Read Books Online and Download eBooks, EPub, PDF, Mobi, Kindle, Text Full Free.
Synthesis Reactivities And Electrochemistry Of Ruthenium And Osmium Oxo Complexes With Polypyridine Ligands
Download Synthesis Reactivities And Electrochemistry Of Ruthenium And Osmium Oxo Complexes With Polypyridine Ligands full books in PDF, epub, and Kindle. Read online Synthesis Reactivities And Electrochemistry Of Ruthenium And Osmium Oxo Complexes With Polypyridine Ligands ebook anywhere anytime directly on your device. Fast Download speed and no annoying ads. We cannot guarantee that every ebooks is available!
Book Synopsis Synthesis, Reactivities and Electrochemistry of Ruthenium and Osmium Oxo Complexes with Polypyridine Ligands by : 梁偉豪
Download or read book Synthesis, Reactivities and Electrochemistry of Ruthenium and Osmium Oxo Complexes with Polypyridine Ligands written by 梁偉豪 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Reactivities and Electrochemistry of Ruthenium and Osmium Oxo Complexes with Polypyridine Ligands by : Wai-ho Leung (Wilkie)
Download or read book Synthesis, Reactivities and Electrochemistry of Ruthenium and Osmium Oxo Complexes with Polypyridine Ligands written by Wai-ho Leung (Wilkie) and published by . This book was released on 1989 with total page 630 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis The Synthesis, Spectroscopic and Electrochemical Characterisation of Ruthenium(II) and Osmium(II) Polypyridyl Complexes Containing Aryl-bridged 1,2,4-traizole Ligands by : Frances Weldon
Download or read book The Synthesis, Spectroscopic and Electrochemical Characterisation of Ruthenium(II) and Osmium(II) Polypyridyl Complexes Containing Aryl-bridged 1,2,4-traizole Ligands written by Frances Weldon and published by . This book was released on 1998 with total page 270 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactivities and Kinetic Studies on High Valent Ruthenium(iv), (V) and (VI) Oxo Complexes of Chelating Tertiary Amine, Polypyridyl and Porphyrinato Ligands by : 何嘉麗
Download or read book Reactivities and Kinetic Studies on High Valent Ruthenium(iv), (V) and (VI) Oxo Complexes of Chelating Tertiary Amine, Polypyridyl and Porphyrinato Ligands written by 何嘉麗 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Reactivities and Kinetic Studies on High Valent Ruthenium(IV), (V) and (VI) Oxo Complexes of Chelating Tertiary Amine, Polypyridyl and Porphyrinato Ligands" by 何嘉麗, Clare, Ho, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123257 Subjects: Reactivity (Chemistry) Chemical kinetics Ruthenium Oxo compounds Ligands
Book Synopsis Synthesis, Structures and Electrochemistry of High-valent Ruthenium and Osmium Complexes with Macrocyclic Polyamine and Sterically Bulky Alkoxide Ligands by : Zao-ying Li
Download or read book Synthesis, Structures and Electrochemistry of High-valent Ruthenium and Osmium Complexes with Macrocyclic Polyamine and Sterically Bulky Alkoxide Ligands written by Zao-ying Li and published by . This book was released on 1994 with total page 518 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Reactivities, and Electrochemistry of Osmium Complexes with Macrocyclic Tertiary Amine and Multianionic Amide and Schiff-Base Ligands by : 鄭永堅
Download or read book Synthesis, Reactivities, and Electrochemistry of Osmium Complexes with Macrocyclic Tertiary Amine and Multianionic Amide and Schiff-Base Ligands written by 鄭永堅 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis, Reactivities, and Electrochemistry of Osmium Complexes With Macrocyclic Tertiary Amine and Multianionic Amide and Schiff-base Ligands" by 鄭永堅, Wing-kin, Cheng, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3123151 Subjects: Osmium Oxidation
Book Synopsis Synthesis and Reactivity of Ruthenium (II) and Osmium (II) Organometallic Imido Complexes by : Richard Ira Michelman
Download or read book Synthesis and Reactivity of Ruthenium (II) and Osmium (II) Organometallic Imido Complexes written by Richard Ira Michelman and published by . This book was released on 1992 with total page 344 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis, Reactivities, and Electrochemistry of Osmium Complexes with Macrocyclic Tertiary Amine and Multianionic Amide and Schiff-base Ligands by : Wing-kin Cheng
Download or read book Synthesis, Reactivities, and Electrochemistry of Osmium Complexes with Macrocyclic Tertiary Amine and Multianionic Amide and Schiff-base Ligands written by Wing-kin Cheng and published by . This book was released on 1989 with total page 488 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Abstracts of Theses by : University of Hong Kong
Download or read book Abstracts of Theses written by University of Hong Kong and published by . This book was released on 1989 with total page 408 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis and Reactivity of Osmium and Ruthenium Vinylidene Complexes by : 鄭呈偉
Download or read book Synthesis and Reactivity of Osmium and Ruthenium Vinylidene Complexes written by 鄭呈偉 and published by . This book was released on 2007 with total page 283 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Comprehensive Coordination Chemistry II: Transition metal groups 7 and 8 by : Jon A. McCleverty
Download or read book Comprehensive Coordination Chemistry II: Transition metal groups 7 and 8 written by Jon A. McCleverty and published by Pergamon. This book was released on 2004 with total page 906 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis of Ruthenium-polypyridine Complexes and the Attempted Formation of Mono- and Bi-dentate Anthraquinone-polypyridine Ligands by : Joshua Malcolm Hubbard
Download or read book Synthesis of Ruthenium-polypyridine Complexes and the Attempted Formation of Mono- and Bi-dentate Anthraquinone-polypyridine Ligands written by Joshua Malcolm Hubbard and published by . This book was released on 1996 with total page 192 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactions of oxo complexes os osmium and ruthenium by : Martin Schroder
Download or read book Reactions of oxo complexes os osmium and ruthenium written by Martin Schroder and published by . This book was released on 1978 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Syntheses, Reactivities and Electrochemical Studies of Some High Valent Oxo Complexes of Ruthenium by : 黃國賢
Download or read book Syntheses, Reactivities and Electrochemical Studies of Some High Valent Oxo Complexes of Ruthenium written by 黃國賢 and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Redox Properties and Catalytic Activity of Some Polypyridyl Ruthenium and Osmium Aquo/oxo Complexes by : John Anthony Gilbert
Download or read book Redox Properties and Catalytic Activity of Some Polypyridyl Ruthenium and Osmium Aquo/oxo Complexes written by John Anthony Gilbert and published by . This book was released on 1984 with total page 574 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Reactivities and Kinetic Studies on High Valent Ruthenium(IV), (V) and (VI) Oxo Complexes of Chelating Tertiary Amine, Polypyridyl and Porphyrinato Ligands by : Clare Ho
Download or read book Reactivities and Kinetic Studies on High Valent Ruthenium(IV), (V) and (VI) Oxo Complexes of Chelating Tertiary Amine, Polypyridyl and Porphyrinato Ligands written by Clare Ho and published by . This book was released on 1991 with total page 512 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Structures, Electrochemistry and Reactivities of Ruthenium Porphyrins Containing Imido Or Conjugated Amido/Iminato Ligands by : Wai-Man Tsui
Download or read book Structures, Electrochemistry and Reactivities of Ruthenium Porphyrins Containing Imido Or Conjugated Amido/Iminato Ligands written by Wai-Man Tsui and published by . This book was released on 2017-01-27 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Structures, electrochemistry and reactivities of ruthenium porphyrins containing imido or conjugated amido/iminato ligands" by Wai-man, Tsui, 徐慧敏, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. Abstract: Abstract of thesis entitled STRUCTURES, ELECTROCHEMISTRY AND REACTIVITIES OF RUTHENIUM PORPHYRINS CONTAINING IMIDO OR CONJUGATED AMIDO/IMINATO LIGANDS Submitted by Tsui Wai Man for the degree of Doctor of Philosophy at The University of Hong Kong in Jun 2006 Metal-nitrogen multiple bonded species such as metal imido complexes play a key role in catalytic C-N bond formation reactions. This thesis is focused on the chemistry of quinoneimido (or conjugated iminato), arylamido and arenesulfonylimido ruthenium porphyrins, with particular attention paid to the driving force dependence of the rate constants of the imido transfer from metal imido complexes to alkenes and C-H bonds. Related chemistry of dioxoruthenium porphyrins and efforts to develop water-soluble ruthenium porphyrin oxidation catalysts are also described. Treatment of dioxoruthenium(VI) porphyrins with 2,6-dimethylaniline or 2,6-dichloroaniline in ethanol afforded quinoneimido ruthenium porphyrins IV 1 1 [Ru (Por)(NQu)(OEt)] (Por = porphyrinato dianion, HNQu = IV 2 N-(2',6'-dimethyl)phenyl-2,6-dimethyl-quinonediimine) and [Ru (Por)(NQu )(OEt)] (Por = TTP, HNQu = N-(2',6'-dichloro)phenyl-2,6-dichloro-quinonediimine). These IV 1 complexes underwent hydrolysis to give [Ru (Por)(NQu)(OH)] and IV 2 [Ru (Por)(NQu)(OH)]. Upon treatment with NaOMe, PhOH, CHCOOH and IV 1 CF COOH in CH Cl, [Ru (TTP)(NQu )(OH)] was quantitatively converted to 3 2 2 IV 1 [Ru (TTP)(NQu )(OR)] (R = Me, Ph, CH CO and CF CO, respectively). X-ray 3 3 IV 1 crystal structures of [Ru (TTP)(NQu)(OEt)] (HTTP = IV 1 meso-tetrakis(p-tolyl)porphyrin) and [Ru (4-OMe-TPP)(NQu )(OEt)] (H (4-OMe-TPP) = meso-tetrakis(4-methoxyphenyl)porphyrin) both feature linear terminal quinoneimido groups, with short Ru-N(quinoneimido) bond distances of 1.788-1.805 A. Reactions of dioxoruthenium(VI) porphyrins with a variety of conjugated arylamines (such as biphenyl- and terphenylamine, phenylethynyl-phenylamine and fluoren-2-ylamine) in ethanol or dichloromethane gave ruthenium(IV) porphyrins bearing conjugated arylamido ligands. The spectroscopic and electrochemical properties and X-ray crystal structures of these complexes were compared with those of ruthenium(IV) porphyrins bearing simple arylamido ligands. VI Bis(arenesulfonylimido)ruthenium(VI) porphyrins [Ru (TMP)(NSO R) ] 2 2 (HTMP = meso-tetramesitylporphyrin) (SOR = Ms, Ts, Bs, Cs, Ns) and 2 2 VI [Ru (Por)(NTs) ] underwent imido transfer reactions with alkenes and C-H bonds to afford aziridines or amides. The cyclic voltammograms of these metal imido VI/V complexes show the Ru reduction couple in the range of -0.41 to -0.12 V vs +/0 Cp Fe . A more strongly electron-withdrawing R group or porphyrin ligand resulted VI/V VI/V in a more anodic E (Ru ) value. The E (Ru ) values linearly correlate with log 1/2 1/2 k (second-order rate constants) for the imido transfer reactions of VI [Ru (TMP)(NSO R)] with styrene, ethylbenzene, toluene, cumene and 2 2 tetrahydrofuran. A linear correlation was also observed between log k′ (k divided by the number of reactive C-H bonds) and the C-H bond dissociation energies of VI hydrocarbons for their C-H bond amidations by [Ru (TMP)(NNs)] and VI [Ru (F -TPP)(NTs)] (H (F-TPP) = 20 2 2 20 5,10,15,20-tetrakis(pentafluorophenyl)porp
