Author : Anthony Joseph Pasquale
Publisher :
ISBN 13 :
Total Pages : 206 pages
Book Rating : 4.:/5 (48 download)
Book Synopsis Synthesis and Characterization of Soluble Poly(p-phenylene) Derivatives Made Via Ni(0)-catalyzed Coupling of Aromatic Dichlorides by : Anthony Joseph Pasquale
Download or read book Synthesis and Characterization of Soluble Poly(p-phenylene) Derivatives Made Via Ni(0)-catalyzed Coupling of Aromatic Dichlorides written by Anthony Joseph Pasquale and published by . This book was released on 1998 with total page 206 pages. Available in PDF, EPUB and Kindle. Book excerpt: The synthesis and characterization of new aromatic dichloride monomers containing benzoyl and phenylsulfonyl pendant groups and the corresponding polymers made via Ni(O)-catalyzed coupling polymerization are described. This work is an outgrowth of the previously described synthesis of poly(benzoyl-1,4-phenylene) from the Ni(O)-catalyzed coupling polymerization of 2,5-dichlorobenzophenone. The new monomers containing benzoyl pendant groups were synthesized by the Friedel-Crafts reaction of 2,5-dichlorobenzoyl chloride and substituted benzenes to give structures that were substituted at the para position on the pendant benzene ring. The substituents include fluorine, methyl, ethyl, and isopropyl.