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Synthesis Of Diamantane And Related Diamondoid Molecules
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Book Synopsis Synthesis of Diamantane and Related Diamondoid Molecules. Computer Assisted Graphical Analyses of Rearrangement Mechanisms by : Tamara Mladineo Gund
Download or read book Synthesis of Diamantane and Related Diamondoid Molecules. Computer Assisted Graphical Analyses of Rearrangement Mechanisms written by Tamara Mladineo Gund and published by . This book was released on 1977 with total page 608 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Synthesis of Diamantane and Related Diamondoid Molecules by : Tamara Mladineo Gund
Download or read book Synthesis of Diamantane and Related Diamondoid Molecules written by Tamara Mladineo Gund and published by . This book was released on 1974 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt:
Download or read book Diamondoids written by Sven Stauss and published by CRC Press. This book was released on 2017-03-16 with total page 258 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past few decades, carbon nanomaterials, most commonly fullerenes, carbon nanotubes, and graphene, have gained increasing interest in both science and industry, due to their advantageous properties that make them attractive for many applications in nanotechnology. Another class of the carbon nanomaterials family that has slowly been gaining (re)newed interest is diamond molecules, also called diamondoids, which consist of polycyclic carbon cages that can be superimposed on a cubic diamond lattice. Derivatives of diamondoids are used in pharmaceutics, but due to their promising properties—well-defined structures, high thermal and chemical stability, negative electron affinity, and the possibility to tune their bandgap—diamondoids could also serve as molecular building blocks in future nanodevices. This book is the first of its kind to give an exhaustive overview of the structures, properties, and current and possible future applications of diamondoids. It contains a brief historical account of diamondoids, from the discovery of the first diamondoid member, adamantane, to the isolation of higher diamondoids about a decade ago. It summarizes the different approaches to synthesizing diamondoids. In particular, current research on the conventional organic synthesis and new approaches based on microplasmas generated in high-pressure and supercritical fluids are reviewed and the advantages and disadvantages of the different methods discussed. The book will serve as a reference for advanced undergraduate- and graduate-level students in chemistry, physics, materials science, and nanotechnology and researchers in macromolecular science, nanotechnology, chemistry, biology, and medicine, especially those with an interest in nanoparticles.
Book Synopsis Diamondoid Molecules: With Applications In Biomedicine, Materials Science, Nanotechnology & Petroleum Science by : G Ali Mansoori
Download or read book Diamondoid Molecules: With Applications In Biomedicine, Materials Science, Nanotechnology & Petroleum Science written by G Ali Mansoori and published by World Scientific. This book was released on 2012-09-06 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diamondoids are cage-like, ultra stable, saturated ringed hydrocarbons, which have a diamond-like structure consisting of a number of six-member carbon rings fused together. Adamantane is the cage compound prototype and the simplest diamondoid molecule. Diamondoids Molecules aims to present these fascinating substances in a novel fashion. The more intriguing facets of diamondoid molecules are comprehensively exposed and discussed, bringing state-of-the-art information to the reader, along with the history, fundamentals and perspectives of diamondoid science and technology.This groundbreaking book, especially devoted to diamondoid molecules, is of critical importance to the global techno-scientific community, and will be of great interest in many research fields such as chemistry, physics, material science, geology, and biological sciences. Moreover, it will attract readers from industrial, government and environmental agencies as well as scholars.
Book Synopsis The Chemistry of Diamondoids by : Peter R. Schreiner
Download or read book The Chemistry of Diamondoids written by Peter R. Schreiner and published by John Wiley & Sons. This book was released on 2024-06-17 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Diamondoids Comprehensive resource on an important and fascinating compound class, covering synthesis, properties, functionalization, and applications in organic synthesis, materials science, and more The Chemistry of Diamondoids gives a state-of-the-art overview of all aspects of diamondoid chemistry, covering nomenclature, natural occurrence, chemical and physical properties, along with synthesis and functionalization of diamondoids as well as their applications as molecular building blocks in organic synthesis, polymer and materials science, nanotechnology, and medicinal chemistry. The book concludes with a perspective towards future developments in the field, thereby drawing attention to areas open for discovery. Written by experts in the field, The Chemistry of Diamondoids includes information on: Naturally occurring diamondoids, their formation, and the role they play in the petroleum industry and in geosciences, plus man-made approaches to prepare them on large scale Growing diamond from diamondoids via seeding, preparation and properties of diamondoid oligomers and doped diamondoids C–H-bond functionalization, a precondition for their use in many applications, and fine-tuning of diamondoid properties by precise cage substitution reactions With its all-encompassing approach, The Chemistry of Diamondoids is a valuable guide for newcomers and researchers in organic chemistry and materials science interested in modern synthetic methods and organic functional materials.
Book Synopsis Diamondoid Molecules by : G. Ali Mansoori
Download or read book Diamondoid Molecules written by G. Ali Mansoori and published by World Scientific. This book was released on 2012 with total page 423 pages. Available in PDF, EPUB and Kindle. Book excerpt: Diamondoids are cage-like, ultra stable, saturated ringed hydrocarbons, which have a diamond-like structure consisting of a number of six-member carbon rings fused together. Adamantane is the cage compound prototype and the simplest diamondoid molecule. Diamondoids Molecules aims to present these fascinating substances in a novel fashion. The more intriguing facets of diamondoid molecules are comprehensively exposed and discussed, bringing state-of-the-art information to the reader, along with the history, fundamentals and perspectives of diamondoid science and technology. This groundbreaking book, especially devoted to diamondoid molecules, is of critical importance to the global techno-scientific community, and will be of great interest in many research fields such as chemistry, physics, material science, geology, and biological sciences. Moreover, it will attract readers from industrial, government and environmental agencies as well as scholars.
Book Synopsis Molecular Diamonds Enabled Synthesis and Growth by : Hitoshi Ishiwata
Download or read book Molecular Diamonds Enabled Synthesis and Growth written by Hitoshi Ishiwata and published by . This book was released on 2015 with total page pages. Available in PDF, EPUB and Kindle. Book excerpt: Diamond has amazing bulk properties including extreme hardness, the highest thermal conductivity of any solid and high refractive index. Furthermore, wide band gap with the possibility of doping offer potential for power electronics. Hydrogen-terminated diamond surface exhibits negative electron affinity (NEA), which enables its use as a cathode for energy conversion or for electron emission devices. Recent developments in diamond research have focused on diamond nanoparticles which have shown a wide range of new applications including quantum computing, drug delivery, biomarkers and biosensors. Molecular diamonds, also known as "diamondoids" are the smallest possible forms of hydrogen-terminated diamond. The smallest diamondoid is an adamantane which consists of a single diamond cage composed of ten carbons terminated with hydrogen at the surface. Diamondoids offers a unique research platform in which diamond and diamond-surface properties can be explored at the molecular level. Fundamental properties of diamondoids, such as photoluminescence of the solid and gas phases, dielectric constants, ionization potentials, band structure etc. have been discussed in previous published papers. This thesis focuses primarily on three topics: 1) The use of diamondoid monolayers to obtain 10nm resolution on X-ray Photoemission Electron Microscope (XPEEM) images. 2) Identification of critical nucleation size for CVD diamond nucleation using diamondoid seeds of various sizes and shapes. 3) Symmetrical structure offered by SiV- color center was used for production of photonic nanocrystal structure with SiV- center to obtain identical emission spectrum. The first part of this thesis discusses applications of diamondoids for X-ray imaging. X-ray Photoemission Electron Microscope (XPEEM) is extremely useful for obtaining chemical and magnetic images. Typical XPEEM resolution is limited due the wide range of electron energies emitted from the target. To overcome this limitation, expensive focusing apparatus are generally necessary for best resolution. Taking advantage of the monochromatic nature of electrons photo-emitted through a diamondoid monolayer (FWHM of 0.3eV), we were able to overcome XPEEM resolution limitations by simply coating sample with a diamondoid monolayer. Using this technique, we were able to obtain the 10nm resolution XPEEM image. We found diamondoid monolayers minimized chromatic aberration by a factor of 10 and increased contrast by a factor of two for samples ranging from 100nm to 10nm. We achieved this resolution by simply dipping the sample in a solution containing diamondoids with functional groups (linkers) designed to form Self Assembled Monolayers on the sample surface. The second part of this thesis describes use of diamondoid seeds of various sizes and shapes can lead to a better understanding of the critical nucleation size of diamond nanoparticles in CVD diamond growth. By comparing diamond growth from various pure seeds including diamantane of different chemical funcationalization configuration, two different tetramantane isomers and two pentamantane isomers, a critical nucleation size at sub 1nm, smaller than previously thought, was determined. Critical nucleation size was determined by an exponential increase in nucleation rate as thermal activation is no longer required for a post-critical size particle. In addition, this study found the critical nuclei depend on both size and structure of the molecule. The third topic of this thesis revolves around the development of a bottom-up method for growing diamond nanoparticles with Silicon-Vacancy (SiV)- color centers. SiV- centers have emerged as promising candidates for quantum information processing applications and possibly as biosensors. The inversion symmetry of SiV- centers provide superior spectral stability and narrow inhomogeneous broadening with linewidths of a few nanometers and nearly transform-limited linewidths at low temperature. We demonstrate stability of SiV- color center by forming nanophotonic crystal structure on SiV film and SiC using diamondoids as seeds for diamond nucleation. The resulting nanopillars contain high quality SiV- centers with very narrow linewidths and very low inhomogeneous broadening, thereby enabling implementation of quantum photonic devices containing identical quantum emitters, as needed for quantum simulations and quantum network.
Book Synopsis Molecular Building Blocks for Nanotechnology by : G.Ali Mansoori
Download or read book Molecular Building Blocks for Nanotechnology written by G.Ali Mansoori and published by Springer Science & Business Media. This book was released on 2007-09-14 with total page 439 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book takes a "bottom-up" approach, beginning with atoms and molecules – molecular building blocks – and assembling them to build nanostructured materials. Coverage includes Carbon Nanotubes, Nanowires, and Diamondoids. The applications presented here will enable practitioners to design and build nanometer-scale systems. These concepts have far-reaching implications: from mechanical to chemical processes, from electronic components to ultra-fine sensors, from medicine to energy, and from pharmaceuticals to agriculture and food.
Book Synopsis Diamond and Related Nanostructures by : Mircea Vasile Diudea
Download or read book Diamond and Related Nanostructures written by Mircea Vasile Diudea and published by Springer Science & Business Media. This book was released on 2013-05-28 with total page 395 pages. Available in PDF, EPUB and Kindle. Book excerpt: Over the past twenty years, the field of carbon structures has been invigorated by the discovery of fullerenes and carbon nanotubes. These nano-structured carbons have attracted a tremendous interest in the fundamental properties of discrete carbon molecules, leading to the discovery of novel complex crystalline and quasi-crystalline materials. As a consequence, a variety of applications have been developed, including technical and bio-medical materials and miniaturized tools. Diamond and Related Nanostructures focuses on the advances in the area of diamond-like carbon nanostructures (hyper-structures built from fullerenes and/or carbon nanotube junctions) and other related carbon nanostructures. Each chapter contributes to the topic from different fields, ranging from theory to synthesis and properties investigation of these new materials. This volume brings together the major findings in the field and provides a source of inspiration and understanding to advanced undergraduates, graduates, and researchers in the fields of Physics, Graph Theory, Crystallography, Computational and Synthetic Chemistry.
Book Synopsis The Chemistry of Diamondoids by : Andrey A. Fokin
Download or read book The Chemistry of Diamondoids written by Andrey A. Fokin and published by John Wiley & Sons. This book was released on 2024-04-17 with total page 373 pages. Available in PDF, EPUB and Kindle. Book excerpt: The Chemistry of Diamondoids Comprehensive resource on an important and fascinating compound class, covering synthesis, properties, functionalization, and applications in organic synthesis, materials science, and more The Chemistry of Diamondoids gives a state-of-the-art overview of all aspects of diamondoid chemistry, covering nomenclature, natural occurrence, chemical and physical properties, along with synthesis and functionalization of diamondoids as well as their applications as molecular building blocks in organic synthesis, polymer and materials science, nanotechnology, and medicinal chemistry. The book concludes with a perspective towards future developments in the field, thereby drawing attention to areas open for discovery. Written by experts in the field, The Chemistry of Diamondoids includes information on: Naturally occurring diamondoids, their formation, and the role they play in the petroleum industry and in geosciences, plus man-made approaches to prepare them on large scale Growing diamond from diamondoids via seeding, preparation and properties of diamondoid oligomers and doped diamondoids C–H-bond functionalization, a precondition for their use in many applications, and fine-tuning of diamondoid properties by precise cage substitution reactions With its all-encompassing approach, The Chemistry of Diamondoids is a valuable guide for newcomers and researchers in organic chemistry and materials science interested in modern synthetic methods and organic functional materials.
Book Synopsis Advances in Chemical Physics, Volume 136 by : Stuart A. Rice
Download or read book Advances in Chemical Physics, Volume 136 written by Stuart A. Rice and published by John Wiley & Sons. This book was released on 2008-04-30 with total page 332 pages. Available in PDF, EPUB and Kindle. Book excerpt: Advances in Chemical Physics is the only series of references available that explores the cutting edge of research in chemical physics. This series provides the chemical physics field with a forum for critical, authoritative evaluations of advances in every area of the discipline.
Book Synopsis Strategies and Tactics in Organic Synthesis by : Michael Harmata
Download or read book Strategies and Tactics in Organic Synthesis written by Michael Harmata and published by Academic Press. This book was released on 2012 with total page 456 pages. Available in PDF, EPUB and Kindle. Book excerpt: A classic in the area of organic synthesis, Strategies and Tactics in Organic Synthesis provides a forum for investigators to discuss their approach to the science and art of organic synthesis. Rather than a simple presentation of data or a second-hand analysis, this book vividly demonstrates through first hand accounts how synthesis is really done and how by discovering new reactions, creating new designs and building molecules with atom and step economies, the advancement of the science of organic synthesis is providing solutions through function to create a better world. Presents state-of-the-art developments in organic synthesisProvides insight and offers new perspective to problem-solvingWritten by leading experts in the field.
Book Synopsis Index to American Doctoral Dissertations by :
Download or read book Index to American Doctoral Dissertations written by and published by . This book was released on 1974 with total page 640 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Book Synopsis Principles Of Nanotechnology: Molecular Based Study Of Condensed Matter In Small Systems by : Mansoori G Ali
Download or read book Principles Of Nanotechnology: Molecular Based Study Of Condensed Matter In Small Systems written by Mansoori G Ali and published by World Scientific Publishing Company. This book was released on 2005-03-03 with total page 360 pages. Available in PDF, EPUB and Kindle. Book excerpt: This invaluable book provides a pointed introduction to the fascinating subject of bottom-up nanotechnology with emphasis on the molecular-based study of condensed matter in small systems. Nanotechnology has its roots in the landmark lecture delivered by the famous Nobel Laureate physicist, Richard Feynman, on 29 December 1959 entitled “There's Plenty of Room at the Bottom.” By the mid-1980s, it had gained real momentum with the invention of scanning probe microscopes. Today, nanotechnology promises to have a revolutionary impact on the way things are designed and manufactured in the future.Principles of Nanotechnology is self-contained and unified in presentation. It may be used as a textbook by graduate students and even ambitious undergraduates in engineering, and the biological and physical sciences who already have some familiarity with quantum and statistical mechanics. It is also suitable for experts in related fields who require an overview of the fundamental topics in nanotechnology. The explanations in the book are detailed enough to capture the interest of the curious reader, and complete enough to provide the necessary background material needed to go further into the subject and explore the research literature. Due to the interdisciplinary nature of nanotechnology, a comprehensive glossary is included detailing abbreviations, chemical formulae, concepts, definitions, equations and theories.
Book Synopsis Graphene, Carbon Nanotubes, and Nanostructures by : James E. Morris
Download or read book Graphene, Carbon Nanotubes, and Nanostructures written by James E. Morris and published by CRC Press. This book was released on 2017-07-28 with total page 364 pages. Available in PDF, EPUB and Kindle. Book excerpt: Graphene, Carbon Nanotubes, and Nanostructures: Techniques and Applications offers a comprehensive review of groundbreaking research in nanofabrication technology and explores myriad applications that this technology has enabled. The book examines the historical evolution and emerging trends of nanofabrication and supplies an analytical understanding of some of the most important underlying nanofabrication technologies, with an emphasis on graphene, carbon nanotubes (CNTs), and nanowires. Featuring contributions by experts from academia and industry around the world, this book presents cutting-edge nanofabrication research in a wide range of areas. Topics include: CNT electrodynamics and signal propagation models Electronic structure calculations of a graphene–hexagonal boron nitride interface to aid the understanding of experimental devices based on these heterostructures How a laser field would modify the electronic structure and transport response of graphene, to generate bandgaps The fabrication of transparent CNT electrodes for organic light-emitting diodes Direct graphene growth on dielectric substrates, and potential applications in electronic and spintronic devices CNTs as a promising candidate for next-generation interconnect conductors CMOS–CNT integration approaches, including the promising localized heating CNT synthesis method CNTs in electrochemical and optical biosensors The synthesis of diamondoids by pulsed laser ablation plasmas generated in supercritical fluids, and possible applications The use of DNA nanostructures in lithography CMOS-compatible silicon nanowire biosensors The use of titanium oxide-B nanowires to detect explosive vapors The properties of protective layers on silver nanoparticles for ink-jet printing Nanostructured thin-film production using microreactors A one-stop reference for professionals, researchers, and graduate students working in nanofabrication, this book will also be useful for investors who want an overview of the current nanofabrication landscape.
Book Synopsis Synthesis, Properties and Applications of Ultrananocrystalline Diamond by : Dieter M. Gruen
Download or read book Synthesis, Properties and Applications of Ultrananocrystalline Diamond written by Dieter M. Gruen and published by Springer Science & Business Media. This book was released on 2006-03-30 with total page 410 pages. Available in PDF, EPUB and Kindle. Book excerpt: We are pleased to present the Proceedings of the NATO Advanced Research Workshop “Syntheses, Properties and Applications of Ultrananocrystalline Diamond” which was held June 7-10, 2004 in St. Petersburg, Russia. The main goal of the Workshop was to provide a forum for the intensive exchange of opinions between scientists from Russia and NATO countries in order to give additional impetus to the development of the science and applications of a new carbon nanostructure, called ultrananocrystalline diamond (UNCD) composed of 2-5 nm crystallites. There are two forms of UNCD, dispersed particles and films. The two communities of researchers working on these two forms of UNCD have hitherto lacked a common forum in which to explore areas of scientific and technological overlap. As a consequence, the two fields have up to now developed independently of each other. The time had clearly come to remedy this situation in order to be able to take full advantage of the enormous potential for societal benefits to be derived from exploiting the synergistic relationships between UNCD dispersed particulates and UNCD films. The NATO sponsored ARW therefore occurred in a very timely manner and was successful in beginning the desired dialogue, a precondition for making progress toward the above stated goal. The discovery of UNCD completes a triadof nanostructured carbonswhich includes fullerenes and nanotubes.
Book Synopsis Fluorescent Nanodiamonds by : Huan-Cheng Chang
Download or read book Fluorescent Nanodiamonds written by Huan-Cheng Chang and published by John Wiley & Sons. This book was released on 2018-09-12 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt: The most comprehensive reference on fluorescent nanodiamond physical and chemical properties and contemporary applications Fluorescent nanodiamonds (FNDs) have drawn a great deal of attention over the past several years, and their applications and development potential are proving to be manifold and vast. The first and only book of its kind, Fluorescent Nanodiamonds is a comprehensive guide to the basic science and technical information needed to fully understand the fundamentals of FNDs and their potential applications across an array of domains. In demonstrating the importance of FNDs in biological applications, the authors bring together all relevant chemistry, physics, materials science and biology. Nanodiamonds are produced by powerful cataclysmic events such as explosions, volcanic eruptions and meteorite impacts. They also can be created in the lab by high-pressure high-temperature treatment of graphite or detonating an explosive in a reactor vessel. A single imperfection can give a nanodiamond a specific, isolated color center which allows it to function as a single, trapped atom. Much smaller than the thickness of a human hair, a nanodiamond can have a huge surface area that allows it to bond with a variety of other materials. Because of their non-toxicity, nanodiamonds may be useful in biomedical applications, such as drug delivery and gene therapy. The most comprehensive reference on a topic of rapidly increasing interest among academic and industrial researchers across an array of fields Includes numerous case studies and practical examples from many areas of research and industrial applications, as well as fascinating and instructive historical perspectives Each chapter addresses, in-depth, a single integral topic including the fundamental properties, synthesis, mechanisms and functionalisation of FNDs The first book published by the key patent holder with his research group in the field of FNDs Fluorescent Nanodiamonds is an important working resource for a broad range of scientists and engineers in industry and academia. It will also be a welcome reference for instructors in chemistry, physics, materials science, biology and related fields.
