, supramolecular and organic chemistry.
Book Synopsis Novelties in Schiff Bases by : Takashiro Akitsu
Download or read book Novelties in Schiff Bases written by Takashiro Akitsu and published by BoD – Books on Demand. This book was released on 2024-08-28 with total page 162 pages. Available in PDF, EPUB and Kindle. Book excerpt: Schiff bases, originally introduced by German chemist Hugo Schiff in 1864, are well-known imine or azomethine (RR’C=NR”) moieties prepared from aldehydes and primary amines through condensation. Since then, Schiff bases have been recognized not only as compounds but also as useful ligands for metal complexes in inorganic coordination chemistry. This is because Schiff bases are essentially Lewis bases having lone pairs on the nitrogen (N) atom (M:N=CHR). In both organic and coordination chemistry, as well as related fields of science, the functions of Schiff base complexes and materials are of great interest. This book introduces and discusses novel aspects of Schiff base compounds.
Book Synopsis A Closer Look at Coordination Complexes by : Sandeep Kaur-Ghumaan
Download or read book A Closer Look at Coordination Complexes written by Sandeep Kaur-Ghumaan and published by Nova Science Publishers. This book was released on 2021 with total page 438 pages. Available in PDF, EPUB and Kindle. Book excerpt: "Coordination chemistry plays an important role in the designing of inorganic metal complexes, materials, organo-synthesis, biological systems and catalysis. In A Closer Look at Coordination Complexes, novel and evolving developments in the field have been described. The book includes chapters on the synthesis of coordination compounds using different ligand combinations (Schiff base ligands, phosphines, thiolates, ligands with N- and S-donors and so on), biological relevance and catalytic applications of the reported metal complexes. Different aspects of metal complexes, viz. structural and coordination properties of the ligands and complexes and applications viz., asymmetric organic transformations, potential anticancer agents, antibacterial-antioxidant-antifungal properties, alkenes epoxidation, olefins polymerization, nitrogen reduction, hydrogen evolution and oxidation and mercury poisoning treatment reviewed by the authors have been delineated in the eight chapters of the book"--
Book Synopsis Structure Determination from Powder Diffraction Data by : William I. F. David
Download or read book Structure Determination from Powder Diffraction Data written by William I. F. David and published by OUP Oxford. This book was released on 2002 with total page 358 pages. Available in PDF, EPUB and Kindle. Book excerpt: Our understanding of the properties of materials, from drugs and proteins to catalysts and ceramics, is almost always based on structural information. This book describes the new developments in the realm of powder diffraction which make it possible for scientists to obtain such information even from polycrystalline materials. Written and edited by experts active in the field, and covering both the fundamental and applied aspects of structure solution from powder diffraction data, this book guides both novices and experienced practitioners alike through the maze of possibilities.
Book Synopsis Synthetic Coordination and Organometallic Chemistry by : Alexander D. Garnovskii
Download or read book Synthetic Coordination and Organometallic Chemistry written by Alexander D. Garnovskii and published by CRC Press. This book was released on 2003-04-25 with total page 536 pages. Available in PDF, EPUB and Kindle. Book excerpt: This reference describes standard and nonstandard coordination modes of ligands in complexes, the intricacies of polyhedron-programmed and regioselective synthesis, and the controlled creation of coordination compounds such as molecular and hn-p-complexes, chelates, and homo- and hetero-nuclear compounds. It offers a clear and concise review of modern synthetic techniques of metal complexes as well as lesser known gas- and solid-phase synthesis, electrosynthesis, and microwave and ultrasonic treatment of the reaction system. The authors pay special attention to o-hydroxyazomethines and their S-, Se-containing analogues, b-diketones, and quinines, among others, and examine the immediate interaction of ligands and metal salts or carbonyls.
Book Synopsis Synthetic Coordination Chemistry by : Julian A. Davies
Download or read book Synthetic Coordination Chemistry written by Julian A. Davies and published by World Scientific. This book was released on 1996 with total page 482 pages. Available in PDF, EPUB and Kindle. Book excerpt: Although coordination chemistry naturally centers on the synthesis of coordination compounds, the synthesis of these materials is typically not an end in itself. Coordination compounds are utilized in all branches of chemistry; from theoretical modeling to industrial and consumer products. While a large amount of information is available on coordination chemistry in general and synthetic methods in particular, no comprehensive work has been presented on the preparation of coordination compounds with an emphasis on synthetic strategies rather than on detailed descriptions of specific syntheses. The goal of this book is to provide an approach to coordination chemistry that is based upon preparative strategies.The main aim of the authors is to present a systematic classification of synthetic reactions rather than an encyclopedic listing of experimental results. Hence, the coverage is more selective than exhaustive. Despite this, the book provides access to the original literature with ca. 2000 references. The edition is well-illustrated and contains almost 250 schemes, figures and illustrations of crystal structures of selected complexes.
Book Synopsis The Synthesis, Coordination Chemistry and Reactivity of Tripodal Schiff Base Ligands by : Claire Margaret Strange
Download or read book The Synthesis, Coordination Chemistry and Reactivity of Tripodal Schiff Base Ligands written by Claire Margaret Strange and published by . This book was released on 1996 with total page 222 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Characterization of Schiff Base Complexes with Hydrogen Bonding Groups by : Austin Shea Penn
Download or read book Synthesis and Characterization of Schiff Base Complexes with Hydrogen Bonding Groups written by Austin Shea Penn and published by . This book was released on 2018 with total page 130 pages. Available in PDF, EPUB and Kindle. Book excerpt: Presented in this thesis is the attempted synthesis and characterization of a diverse series of sulfonamidyl-pyridyl and carboxyl-pyridyl substituted Schiff base ligands as well as several copper and nickel coordination complexes. Chapter II focuses on the successful synthesis and characterization of the Schiff base ligands. Chapter III discusses the coordination chemistry involving Schiff base ligands and varying transition metals. Chapter IV contains details several novel side products observed in the pursuit of the desired Schiff base complexes.
Book Synopsis Comprehensive Coordination Chemistry: Ligands by : Geoffrey Wilkinson
Download or read book Comprehensive Coordination Chemistry: Ligands written by Geoffrey Wilkinson and published by . This book was released on 1987 with total page 1216 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Coordination Chemistry by : Geoffrey Wilkinson
Download or read book Comprehensive Coordination Chemistry written by Geoffrey Wilkinson and published by Pergamon. This book was released on 1987 with total page 674 pages. Available in PDF, EPUB and Kindle. Book excerpt:
