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Author : Jeremy R. Zink
Publisher :
ISBN 13 :
Total Pages : 0 pages
Book Rating : 4.:/5 (137 download)
Download or read book Synthesis and Redox Behavior of Ruthenium Nitrosyl Porphyrin Complexes written by Jeremy R. Zink and published by . This book was released on 2022 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Bryan Drew Smith
Publisher :
ISBN 13 :
Total Pages : 190 pages
Book Rating : 4.:/5 (387 download)
Download or read book Synthesis and Reactivity of Ruthenium Porphyrin Complexes Containing a Nitrosyl Or Thionitrosyl Ligand written by Bryan Drew Smith and published by . This book was released on 1997 with total page 190 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Krishna P. Sharmah Gautam
Publisher :
ISBN 13 :
Total Pages : 128 pages
Book Rating : 4.:/5 (798 download)
Download or read book Redox Studies of Ruthenium Porphyrin Nitrosyl Complexes written by Krishna P. Sharmah Gautam and published by . This book was released on 2011 with total page 128 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Anthony Sauve
Publisher :
ISBN 13 :
Total Pages : 620 pages
Book Rating : 4.:/5 (36 download)
Download or read book Synthesis, Characterization, and Oxidation and Desulfurization Reactivity of Ruthenium Nitrosyl Complexes of Salens and Porphyrins written by Anthony Sauve and published by . This book was released on 1997 with total page 620 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : 鄧天祐
Publisher : Open Dissertation Press
ISBN 13 : 9781374773745
Total Pages : 264 pages
Book Rating : 4.7/5 (737 download)
Download or read book SYNTHESIS & REDOX BEHAVIOUR OF written by 鄧天祐 and published by Open Dissertation Press. This book was released on 2017-01-27 with total page 264 pages. Available in PDF, EPUB and Kindle. Book excerpt: This dissertation, "Synthesis and Redox Behaviour of Some Tetramine Complexes of Ruthenium III and Iridium III" by 鄧天祐, Tin-wu, Tang, was obtained from The University of Hong Kong (Pokfulam, Hong Kong) and is being sold pursuant to Creative Commons: Attribution 3.0 Hong Kong License. The content of this dissertation has not been altered in any way. We have altered the formatting in order to facilitate the ease of printing and reading of the dissertation. All rights not granted by the above license are retained by the author. DOI: 10.5353/th_b3122999 Subjects: Ruthenium III amine Iridium III amine Organic compounds - Synthesis Oxidation-reduction reaction
Author : Dennis Awasabisah
Publisher :
ISBN 13 :
Total Pages : 550 pages
Book Rating : 4.:/5 (92 download)
Download or read book Synthesis and Redox Behavior of Group 8 Metalloporphyrins and Related Compounds written by Dennis Awasabisah and published by . This book was released on 2015 with total page 550 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : James Michael Garner
Publisher :
ISBN 13 :
Total Pages : 374 pages
Book Rating : 4.F/5 ( download)
Download or read book The Chemistry of Rhenium and Tungsten Porphyrin Complexes in Low Oxidation States ; Synthesis and Characterization of Rhenium and Tungsten Porphyrin Dimers Containing Metal-metal Multiple Bonds written by James Michael Garner and published by . This book was released on 1989 with total page 374 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Ajay Kumar Mishra
Publisher : CRC Press
ISBN 13 : 1351616498
Total Pages : 260 pages
Book Rating : 4.3/5 (516 download)
Download or read book Ruthenium Chemistry written by Ajay Kumar Mishra and published by CRC Press. This book was released on 2018-01-17 with total page 260 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book will describe Ruthenium complexes as chemotherapeutic agent specifically at tumor site. It has been the most challenging task in the area of cancer therapy. Nanoparticles are now emerging as the most effective alternative to traditional chemotherapeutic approach. Nanoparticles have been shown to be useful in this respect. However, in view of organ system complicacies, instead of using nanoparticles as a delivery tool, it will be more appropriate to synthesize a drug of nanoparticle size that can use blood transport mechanism to reach the tumor site and regress cancer. Due to less toxicity and effective bio-distribution, ruthenium (Ru) complexes are of much current interest. Additionally, lumiscent Ru-complexes can be synthesized in nanoparticle size and can be directly traced at tissue level. The book will contain the synthesis, characterization, and applications of various Ruthenium complexes as chemotherapeutic agents. The book will also cover the introduction to chemotherapy, classification of Ru- complexes with respect to their oxidation states and geometry, Ruthenium complexes of nano size: shape and binding- selectivity, binding of ruthenium complexes with DNA, DNA cleavage studies and cytotoxicity. The present book will be more beneficial to researchers, scientists and biomedical. Current book will empower specially to younger generation to create a new world of ruthenium chemistry in material science as well as in medicines. This book will be also beneficial to national/international research laboratories, and academia with interest in the area of coordination chemistry more especially to the Ruthenium compounds and its applications.
Author : Karl M Kadish
Publisher : World Scientific
ISBN 13 : 9811267634
Total Pages : 645 pages
Book Rating : 4.8/5 (112 download)
Download or read book Electrochemistry Of Metalloporphyrins written by Karl M Kadish and published by World Scientific. This book was released on 2023-06-22 with total page 645 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book is part of a series of ongoing volumes in the Series on Chemistry, Energy and the Environment, edited by Karl Kadish and Roger Guilard. The current volume on Electrochemistry of Metalloporphyrins covers all aspects of porphyrin electrochemistry in nonaqueous media and should be of benefit and interest to beginning graduate students as well as experienced researchers in many fields of porphyrin chemistry where electrochemistry is known to play a key role in influencing properties of the compounds as well as mechanisms and biological functions. The first half of the book is aimed at non-experts in the field of electrochemistry who would like to begin studies on porphyrin electrochemistry or understand the literature on porphyrin electrochemistry and this is then followed by detailed examples of how changes in the central metal ion of a given metalloporphyrin will affect its redox properties. The scope of the work covers the period in the literature between the mid-1960s and mid-2022 and expands greatly upon several earlier reviews by the senior author which are no longer in print and were never accessible in electronic form. This is the only book of its kind in the field which covers the basic electrochemistry of metalloporphyrins as well as describes the published data as a function of the central metal ion, considering all elements in the periodic table.
Author : Yan Huang
Publisher :
ISBN 13 :
Total Pages : 160 pages
Book Rating : 4.:/5 (671 download)
Download or read book Synthesis, Kinetic and Photocatalytic Studies of Porphyrin-ruthenium-oxo Complexes written by Yan Huang and published by . This book was released on 2008 with total page 160 pages. Available in PDF, EPUB and Kindle. Book excerpt: Macrocyclic ligand-complexed transition metal-oxo intermediates are the active oxidizing species in a variety of important biological and catalytic oxidation reactions. Many transition metal catalysts have been designed to mimic the predominant oxidation catalysts in Nature, namely the cytochrome P450 enzymes. Ruthenium porphyrin complexes have been the center of the research and have successfully been utilized, as catalysts, in major oxidation reactions such as the hydroxylation of alkanes. This study focuses on kinetic and photocatalytic studies of oxidation reactions with wellcharacterized high-valent ruthenium-oxo porphyrin complexes. The trans-dioxoruthenium(VI) porphyrins have been among the best characterized metal-oxo intermediates and their involvement as the active oxidant in the hydrocarbon oxidation have been extensively studied. Following the literature known methods, a series of trans-dioxoruthenium(VI) porphyrin complexes (3a-b) were synthesized and spectroscopically characterized by UV-vis, IR and lH-NMR. In addition to the well-known chemical methods, we developed a novel photochemical approach for generation of trans-dioxoruthenium(VI) porphyrins with visible light. The fast kinetic study of two-electron oxidations of para-substituted phenyl methyl sulfides by these dioxoruthenium(VI) species was conducted by using stopped-flow spectroscopy. Results showed that the decay of trans--dioxoruthenium(VI) porphyrins in the presence of reactive sulfides follows a biexponential process. The reactivity order in the series of dioxoruthenium complexes follows TPFPP> TPP> TMP, consistent with expectations based on the electrophilic nature of high-valent metal-oxo species. Moreover, the sulfoxidation reactions are 3 to 4 orders of magnitude faster than the well-known epoxidation reactions. In addition, several ruthenium porphyrins were used as the catalysts in the competitive oxidation reactions to identify the kinetically competent oxidants during catalytic turnover conditions.
Author : Lina K. Blusch
Publisher : Springer
ISBN 13 : 9783319343655
Total Pages : 0 pages
Book Rating : 4.3/5 (436 download)
Download or read book The Siamese-Twin Porphyrin and Its Copper and Nickel Complexes: A Non-Innocent Twist written by Lina K. Blusch and published by Springer. This book was released on 2016-08-23 with total page 0 pages. Available in PDF, EPUB and Kindle. Book excerpt: This thesis describes the first and long-sought successful synthesis of a new pyrazole-expanded porphyrin, a higher analog of porphyrin. This "Siamese-Twin Porphyrin" provides two conjoined porphyrin-like coordination spheres, thus being able to accommodate two metal ions within the same ligand. In her thesis, Lina Blusch not only explains the challenging synthesis and characterization of the ligand system, but also its application to the synthesis of homo- and hetero-bimetallic Ni and Cu complexes. She observes interesting metal-metal-interactions in the complexes, that lead to a non-innocent multistep redox chemistry. The ligand system and its complexes show an intriguing twisted geometry, giving rise to helical chirality and other fascinating properties. This study explores the first steps and opens up a new chemistry of expanded porphyrins with the potential to biomimetic applications.
Author :
Publisher :
ISBN 13 :
Total Pages : 924 pages
Book Rating : 4.F/5 ( download)
Download or read book Dissertation Abstracts International written by and published by . This book was released on 2007 with total page 924 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Hoi Ki Kwong
Publisher :
ISBN 13 :
Total Pages : 296 pages
Book Rating : 4.:/5 (237 download)
Download or read book Synthesis and Characterization of Ruthenium Complexes as Redox Mediators of Biosensors written by Hoi Ki Kwong and published by . This book was released on 2008 with total page 296 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : Rachel A. Harris
Publisher :
ISBN 13 :
Total Pages : 68 pages
Book Rating : 4.:/5 (768 download)
Download or read book Spectrophotometric Studies of Ruthenium Porphyrin Nitrosyl Complexes in Buffered DMSO Solutions written by Rachel A. Harris and published by . This book was released on 2011 with total page 68 pages. Available in PDF, EPUB and Kindle. Book excerpt:
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Author : Mingzhe Ke
Publisher : National Library of Canada
ISBN 13 :
Total Pages : 444 pages
Book Rating : 4.:/5 (28 download)
Download or read book Synthesis, Characterization and Reactivity of Ruthenium Porphyrin Complexes Containing Metal-carbon Bonds [microform] written by Mingzhe Ke and published by National Library of Canada. This book was released on 1988 with total page 444 pages. Available in PDF, EPUB and Kindle. Book excerpt:
Author : George B. Richter-Addo
Publisher : Oxford University Press, USA
ISBN 13 : 9780195067934
Total Pages : 369 pages
Book Rating : 4.0/5 (679 download)
Download or read book Metal Nitrosyls written by George B. Richter-Addo and published by Oxford University Press, USA. This book was released on 1992 with total page 369 pages. Available in PDF, EPUB and Kindle. Book excerpt: This book covers all aspects of metal-nitric oxide chemistry. Topics range from descriptions of the metal-NO bond to their chemical reactions and environmental significance. Treated in detail are coordination and organometallic nitrosyl complexes, interactions of nitric oxide with surfaces, metal nitrosyl clusters and the biosynthesis, biotransformation, and bioinorganic chemistry of nitric oxide. The book includes an examination of all known classes of reactions of metal nitrosyls. The roles of nitric and nitrous oxides in environmental chemistry are outlined in the closing chapter. This book will be of interest to students and researchers in the fields of inorganic, organometallic, and bioinorganic chemistry.
Author : Karl Kadish
Publisher : Elsevier
ISBN 13 : 9780123932037
Total Pages : 472 pages
Book Rating : 4.9/5 (32 download)
Download or read book The Porphyrin Handbook, Volume 3 written by Karl Kadish and published by Elsevier. This book was released on 2000 with total page 472 pages. Available in PDF, EPUB and Kindle. Book excerpt: Scientists in such fields as mathematics, physics, chemistry, biochemistry, biology, and medicine are currently involved in investigations of porphyrins and their numerous analogues and derivatives. Porphyrins are being used as platforms for the study of theoretical principles, as catalysts, as drugs, as electronic devices, and as spectroscopic probes in biology and medicine. The need for an up-to-date and authoritative treatise on the porphyrin system has met with universal acclaim amongst scientists and investigators.
